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Scott Rychnovsky

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TOP 3
Matthew A Perry; Richard R Hill; Scott D Rychnovsky
Trianion synthon approach to spirocyclic heterocycles.
Alexander J Wagner; Scott D Rychnovsky
Determination of absolute configuration of secondary alcohols using thin-layer chromatography.
Leah Cleary; Victor W Mak; Scott D Rychnovsky; Kenneth J Shea; Nicholas Sizemore
Origins of regio- and stereochemistry in type 2 intramolecular N-acylnitroso diels-alder reactions: a computational study of tether length and substituent effects.

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All Publications

2013: Matthew A Perry; Richard R Hill; Scott D Rychnovsky
Trianion synthon approach to spirocyclic heterocycles.
Organic letters 2013;15(9):2226-9.
2013: Alexander J Wagner; Scott D Rychnovsky
Determination of absolute configuration of secondary alcohols using thin-layer chromatography.
The Journal of organic chemistry 2013;78(9):4594-8.
2013: Leah Cleary; Victor W Mak; Scott D Rychnovsky; Kenneth J Shea; Nicholas Sizemore
Origins of regio- and stereochemistry in type 2 intramolecular N-acylnitroso diels-alder reactions: a computational study of tether length and substituent effects.
The Journal of organic chemistry 2013;78(8):4090-8.
2013: Matthew A Perry; Jonathan V Trinidad; Scott D Rychnovsky
Absolute configuration of lactams and oxazolidinones using kinetic resolution catalysts.
Organic letters 2013;15(3):472-5.
2012: Shawn M Miller; Renzo A Samame; Scott D Rychnovsky
Nanomole-scale assignment of configuration for primary amines using a kinetic resolution strategy.
Journal of the American Chemical Society 2012;134(50):20318-21.
2012: Athit Kao; Vishal R Patel; Arlo Randall; Scott D Rychnovsky; Yingying Yang; Pierre Baldi; Shenheng Guan; Wynne Kandur; Lan Huang
Mapping the structural topology of the yeast 19S proteasomal regulatory particle using chemical cross-linking and probabilistic modeling.
Molecular & cellular proteomics : MCP 2012;11(12):1566-77.
2012: Ika Kristiana; Winnie Luu; Scott D Rychnovsky; Julian Stevenson; Jitendra D Belani; Sian Cartland; Wendy Jessup; Andrew J Brown
Cholesterol through the looking glass: ability of its enantiomer also to elicit homeostatic responses.
The Journal of biological chemistry 2012;287(40):33897-904.
2012: Matthew A Perry; Matthew D Morin; Brian W Slafer; Scott D Rychnovsky
Total synthesis of lepadiformine alkaloids using N-Boc α-amino nitriles as trianion synthons.
The Journal of organic chemistry 2012;77(7):3390-400.
2011: Alexander J Wagner; Jonathan G David; Scott D Rychnovsky
Determination of absolute configuration using kinetic resolution catalysts.
Organic letters 2011;13(16):4470-3.
2011: Michael R Gesinski; Scott D Rychnovsky
Total synthesis of the cyanolide A aglycon.
Journal of the American Chemical Society 2011;133(25):9727-9.
2011: Athit Kao; Chi-li Chiu; Danielle Vellucci; Yingying Yang; Vishal R Patel; Shenheng Guan; Arlo Randall; Pierre Baldi; Scott D Rychnovsky; Lan Huang
Development of a novel cross-linking strategy for fast and accurate identification of cross-linked peptides of protein complexes.
Molecular & cellular proteomics : MCP 2011;10(1):M110.002212.
2010: Maureen K Reilly; Scott D Rychnovsky
Allyl transfer to aldehydes and ketones by Brønsted acid activation of allyl and crotyl 1,3,2-dioxazaborolidines.
Organic letters 2010;12(21):4892-5.
2010: Danielle Vellucci; Athit Kao; Robyn M Kaake; Scott D Rychnovsky; Lan Huang
Selective enrichment and identification of azide-tagged cross-linked peptides using chemical ligation and mass spectrometry.
Journal of the American Society for Mass Spectrometry 2010;21(8):1432-45.
2010: Matthew A Perry; Matthew D Morin; Brian W Slafer; Scott A Wolckenhauer; Scott D Rychnovsky
Fully substituted carbon centers by diastereoselective spirocyclization: stereoselective synthesis of (+)-lepadiformine C.
Journal of the American Chemical Society 2010;132(28):9591-3.
