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Robin Perutz

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Christopher D Windle; Marius V Câmpian; Anne-K Duhme-Klair; Elizabeth A Gibson; Robin N Perutz; Jacob Schneider
CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine.
Marius V Câmpian; Robin N Perutz; Barbara Procacci; Robert J Thatcher; Olga Torres; Adrian C Whitwood
Selective photochemistry at stereogenic metal and ligand centers of cis-[Ru(diphosphine)2(H)2]: preparative, NMR, solid state, and laser flash studies.
Jacob Schneider; Xue-Zhong Sun; Khuong Q Vuong; Adrian C Whitwood; James A Calladine; Michael W George; Robin N Perutz
Photochemistry and photophysics of a Pd(II) metalloporphyrin: Re(I) tricarbonyl bipyridine molecular dyad and its activity toward the photoreduction of CO2 to CO.

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All Publications

2012: Christopher D Windle; Marius V Câmpian; Anne-K Duhme-Klair; Elizabeth A Gibson; Robin N Perutz; Jacob Schneider
CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine.
Chemical communications (Cambridge, England) 2012;48(66):8189-91.
2012: Marius V Câmpian; Robin N Perutz; Barbara Procacci; Robert J Thatcher; Olga Torres; Adrian C Whitwood
Selective photochemistry at stereogenic metal and ligand centers of cis-[Ru(diphosphine)2(H)2]: preparative, NMR, solid state, and laser flash studies.
Journal of the American Chemical Society 2012;134(7):3480-97.
2011: Jacob Schneider; Xue-Zhong Sun; Khuong Q Vuong; Adrian C Whitwood; James A Calladine; Michael W George; Robin N Perutz
Photochemistry and photophysics of a Pd(II) metalloporphyrin: Re(I) tricarbonyl bipyridine molecular dyad and its activity toward the photoreduction of CO2 to CO.
Inorganic chemistry 2011;50(23):11877-89.
2011: Torsten Beweries; Lee Brammer; Naseralla A Jasim; John E McGrady; Robin N Perutz; Adrian C Whitwood
Energetics of halogen bonding of group 10 metal fluoride complexes.
Journal of the American Chemical Society 2011;133(36):14338-48.
2011: Eric Clot; Odile Eisenstein; Naseralla Jasim; Stuart A Macgregor; John E McGrady; Robin N Perutz
C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales.
Accounts of chemical research 2011;44(5):333-48.
2011: James A Calladine; Simon B Duckett; Michael W George; Steven L Matthews; Robin N Perutz; Olga Torres; Khuong Q Vuong
Manganese alkane complexes: an IR and NMR spectroscopic investigation.
Journal of the American Chemical Society 2011;133(7):2303-10.
2011: Vincent A Corden; Anne-K Duhme-Klair; Sarah Hostachy; Robin N Perutz; Nicole Reddig; Hans-Christian Becker; Leif Hammarström
Spectroscopic and structural investigations reveal the signaling mechanism of a luminescent molybdate sensor.
Inorganic chemistry 2011;50(3):1105-15.
2010: Julie Guihaumé; Eric Clot; Odile Eisenstein; Robin N Perutz
Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes.
Dalton transactions (Cambridge, England : 2003) 2010;39(43):10510-9.
2009: A John Blacker; Eric Clot; Simon B Duckett; Odile Eisenstein; Jake Grace; Ainara Nova; Robin N Perutz; David J Taylor; Adrian C Whitwood
Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.
Chemical communications (Cambridge, England) 2009;(44):6801-3.
2009: Eric Clot; Claire Mégret; Odile Eisenstein; Robin N Perutz
Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations.
Journal of the American Chemical Society 2009;131(22):7817-27.
2009: Fernando Godoy; A Hugo Klahn; Beatriz Oelckers; María Teresa Garland; Andres Ibáñez; Robin N Perutz
Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2.
