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Masakatsu Shibasaki

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Phenomena

Catalysis

Chemicals & Drugs

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Molecular Structure

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Co-Publications
Name
57
Kanai, Motomu
51
Matsunaga, Shigeki
26
Ohshima, Takashi
20
Kumagai, Naoya
12
Yamagiwa, Noriyuki
9
Harada, Shinji
9
Morimoto, Hiroyuki
9
Nemoto, Tetsuhiro
8
Oisaki, Konosuke
7
Tosaki, Shin-ya
7
Gnanadesikan, Vijay
6
Mita, Tsuyoshi
6
Wada, Reiko
6
Shibuguchi, Tomoyuki
5
Motoki, Rie

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Publications

TOP 3
Shibasaki Masakatsu; Kumagai Naoya; Mashiko Tomoyuki
Inventing and understanding catalytic, enantioselective reactions.
Mashiko Tomoyuki; Kumagai Naoya; Shibasaki Masakatsu
Managing highly coordinative substrates in asymmetric catalysis: a catalytic asymmetric amination with a lanthanum-based ternary catalyst.
Nitabaru Tatsuya; Nojiri Akihiro; Kobayashi Makoto; Kumagai Naoya; Shibasaki Masakatsu
anti-Selective catalytic asymmetric nitroaldol reaction via a heterobimetallic heterogeneous catalyst.

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All Publications

2009: Shibasaki Masakatsu; Kumagai Naoya; Mashiko Tomoyuki
Inventing and understanding catalytic, enantioselective reactions.
Current opinion in drug discovery & development 2009;12(6):862-75.
2009: Mashiko Tomoyuki; Kumagai Naoya; Shibasaki Masakatsu
Managing highly coordinative substrates in asymmetric catalysis: a catalytic asymmetric amination with a lanthanum-based ternary catalyst.
Journal of the American Chemical Society 2009;131(41):14990-9.
2009: Nitabaru Tatsuya; Nojiri Akihiro; Kobayashi Makoto; Kumagai Naoya; Shibasaki Masakatsu
anti-Selective catalytic asymmetric nitroaldol reaction via a heterobimetallic heterogeneous catalyst.
Journal of the American Chemical Society 2009;131(38):13860-9.
2009: Yamaguchi Akitake; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric synthesis of alpha-alkylidene-beta-hydroxy esters via dynamic kinetic asymmetric transformation involving Ba-catalyzed direct aldol reaction.
Journal of the American Chemical Society 2009;131(31):10842-3.
2009: Chen I-Hon; Yin Liang; Itano Wataru; Kanai Motomu; Shibasaki Masakatsu
Catalytic asymmetric synthesis of chiral tertiary organoboronic esters through conjugate boration of beta-substituted cyclic enones.
Journal of the American Chemical Society 2009;131(33):11664-5.
2009: Shibasaki Masakatsu; Kanai Motomu; Matsunaga Shigeki; Kumagai Naoya
Recent progress in asymmetric bifunctional catalysis using multimetallic systems.
Accounts of chemical research 2009;42(8):1117-27.
2009: Endo Tomoko; Kano Kuniyuki; Motoki Rie; Hama Kotaro; Okudaira Shinichi; Ishida Mayuko; Ogiso Hideo; Tanaka Masayuki; Matsuki Norio; Taguchi Ryo; Kanai Motomu; Shibasaki Masakatsu; Arai Hiroyuki; Aoki Junken
Lysophosphatidylmethanol is a pan lysophosphatidic acid receptor agonist and is produced by autotaxin in blood.
Journal of biochemistry 2009;146(2):283-93.
2009: Yin Liang; Kanai Motomu; Shibasaki Masakatsu
Nucleophile generation via decarboxylation: asymmetric construction of contiguous trisubstituted and quaternary stereocenters through a Cu(I)-catalyzed decarboxylative Mannich-type reaction.
Journal of the American Chemical Society 2009;131(28):9610-1.
