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Herbert Roesky

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Amit Pratap Singh; Gernot Frenking; Herbert W Roesky; Prinson P Samuel; Martin C Schwarzer; Navdeep S Sidhu; Birger Dittrich
A singlet biradicaloid zinc compound and its nonradical counterpart.
Kartik Chandra Mondal; Benedikt Niepötter; Herbert W Roesky; Prinson P Samuel; Amit Pratap Singh; Elena Carl; Regine Herbst-Irmer; A Claudia Stückl; Mykyta Tretiakov; Hilke Wolf; Dietmar Stalke
Easy access to silicon(0) and silicon(II) compounds.
Ramachandran Azhakar; Rajendra Ghadwal; Regine Herbst-Irmer; Ricardo A Mata; Herbert W Roesky; Hilke Wolf; Dietmar Stalke
Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.

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2013: Amit Pratap Singh; Gernot Frenking; Herbert W Roesky; Prinson P Samuel; Martin C Schwarzer; Navdeep S Sidhu; Birger Dittrich
A singlet biradicaloid zinc compound and its nonradical counterpart.
Journal of the American Chemical Society 2013;135(19):7324-9.
2013: Kartik Chandra Mondal; Benedikt Niepötter; Herbert W Roesky; Prinson P Samuel; Amit Pratap Singh; Elena Carl; Regine Herbst-Irmer; A Claudia Stückl; Mykyta Tretiakov; Hilke Wolf; Dietmar Stalke
Easy access to silicon(0) and silicon(II) compounds.
Inorganic chemistry 2013;52(8):4736-43.
2013: Ramachandran Azhakar; Rajendra Ghadwal; Regine Herbst-Irmer; Ricardo A Mata; Herbert W Roesky; Hilke Wolf; Dietmar Stalke
Reaction of N-heterocyclic silylenes with thioketone: formation of silicon-sulfur three (Si-C-S)- and five (Si-C-C-C-S)-membered ring systems.
Chemistry (Weinheim an der Bergstrasse, Germany) 2013;19(11):3715-20.
2013: Ramachandran Azhakar; Herbert W Roesky; Hilke Wolf; Dietmar Stalke
Metal free and selective activation of one C-F bond in a bound CF3 group.
Chemical communications (Cambridge, England) 2013;49(18):1841-3.
2013: Kartik Chandra Mondal; Benedikt Niepötter; Herbert W Roesky; Martin C Schwarzer; Gernot Frenking; Regine Herbst-Irmer; Hilke Wolf; Dietmar Stalke
A stable singlet biradicaloid siladicarbene: (L:)2Si.
Angewandte Chemie (International ed. in English) 2013;52(10):2963-7.
2013: Rajendra Ghadwal; Ramachandran Azhakar; Herbert W Roesky
Dichlorosilylene: a high temperature transient species to an indispensable building block.
Accounts of chemical research 2013;46(2):444-56.
2013: Prinson P Samuel; Sankaranarayana Pillai Sarish; Amit Pratap Singh; Julia Matussek; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Oxidative addition versus substitution reactions of group 14 dialkylamino metalylenes with pentafluoropyridine.
Inorganic chemistry 2013;52(3):1544-9.
2013: Kartik Chandra Mondal; Benedikt Niepötter; Herbert W Roesky; Martin C Schwarzer; Gernot Frenking; Regine Herbst-Irmer; Daniel Kratzert; Igor Tkach; Hilke Wolf; Dietmar Stalke
Conversion of a singlet silylene to a stable biradical.
Angewandte Chemie (International ed. in English) 2013;52(6):1801-5.
2012: Pengfei Hao; Jiarong Li; Zhihong Liu; Xiaoli Ma; Herbert W Roesky; Kening Sun; Xiujuan Wang; Zhi Yang; Mingdong Zhong
Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif.
Dalton transactions (Cambridge, England : 2003) 2012;41(43):13520-4.
2012: Ramachandran Azhakar; Julian J Holstein; Herbert W Roesky; Birger Dittrich
The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2.
Dalton transactions (Cambridge, England : 2003) 2012;41(39):12096-100.
2012: Prinson P Samuel; Sakya S Sen; Ramachandran Azhakar; Rajendra Ghadwal; Markus Granitzka; Regine Herbst-Irmer; Julia Matussek; Herbert W Roesky; Dietmar Stalke
Stable silaimines with three- and four-coordinate silicon atoms.
Inorganic chemistry 2012;51(20):11049-54.
2012: Ramachandran Azhakar; Rajendra Ghadwal; Julian J Holstein; Herbert W Roesky; Birger Dittrich
An access to base-stabilized three-membered silicon heterocycles.
Dalton transactions (Cambridge, England : 2003) 2012;41(32):9601-3.
2012: Rajendra Ghadwal; Catharina Goedecke; Kevin Pröpper; Herbert W Roesky; Ramachandran Azhakar; Birger Dittrich; Gernot Frenking
Donor-acceptor stabilized silaformyl chloride.
Chemical communications (Cambridge, England) 2012;48(66):8186-8.
2012: Amit Pratap Singh; Herbert W Roesky; Veniamin Chevelkov; Jean-Philippe Demers; Birger Dittrich; Rajendra Ghadwal; Julian J Holstein; Adam Lange
Lewis base mediated dismutation of trichlorosilane.
Chemical communications (Cambridge, England) 2012;48(61):7574-6.
2012: Shabana Khan; Adam Lange; Ricardo A Mata; Reent Michel; Herbert W Roesky; Prinson P Samuel; Jean-Philippe Demers; Johannes M Dieterich; Dietmar Stalke
Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand.
Chemical communications (Cambridge, England) 2012;48(40):4890-2.
2012: Ramachandran Azhakar; Rajendra Ghadwal; Herbert W Roesky; Hilke Wolf; Dietmar Stalke
A début for base stabilized monoalkylsilylenes.
Chemical communications (Cambridge, England) 2012;48(38):4561-3.
2012: Sakya S Sen; Shabana Khan; Selvarajan Nagendran; Herbert W Roesky
Interconnected bis-silylenes: a new dimension in organosilicon chemistry.
Accounts of chemical research 2012;45(4):578-87.
2012: Amit Pratap Singh; Dietmar Stalke; Elena Carl; Jean-Philippe Demers; Herbert W Roesky; Adam Lange
Lewis base mediated autoionization of GeCl2 and SnCl2.
Journal of the American Chemical Society 2012;134(10):4998-5003.
2012: Ramachandran Azhakar; Rajendra Ghadwal; Jakob Hey; Herbert W Roesky; Dietmar Stalke
Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand.
Chemistry, an Asian journal 2012;7(3):528-33.
2012: Shabana Khan; Sakya S Sen; Herbert W Roesky
Activation of phosphorus by group 14 elements in low oxidation states.
Chemical communications (Cambridge, England) 2012;48(16):2169-79.
2012: Swadhin K Mandal; Herbert W Roesky
Group 14 hydrides with low valent elements for activation of small molecules.
Accounts of chemical research 2012;45(2):298-307.
2012: Ying Yang; Chen Wang; Haipu Li; Herbert W Roesky
Studies of the ligand effect on the synthesis of dialuminoxanes by various β-diketiminato ligands.
Inorganic chemistry 2012;51(4):2204-11.
2012: Ying Yang; Na Zhao; Hongping Zhu; Yile Wu; Herbert W Roesky
Synthesis and characterization of β-diketiminate germanium(II) compounds.
Inorganic chemistry 2012;51(4):2425-31.
2012: Ramachandran Azhakar; Rajendra Ghadwal; Herbert W Roesky; Hilke Wolf; Dietmar Stalke
Stabilization of low valent silicon fluorides in the coordination sphere of transition metals.
Journal of the American Chemical Society 2012;134(4):2423-8.
