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2007:
Sardinha João; Guieu Samuel; Deleuze Aurélie; Fernández-Alonso M Carmen; Rauter Amelia Pilar; Sinaÿ Pierre; Marrot Jérôme; Jiménez-Barbero Jesús; Sollogoub Matthieu
gem-Difluoro-carbasugars, the cases of mannopyranose and galactopyranose.
Carbohydrate research 2007;
342(
12-13):.
5a-Difluoro-5a-carbamannopyranose (gem-difluoro-carbamannopyranose) and 5a-difluoro-5a-carbagalactopyranose (gem-difluoro-carbagalactopyranose), close congeners of their respective natural sugars, in which the endocyclic oxygen atom has been replaced by a gem-difluoromethylene group, were synthesized from D-mannose and D-galactose, using a rearrangement strategy.
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