2009: Kato Yuko; Furutachi Makoto; Chen Zhihua; Mitsunuma Harunobu; Matsunaga Shigeki; Shibasaki Masakatsu
A homodinuclear Mn(III)2-Schiff base complex for catalytic asymmetric 1,4-additions of oxindoles to nitroalkenes.
Journal of the American Chemical Society 2009;131(26):9168-9.
2009: Mihara Hisashi; Xu Yingjie; Shepherd Nicholas E; Matsunaga Shigeki; Shibasaki Masakatsu
A heterobimetallic Ga/Yb-Schiff base complex for catalytic asymmetric alpha-addition of isocyanides to aldehydes.
Journal of the American Chemical Society 2009;131(24):8384-5.
2009: Tomita Daisuke; Yamatsugu Kenzo; Kanai Motomu; Shibasaki Masakatsu
Enantioselective synthesis of SM-130686 based on the development of asymmetric Cu(I)F catalysis to access 2-oxindoles containing a tetrasubstituted carbon.
Journal of the American Chemical Society 2009;131(20):6946-8.
2009: Morita Masataka; Drouin Ludovic; Motoki Rie; Kimura Yasuaki; Fujimori Ikuo; Kanai Motomu; Shibasaki Masakatsu
Two methods for catalytic generation of reactive enolates promoted by a chiral poly gd complex: application to catalytic enantioselective protonation reactions.
Journal of the American Chemical Society 2009;131(11):3858-9.
2009: Nojiri Akihiro; Kumagai Naoya; Shibasaki Masakatsu
Linking structural dynamics and functional diversity in asymmetric catalysis.
Journal of the American Chemical Society 2009;131(10):3779-84.
2009: Ose Atsushi; Ito Mototsugu; Kusuhara Hiroyuki; Yamatsugu Kenzo; Kanai Motomu; Shibasaki Masakatsu; Hosokawa Masakiyo; Schuetz John D; Sugiyama Yuichi
Limited brain distribution of [3R,4R,5S]-4-acetamido-5-amino-3-(1-ethylpropoxy)-1-cyclohexene-1-carboxylate phosphate (Ro 64-0802), a pharmacologically active form of oseltamivir, by active efflux across the blood-brain barrier mediated by organic anion transporter 3 (Oat3/Slc22a8) and multidrug resistance-associated protein 4 (Mrp4/Abcc4).
Drug metabolism and disposition: the biological fate of chemicals 2009;37(2):315-21.
2009: Suzuki Yuta; Yazaki Ryo; Kumagai Naoya; Shibasaki Masakatsu
Direct catalytic asymmetric Mannich-type reaction of thioamides.
Angewandte Chemie (International ed. in English) 2009;48(27):5026-9.
2009: Xu Yingjie; Lu Gang; Matsunaga Shigeki; Shibasaki Masakatsu
Direct anti-selective catalytic asymmetric Mannich-type reactions of alpha-ketoanilides for the synthesis of gamma-amino amides and azetidine-2-amides.
Angewandte Chemie (International ed. in English) 2009;48(18):3353-6.
2009: Chen Zhihua; Furutachi Makoto; Kato Yuko; Matsunaga Shigeki; Shibasaki Masakatsu
A stable homodinuclear biscobalt(III)-Schiff base complex for catalytic asymmetric 1,4-addition reactions of beta-keto esters to alkynones.
Angewandte Chemie (International ed. in English) 2009;48(12):2218-20.
2009: Sone Toshihiko; Lu Gang; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric synthesis of 2,2-disubstituted oxetanes from ketones by using a one-pot sequential addition of sulfur ylide.
Angewandte Chemie (International ed. in English) 2009;48(9):1677-80.
2009: Yamatsugu Kenzo; Yin Liang; Kamijo Shin; Kimura Yasuaki; Kanai Motomu; Shibasaki Masakatsu
A synthesis of Tamiflu by using a barium-catalyzed asymmetric Diels-Alder-type reaction.