2011: Shabana Khan; Reent Michel; Herbert W Roesky; Sakya S Sen; Dietmar Stalke
A P4 chain and cage from silylene-activated white phosphorus.
Angewandte Chemie (International ed. in English) 2011;50(49):11786-9.
2011: Rajendra Ghadwal; Susanne Klein; Kevin Pröpper; Herbert W Roesky; Ramachandran Azhakar; Birger Dittrich; Gernot Frenking
Donor-acceptor-stabilized silicon analogue of an acid anhydride.
Journal of the American Chemical Society 2011;133(44):17552-5.
2011: Shabana Khan; Adam Lange; Ricardo A Mata; Reent Michel; Herbert W Roesky; Jean-Philippe Demers; Johannes M Dieterich; Dietmar Stalke
Preparation of RSn(I)-Sn(I)R with two unsymmetrically coordinated Sn(I) atoms and subsequent gentle activation of P4.
Journal of the American Chemical Society 2011;133(44):17889-94.
2011: Shabana Khan; Debasis Koley; Reent Michel; Herbert W Roesky; Dietmar Stalke
Reactivity studies of a disilene with N2O and elemental sulfur.
Inorganic chemistry 2011;50(21):10878-83.
2011: Paul W Percival; Robert West; Ramachandran Azhakar; Jean-Claude Brodovitch; Rajendra Ghadwal; Amitabha Mitra; Mina Mozafari; Herbert W Roesky
Free radical reactivity of mono- and dichlorosilylene with muonium.
Chemistry (Weinheim an der Bergstrasse, Germany) 2011;17(43):11970-3.
2011: Rajendra Ghadwal; Julian J Holstein; Kevin Pröpper; Ramachandran Azhakar; Birger Dittrich; Herbert W Roesky
N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0).
Inorganic chemistry 2011;50(17):8502-8.
2011: Jingjun Hao; Jianfeng Li; Chunming Cui; Herbert W Roesky
Synthesis and characterization of heterobimetallic oxo-bridged aluminum-rare earth metal complexes.
Inorganic chemistry 2011;50(16):7453-9.
2011: Sakya S Sen; Regine Herbst-Irmer; Jakob Hey; Herbert W Roesky; Dietmar Stalke
Striking stability of a substituted silicon(II) bis(trimethylsilyl)amide and the facile Si-Me bond cleavage without a transition metal catalyst.
Journal of the American Chemical Society 2011;133(31):12311-6.
2011: Sankaranarayana Pillai Sarish; Sakya S Sen; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Elegant approach to spacer arranged silagermylene and bis(germylene) compounds.
Chemical communications (Cambridge, England) 2011;47(25):7206-8.
2011: Ramachandran Azhakar; Sankaranarayana Pillai Sarish; Herbert W Roesky; Jakob Hey; Dietmar Stalke
Syntheses of group 7 metal carbonyl complexes with a stable N-heterocyclic chlorosilylene.
Inorganic chemistry 2011;50(11):5039-43.
2011: Anukul Jana; Dirk Leusser; Ina Objartel; Herbert W Roesky; Dietmar Stalke
A stable silicon(II) monohydride.
Dalton transactions (Cambridge, England : 2003) 2011;40(20):5458-63.
2011: Rajendra Ghadwal; Herbert W Roesky; Kevin Pröpper; Birger Dittrich; Susanne Klein; Gernot Frenking
A dimer of silaisonitrile with two-coordinate silicon atoms.
Angewandte Chemie (International ed. in English) 2011;50(23):5374-8.
2011: Anukul Jana; Sankaranarayana Pillai Sarish; Herbert W Roesky; Dirk Leusser; Ina Objartel; Dietmar Stalke
Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble β-diketiminatolead(II) monofluoride.
Chemical communications (Cambridge, England) 2011;47(19):5434-6.
2011: Arup Mukherjee; Sharanappa Nembenna; Tamal K Sen; Sankaranarayana Pillai Sarish; Pradip Kr Ghorai; Holger Ott; Dietmar Stalke; Swadhin K Mandal; Herbert W Roesky
Assembling zirconium and calcium moieties through an oxygen center for an intramolecular hydroamination reaction: a single system for double activation.
Angewandte Chemie (International ed. in English) 2011;50(17):3968-72.
2011: Ramachandran Azhakar; Sankaranarayana Pillai Sarish; Gasper Tavcar; Herbert W Roesky; Jakob Hey; Dietmar Stalke; Debasis Koley
Formation of silicon centered spirocyclic compounds: reaction of N-heterocyclic stable silylene with benzoylpyridine, diisopropyl azodicarboxylate, and 1,2-diphenylhydrazine.
Inorganic chemistry 2011;50(7):3028-36.
2011: Shabana Khan; Sakya S Sen; Daniel Kratzert; Gašper Tavčar; Herbert W Roesky; Dietmar Stalke
Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl].
Chemistry (Weinheim an der Bergstrasse, Germany) 2011;17(15):4283-90.
2011: Sankaranarayana Pillai Sarish; Sharanappa Nembenna; Selvarajan Nagendran; Herbert W Roesky
Chemistry of soluble β-diketiminatoalkaline-earth metal complexes with M-X bonds (M=Mg, Ca, Sr; X=OH, Halides, H).
Accounts of chemical research 2011;44(3):157-70.
2011: Xiaoli Ma; Zhi Yang; Xiujuan Wang; Herbert W Roesky; Feng Wu; Hongping Zhu
Synthesis of boroxine-linked aluminum complexes.
Inorganic chemistry 2011;50(5):2010-4.
2011: Sakya S Sen; Shabana Khan; Herbert W Roesky; Daniel Kratzert; Kathrin Meindl; Julian Henn; Dietmar Stalke; Jean-Philippe Demers; Adam Lange
Zwitterionic Si-C-Si-P and Si-P-Si-P four-membered rings with two-coordinate phosphorus atoms.
Angewandte Chemie (International ed. in English) 2011;50(10):2322-5.
2011: Sankaranarayana Pillai Sarish; Bijan Nekoueishahraki; Anukul Jana; Herbert W Roesky; Thomas Schulz; Dietmar Stalke
A new entry into aluminum chemistry: [L(1)AlMe]⋅THF, a versatile building block for bimetallic and polymetallic complexes.
Chemistry (Weinheim an der Bergstrasse, Germany) 2011;17(3):890-4.
2011: Rajendra Ghadwal; Kevin Pröpper; Birger Dittrich; Peter G Jones; Herbert W Roesky
Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes.
Inorganic chemistry 2011;50(1):358-64.
2010: Ying Yang; Hongping Zhu; Herbert W Roesky; Zhi Yang; Gengwen Tan; Haipu Li; Michael John; Regine Herbst-Irmer
Trinuclear alumoxanes with an acyclic Al-O-Al-O-Al core and studies of their reactivity.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(42):12530-3.
2010: Gasper Tavcar; Sakya S Sen; Ramachandran Azhakar; Andrea Thorn; Herbert W Roesky
Facile syntheses of silylene nickel carbonyl complexes from Lewis base stabilized chlorosilylenes.
Inorganic chemistry 2010;49(21):10199-202.
2010: Anukul Jana; Gašper Tavčar; Herbert W Roesky; Michael John
Germanium(II) hydride mediated reduction of carbon dioxide to formic acid and methanol with ammonia borane as the hydrogen source.
Dalton transactions (Cambridge, England : 2003) 2010;39(40):9487-9.
2010: Shabana Khan; Sakya S Sen; Herbert W Roesky; Daniel Kratzert; Reent Michel; Dietmar Stalke
One pot synthesis of disilatricycloheptene analogue and Jutzi's disilene.
Inorganic chemistry 2010;49(20):9689-93.
