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Raffaele Saladino

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Raffaele Saladino; Ignacio Celestino; Paola Checconi; Lucia Nencioni; Veronica Neri; Anna Teresa Palamara; Marcello Crucianelli
Synthesis of 2'-deoxy-1'-homo-N-nucleosides with anti-influenza activity by catalytic methyltrioxorhenium (MTO)/H2O2 oxyfunctionalization.
Raffaele Saladino; Samanta Pino; Giorgia Botta; Giovanna Costanzo; Ernesto Di Mauro
Genetics first or metabolism first? The formamide clue.
Raffaele Saladino; Samanta Pino; Giorgia Botta; Giovanna Costanzo; Ernesto Di Mauro
From the one-carbon amide formamide to RNA all the steps are prebiotically possible.

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All Publications

2013: Raffaele Saladino; Ignacio Celestino; Paola Checconi; Lucia Nencioni; Veronica Neri; Anna Teresa Palamara; Marcello Crucianelli
Synthesis of 2'-deoxy-1'-homo-N-nucleosides with anti-influenza activity by catalytic methyltrioxorhenium (MTO)/H2O2 oxyfunctionalization.
Chemistry (Weinheim an der Bergstrasse, Germany) 2013;19(7):2392-404.
2012: Raffaele Saladino; Samanta Pino; Giorgia Botta; Giovanna Costanzo; Ernesto Di Mauro
Genetics first or metabolism first? The formamide clue.
Chemical Society reviews 2012;41(16):5526-65.
2012: Raffaele Saladino; Samanta Pino; Giorgia Botta; Giovanna Costanzo; Ernesto Di Mauro
From the one-carbon amide formamide to RNA all the steps are prebiotically possible.
Biochimie 2012;94(7):1451-6.
2012: Patricio Leyton; C Paipa; Raffaele Saladino; A Berríos; MM Campos-Vallette; Claudia Crestini; S Fuentes; R A Zárate
Influence of TiO2 on prebiotic thermal synthesis of the Gly-Gln polymer.
Amino acids 2012;42(6):2079-88.
2012: Giovanna Costanzo; Giorgia Botta; Alessandra Giorgi; Samanta Pino; Raffaele Saladino; Anita Scipioni; Ernesto Di Mauro
Generation of RNA molecules by a base-catalysed click-like reaction.
Chembiochem : a European journal of chemical biology 2012;13(7):999-1008.
2012: Raffaele Saladino; G Botta; Marcello Crucianelli
Advances in the synthesis of bioactive unnatural amino acids and peptides.
Mini reviews in medicinal chemistry 2012;12(4):277-300.
2012: Raffaele Saladino; Samanta Pino; Giovanna Costanzo; Claudia Crestini; Ernesto Di Mauro
Formamide and the origin of life.
Physics of life reviews 2012;9(1):84-104.
2012: G Botta; L P De Santis; Raffaele Saladino
Current advances in the synthesis and antitumoral activity of SIRT1-2 inhibitors by modulation of p53 and pro-apoptotic proteins.
Current medicinal chemistry 2012;19(34):5871-84.
2011: Claudia Crestini; Federica Melone; Marco Sette; Raffaele Saladino
Milled wood lignin: a linear oligomer.
Biomacromolecules 2011;12(11):3928-35.
2011: Raffaele Saladino; Emanuele Pace; Giorgia Botta; John R Brucato; Antonio De Sio; Lisa Gambicorti
Photochemical synthesis of citric acid cycle intermediates based on titanium dioxide.
Astrobiology 2011;11(8):815-24.
2011: Raffaele Saladino; Ernesto Di Mauro; Cristina Cossetti; Claudia Crestini; David Deamer
Catalytic effects of Murchison material: prebiotic synthesis and degradation of RNA precursors.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life 2011;41(5):437-51.
2011: Claudia Crestini; Federica Melone; Raffaele Saladino
Novel multienzyme oxidative biocatalyst for lignin bioprocessing.
Bioorganic & medicinal chemistry 2011;19(16):5071-8.
