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2005:
Harding Wayne W; Tidgewell Kevin; Schmidt Matthew; Shah Kushal; Dersch Christina M; Snyder John; Parrish Damon; Deschamps Jeffrey R; Rothman Richard B; Prisinzano Thomas E
Salvinicins A and B, new neoclerodane diterpenes from Salvia divinorum.
Organic letters 2005;
7(
14):.
[reaction: see text] Two new neoclerodane diterpenes, salvinicins A (4) and B (5), were isolated from the dried leaves of Salvia divinorum. The structures of these compounds were elucidated by spectroscopic techniques, including (1)H and (13)C NMR, NOESY, HMQC, and HMBC. The absolute stereochemistry of these compounds was assigned on the basis of single-crystal X-ray crystallographic analysis of salvinicin A (4) and a 3,4-dichlorobenzoate derivative of salvinorin B.
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