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Francisco Palacios

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Francisco Palacios; Ana María Ochoa De Retana; Ander Vélez del Burgo
Selective synthesis of substituted pyrrole-2-phosphine oxides and -phosphonates from 2H-azirines and enolates from acetyl acetates and malonates.
Jesús M de los Santos; Roberto Ignacio; Domitila Aparicio; Gloria Rubiales; Francisco Palacios
Hetero-Diels-Alder reaction of phosphinyl and phosphonyl nitroso alkenes with conjugated dienes: an aza-Cope rearrangement.
Francisco Palacios; Tomasz K Olszewski; Jose L Vicario
Diastereoselective hydrophosphonylation of imines using (R,R)-TADDOL phosphite. Asymmetric synthesis of alpha-aminophosphonic acid derivatives.

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All Publications

2011: Francisco Palacios; Ana María Ochoa De Retana; Ander Vélez del Burgo
Selective synthesis of substituted pyrrole-2-phosphine oxides and -phosphonates from 2H-azirines and enolates from acetyl acetates and malonates.
The Journal of organic chemistry 2011;76(22):9472-7.
2011: Jesús M de los Santos; Roberto Ignacio; Domitila Aparicio; Gloria Rubiales; Francisco Palacios
Hetero-Diels-Alder reaction of phosphinyl and phosphonyl nitroso alkenes with conjugated dienes: an aza-Cope rearrangement.
The Journal of organic chemistry 2011;76(16):6715-25.
2010: Francisco Palacios; Tomasz K Olszewski; Jose L Vicario
Diastereoselective hydrophosphonylation of imines using (R,R)-TADDOL phosphite. Asymmetric synthesis of alpha-aminophosphonic acid derivatives.
Organic & biomolecular chemistry 2010;8(19):4255-8.
2009: Jesús M de los Santos; Roberto Ignacio; Domitila Aparicio; Francisco Palacios; José M Ezpeleta
Reactions of conjugate phosphinyl- and phosphonyl-nitroso alkenes with enamines. Preparation of N-hydroxypyrrole derivatives.
The Journal of organic chemistry 2009;74(9):3444-8.
2009: Jose L Vicario; Domitila Aparicio; Francisco Palacios
Conjugate addition of amines to an alpha,beta-unsaturated imine derived from alpha-aminophosphonate. Synthesis of gamma-amino-alpha-dehydroaminophosphonates.
The Journal of organic chemistry 2009;74(1):452-5.
2008: Jesús M de los Santos; Yago López; Domitila Aparicio; Francisco Palacios
A convenient synthesis of substituted pyrazolidines and azaproline derivatives through highly regio- and diastereoselective reduction of 2-pyrazolines.
The Journal of organic chemistry 2008;73(2):550-7.
2007: Jesús M de los Santos; Roberto Ignacio; Domitila Aparicio; Francisco Palacios
Michael addition of amine derivatives to conjugate phosphinyl and phosphonyl nitrosoalkenes. Preparation of alpha-amino phosphine oxide and phosphonate derivatives.
The Journal of organic chemistry 2007;72(14):5202-6.
2007: Francisco Palacios; Javier Vicario; Agnieszka Maliszewska; Domitila Aparicio
Synthesis of alpha-phosphorylated alpha,beta-unsaturated imines and their selective reduction to vinylogous and saturated alpha-aminophosphonates.
The Journal of organic chemistry 2007;72(7):2682-5.
2006: Francisco Palacios; Javier Vicario
Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters.
Organic letters 2006;8(23):5405-8.
2006: Francisco Palacios; Javier Vicario; Domitila Aparicio
Efficient synthesis of 1-azadienes derived from alpha-aminoesters. Regioselective preparation of alpha-dehydroamino acids, vinylglycines, and alpha-amino acids.
The Journal of organic chemistry 2006;71(20):7690-6.
2006: Francisco Palacios; Ana María Ochoa De Retana; José M Alonso
Regioselective synthesis of fluoroalkylated beta-aminophosphorus derivatives and aziridines from phosphorylated oximes and nucleophilic reagents.