Dalton transactions (Cambridge, England : 2003) 2009;(16):3044-51.
2009: Rugiada Girotti; Antonio Romerosa; Sonia Mañas; Manuel Serrano-Ruiz; Robin N Perutz
Visible-light photoisomerization and photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)4Cl2] in organic solvent and water.
Inorganic chemistry 2009;48(8):3692-8.
2009: Simon B Duckett; Michael W George; Omar S Jina; Steven L Matthews; Robin N Perutz; Xue-Zhong Sun; Khuong Q Vuong
A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane).
Chemical communications (Cambridge, England) 2009;(11):1401-3.
2008: Ainara Nova; Stefan Erhardt; Naseralla A Jasim; Robin N Perutz; Stuart A Macgregor; John E McGrady; Adrian C Whitwood
Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition.
Journal of the American Chemical Society 2008;130(46):15499-511.
2008: Robin N Perutz
Chemistry. A catalytic foothold for fluorocarbon reactions.
Science (New York, N.Y.) 2008;321(5893):1168-9.
2008: Anders Gabrielsson; John R Lindsay Smith; Robin N Perutz
Remote site photosubstitution in metalloporphyrin-rhenium tricarbonylbipyridine assemblies: photo-reactions of molecules with very short lived excited states.
Dalton transactions (Cambridge, England : 2003) 2008;(32):4259-69.
2008: Stefano Libri; Naseralla A Jasim; Robin N Perutz; Lee Brammer
Metal fluorides form strong hydrogen bonds and halogen bonds: measuring interaction enthalpies and entropies in solution.
Journal of the American Chemical Society 2008;130(25):7842-4.
2008: Marius V Câmpian; Eric Clot; Odile Eisenstein; Ulrike Helmstedt; Naseralla Jasim; Robin N Perutz; Adrian C Whitwood; David Williamson
Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization.
Journal of the American Chemical Society 2008;130(13):4375-85.
2007: Richard J Lindup; Todd B Marder; Robin N Perutz; Adrian C Whitwood
Sequential C-F activation and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR investigation.
Chemical communications (Cambridge, England) 2007;(35):3664-6.
2007: Kirsten A M Ampt; Simon B Duckett; Robin N Perutz
Low temperature in situ UV irradiation of [(eta 5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(III) silyl hydride complexes.
Dalton transactions (Cambridge, England : 2003) 2007;(28):2993-6.
2007: Robin N Perutz; Sylviane Sabo-Etienne
The sigma-CAM Mechanism: sigma complexes as the basis of sigma-bond metathesis at late-transition-metal centers.
Angewandte Chemie (International ed. in English) 2007;46(15):2578-92.
2006: Eric Clot; Claire Mégret; Odile Eisenstein; Robin N Perutz
Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory.
Journal of the American Chemical Society 2006;128(25):8350-7.
2006: Kirsten A M Ampt; Suzanne Burling; Steven M A Donald; Susie Douglas; Simon B Duckett; Stuart A Macgregor; Robin N Perutz; Michael K Whittlesey
Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies.
Journal of the American Chemical Society 2006;128(23):7452-3.
2006: Anders Gabrielsson; Frantisek Hartl; Hong Zhang; John R Lindsay Smith; Michael Towrie; Antonín Vlcek; Robin N Perutz
Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy.
Journal of the American Chemical Society 2006;128(13):4253-66.
2006: Ibraheem A I Mkhalid; David N Coventry; David Albesa-Jove; Andrei S Batsanov; Judith A K Howard; Robin N Perutz; Todd B Marder
Ir-catalyzed borylation of C-H bonds in N-containing heterocycles: regioselectivity in the synthesis of heteroaryl boronate esters.
Angewandte Chemie (International ed. in English) 2006;45(3):489-91.
2005: Suzanne Burling; Paul I P Elliott; Naser A Jasim; Richard J Lindup; Jennifer McKenna; Robin N Perutz; Stephen J Archibald; Adrian C Whitwood
C-F Bond activation at Ni(0) and simple reactions of square planar Ni(II) fluoride complexes.