Angewandte Chemie (International ed. in English) 2009;48(6):1070-6.
2008: Du Yao; Xu Li-Wen; Shimizu Yohei; Oisaki Kounosuke; Kanai Motomu; Shibasaki Masakatsu
Asymmetric reductive Mannich reaction to ketimines catalyzed by a Cu(I) complex.
Journal of the American Chemical Society 2008;130(48):16146-7.
2008: Chen I-Hon; Oisaki Kounosuke; Kanai Motomu; Shibasaki Masakatsu
Cu(I)-catalyzed hetero-Diels-Alder reaction between Danishefsky-type siloxy dienes and ketones.
Organic letters 2008;10(22):5151-4.
2008: Hara Keiichi; Park So-Young; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric epoxidation of alpha,beta-unsaturated phosphane oxides with a Y(O-iPr)3/biphenyldiol complex.
Chemistry, an Asian journal 2008;3(8-9):1500-4.
2008: Sone Toshihiko; Yamaguchi Akitake; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric synthesis of 2,2-disubstituted terminal epoxides via dimethyloxosulfonium methylide addition to ketones.
Journal of the American Chemical Society 2008;130(31):10078-9.
2008: Sohtome Yoshihiro; Kato Yuko; Handa Shinya; Aoyama Naohiro; Nagawa Keita; Matsunaga Shigeki; Shibasaki Masakatsu
Stereodivergent catalytic doubly diastereoselective nitroaldol reactions using heterobimetallic complexes.
Organic letters 2008;10(11):2231-4.
2008: Tanaka Yuta; Kanai Motomu; Shibasaki Masakatsu
A catalytic enantioselective conjugate addition of cyanide to enones.
Journal of the American Chemical Society 2008;130(19):6072-3.
2008: Usami Atsushi; Sasaki Takuya; Satoh Nobuhiro; Akiba Takahiro; Yokoshima Satoshi; Fukuyama Tohru; Yamatsugu Kenzo; Kanai Motomu; Shibasaki Masakatsu; Matsuki Norio; Ikegaya Yuji
Oseltamivir enhances hippocampal network synchronization.
Journal of pharmacological sciences 2008;106(4):659-62.
2008: Nojiri Akihiro; Kumagai Naoya; Shibasaki Masakatsu
Asymmetric catalysis via dynamic substrate/ligand/rare earth metal conglomerate.
Journal of the American Chemical Society 2008;130(17):5630-1.
2008: Wiedemann Sean H; Noda Hidetoshi; Harada Shinji; Matsunaga Shigeki; Shibasaki Masakatsu
Sc3+-catalyzed aldol-type additions of N-benzoylcyclopropanecarboxamides via iodide-mediated ring-opening: stereoselective synthesis of gamma-lactams.
Organic letters 2008;10(8):1661-4.
2008: Chen Zhihua; Morimoto Hiroyuki; Matsunaga Shigeki; Shibasaki Masakatsu
A bench-stable homodinuclear Ni2-Schiff base complex for catalytic asymmetric synthesis of alpha-tetrasubstituted anti-alpha,beta-diamino acid surrogates.
Journal of the American Chemical Society 2008;130(7):2170-1.
2008: Mihara Hisashi; Sohtome Yoshihiro; Matsunaga Shigeki; Shibasaki Masakatsu
Chiral-catalyst-based convergent synthesis of HIV protease inhibitor GRL-06579A.
Chemistry, an Asian journal 2008;3(2):359-66.
2008: Ose Atsushi; Kusuhara Hiroyuki; Yamatsugu Kenzo; Kanai Motomu; Shibasaki Masakatsu; Fujita Takuya; Yamamoto Akira; Sugiyama Yuichi
P-glycoprotein restricts the penetration of oseltamivir across the blood-brain barrier.
Drug metabolism and disposition: the biological fate of chemicals 2008;36(2):427-34.