2011: Raffaele Saladino; Ernesto Di Mauro; Maurizio Barontini; Cristina Cossetti; Claudia Crestini
The effects of borate minerals on the synthesis of nucleic acid bases, amino acids and biogenic carboxylic acids from formamide.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life 2011;41(4):317-30.
2011: Raffaella Perazzini; Raffaele Saladino; MR Guazzaroni; Claudia Crestini
A novel and efficient oxidative functionalization of lignin by layer-by-layer immobilised Horseradish peroxidase.
Bioorganic & medicinal chemistry 2011;19(1):440-7.
2010: Raffaele Saladino; Veronica Neri; Claudia Crestini; Giovanna Costanzo; Michele Graciotti; Ernesto Di Mauro
The role of the formamide/zirconia system in the synthesis of nucleobases and biogenic carboxylic acid derivatives.
Journal of molecular evolution 2010;71(2):100-10.
2010: Raffaele Saladino; M Barontini; M Crucianelli; Nencioni Lucia; Rossella Sgarbanti; Anna Teresa Palamara
Current advances in anti-influenza therapy.
Current medicinal chemistry 2010;17(20):2101-40.
2009: Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Samanta Pino; Giovanna Costanzo; Ernesto Di Mauro
From formamide to RNA: the roles of formamide and water in the evolution of chemical information.
Research in microbiology 2009;160(7):441-8.
2009: Roberta Bernini; Giampiero Gualandi; Claudia Crestini; Maurizio Barontini; Maria Cristina Belfiore; Stefan Willför; Patrik C Eklund; Raffaele Saladino
A novel and efficient synthesis of highly oxidized lignans by a methyltrioxorhenium/hydrogen peroxide catalytic system. Studies on their apoptogenic and antioxidant activity.
Bioorganic & medicinal chemistry 2009;17(15):5676-82.
2008: Raffaele Saladino; Veronica Neri; Claudia Crestini; Giovanna Costanzo; Michele Graciotti; Ernesto Di Mauro
Synthesis and degradation of nucleic acid components by formamide and iron sulfur minerals.
Journal of the American Chemical Society 2008;130(46):15512-8.
2008: Fabiana Ciciriello; Giovanna Costanzo; Samanta Pino; Claudia Crestini; Raffaele Saladino; Ernesto Di Mauro
Molecular complexity favors the evolution of ribopolymers.
Biochemistry 2008;47(9):2732-42.
2008: Raffaele Saladino; Giampiero Gualandi; Angela Farina; Claudia Crestini; Nencioni Lucia; Anna Teresa Palamara
Advances and challenges in the synthesis of highly oxidised natural phenols with antiviral, antioxidant and cytotoxic activities.
Current medicinal chemistry 2008;15(15):1500-19.
2007: Fabiana Ciciriello; Giovanna Costanzo; Claudia Crestini; Raffaele Saladino; Ernesto Di Mauro
Origin of informational polymers and the search for non-terran life: protection of the polymeric state of DNA by phosphate minerals.
Astrobiology 2007;7(4):616-30.
2007: Giovanna Costanzo; Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Ernesto Di Mauro
Nucleoside phosphorylation by phosphate minerals.
The Journal of biological chemistry 2007;282(23):16729-35.
2007: Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Giovanna Costanzo; Ernesto Di Mauro
Formamide chemistry and the origin of informational polymers.
Chemistry & biodiversity 2007;4(4):694-720.
2007: Giovanna Costanzo; Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Ernesto Di Mauro
Formamide as the main building block in the origin of nucleic acids.
BMC evolutionary biology 2007;7 Suppl 2():S1.
2007: Raffaele Saladino; Cinzia Fiani; Claudia Crestini; Dimitris S Argyropoulos; Stefano Marini; Massimiliano Coletta
An efficient and stereoselective dearylation of asarinin and sesamin tetrahydrofurofuran lignans to acuminatolide by methyltrioxorhenium/H(2)O(2) and UHP systems.
Journal of natural products 2007;70(1):39-42.
2006: Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Giovanna Costanzo; Ernesto Di Mauro
About a formamide-based origin of informational polymers: syntheses of nucleobases and favourable thermodynamic niches for early polymers.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life 2006;36(5-6):523-31.
