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2007:
Mari Silvia; Sánchez-Medina Inmaculada; Mereghetti Pierangelo; Belvisi Laura; Jiménez-Barbero Jesus; Bernardi Anna
Synthesis and conformational analysis of an alpha-D-mannopyranosyl-(1-->2)-alpha-D-mannopyranosyl-(1-->6)-alpha-D-mannopyranose mimic.
Carbohydrate research 2007;
342(
12-13):.
A mimic of a (1-->2),(1-->6)-mannotrioside was synthesized by replacing the central mannose unit with an enantiomerically pure, conformationally stable trans-diaxial cyclohexanediol. The three-dimensional structure of the molecule was investigated by NMR spectroscopy supported by molecular modelling and was compared to the known features of the natural mannotrioside.
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