2010: Gengwen Tan; Ying Yang; Chenhui Chu; Hongping Zhu; Herbert W Roesky
Cu24O24Si8R8: organic soluble 56-membered copper(I) siloxane cage and its use in homogeneous catalysis.
Journal of the American Chemical Society 2010;132(35):12231-3.
2010: Swadhin K Mandal; Herbert W Roesky
Interstellar molecules: guides for new chemistry.
Chemical communications (Cambridge, England) 2010;46(33):6016-41.
2010: Sakya S Sen; Herbert W Roesky; Kathrin Meindl; Daniel Stern; Julian Henn; A Claudia Stückl; Dietmar Stalke
Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene.
Chemical communications (Cambridge, England) 2010;46(32):5873-5.
2010: Anukul Jana; Prinson P Samuel; Gasper Tavcar; Herbert W Roesky; Carola Schulzke
Selective aromatic C-F and C-H bond activation with silylenes of different coordinate silicon.
Journal of the American Chemical Society 2010;132(29):10164-70.
2010: Rajendra S Ghadwal; Herbert W Roesky; Markus Granitzka; Dietmar Stalke
A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene.
Journal of the American Chemical Society 2010;132(29):10018-20.
2010: Anukul Jana; Gasper Tavcar; Herbert W Roesky; Carola Schulzke
Facile synthesis of dichlorosilane by metathesis reaction and dehydrogenation of dihydrogermane by a frustrated Lewis pair.
Dalton transactions (Cambridge, England : 2003) 2010;39(27):6217-20.
2010: Sakya S Sen; Daniel Kratzert; Daniel Stern; Herbert W Roesky; Dietmar Stalke
Reactivity studies of a Ge(I)-Ge(I) compound with and without cleavage of the Ge-Ge bond.
Inorganic chemistry 2010;49(13):5786-8.
2010: Anukul Jana; Herbert W Roesky; Carola Schulzke; Prinson P Samuel; Alexander Döring
Synthesis and reaction of monomeric germanium(II) and lead(II) dimethylamide and the synthesis of germanium(II) hydrazide by cleavage of one N-H bond of hydrazine.
Inorganic chemistry 2010;49(12):5554-9.
2010: Rajendra Ghadwal; Sakya S Sen; Herbert W Roesky; Markus Granitzka; Daniel Kratzert; Sebastian Merkel; Dietmar Stalke
Convenient access to monosilicon epoxides with pentacoordinate silicon.
Angewandte Chemie (International ed. in English) 2010;49(23):3952-5.
2010: Anukul Jana; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Reaction of β-diketiminate tin(II) dimethylamide LSnNMe₂ [L = HC(CMeNAr)₂; Ar = 2,6-iPr₂C₆H₃] with ketones and alkynes.
Dalton transactions (Cambridge, England : 2003) 2010;39(19):4647-50.
2010: Sankaranarayana Pillai Sarish; Anukul Jana; Herbert W Roesky; Thomas Schulz; Michael John; Dietmar Stalke
Heavier alkaline earth metal borohydride complexes stabilized by beta-diketiminate ligand.
Inorganic chemistry 2010;49(8):3816-20.
2010: Anukul Jana; Herbert W Roesky; Carola Schulzke; Prinson P Samuel
An efficient route for the synthesis of a Tin(II) substituted carbodiimide from a diazo compound.
Inorganic chemistry 2010;49(7):3461-4.
2010: Herbert W Roesky
A flourish of fluorine.
Nature chemistry 2010;2(3):240.
2010: Swadhin K Mandal; Herbert W Roesky
Assembling heterometals through oxygen: an efficient way to design homogeneous catalysts.
Accounts of chemical research 2010;43(2):248-59.
2010: Anukul Jana; Sankaranarayana Pillai Sarish; Herbert W Roesky; Carola Schulzke; Prinson P Samuel
A rational design for an efficient synthesis of a monomeric tin(II) hydroxide.
Chemical communications (Cambridge, England) 2010;46(5):707-9.
2010: Jianfeng Li; Sebastian Merkel; Julian Henn; Kathrin Meindl; Alexander Döring; Herbert W Roesky; Rajendra Ghadwal; Dietmar Stalke
Lewis-base-stabilized dichlorosilylene: a two-electron sigma-donor ligand.
Inorganic chemistry 2010;49(3):775-7.
2010: Sakya S Sen; Herbert W Roesky; Daniel Stern; Julian Henn; Dietmar Stalke
High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene.
Journal of the American Chemical Society 2010;132(3):1123-6.
2010: Namrata Dixit; P K Shukla; Phool C Mishra; Lallan Mishra; Herbert W Roesky
Binding of urea and thiourea with a barbiturate derivative: experimental and theoretical approach.
The journal of physical chemistry. A 2010;114(1):97-104.
2010: N Dastagiri Reddy; Anukul Jana; Herbert W Roesky; Prinson P Samuel; Carola Schulzke
Synthesis of phosphine substituted beta-diketiminate based isomeric Ge(II) complexes.
Dalton transactions (Cambridge, England : 2003) 2010;(1):234-8.
2010: Anukul Jana; Herbert W Roesky; Carola Schulzke
Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane.
Dalton transactions (Cambridge, England : 2003) 2010;(1):132-8.
2010: Rajendra Ghadwal; Herbert W Roesky; Sebastian Merkel; Dietmar Stalke
Ambiphilicity of dichlorosilylene in a single molecule.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(1):85-8.
2009: Bijan Nekoueishahraki; Herbert W Roesky; Gerald Schwab; Daniel Stern; Dietmar Stalke
Synthesis and structural characterization of aluminum iminophosphonamide complexes.
Inorganic chemistry 2009;48(19):9174-9.
2009: Anukul Jana; Herbert W Roesky; Carola Schulzke
Hydrostannylation of ketones and alkynes with LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3].
Inorganic chemistry 2009;48(19):9543-8.
2009: Andreas Stasch; Sankaranarayana Pillai Sarish; Herbert W Roesky; Kathrin Meindl; Fabio Dall'Antonia; Thomas Schulz; Dietmar Stalke
Synthesis and characterization of alkynyl complexes of groups 1 and 2.
Chemistry, an Asian journal 2009;4(9):1451-7.
2009: Anukul Jana; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Dehydrogenation of LGeH by a Lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C(6)F(5))(3) and trimethylsilyl diazomethane: an unprecedented rearrangement of a diazocompound to an isonitrile.
Inorganic chemistry 2009;48(16):7645-9.
2009: S E Kabir; J Alam; S Ghosh; K Kundu; G Hogarth; Derek A Tocher; G M G Hossain; Herbert W Roesky
Synthesis, structure and reactivity of tetranuclear square-type complexes of rhenium and manganese bearing pyrimidine-2-thiolate (pymS) ligands: versatile and efficient precursors for mono- and polynuclear compounds containing M(CO)(3) (M = Re, Mn) fragments.
Dalton transactions (Cambridge, England : 2003) 2009;(23):4458-67.
2009: Wei Yang; Hao Fu; Haijun Wang; Mingqing Chen; Yuqiang Ding; Herbert W Roesky; Anukul Jana
A base-stabilized silylene with a tricoordinate silicon atom as a ligand for a metal complex.
Inorganic chemistry 2009;48(12):5058-60.
2009: Shishir Ghosh; Shariff E Kabir; Salina Pervin; Arun K Raha; G M Golzar Hossain; Daniel T Haworth; Sergey V Lindeman; Dennis W Bennett; Tasneem A Siddiquee; Luca Salassa; Herbert W Roesky
Tetranuclear group 7/8 mixed-metal and open trinuclear group 7 metal carbonyl clusters bearing bridging 2-mercapto-1-methylimidazole ligands.
Dalton transactions (Cambridge, England : 2003) 2009;(18):3510-8.
