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2001Dzubiella J; Jusufi A; Likos C N; von Ferber C; Löwen H; Stellbrink J; Allgaier J; Richter D; Schofield A B; Smith P A; Poon W C; Pusey P N
Phase separation in star-polymer-colloid mixtures.
Physical review. E, Statistical, nonlinear, and soft matter physics 2001;64(1 Pt 1):010401.
We examine the demixing transition in star-polymer-colloid mixtures for star arm numbers f=2,6,16,32 and different star-polymer-colloid size ratios 0.18< or =q< or =0.50. Theoretically, we solve the thermodynamically self-consistent Rogers-Young integral equations for binary mixtures using three effective pair potentials obtained from direct molecular computer simulations. The numerical results show a spinodal instability. The demixing binodals are approximately calculated and found to be consistent with experimental observations.

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