2010: Yoshitaka Nakamura; Anthony M Burke; Shunsuke Kotani; Joseph W Ziller; Scott D Rychnovsky
Total synthesis of (-)-lycoperine A.
Organic letters 2010;12(1):72-5.
2009: Michael R Gesinski; Kwanruthai Tadpetch; Scott D Rychnovsky
Symmetric macrocycles by a Prins dimerization and macrocyclization strategy.
Organic letters 2009;11(22):5342-5.
2009: Viengkham Malathong; Scott D Rychnovsky
Polyol synthesis with beta-oxyanionic alkyllithium reagents: syntheses of aculeatins A, B, and D.
Organic letters 2009;11(18):4220-3.
2008: Kwanruthai Tadpetch; Scott D Rychnovsky
Rhenium(VII) catalysis of Prins cyclization reactions.
Organic letters 2008;10(21):4839-42.
2008: Kevin Bahnck; Scott D Rychnovsky
Formal synthesis of (-)-kendomycin featuring a Prins-cyclization to construct the macrocycle.
Journal of the American Chemical Society 2008;130(39):13177-81.
2008: Robert J Bahde; Scott D Rychnovsky
Cyclization via carbolithiation of alpha-amino alkyllithium reagents.
Organic letters 2008;10(18):4017-20.
2008: Lael L Cheung; Shinji Marumoto; Christopher D Anderson; Scott D Rychnovsky
Assignment of absolute configuration to SCH 351448 via total synthesis.
Organic letters 2008;10(14):3101-4.
2008: Jitendra D Belani; Scott D Rychnovsky
A concise synthesis of ent-Cholesterol.
The Journal of organic chemistry 2008;73(7):2768-73.
2007: Richard M Epand; Yulia V Shulga; Heath C Timmons; Alexandra L Perri; Jitendra D Belani; Kirishanth Perinpanathan; Laura Beth Johnson-McIntire; Sandra Bajjalieh; Armela O Dicu; Cynthia Elias; Scott D Rychnovsky; Matthew K Topham
Substrate chirality and specificity of diacylglycerol kinases and the multisubstrate lipid kinase.
Biochemistry 2007;46(49):14225-31.
2007: Xia Tian; Scott D Rychnovsky
Synthesis and structural reassignment of (+)-epicalyxin F.
Organic letters 2007;9(24):4955-8.
2007: John R Huckins; Javier de Vicente; Scott D Rychnovsky
Synthesis of the C1-C52 fragment of amphidinol 3, featuring a beta-alkoxy alkyllithium addition reaction.
Organic letters 2007;9(23):4757-60.
2007: Lori J Van Orden; Brian D Patterson; Scott D Rychnovsky
Total synthesis of leucascandrolide a: a new application of the Mukaiyama aldol-Prins reaction.
The Journal of organic chemistry 2007;72(15):5784-93.
2007: Thomas E La Cruz; Scott D Rychnovsky
A reductive cyclization approach to attenol A.
The Journal of organic chemistry 2007;72(7):2602-11.
2007: Danielle Vellucci; Scott D Rychnovsky
Diastereoselective synthesis of the pectenotoxin 2 non-anomeric AB spiroacetal.
Organic letters 2007;9(4):711-4.
2006: Nikolaus M Loening; Carolyn E Anderson; Wendy S Iskenderian; Christopher D Anderson; Scott D Rychnovsky; Michael Barfield; Daniel J O'Leary
Qualitative and quantitative measurements of hydrogen bond mediated scalar couplings in acyclic 1,3-diols.
Organic letters 2006;8(23):5321-3.
2006: Javier de Vicente; John R Huckins; Scott D Rychnovsky
Synthesis of the C31-C67 fragment of amphidinol 3.
Angewandte Chemie (International ed. in English) 2006;45(43):7258-62.
2006: Ramesh Jasti; Scott D Rychnovsky
Racemization in Prins cyclization reactions.
Journal of the American Chemical Society 2006;128(41):13640-8.
2006: John A Porco; Shun Su; Xiaoguang Lei; Sujata Bardhan; Scott D Rychnovsky
Total synthesis and structure assignment of (+)-hexacyclinol.
Angewandte Chemie (International ed. in English) 2006;45(35):5790-2.
2006: Scott D Rychnovsky
Predicting NMR spectra by computational methods: structure revision of hexacyclinol.
Organic letters 2006;8(13):2895-8.