2009: Sankaranarayana Pillai Sarish; Herbert W Roesky; Michael John; Arne Ringe; Jörg Magull
Well-defined hydrocarbon soluble strontium fluoride and chloride complexes of composition [LSr(thf)(micro-F)2Sr(thf)2L] and [LSr(thf)(micro-Cl)2Sr(thf)2L].
Chemical communications (Cambridge, England) 2009;(17):2390-2.
2009: Anukul Jana; Carola Schulzke; Herbert W Roesky
Oxidative addition of ammonia at a silicon(II) center and an unprecedented hydrogenation reaction of compounds with low-valent group 14 elements using ammonia borane.
Journal of the American Chemical Society 2009;131(13):4600-1.
2009: Sharanappa Nembenna; Sanjay Singh; Anukul Jana; Herbert W Roesky; Ying Yang; Hongqi Ye; Holger Ott; Dietmar Stalke
Preparation and structural characterization of molecular Al-O-Sn(II) and Al-O-Sn(IV) compounds.
Inorganic chemistry 2009;48(5):2273-6.
2009: Anukul Jana; Ina Objartel; Herbert W Roesky; Dietmar Stalke
Cleavage of a N-H bond of ammonia at room temperature by a germylene.
Inorganic chemistry 2009;48(3):798-800.
2009: Anukul Jana; Debajyoti Ghoshal; Herbert W Roesky; Ina Objartel; Gerald Schwab; Dietmar Stalke
A germanium(II) hydride as an effective reagent for hydrogermylation reactions.
Journal of the American Chemical Society 2009;131(3):1288-93.
2009: Anukul Jana; Herbert W Roesky; Carola Schulzke; Alexander Döring; Tobias Beck; Aritra Pal; Regine Herbst-Irmer
Facile access of stable divalent tin compounds with terminal methyl, amide, fluoride, and iodide substituents.
Inorganic chemistry 2009;48(1):193-7.
2009: Sankaranarayana Pillai Sarish; Sharanappa Nembenna; Herbert W Roesky; Holger Ott; Aritra Pal; Dietmar Stalke; Sudipta Dutta; Swapan K Pati
Soluble molecular dimers of CaO and SrO stabilized by a Lewis acid.
Angewandte Chemie (International ed. in English) 2009;48(46):8740-2.
2009: Sakya S Sen; Anukul Jana; Herbert W Roesky; Carola Schulzke
A remarkable base-stabilized bis(silylene) with a silicon(I)-silicon(I) bond.
Angewandte Chemie (International ed. in English) 2009;48(45):8536-8.
2009: Rajendra Ghadwal; Herbert W Roesky; Sebastian Merkel; Julian Henn; Dietmar Stalke
Lewis base stabilized dichlorosilylene.
Angewandte Chemie (International ed. in English) 2009;48(31):5683-6.
2009: Bijan Nekoueishahraki; Sankaranarayana Pillai Sarish; Herbert W Roesky; Daniel Stern; Carola Schulzke; Dietmar Stalke
Addition of dimethylaminobismuth to aldehydes, ketones, alkenes, and alkynes.
Angewandte Chemie (International ed. in English) 2009;48(25):4517-20.
2009: Anukul Jana; Sakya S Sen; Herbert W Roesky; Carola Schulzke; Sudipta Dutta; Swapan K Pati
End-on nitrogen insertion of a diazo compound into a germanium(II) hydrogen bond and a comparable reaction with diethyl azodicarboxylate.
Angewandte Chemie (International ed. in English) 2009;48(23):4246-8.
2009: Anukul Jana; Herbert W Roesky; Carola Schulzke; Alexander Döring
Reactions of tin(II) hydride species with unsaturated molecules.
Angewandte Chemie (International ed. in English) 2009;48(6):1106-9.
2008: Anukul Jana; Gerald Schwab; Herbert W Roesky; Dietmar Stalke
Functionalization of aminophosphanes: synthesis and X-ray crystal structure of novel dilithium and trilithium complexes containing silicon-fused heteronuclear SiN2PLi five-membered rings.
Inorganic chemistry 2008;47(19):8990-4.
2008: Grigory B Nikiforov; Herbert W Roesky; Thomas Schulz; Dietmar Stalke; M Witt
On the quest for new mixed-metal mu-oxo-bridged complexes: synthesis of compounds containing transition metal-oxygen-main group metal motifs M-O-M1 (M = Ti, Zr; M1 = Al, Ga) without cyclopentadienyl ligands.
Inorganic chemistry 2008;47(14):6435-43.
2008: Sankaranarayanapillai Sarish; Sharanappa Nembenna; Selvarajan Nagendran; Herbert W Roesky; Aritra Pal; Regine Herbst-Irmer; Arne Ringe; Jörg Magull
A reactivity change of a strontium monohydroxide by umpolung to an acid.
Inorganic chemistry 2008;47(13):5971-7.
2008: prabhuodeyara Gurubasavaraj; Herbert W Roesky; Bijan Nekoueishahraki; Aritra Pal; Regine Herbst-Irmer
From unstable to stable: half-metallocene catalysts for olefin polymerization.
Inorganic chemistry 2008;47(12):5324-31.
2008: Ying Yang; Thomas Schulz; Michael John; Arne Ringe; Herbert W Roesky; Dietmar Stalke; Jörg Magull; Hongqi Ye
Synthesis, characterization, and reaction of aluminum halide amides supported by a bulky beta-diketiminato ligand.
Inorganic chemistry 2008;47(7):2585-92.
2008: Grigory B Nikiforov; Herbert W Roesky; Peter G Jones; Jörg Magull; Arne Ringe; Rainer B Oswald
Preparation of Ti(IV) fluoride N-heterocyclic carbene complexes.
Inorganic chemistry 2008;47(6):2171-9.
2007: Sanjay Singh; Jianfang Chai; Aritra Pal; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer
Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies.
Chemical communications (Cambridge, England) 2007;(46):4934-6.
2007: Ying Yang; Herbert W Roesky; Peter G Jones; Cheuk-Wai So; Zhensheng Zhang; Regine Herbst-Irmer; Hongqi Ye
Synthesis and structural characterization of monomeric heterobimetallic oxides with a GeII-O-M skeleton (M = Yb, Y).
Inorganic chemistry 2007;46(25):10860-3.
2007: Cheuk-Wai So; Herbert W Roesky; Rainer B Oswald; Aritra Pal; Peter G Jones
Synthesis and characterization of [[PhC(NBu(t))2]Si(S)SBu(t)]: a silicon thioester analogue with the Si(=S)-S-skeleton.
Dalton transactions (Cambridge, England : 2003) 2007;(45):5241-4.
2007: Swadhin K Mandal; prabhuodeyara Gurubasavaraj; Herbert W Roesky; Gerald Schwab; Dietmar Stalke; Rainer B Oswald; Volker Dolle
Oxygen-bridged hybrid metallocene-nonmetallocene polymetallic catalysts of group 4 metals for bimodal activity in olefin polymerization: synthesis, characterization, and theoretical investigation.
Inorganic chemistry 2007;46(24):10158-67.
2007: Cheuk-Wai So; Herbert W Roesky; prabhuodeyara Gurubasavaraj; Rainer B Oswald; Michael T Gamer; Peter G Jones; Steffen Blaurock
Synthesis and structures of heteroleptic silylenes.
Journal of the American Chemical Society 2007;129(39):12049-54.
2007: Swadhin K Mandal; prabhuodeyara Gurubasavaraj; Herbert W Roesky; Rainer B Oswald; Jörg Magull; Arne Ringe
Synthesis, structural characterization, and theoretical investigation of compounds containing an Al-O-M-O-Al (M=Ti, Zr) core.
Inorganic chemistry 2007;46(18):7594-600.
2007: Zhi Yang; Xiaoli Ma; Herbert W Roesky; Ying Yang; Jörg Magull; Arne Ringe
Synthesis and characterization of well-defined aluminum-containing heterobimetallic selenides.