2008: Morita Masataka; Sone Toshihiko; Yamatsugu Kenzo; Sohtome Yoshihiro; Matsunaga Shigeki; Kanai Motomu; Watanabe Yasuyoshi; Shibasaki Masakatsu
A method for the synthesis of an oseltamivir PET tracer.
Bioorganic & medicinal chemistry letters 2008;18(2):600-2.
2008: Morimoto Hiroyuki; Yoshino Tatsuhiko; Yukawa Takafumi; Lu Gang; Matsunaga Shigeki; Shibasaki Masakatsu
Lewis base assisted Brønsted base catalysis: bidentate phosphine oxides as activators and modulators of Brønsted basic lanthanum-aryloxides.
Angewandte Chemie (International ed. in English) 2008;47(47):9125-9.
2008: Lu Gang; Morimoto Hiroyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Chiral gamma-amino amide synthesis by heterobimetallic lanthanum/lithium/Pybox-catalyzed direct asymmetric mannich-type reactions of alpha-keto anilides.
Angewandte Chemie (International ed. in English) 2008;47(36):6847-50.
2008: Handa Shinya; Nagawa Keita; Sohtome Yoshihiro; Matsunaga Shigeki; Shibasaki Masakatsu
A heterobimetallic Pd/La/Schiff base complex for anti-selective catalytic asymmetric nitroaldol reactions and applications to short syntheses of beta-adrenoceptor agonists.
Angewandte Chemie (International ed. in English) 2008;47(17):3230-3.
2007: Hama Kotaro; Aoki Junken; Inoue Asuka; Endo Tomoko; Amano Tomokazu; Motoki Rie; Kanai Motomu; Ye Xiaoqin; Chun Jerold; Matsuki Norio; Suzuki Hiroshi; Shibasaki Masakatsu; Arai Hiroyuki
Embryo spacing and implantation timing are differentially regulated by LPA3-mediated lysophosphatidic acid signaling in mice.
Biology of reproduction 2007;77(6):954-9.
2007: Kakei Hiroyuki; Sone Toshihiko; Sohtome Yoshihiro; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric cyclopropanation of enones with dimethyloxosulfonium methylide promoted by a La-Li3-(biphenyldiolate)3 + NaI complex.
Journal of the American Chemical Society 2007;129(44):13410-1.
2007: Mashiko Tomoyuki; Hara Keiichi; Tanaka Daisuke; Fujiwara Yuji; Kumagai Naoya; Shibasaki Masakatsu
En route to an efficient catalytic asymmetric synthesis of AS-3201.
Journal of the American Chemical Society 2007;129(37):11342-3.
2007: Yamaguchi Akitake; Aoyama Naohiro; Matsunaga Shigeki; Shibasaki Masakatsu
Ba-catalyzed direct Mannich-type reactions of a beta,gamma-unsaturated ester providing beta-methyl aza-Morita-Baylis-Hillman-type products.
Organic letters 2007;9(17):3387-90.
2007: Morimoto Hiroyuki; Lu Gang; Aoyama Naohiro; Matsunaga Shigeki; Shibasaki Masakatsu
Lanthanum aryloxide/pybox-catalyzed direct asymmetric Mannich-type reactions using a trichloromethyl ketone as a propionate equivalent donor.
Journal of the American Chemical Society 2007;129(31):9588-9.
2007: Motoki Rie; Kanai Motomu; Shibasaki Masakatsu
Copper(I) alkoxide-catalyzed alkynylation of trifluoromethyl ketones.
Organic letters 2007;9(16):2997-3000.
2007: Shibasaki Masakatsu; Kanai Motomu
Catalytic enantioselective construction of tetrasubstituted carbons by self-assembled poly rare earth metal complexes.
Organic & biomolecular chemistry 2007;5(13):2027-39.
2007: Oisaki Kounosuke; Zhao Dongbo; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective alkylative aldol reaction: efficient multicomponent assembly of dialkylzincs, allenic esters, and ketones toward highly functionalized delta-lactones with tetrasubstituted chiral centers.
Journal of the American Chemical Society 2007;129(23):7439-43.