2006: Kevin Bahnck; Scott D Rychnovsky
Rapid stereocontrolled assembly of the fully substituted C-aryl glycoside of kendomycin with a Prins cyclization: a formal synthesis.
Chemical communications (Cambridge, England) 2006;(22):2388-90.
2006: Ramesh Jasti; Scott D Rychnovsky
Solvolysis of a tetrahydropyranyl mesylate: mechanistic implications for the Prins cyclization, 2-oxonia-cope rearrangement, and Grob fragmentation.
Organic letters 2006;8(10):2175-8.
2006: Xia Tian; James J Jaber; Scott D Rychnovsky
Synthesis and structure revision of calyxin natural products.
The Journal of organic chemistry 2006;71(8):3176-83.
2006: Thomas E La Cruz; Scott D Rychnovsky
Stereoselectivity of intramolecular SN' cyclizations of alkyllithium reagents on methoxy alkenes.
The Journal of organic chemistry 2006;71(3):1068-73.
2005: Carolyn E Anderson; David K Britt; Sheharbano Sangji; Daniel J O'Leary; Christopher D Anderson; Scott D Rychnovsky
Direct assignment of the relative configuration in acyclic 1,3-diols by 1H NMR spectroscopy.
Organic letters 2005;7(25):5721-3.
2005: Megan L Bolla; Brian Patterson; Scott D Rychnovsky
Tetrahydropyran rings from a Mukaiyama-Michael cascade reaction.
Journal of the American Chemical Society 2005;127(46):16044-5.
2005: Christopher D Anderson; Kenneth J Shea; Scott D Rychnovsky
Strategies for the generation of molecularly imprinted polymeric nitroxide catalysts.
Organic letters 2005;7(22):4879-82.
2005: Fang Xu; Scott D Rychnovsky; Jitendra D Belani; Helen H Hobbs; Jonathan C Cohen; Robert B Rawson
Dual roles for cholesterol in mammalian cells.
Proceedings of the National Academy of Sciences of the United States of America 2005;102(41):14551-6.
2005: Richard M Epand; Scott D Rychnovsky; Jitendra D Belani; Raquel F Epand
Role of chirality in peptide-induced formation of cholesterol-rich domains.
The Biochemical journal 2005;390(Pt 2):541-8.
2005: Justin P Vitale; Scott A Wolckenhauer; Nga M Do; Scott D Rychnovsky
Synthesis of the C3-C19 segment of phorboxazole B.
Organic letters 2005;7(15):3255-8.
2005: Ramesh Jasti; Christopher D Anderson; Scott D Rychnovsky
Utilization of an oxonia-Cope rearrangement as a mechanistic probe for Prins cyclizations.
Journal of the American Chemical Society 2005;127(27):9939-45.
2005: Matthew D Morin; Scott D Rychnovsky
Reductive spiroannulation of nitriles with secondary electrophiles.
Organic letters 2005;7(10):2051-3.
2005: Thomas E La Cruz; Scott D Rychnovsky
Synthesis of the spirofungin B core by a reductive cyclization strategy.
Organic letters 2005;7(9):1873-5.
2005: Javier de Vicente; Bodo Betzemeier; Scott D Rychnovsky
A C-glycosidation approach to the central core of amphidinol 3: synthesis of the c39-c52 fragment.
Organic letters 2005;7(9):1853-6.
2005: Jackline E Dalgard; Scott D Rychnovsky
Enantioselective synthesis of the C18-C25 segment of lasonolide A by an oxonia-cope prins cascade.
Organic letters 2005;7(8):1589-91.
2005: Leo R Takaoka; Alexandre J Buckmelter; Thomas E LaCruz; Scott D Rychnovsky
Rational synthesis of contra-thermodynamic spiroacetals by reductive cyclizations.
Journal of the American Chemical Society 2005;127(2):528-9.
2004: Jackline E Dalgard; Scott D Rychnovsky
Oxonia-cope prins cyclizations: a facile method for the synthesis of tetrahydropyranones bearing quaternary centers.
Journal of the American Chemical Society 2004;126(48):15662-3.
2004: Ramesh Jasti; Justin P Vitale; Scott D Rychnovsky
Axial-selective prins cyclizations by solvolysis of alpha-bromo ethers.
Journal of the American Chemical Society 2004;126(32):9904-5.
2004: Isao Kadota; Yueqing Hu; Garrick K Packard; Scott D Rychnovsky
A unified approach to polyene macrolides: synthesis of candidin and nystatin polyols.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(33):11992-5.