Inorganic chemistry 2007;46(17):7093-6.
2007: Jiri Löbl; Alexey Y Timoshkin; Trinh Cong; Marek Necas; Herbert W Roesky; Jiri Pinkas
Alumazene adducts with pyridines: synthesis, structure, and stability studies.
Inorganic chemistry 2007;46(14):5678-85.
2007: Sanjay Singh; Herbert W Roesky
Robust and efficient molecular catalysts with a M-O-M' framework.
Dalton transactions (Cambridge, England : 2003) 2007;(14):1360-70.
2007: prabhuodeyara Gurubasavaraj; Swadhin K Mandal; Herbert W Roesky; Rainer B Oswald; Aritra Pal; Mathias Noltemeyer
Synthesis, structural characterization, catalytic properties, and theoretical study of compounds containing an Al-O-M (M = Ti, Hf) core.
Inorganic chemistry 2007;46(4):1056-61.
2007: Sharanappa Nembenna; Herbert W Roesky; Selvarajan Nagendran; Anja Hofmeister; Jörg Magull; Peter-J Wilbrandt; Matthias Hahn
A well-defined hydrocarbon-soluble calcium monofluoride, [{LCaF(thf)}2]: the application of soluble calcium derivatives for surface coating.
Angewandte Chemie (International ed. in English) 2007;46(14):2512-4.
2006: Christian Ruspic; Sharanappa Nembenna; Anja Hofmeister; Jörg Magull; Sjoerd Harder; Herbert W Roesky
A well-defined hydrocarbon-soluble calcium hydroxide: synthesis, structure, and reactivity.
Journal of the American Chemical Society 2006;128(46):15000-4.
2006: Sharanappa Nembenna; Herbert W Roesky; Swadhin K Mandal; Rainer B Oswald; Aritra Pal; Regine Herbst-Irmer; Mathias Noltemeyer; Hans-Georg Schmidt
Soluble molecular compounds with the Mg-O-Al structural motif: a model approach for the fixation of organometallics on a MgO surface.
Journal of the American Chemical Society 2006;128(40):13056-7.
2006: Zhi Yang; Xiaoli Ma; Rainer B Oswald; Herbert W Roesky; Mathias Noltemeyer
Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core.
Journal of the American Chemical Society 2006;128(38):12406-7.
2006: Herbert W Roesky; Sanjay Singh; K K M Yusuff; John A Maguire; Narayan S Hosmane
Organometallic hydroxides of transition elements.
Chemical reviews 2006;106(9):3813-43.
2006: Jiri Löbl; Jiri Pinkas; Herbert W Roesky; Winfried Plass; Helmar Görls
A supramolecular hexameric ring from alumazene and methylsulfonate.
Inorganic chemistry 2006;45(17):6571-3.
2006: Mónica Moya-Cabrera; Vojtech Jancik; Rafael A Castro; Regine Herbst-Irmer; Herbert W Roesky
Unusual In2N4 cores in complexes containing triazole-based chalcogen-phosphoranyl ligands.
Inorganic chemistry 2006;45(13):5167-71.
2006: Cheuk-Wai So; Herbert W Roesky; Jörg Magull; Rainer B Oswald
Synthesis and characterization of [PhC(NtBu)2]SiCl: a stable monomeric chlorosilylene.
Angewandte Chemie (International ed. in English) 2006;45(24):3948-50.
2006: Hongping Zhu; Rainer B Oswald; Hongjun Fan; Herbert W Roesky; Qingjun Ma; Zhi Yang; Hans-Georg Schmidt; Mathias Noltemeyer; Kerstin Starke; Narayan S Hosmane
Aluminacyclopropene: syntheses, characterization, and reactivity toward terminal alkynes.
Journal of the American Chemical Society 2006;128(15):5100-8.
2006: Zhi Yang; Xiaoli Ma; Vojtech Jancik; Zhensheng Zhang; Herbert W Roesky; Jörg Magull; Mathias Noltemeyer; Hans-Georg Schmidt; Raymundo Cea-Olivares; Rubén A Toscano
Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides.
Inorganic chemistry 2006;45(8):3312-5.
2006: Leslie W Pineda; Vojtech Jancik; Kerstin Starke; Rainer B Oswald; Herbert W Roesky
Stable monomeric germanium(II) and tin(II) compounds with terminal hydrides.
Angewandte Chemie (International ed. in English) 2006;45(16):2602-5.
2006: Zhi Yang; Xiaoli Ma; Rainer B Oswald; Herbert W Roesky; Chunming Cui; Hans-Georg Schmidt; Mathias Noltemeyer
An unprecedented example of a hetero-trimetallic main-group [L2Al2Ge4Li2S7] cluster containing a Ge(II)-Ge(II) donor-acceptor bond.
Angewandte Chemie (International ed. in English) 2006;45(14):2277-80.
2006: Xiaofei Li; Haibin Song; Lili Duan; Chunming Cui; Herbert W Roesky
C-H-Activated aluminum hydroxide via molecular oxygen.
Inorganic chemistry 2006;45(5):1912-4.
2006: Sanjay Singh; Hans-Jürgen Ahn; Andreas Stasch; Vojtech Jancik; Herbert W Roesky; Aritra Pal; Marianna Biadene; Regine Herbst-Irmer; Mathias Noltemeyer; Hans-Georg Schmidt
Syntheses, characterization, and X-ray crystal structures of beta-diketiminate group 13 hydrides, chlorides, and fluorides.
Inorganic chemistry 2006;45(4):1853-60.
2006: Zhi Yang; Hongping Zhu; Xiaoli Ma; Jianfang Chai; Herbert W Roesky; Cheng He; Jörg Magull; Hans-Georg Schmidt; Mathias Noltemeyer
Synthesis, characterization, and hydrolysis of aluminum(III) compounds bearing the C6F5-substituted beta-diketiminate HC[(CMe)(NC6F5)]2 (L) ligand.
Inorganic chemistry 2006;45(4):1823-7.
2006: Sanjay Singh; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer
Synthesis, characterization, and X-ray crystal structure of a gallium monohydroxide and a hetero-bimetallic gallium zirconium oxide.
Inorganic chemistry 2006;45(3):949-51.
2006: Lorenzo Sorace; Christian Golze; Dante Gatteschi; Andrea Bencini; Herbert W Roesky; Jianfang Chai; A Claudia Stückl
Low-valent low-coordinated manganese(I) ion dimer: a temperature dependent W-band EPR study.
Inorganic chemistry 2006;45(1):395-400.
2005: Peter Lobinger; Harald Jarzina; Herbert W Roesky; Sanjay Singh; S Shravan Kumar; Hans-Georg Schmidt; Mathias Noltemeyer; Herbert C Freyhardt
New synthetic approach to yttrium hydroxoacetates, structural characterization, and use as a precursor for coated conductors.
Inorganic chemistry 2005;44(25):9192-6.
2005: Zhi Yang; Xiaoli Ma; Rainer B Oswald; Herbert W Roesky; Hongping Zhu; Carola Schulzke; Kerstin Starke; Marc Baldus; Hans-Georg Schmidt; Mathias Noltemeyer
Janus-faced aluminum: a demonstration of unique Lewis acid and Lewis base behavior of the aluminum atom in [LALB(C6F5)3].
Angewandte Chemie (International ed. in English) 2005;44(43):7072-4.
2005: Umesh N Nehete; Herbert W Roesky; Hongping Zhu; Sharanappa Nembenna; Hans-Georg Schmidt; Mathias Noltemeyer; Dmitrij Bogdanov; Konrad Samwer
Polyhedral cobalt(II) and iron(II) siloxanes: synthesis and x-ray crystal structure of [(RSi(OH)O2)Co(OPMe3)]4 and [(RSiO3)2(RSi(OH)O2)4(mu3-OH)2Fe8(THF)4] (R = (2,6-iPr2C6H3)N(SiMe3)).