2007: Shibuguchi Tomoyuki; Mihara Hisashi; Kuramochi Akiyoshi; Ohshima Takashi; Shibasaki Masakatsu
Catalytic asymmetric phase-transfer Michael reaction and Mannich-type reaction of glycine Schiff bases with tartrate-derived diammonium salts.
Chemistry, an Asian journal 2007;2(6):794-801.
2007: Handa Shinya; Gnanadesikan Vijay; Matsunaga Shigeki; Shibasaki Masakatsu
syn-Selective catalytic asymmetric nitro-Mannich reactions using a heterobimetallic Cu-Sm-Schiff base complex.
Journal of the American Chemical Society 2007;129(16):4900-1.
2007: Harada Shinji; Takita Ryo; Ohshima Takashi; Matsunaga Shigeki; Shibasaki Masakatsu
Ligand accelerated indium(III)-catalyzed asymmetric alkynylation of aldehydes with 2-methyl-3-butyn-2-ol as an ethyne equivalent donor.
Chemical communications (Cambridge, England) 2007;(9):948-50.
2007: Kakei Hiroyuki; Tsuji Riichiro; Ohshima Takashi; Morimoto Hiroyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters with chiral yttrium-biaryldiol complexes.
Chemistry, an Asian journal 2007;2(2):257-64.
2007: Qin Hongbo; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Bismuth- and hafnium-catalyzed hydroamination of vinyl arenes with sulfonamides, carbamates, and carboxamides.
Chemistry, an Asian journal 2007;2(1):150-4.
2007: Shibasaki Masakatsu; Kanai Motomu; Fukuda Nobuhisa
Total synthesis of lactacystin and salinosporamide A.
Chemistry, an Asian journal 2007;2(1):20-38.
2007: Suto Yutaka; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective Mannich-type reactions of ketoimines.
Journal of the American Chemical Society 2007;129(3):500-1.
2007: Mita Tsuyoshi; Fukuda Nobuhisa; Roca Francesc X; Kanai Motomu; Shibasaki Masakatsu
Second generation catalytic asymmetric synthesis of Tamiflu: allylic substitution route.
Organic letters 2007;9(2):259-62.
2007: Shibasaki Masakatsu; Ohshima Takashi
Recent studies on the synthesis of strychnine.
The Alkaloids. Chemistry and biology 2007;64():103-38.
2007: Qin Hongbo; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Bismuth-catalyzed direct substitution of the hydroxy group in alcohols with sulfonamides, carbamates, and carboxamides.
Angewandte Chemie (International ed. in English) 2007;46(3):409-13.
2006: Fujimori Ikuo; Mita Tsuyoshi; Maki Keisuke; Shiro Motoo; Sato Akihiro; Furusho Sanae; Kanai Motomu; Shibasaki Masakatsu
Key role of the Lewis base position in asymmetric bifunctional catalysis: design and evaluation of a new ligand for chiral polymetallic catalysts.
Journal of the American Chemical Society 2006;128(51):16438-9.
2006: Zhao Dongbo; Oisaki Kounosuke; Kanai Motomu; Shibasaki Masakatsu
Dramatic ligand effect in catalytic asymmetric reductive aldol reaction of allenic esters to ketones.
Journal of the American Chemical Society 2006;128(45):14440-1.
2006: Yamatsugu Kenzo; Motoki Rie; Kanai Motomu; Shibasaki Masakatsu
Identification of potent, selective protein kinase C inhibitors based on a phorbol skeleton.
Chemistry, an Asian journal 2006;1(3):314-21.
2006: Tosaki Shin-ya; Hara Keiichi; Gnanadesikan Vijay; Morimoto Hiroyuki; Harada Shinji; Sugita Mari; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution.
Journal of the American Chemical Society 2006;128(36):11776-7.
2006: Tomita Daisuke; Kanai Motomu; Shibasaki Masakatsu
Nucleophilic activation of alkenyl and aryl boronates by a chiral Cu(I)F complex: catalytic enantioselective alkenylation and arylation of aldehydes.