2004: Scott A Wolckenhauer; Scott D Rychnovsky
Generation and utility of tertiary alpha-aminoorganolithium reagents.
Organic letters 2004;6(16):2745-8.
2004: Jackline E Dalgard; Scott D Rychnovsky
Memory of chirality in the transannular cyclization of cyclodecenyl radicals.
Organic letters 2004;6(16):2713-6.
2004: Garrick K Packard; Yueqing Hu; Andrea Vescovi; Scott D Rychnovsky
Synthesis of rimocidinolide methyl ester, the aglycone of (+)-rimocidin.
Angewandte Chemie (International ed. in English) 2004;43(21):2822-6.
2004: Thomas E La Cruz; Scott D Rychnovsky
Intramolecular S(N)2' cyclization of an alkyllithium species onto a methoxy allyl ether is syn selective.
Chemical communications (Cambridge, England) 2004;(2):168-9.
2004: Rowena K Richter; Daniel E Mickus; Scott D Rychnovsky; Tadeusz F Molinski
Differential modulation of the antifungal activity of amphotericin B by natural and ent-cholesterol.
Bioorganic & medicinal chemistry letters 2004;14(1):115-8.
2003: John R Huckins; Scott D Rychnovsky
Synthesis of optically pure arylsilylcarbinols and their use as chiral auxiliaries in oxacarbenium ion reactions.
The Journal of organic chemistry 2003;68(26):10135-45.
2003: Benjamin R Graetz; Scott D Rychnovsky
Formal synthesis of (-)-apicularen A.
Organic letters 2003;5(18):3357-60.
2003: Brian Patterson; Shinji Marumoto; Scott D Rychnovsky
Titanium(IV)-promoted Mukaiyama aldol-Prins cyclizations.
Organic letters 2003;5(17):3163-6.
2003: Scott D Rychnovsky; Jennifer Cossrow
Diastereoselective additions of nucleophiles to alpha-acetoxy ethers using the alpha-(trimethylsilyl)benzyl auxiliary.
Organic letters 2003;5(13):2367-70.
2003: Angie I Kim; Scott D Rychnovsky
Unified strategy for the synthesis of (-)-elisapterosin B and (-)-colombiasin A.
Angewandte Chemie (International ed. in English) 2003;42(11):1267-70.
2003: Scott D Rychnovsky; Leo R Takaoka
Spiroannulation by alkylation and reductive cyclization of nitriles.
Angewandte Chemie (International ed. in English) 2003;42(7):818-20.
2002: Shinji Marumoto; James J Jaber; Justin P Vitale; Scott D Rychnovsky
Synthesis of (-)-centrolobine by Prins cyclizations that avoid racemization.
Organic letters 2002;4(22):3919-22.
2002: Christopher D Anderson; Scott D Rychnovsky
Empirical model for the molar rotations of syn-2,2-dimethyl-1,3-dioxanes.
Organic letters 2002;4(18):3075-8.
2002: Jennifer Cossrow; Scott D Rychnovsky
Optically pure alpha-(trimethylsilyl)benzyl alcohol: a practical chiral auxiliary for oxocarbenium ion reactions.
Organic letters 2002;4(1):147-50.
2001: Scott D Rychnovsky; Shinji Marumoto; James J Jaber
Role of 2-oxonia Cope rearrangements in Prins cyclization reactions.
Organic letters 2001;3(23):3815-8.
2001: Garrick K Packard; Scott D Rychnovsky
Beta-selective glycosylations with masked D-mycosamine precursors.
Organic letters 2001;3(21):3393-6.
2001: D J Kopecky; Scott D Rychnovsky
Mukaiyama aldol-Prins cyclization cascade reaction: a formal total synthesis of leucascandrolide A.
Journal of the American Chemical Society 2001;123(34):8420-1.
2001: James J Jaber; K Mitsui; Scott D Rychnovsky
Stereoselectivity and regioselectivity in the segment-coupling Prins cyclization.
The Journal of organic chemistry 2001;66(13):4679-86.
2001: Scott D Rychnovsky; T Hata; Angie I Kim; A J Buckmelter
Use of a conformational radical clock for evaluating alkyllithium-mediated cyclization reactions.
Organic letters 2001;3(6):807-10.
2000: D J Kopecky; Scott D Rychnovsky
Improved procedure for the reductive acetylation of acyclic esters and a new synthesis of ethers.
The Journal of organic chemistry 2000;65(1):191-8.