Inorganic chemistry 2005;44(20):7243-8.
2005: Vojtech Jancik; Herbert W Roesky
Preparation of heterobimetallic oxide-hydroxide-hydrogensulfides [LAl(OH)(mu-O)MCp2(SH)] (M=Ti, Zr).
Angewandte Chemie (International ed. in English) 2005;44(37):6016-8.
2005: Herbert W Roesky; S Shravan Kumar
Chemistry of aluminium(I).
Chemical communications (Cambridge, England) 2005;(32):4027-38.
2005: Hongping Zhu; Jianfang Chai; Hongjun Fan; Herbert W Roesky; Cheng He; Vojtech Jancik; Hans-Georg Schmidt; Mathias Noltemeyer; W Alexander Merrill; Philip P Power
A stable aluminacyclopropene LAl(eta2-C2H2) and its end-on azide insertion to an aluminaazacyclobutene.
Angewandte Chemie (International ed. in English) 2005;44(32):5090-3.
2005: Andreas Stasch; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Aluminum hydride cations stabilized by weakly coordinating carbaalanates.
Inorganic chemistry 2005;44(16):5854-7.
2005: Vojtech Jancik; Herbert W Roesky
Unusual Anions [LAl(SH)(S)]- and [LAl(S)2]2- stabilized by weakly coordinating imidazolium cations. synthesis of LAl(SSiMe2)2O (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3).
Inorganic chemistry 2005;44(16):5556-8.
2005: Hongping Zhu; Jianfang Chai; Vojtech Jancik; Herbert W Roesky; W Alexander Merrill; Philip P Power
The selective preparation of an aluminum oxide and its isomeric C-H-activated hydroxide.
Journal of the American Chemical Society 2005;127(29):10170-1.
2005: Jianfang Chai; Hongping Zhu; A Claudia Stückl; Herbert W Roesky; Jörg Magull; Andrea Bencini; Andrea Caneschi; Dante Gatteschi
Synthesis and reaction of [[HC(CMeNAr)2]Mn]2 (Ar = 2,6-iPr2C6H3): the complex containing three-coordinate manganese(I) with a Mn-Mn bond exhibiting unusual magnetic properties and electronic structure.
Journal of the American Chemical Society 2005;127(25):9201-6.
2005: Jianfang Chai; Vojtech Jancik; Sanjay Singh; Hongping Zhu; Cheng He; Herbert W Roesky; Hans-Georg Schmidt; Mathias Noltemeyer; Narayan S Hosmane
Synthesis of a new class of compounds containing a Ln-O-Al arrangement and their reactions and catalytic properties.
Journal of the American Chemical Society 2005;127(20):7521-8.
2005: Leslie W Pineda; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer
OH functionality of germanium(II) compounds for the formation of heterobimetallic oxides.
Inorganic chemistry 2005;44(10):3537-40.
2005: Guangcai Bai; Sanjay Singh; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Mononuclear aluminum hydroxide for the design of well-defined homogeneous catalysts.
Journal of the American Chemical Society 2005;127(10):3449-55.
2005: S Shravan Kumar; Sanjay Singh; Herbert W Roesky; Jörg Magull
Reaction of LAlH2 with tert-butyl hydrogenperoxide under C-H Bond activation and substitution leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound.
Inorganic chemistry 2005;44(5):1199-201.
2004: Umesh N Nehete; Vadapalli Chandrasekhar; Herbert W Roesky; Jörg Magull
The formal conversion of SiOH protons into hydrides by germanium(II) species leads to the formation of the germanium(IV) hydride cluster [(RSiO3GeH)4].
Angewandte Chemie (International ed. in English) 2004;44(2):281-4.
2004: S Shravan Kumar; Herbert W Roesky
Hydroalumination reactions on acetylenes and nitriles in the synthesis of carbaalanes and imidoalanes: an overview.
Dalton transactions (Cambridge, England : 2003) 2004;(23):3927-37.
2004: Herbert W Roesky; Sanjay Singh; Vojtech Jancik; Vadapalli Chandrasekhar
A paradigm change in assembling OH functionalities on metal centers.
Accounts of chemical research 2004;37(12):969-81.
2004: Vojtech Jancik; Herbert W Roesky; Dante Neculai; Ana M Neculai; Regine Herbst-Irmer
Preparation of [LAl(mu-S)2MCp2] (M = Ti, Zr) from the structurally characterized lithium complexes [[LAl(SH)[SLi(thf)2]]2] and [[LAl[(SLi)2(thf)3]]2]2 THF.
Angewandte Chemie (International ed. in English) 2004;43(45):6192-6.
2004: Ying Peng; Hongjun Fan; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer
[LAl(mu-S3)2AlL]: a homobimetallic derivative of the sulfur crown S8.
Angewandte Chemie (International ed. in English) 2004;43(45):6190-2.
2004: Herbert W Roesky
The renaissance of aluminum chemistry.
Inorganic chemistry 2004;43(23):7284-93.
2004: Ying Peng; Haijun Hao; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer; Jörg Magull
Synthesis and structures of aluminium monohydride and chalcogenides bearing a bidentate [N,O] ligand.
Dalton transactions (Cambridge, England : 2003) 2004;(21):3548-51.
2004: Leslie W Pineda; Vojtech Jancik; Herbert W Roesky; Regine Herbst-Irmer
Germacarboxylic acid: an organic-acid analogue based on a heavier group 14 element.
Angewandte Chemie (International ed. in English) 2004;43(41):5534-6.
2004: Ramaswamy Murugavel; Mrinalini G Walawalkar; Meenakshi Dan; Herbert W Roesky; C N R Rao
Transformations of molecules and secondary building units to materials: a bottom-up approach.
Accounts of chemical research 2004;37(10):763-74.
2004: Sanjay Singh; S Shravan Kumar; Vadapalli Chandrasekhar; Hans-Jürgen Ahn; Marianna Biadene; Herbert W Roesky; Narayan S Hosmane; Mathias Noltemeyer; Hans-Georg Schmidt
Tetranuclear homo- and heteroalumoxanes containing reactive functional groups: syntheses and X-ray crystal structures of [[[LAlMe](mu-O)(MH2)]2].
Angewandte Chemie (International ed. in English) 2004;43(37):4940-3.
2004: Herbert W Roesky; Ganapathi Anantharaman; Vadapalli Chandrasekhar; Vojtech Jancik; Sanjay Singh
Control of molecular topology and metal nuclearity in multimetallic assemblies: designer metallosiloxanes derived from silanetriols.
Chemistry (Weinheim an der Bergstrasse, Germany) 2004;10(17):4106-14.
2004: Hongping Zhu; Jianfang Chai; Qingjun Ma; Vojtech Jancik; Herbert W Roesky; Hongjun Fan; Regine Herbst-Irmer
A seven-membered aluminum sulfur allenyl heterocycle arising from the conversion of an aluminacyclopropene with CS2.
Journal of the American Chemical Society 2004;126(33):10194-5.
2004: Hongping Zhu; Jianfang Chai; Vadapalli Chandrasekhar; Herbert W Roesky; Jörg Magull; Denis Vidovic; Hans-Georg Schmidt; Mathias Noltemeyer; Philip P Power; W Alexander Merrill
Two types of intramolecular addition of an Al-N multiple-bonded monomer LAlNAr' arising from the reaction of LAl with N3Ar' (L = HC[(CMe)(NAr)]2, Ar' = 2,6-Ar2C6H3, Ar = 2,6-iPr2C6H3).
Journal of the American Chemical Society 2004;126(31):9472-3.