Dalton transactions (Cambridge, England : 2003) 2005;(22):3686-95.
2005: David N Coventry; Andrei S Batsanov; Andrés E Goeta; Judith A K Howard; Todd B Marder; Robin N Perutz
Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters.
Chemical communications (Cambridge, England) 2005;(16):2172-4.
2005: Anna F A Peacock; Helen D Batey; Claudia Raendler; Adrian C Whitwood; Robin N Perutz; Anne-K Duhme-Klair
A metal-based lumophore tailored to sense biologically relevant oxometalates.
Angewandte Chemie (International ed. in English) 2005;44(11):1712-4.
2004: Kirsten A M Ampt; Simon B Duckett; Robin N Perutz
Photochemical reactions of (eta 5-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: dynamics of isomer interconversion via Rh(eta 2-silane) species.
Dalton transactions (Cambridge, England : 2003) 2004;(20):3331-7.
2004: Daniele Schott; Philip Callaghan; John Dunne; Simon B Duckett; Cyril Godard; José M Goicoechea; Jeremy N Harvey; John P Lowe; Roger J Mawby; Georg Müller; Robin N Perutz; Rinaldo Poli; Michael K Whittlesey
The reaction of M(CO)3(Ph2PCH2CH2PPh2)(M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products.
Dalton transactions (Cambridge, England : 2003) 2004;(20):3218-24.
2004: Simon B Duckett; Maria-Dolores Galvez-Lopez; Robin N Perutz; Daniele Schott
Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I).
Dalton transactions (Cambridge, England : 2003) 2004;(17):2746-9.
2004: Wai Han Lam; King Chung Lam; Zhenyang Lin; Shigeru Shimada; Robin N Perutz; Todd B Marder
Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane.
Dalton transactions (Cambridge, England : 2003) 2004;(10):1556-62.
2004: Meike Reinhold; John E McGrady; Robin N Perutz
A comparison of C-F and C-H bond activation by zerovalent ni and pt: a density functional study.
Journal of the American Chemical Society 2004;126(16):5268-76.
2004: Philip Callaghan; Rodrigo Fernández-Pacheco; Naser Jasim; Sébastien Lachaize; Todd B Marder; Robin N Perutz; Eleonora Rivalta; Sylviane Sabo-Etienne
Photochemical oxidative addition of B-H bonds at ruthenium and rhodium.
Chemical communications (Cambridge, England) 2004;(2):242-3.
2003: Cyril Godard; Simon B Duckett; Simon Parsons; Robin N Perutz
Dipyridylketone binding and subsequent C-C bond insertion reactions at cyclopentadienylrhodium.
Chemical communications (Cambridge, England) 2003;(18):2332-3.
2003: Eric Clot; Maria Besora; Feliu Maseras; Claire Mégret; Odile Eisenstein; Beatriz Oelckers; Robin N Perutz
Bond energy M-C/H-C correlations: dual theoretical and experimental approach to the sensitivity of M-C bond strength to substituents.
Chemical communications (Cambridge, England) 2003;(4):490-1.
2002: Cyril Godard; Philip Callaghan; Jenny L Cunningham; Simon B Duckett; Joost A B Lohman; Robin N Perutz
NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation.
Chemical communications (Cambridge, England) 2002;(23):2836-7.
2002: Thomas Braun; Robin N Perutz
Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics.
Chemical communications (Cambridge, England) 2002;(23):2749-57.
2002: Anders Gabrielsson; Frantisek Hartl; John R Lindsay Smith; Robin N Perutz
Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule.
Chemical communications (Cambridge, England) 2002;(9):950-1.
2001: Thomas Braun; Robin N Perutz; M I Sladek
Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions.
Chemical communications (Cambridge, England) 2001;(21):2254-5.