The Journal of organic chemistry 2006;71(16):6141-8.
2006: Francisco Palacios; Esther Herran; Concepción Alonso; Gloria Rubiales; Begoña Lecea; Mirari Ayerbe; Fernando P Cossío
Reaction of N-vinylic phosphazenes with alpha,beta-unsaturated aldehydes. Azatriene-mediated synthesis of dihydropyridines and pyridines derived from beta-amino acids.
The Journal of organic chemistry 2006;71(16):6020-30.
2006: Domitila Aparicio; Orazio A Attanasi; Paolino Filippone; Roberto Ignacio; Samuele Lillini; Fabio Mantellini; Francisco Palacios; Jesús M de los Santos
Straightforward access to pyrazines, piperazinones, and quinoxalines by reactions of 1,2-diaza-1,3-butadienes with 1,2-diamines under solution, solvent-free, or solid-phase conditions.
The Journal of organic chemistry 2006;71(16):5897-905.
2006: Fernando P Cossío; Concepción Alonso; Begoña Lecea; Mirari Ayerbe; Gloria Rubiales; Francisco Palacios
Mechanism and stereoselectivity of the aza-Wittig reaction between phosphazenes and aldehydes.
The Journal of organic chemistry 2006;71(7):2839-47.
2005: Francisco Palacios; Ana M Ochoa de Retana; José M Alonso
Reaction of 2H-azirine phosphine oxide and -phosphonates with nucleophiles. Stereoselective Synthesis of functionalized aziridines and alpha- and beta-aminophosphorus derivatives.
The Journal of organic chemistry 2005;70(22):8895-901.
2005: Francisco Palacios; Concepción Alonso; Jesús M de los Santos
Synthesis of beta-aminophosphonates and -phosphinates.
Chemical reviews 2005;105(3):899-931.
2004: Francisco Palacios; Ana María Ochoa De Retana; Sergio Pascual; Julen Oyarzabal
Preparation of fluoroalkyl imines, amines, enamines, ketones, alpha-amino carbonyls, and alpha-amino acids from primary enamine phosphonates.
The Journal of organic chemistry 2004;69(25):8767-74.
2003: Francisco Palacios; Concepción Alonso; Jaione Pagalday; Ana María Ochoa De Retana; Gloria Rubiales
Reaction of acetylenic esters and N-functionalized phosphazenes. 1,2-versus 1,4-addition of N-vinylic phosphazenes.
Organic & biomolecular chemistry 2003;1(7):1112-8.
2002: Francisco Palacios; Domitila Aparicio; Ana María Ochoa De Retana; Jesús M de los Santos; José Ignacio Gil; José M Alonso
Asymmetric synthesis of 2H-azirines derived from phosphine oxides using solid-supported amines. Ring opening of azirines with carboxylic acids.
The Journal of organic chemistry 2002;67(21):7283-8.
2002: Francisco Palacios; Ana María Ochoa De Retana; José Ignacio Gil; Rafael López de Munain
Synthesis of pyrazine-phosphonates and -phosphine oxides from 2H-azirines or oximes.
Organic letters 2002;4(14):2405-8.
2002: Francisco Palacios; Esther Herrán; Gloria Rubiales; Jose María Ezpeleta
Cycloaddition reaction of 2-azadienes derived from beta-amino acids with electron-rich and electron-deficient alkenes and carbonyl compounds. Synthesis of pyridine and 1,3-oxazine derivatives.
The Journal of organic chemistry 2002;67(7):2131-5.
2002: Francisco Palacios; Concepción Alonso; Patricia Amezua; Gloria Rubiales
Synthesis of aza polycyclic compounds derived from pyrrolidine, indolizidine, and indole via intramolecular Diels-Alder cycloadditions of neutral 2-azadienes.
The Journal of organic chemistry 2002;67(6):1941-6.
2002: Francisco Palacios; Sergio Pascual; Julen Oyarzabal; Ana María Ochoa De Retana
Fluoroalkyl alpha,beta-unsaturated imines. Valuable synthetic intermediates from primary fluorinated enamine phosphonates.
Organic letters 2002;4(5):769-72.
2000: Francisco Palacios; Ana María Ochoa De Retana; José Ignacio Gil; J M Ezpeleta
Simple asymmetric synthesis of 2H-azirines derived from phosphine oxides.
The Journal of organic chemistry 2000;65(10):3213-7.