2006: Raffaele Saladino; Claudia Crestini; Veronica Neri; Fabiana Ciciriello; Giovanna Costanzo; Ernesto Di Mauro
Origin of informational polymers: The concurrent roles of formamide and phosphates.
Chembiochem : a European journal of chemical biology 2006;7(11):1707-14.
2006: Orazio A Attanasi; Stefano Berretta; Gianfranco Favi; Paolino Filippone; Giuseppe Mele; Giada Moscatelli; Raffaele Saladino
Tetrabromo hydrogenated cardanol: Efficient and renewable brominating agent.
Organic letters 2006;8(19):4291-3.
2006: Claudia Crestini; Maria Chiara Caponi; Dimitris S Argyropoulos; Raffaele Saladino
Immobilized methyltrioxo rhenium (MTO)/H2O2 systems for the oxidation of lignin and lignin model compounds.
Bioorganic & medicinal chemistry 2006;14(15):5292-302.
2006: Raffaele Saladino; Claudia Crestini; Fabiana Ciciriello; Ernesto Di Mauro; Giovanna Costanzo
Origin of informational polymers: differential stability of phosphoester bonds in ribomonomers and ribooligomers.
The Journal of biological chemistry 2006;281(9):5790-6.
2005: Raffaele Saladino; Cinzia Fiani; Maria Cristina Belfiore; Giampiero Gualandi; Sabrina Penna; Pasquale Mosesso
Methyltrioxorhenium catalysed synthesis of highly oxidised aryltetralin lignans with anti-topoisomerase II and apoptogenic activities.
Bioorganic & medicinal chemistry 2005;13(21):5949-60.
2005: Raffaele Saladino; Claudia Crestini; Vincenzo Busiello; Fabiana Ciciriello; Giovanna Costanzo; Ernesto Di Mauro
Origin of informational polymers. Differential stability of 3'- and 5'-phosphoester bonds in deoxy monomers and oligomers.
The Journal of biological chemistry 2005;280(42):35658-69.
2005: Raffaele Saladino; Claudia Crestini; Veronica Neri; John R Brucato; Luigi Colangeli; Fabiana Ciciriello; Ernesto Di Mauro; Giovanna Costanzo
Synthesis and degradation of nucleic Acid components by formamide and cosmic dust analogues.
Chembiochem : a European journal of chemical biology 2005;6(8):1368-74.
2005: Claudia Crestini; Paola Pro; Veronica Neri; Raffaele Saladino
Methyltrioxorhenium: a new catalyst for the activation of hydrogen peroxide to the oxidation of lignin and lignin model compounds.
Bioorganic & medicinal chemistry 2005;13(7):2569-78.
2004: Raffaele Saladino; Claudia Crestini; Umberto Ciambecchini; Fabiana Ciciriello; Giovanna Costanzo; Ernesto Di Mauro
Synthesis and degradation of nucleobases and nucleic acids by formamide in the presence of montmorillonites.
Chembiochem : a European journal of chemical biology 2004;5(11):1558-66.
2003: Raffaele Saladino; Umberto Ciambecchini; Lucia Nencioni; Anna Teresa Palamara
Recent advances in the chemistry of parainfluenza-1 (Sendai) virus inhibitors.
Medicinal research reviews 2003;23(4):427-55.
2003: Raffaele Saladino; Umberto Ciambecchini; Claudia Crestini; Giovanna Costanzo; Rodolfo Negri; Ernesto Di Mauro
One-pot TiO2-catalyzed synthesis of nucleic bases and acyclonucleosides from formamide: implications for the origin of life.
Chembiochem : a European journal of chemical biology 2003;4(6):514-21.
2002: Raffaele Saladino; Umberto Ciambecchini; giovanni maga; Paola Mastromarino; Cinzia Conti; Maurizio Botta
A new and efficient synthesis of substituted 6-[(2'-dialkylamino)ethyl] pyrimidine and 4-N,N-dialkyl-6-vinyl-cytosine derivatives and evaluation of their anti-rubella activity.
Bioorganic & medicinal chemistry 2002;10(7):2143-53.