2004: Umesh N Nehete; Vadapalli Chandrasekhar; Ganapathi Anantharaman; Herbert W Roesky; Denis Vidovic; Jörg Magull
Molecular [(SnO)6] trapped by two [R2Si2O3] fragments: X-ray single-crystal structure of [(SnO)6(R2Si2O3)2].
Angewandte Chemie (International ed. in English) 2004;43(29):3842-4.
2004: Umesh N Nehete; Ganapathi Anantharaman; Vadapalli Chandrasekhar; Ramaswamy Murugavel; Mrinalini G Walawalkar; Herbert W Roesky; Denis Vidovic; Jörg Magull; Konrad Samwer; Björn Sass
Polyhedral ferrous and ferric siloxanes.
Angewandte Chemie (International ed. in English) 2004;43(29):3832-5.
2004: Ying Peng; Hongjun Fan; Hongping Zhu; Herbert W Roesky; Jörg Magull; Colan E Hughes
[[HC(CMeNAr)(2)](2)Al(2)P(4)] (Ar=2,6-iPr(2)C(6)H(3)): a reduction to a formal [P(4)](4-) charged species.
Angewandte Chemie (International ed. in English) 2004;43(26):3443-5.
2004: Andreas Stasch; Herbert W Roesky; Denis Vidovic; Jörg Magull; Hans-Georg Schmidt; Mathias Noltemeyer
Synthesis of carbaalane halogen derivatives.
Inorganic chemistry 2004;43(12):3625-30.
2004: Ganapathi Anantharaman; Vadapalli Chandrasekhar; Mrinalini G Walawalkar; Herbert W Roesky; Denis Vidovic; Jörg Magull; Mathias Noltemeyer
Molecular zinc phosphonates: synthesis and X-ray crystal structures of [[(ZnMe)4(THF)2][tBuPO3]2] and [[(ZnEt)3(Zn(THF))3][tBuPO3]4[mu3-OEt]].
Dalton transactions (Cambridge, England : 2003) 2004;(8):1271-5.
2004: Vojtech Jancik; Leslie W Pineda; Jiri Pinkas; Herbert W Roesky; Dante Neculai; Ana M Neculai; Regine Herbst-Irmer
Preparation of monomeric [LAl(NH2)2]--a main-group metal diamide containing two terminal NH2 groups.
Angewandte Chemie (International ed. in English) 2004;43(16):2142-5.
2004: Leslie W Pineda; Vojtech Jancik; Herbert W Roesky; Dante Neculai; Ana M Neculai
Preparation and structure of the first germanium(II) hydroxide: the congener of an unknown low-valent carbon analogue.
Angewandte Chemie (International ed. in English) 2004;43(11):1419-21.
2004: Ying Peng; Guangcai Bai; Hongjun Fan; Denis Vidovic; Herbert W Roesky; Jörg Magull
Synthesis and structural characterization of a terminal hydroxide containing alumoxane via hydrolysis of aluminum hydrides.
Inorganic chemistry 2004;43(4):1217-9.
2004: Herbert W Roesky; Ramaswamy Murugavel; Mrinalini G Walawalkar
Stabilization of p-block organoelement terminal hydroxides, thiols, and selenols requires newer synthetic strategies.
Chemistry (Weinheim an der Bergstrasse, Germany) 2004;10(2):324-31.
2003: Ana M Neculai; Christopher C Cummins; Dante Neculai; Herbert W Roesky; Gàbor Bunkòczi; Bernhard Walfort; Dietmar Stalke
Elucidation of a Sc(I) complex by DFT calculations and reactivity studies.
Inorganic chemistry 2003;42(26):8803-10.
2003: Andreas Stasch; Herbert W Roesky; Paul von Ragué Schleyer; Jörg Magull
A threefold AlH2-coordinated carbon atom as part of the first carbaalanate.
Angewandte Chemie (International ed. in English) 2003;42(44):5507-9.
2003: Guangcai Bai; Herbert W Roesky; Jiyang Li; Mathias Noltemeyer; Hans-Georg Schmidt
Synthesis, structural characterization, and reaction of the first terminal hydroxide-containing alumoxane with an [[Al(OH)]2(mu-O)] core.
Angewandte Chemie (International ed. in English) 2003;42(44):5502-6.
2003: Ganapathi Anantharaman; Mrinalini G Walawalkar; Ramaswamy Murugavel; Bunkóczi Gábor; Regine Herbst-Irmer; Marc Baldus; Brigitta Angerstein; Herbert W Roesky
A nanoscopic molecular cadmium phosphonate wrapped in a hydrocarbon sheath.
Angewandte Chemie (International ed. in English) 2003;42(37):4482-5.
2003: Marcus Schiefer; N Dastagiri Reddy; Hans-Jürgen Ahn; Andreas Stasch; Herbert W Roesky; A Christine Schlicker; Hans-Georg Schmidt; Mathias Noltemeyer; Denis Vidovic
Neutral and ionic aluminum, gallium, and indium compounds carrying two or three terminal ethynyl groups.
Inorganic chemistry 2003;42(16):4970-6.
2003: Herbert W Roesky; Ionel Haiduc; Narayan S Hosmane
Organometallic oxides of main group and transition elements downsizing inorganic solids to small molecular fragments.
Chemical reviews 2003;103(7):2579-95.
2003: Guangcai Bai; Qingjun Ma; Herbert W Roesky; Denis Vidovic; Regine Herbst-Irmer
New synthetic route for organic polyoxometallic clusters: synthetic and structural investigations on the first dumb-bell shaped polyoxozirconium hydroxide with the [Zr9(mu5-O)2(mu3-O)4(mu-O)4(mu-OH)8] core structure.
Chemical communications (Cambridge, England) 2003;(7):898-9.
2003: Guangcai Bai; Ying Peng; Herbert W Roesky; Jiyang Li; Hans-Georg Schmidt; Mathias Noltemeyer
Aluminum dihydroxide with terminal OH groups: an unprecedented congener of boronic acid.
Angewandte Chemie (International ed. in English) 2003;42(10):1132-5.
2003: Ganapathi Anantharaman; Herbert W Roesky; Hans-Georg Schmidt; Mathias Noltemeyer; Jiri Pinkas
Synthesis and x-ray crystal structure of [(THF)Zn(O(2)(OH)SiR)](4) (R = (2,6-i-Pr(2)C(6)H(3))N(SiMe(3))): enroute to larger aggregates.
Inorganic chemistry 2003;42(4):970-3.
2003: Vojtech Jancik; Ying Peng; Herbert W Roesky; Jiyang Li; Dante Neculai; Ana M Neculai; Regine Herbst-Irmer
The first structurally characterized aluminum compound with two SH groups: [LAl(SH)(2)] (L = N(Ar)C(Me)CHC(Me)N(Ar), Ar = 2,6-i-Pr(2)C(6)H(3)) and the catalytic properties of the sulfur P(NMe(2))(3) system.
Journal of the American Chemical Society 2003;125(6):1452-3.
2003: Michael Gorol; Nadia C Mösch-Zanetti; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Unprecedented stabilisation of the Ag2(2+)-ion by two hydrido-iridium(III) complexes.
Chemical communications (Cambridge, England) 2003;(1):46-7.
2002: Jiri Pinkas; Jiri Löbl; Dalibor Dastych; Marek Necas; Herbert W Roesky
Adamantane-like aluminum amide-phosphate from alumazene.
Inorganic chemistry 2002;41(25):6914-8.
2002: Dante Neculai; Herbert W Roesky; Ana M Neculai; Jörg Magull; Bernhard Walfort; Dietmar Stalke
Formation and characterization of the first monoalumoxane, LAlO.B(C6F5)3.
Angewandte Chemie (International ed. in English) 2002;41(22):4294-6.