2002: Raffaele Saladino; Veronica Neri; Anna Rita Pelliccia; Ruggero Caminiti; Claudia Sadun
Preparation and structural characterization of polymer-supported methylrhenium trioxide systems as efficient and selective catalysts for the epoxidation of olefins.
The Journal of organic chemistry 2002;67(4):1323-32.
2001: Raffaele Saladino; Claudia Crestini; Anna Teresa Palamara; M C Danti; Fabrizio Manetti; Federico Corelli; Enrico Garaci; M Botta
Synthesis, biological evaluation, and pharmacophore generation of uracil, 4(3H)-pyrimidinone, and uridine derivatives as potent and selective inhibitors of parainfluenza 1 (Sendai) virus.
Journal of medicinal chemistry 2001;44(26):4554-62.
2001: Raffaele Saladino; Claudia Crestini; Giovanna Costanzo; Rodolfo Negri; Ernesto Di Mauro
A possible prebiotic synthesis of purine, adenine, cytosine, and 4(3H)-pyrimidinone from formamide: implications for the origin of life.
Bioorganic & medicinal chemistry 2001;9(5):1249-53.
2000: Claudia Crestini; Alessandro D'Annibale; Giovanni Giovannozzi Sermanni; Raffaele Saladino
The reactivity of phenolic and non-phenolic residual kraft lignin model compounds with Mn(II)-peroxidase from Lentinula edodes.
Bioorganic & medicinal chemistry 2000;8(2):433-8.
1999: Raffaele Saladino; M Mezzetti; E Mincione; Anna Teresa Palamara; P Savini; Stefano Marini
Synthesis, cytotoxic effect and antiviral activity of 1-(beta-D-arabinofuranosyl)-5-bromo-N4-substituted cytosine and 1-(beta-D-arabinofuranosyl)-5-bromo-4-methoxypyrimidin-2(1H)-one derivatives.
Nucleosides & nucleotides 1999;18(11-12):2499-510.
1999: M Botta; F Occhionero; R Nicoletti; Paola Mastromarino; Cinzia Conti; M Magrini; Raffaele Saladino
Synthesis and biological evaluation of 2-methoxy- and 2-methylthio-6-[2'-alkylamino)ethyl]-4(3H)-pyrimidinones with anti-rubella virus activity.
Bioorganic & medicinal chemistry 1999;7(9):1925-31.
1999: Claudia Crestini; Raffaele Saladino; Pietro Tagliatesta; T Boschi
Biomimetic degradation of lignin and lignin model compounds by synthetic anionic and cationic water soluble manganese and iron porphyrins.
Bioorganic & medicinal chemistry 1999;7(9):1897-905.
1998: Ernesto Di Mauro; Raffaele Saladino; Pietro Tagliatesta; Veronica De Sanctis; Rodolfo Negri
Manganese water-soluble porphyrin senses DNA conformation.
Journal of molecular biology 1998;282(1):43-57.
1998: Raffaele Saladino; M C Danti; E Mincione; Claudia Crestini; Anna Teresa Palamara; P Savini; Stefano Marini; M Botta
A potent and selective inhibition of parainfluenza 1 (Sendai) virus by new 6-oxiranyl-, 6-methyloxiranyluracils, and 4(3H)-pyrimidinone derivatives.
Bioorganic & medicinal chemistry letters 1998;8(14):1833-8.
1997: Raffaele Saladino; Claudia Crestini; E Mincione; Giovanna Costanzo; Ernesto Di Mauro; Rodolfo Negri
Mechanism of degradation of 2'-deoxycytidine by formamide: implications for chemical DNA sequencing procedures.
Bioorganic & medicinal chemistry 1997;5(11):2041-8.
1996: Rodolfo Negri; Giovanna Costanzo; Raffaele Saladino; Ernesto Di Mauro
One-step, one-lane chemical DNA sequencing by N-methylformamide in the presence of metal ions.
BioTechniques 1996;21(5):910-7.
1992: Maurizio Botta; G Fabrizi; Doriano Lamba; Raffaele Saladino
Structure of (+)-(S)-1,3-dimethyl-6-oxiranyl-2,4-pyrimidinedione showing anti-ASFV activity.
Acta crystallographica. Section C, Crystal structure communications 1992;48 ( Pt 1)():81-3.