2002: Augustin M Madalan; Herbert W Roesky; Marius Andruh; Mathias Noltemeyer; Nicolae Stanica
The first coordination compound containing three different types of spin carriers: 2p-3d-4f (TCNQ.-, Cu2+ and Gd3+).
Chemical communications (Cambridge, England) 2002;(15):1638-9.
2002: Yuqiang Ding; Qingjun Ma; Isabel Usón; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Synthesis and structures of [[HC(CMeNAr)(2)]Ge(S)X] (Ar = 2,6-iPr(2)C(6)H(3), X = F, Cl, Me): structurally characterized examples with a formal double bond between group 14 and 16 elements bearing a halide.
Journal of the American Chemical Society 2002;124(29):8542-3.
2002: Andreas Stasch; Marilena Ferbinteanu; Jörg Prust; Wenjun Zheng; Fanica Cimpoesu; Herbert W Roesky; Jörg Magull; Hans-Georg Schmidt; Mathias Noltemeyer
Syntheses, structures, and surface aromaticity of the new carbaalane [(AlH)(6)(AlNMe(3))(2)(CCH(2)R)(6)] (R = Ph, CH(2)SiMe(3)) and a stepwise functionalization of the inner and outer sphere of the cluster.
Journal of the American Chemical Society 2002;124(19):5441-8.
2002: N Dastagiri Reddy; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Reactions of AlH(3) x NMe(3) with nitriles: structural characterization and substitution reactions of hexameric aluminum imides.
Inorganic chemistry 2002;41(9):2374-8.
2002: Jörg Janssen; Jörg Magull; Herbert W Roesky
X-ray structural characterization of a monoorganotin acid.
Angewandte Chemie (International ed. in English) 2002;41(8):1365-7.
2002: Ganapathi Anantharaman; Herbert W Roesky; Jörg Magull
[Zn4(thf)(4)(MeZn)(4)(O(3)SiR)(4)] (R=2,6-iPr(2)C(6)H(3)N(SiMe3)), a compound containing trigonal-planar, tetrahedral, and trigonal-bipyramidal metal atoms: a new route to larger aggregates.
Angewandte Chemie (International ed. in English) 2002;41(7):1226-9.
2002: Hagen Hatop; Marilena Ferbinteanu; Herbert W Roesky; Fanica Cimpoesu; Marcus Schiefer; Hans-Georg Schmidt; Mathias Noltemeyer
Lightest member of the basic carboxylate structural pattern: [Al(3)(mu)-O)(mu(2)CCF(3))(6)(THF)(3)][(Me(3)Si)(3)CAl(O(2)CCF(3))(3)] x C(7)H(8).
Inorganic chemistry 2002;41(4):1022-5.
2001: Herbert W Roesky
A facile and environmentally friendly disposal of sodium and potassium with water.
Inorganic chemistry 2001;40(26):6855-6.
2001: C Cui; Sinje Köpke; Regine Herbst-Irmer; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt; B Wrackmeyer
Facile synthesis of cyclopropene analogues of aluminum and an aluminum pinacolate, and the reactivity of LAl[eta(2)-C(2)(SiMe(3))(2)] toward unsaturated molecules (L=HC[(CMe)(NAr)](2), Ar=2,6-i-Pr(2)C(6)H(3)).
Journal of the American Chemical Society 2001;123(37):9091-8.
2001: Marilena Ferbinteanu; Herbert W Roesky; Fanica Cimpoesu; M Atanasov; Sinje Köpke; Regine Herbst-Irmer
New synthetic and structural aspects in the chemistry of alkylaluminum fluorides. The mutual influence of hard and soft ligands and the hybridization as rigorous structural criterion.
Inorganic chemistry 2001;40(19):4947-55.
2001: C Ackerhans; P Böttcher; Paul Müller; Herbert W Roesky; Isabel Usón; Hans-Georg Schmidt; Mathias Noltemeyer
Halogenodisilanes: precursors for new disilane derivatives.
Inorganic chemistry 2001;40(15):3766-73.
2001: Matthias Stender; Barrett E Eichler; Ned J Hardman; Philip P Power; Jörg Prust; Mathias Noltemeyer; Herbert W Roesky
Synthesis and characterization of HC[C(Me)N(C(6)H(3)-2,6-i-Pr(2))](2)MX(2) (M = Al, X = Cl, I; M = Ga, In, X = Me, Cl, I): sterically encumbered beta-diketiminate group 13 metal derivatives.
Inorganic chemistry 2001;40(12):2794-9.
2001: D Chakraborty; S Horchler; R Krätzner; S P Varkey; Jiri Pinkas; Herbert W Roesky; Isabel Usón; Mathias Noltemeyer; Hans-Georg Schmidt
Synthesis and structural characterization of functionalized dimeric aluminophosphonates and a monomeric gallophosphonate anion.
Inorganic chemistry 2001;40(11):2620-4.
2001: S P Varkey; M Schormann; T Pape; Herbert W Roesky; Mathias Noltemeyer; Regine Herbst-Irmer; Hans-Georg Schmidt
Organotitanoxanes [C(5)Me(5)TiMe(2)](2)(mu-O) and [(C(5)Me(5)(4)Ti(4)Me(2)](mu-O)(5): synthesis and crystal structures.
Inorganic chemistry 2001;40(10):2427-9.
2001: G Bai; Herbert W Roesky; H Hao; Mathias Noltemeyer; Hans-Georg Schmidt
Synthesis of the titanium compound [(MeC(5)H(4)TiCl(mu-NSiMe(3)](2) with migration of a SiMe(3) group and preparation of CpZrCl(eta(2)-NHNCHSiMe(3)).
Inorganic chemistry 2001;40(10):2424-6.
2001: W Zheng; H Hohmeister; Nadia C Mösch-Zanetti; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Syntheses and characterization of mu,eta(1),eta(1)-3,5-di-tert-butylpyrazolato derivatives of aluminum.
Inorganic chemistry 2001;40(10):2363-7.
2001: Herbert W Roesky; Mrinalini G Walawalkar; Ramaswamy Murugavel
Is water a friend or foe in organometallic chemistry? The case of group 13 organometallic compounds.
Accounts of chemical research 2001;34(3):201-11.
2000: P Müller; Isabel Usón; Jörg Prust; Herbert W Roesky
Tetrameric indium trichloride, a new modification of a widely used compound.
Acta crystallographica. Section C, Crystal structure communications 2000;56 Pt 11():1300-1.
2000: D Chakraborty; S Horchler; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Application of n-Bu4NHF2 as a fluorinating agent for the preparation of fluoroanions: synthesis and crystal structure of the anions [t-BuPO3AlF2]2(2-), [PhPO3AlF2]2(2-), and [(O-i-Pr)3Ti(mu-F)2(mu-O-i-Pr)Ti(O-i-Pr)3]-.
Inorganic chemistry 2000;39(18):3995-8.
2000: C Cui; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Syntheses and structures of the arylaluminum chalcogenides (ArAlE)2 (Ar = 2-(NEt2CH2)-6-MeC6H3, E = Se; Ar = 2,6-(NEt2CH2)2C6H3, E = Se, Te).
Inorganic chemistry 2000;39(16):3678-81.
2000: O I Guzyr; R Siefken; D Chakraborty; Herbert W Roesky; M Teichert
Synthesis and structure of organic-soluble binuclear molecular phosphonates of tantalum, molybdenum, and tungsten.
Inorganic chemistry 2000;39(8):1680-3.
2000: D Chakraborty; Vadapalli Chandrasekhar; M Bhattacharjee; R Krätzner; Herbert W Roesky; Mathias Noltemeyer; Hans-Georg Schmidt
Metal alkoxides as versatile precursors for group 4 phosphonates: synthesis and X-ray structure of a novel organosoluble zirconium phosphonate.
Inorganic chemistry 2000;39(1):23-6.