Chemistry, an Asian journal 2006;1(1-2):161-6.
2006: Shibuguchi Tomoyuki; Mihara Hisashi; Kuramochi Akiyoshi; Sakuraba Shun; Ohshima Takashi; Shibasaki Masakatsu
Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst.
Angewandte Chemie (International ed. in English) 2006;45(28):4635-7.
2006: Wada Reiko; Shibuguchi Tomoyuki; Makino Sae; Oisaki Kounosuke; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective allylation of ketoimines.
Journal of the American Chemical Society 2006;128(23):7687-91.
2006: Oisaki Kounosuke; Zhao Dongbo; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective aldol reaction to ketones.
Journal of the American Chemical Society 2006;128(22):7164-5.
2006: Kato Nobuki; Mita Tsuyoshi; Kanai Motomu; Therrien Bruno; Kawano Masaki; Yamaguchi Kentaro; Danjo Hiroshi; Sei Yoshihisa; Sato Akihiro; Furusho Sanae; Shibasaki Masakatsu
Assembly state of catalytic modules as chiral switches in asymmetric Strecker amino acid synthesis.
Journal of the American Chemical Society 2006;128(21):6768-9.
2006: Fukuta Yuhei; Mita Tsuyoshi; Fukuda Nobuhisa; Kanai Motomu; Shibasaki Masakatsu
De novo synthesis of Tamiflu via a catalytic asymmetric ring-opening of meso-aziridines with TMSN3.
Journal of the American Chemical Society 2006;128(19):6312-3.
2006: Morimoto Hiroyuki; Wiedemann Sean H; Yamaguchi Akitake; Harada Shinji; Chen Zhihua; Matsunaga Shigeki; Shibasaki Masakatsu
Trichloromethyl ketones as synthetically versatile donors: application in direct catalytic mannich-type reactions and the stereoselective synthesis of azetidines.
Angewandte Chemie (International ed. in English) 2006;45(19):3146-50.
2006: Shibasaki Masakatsu; Matsunaga Shigeki
Design and application of linked-BINOL chiral ligands in bifunctional asymmetric catalysis.
Chemical Society reviews 2006;35(3):269-79.
2006: Qin Hongbo; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Bismuth-catalyzed intermolecular hydroamination of 1,3-dienes with carbamates, sulfonamides, and carboxamides.
Journal of the American Chemical Society 2006;128(5):1611-4.
2006: Fukuda Nobuhisa; Sasaki Kazuki; Sastry T V R S; Kanai Motomu; Shibasaki Masakatsu
Catalytic asymmetric total synthesis of (+)-lactacystin.
The Journal of organic chemistry 2006;71(3):1220-5.
2005: Maki Keisuke; Motoki Rie; Fujii Kunihiko; Kanai Motomu; Kobayashi Takayasu; Tamura Shinri; Shibasaki Masakatsu
Catalyst-controlled asymmetric synthesis of fostriecin and 8-epi-fostriecin.
Journal of the American Chemical Society 2005;127(48):17111-7.
2005: Sugita Mari; Yamaguchi Akitake; Yamagiwa Noriyuki; Handa Shinya; Matsunaga Shigeki; Shibasaki Masakatsu
syn-selective direct catalytic asymmetric Mannich-type reactions of hydroxyketones using Y{N(SiMe3)2}3/linked-BINOL complexes.
Organic letters 2005;7(23):5339-42.
2005: Kuramochi Akiyoshi; Usuda Hiroyuki; Yamatsugu Kenzo; Kanai Motomu; Shibasaki Masakatsu
Total synthesis of (+/-)-garsubellin A.
Journal of the American Chemical Society 2005;127(41):14200-1.
2005: Takita Ryo; Yakura Kenichiro; Ohshima Takashi; Shibasaki Masakatsu
Asymmetric alkynylation of aldehydes catalyzed by an In(III)/BINOL complex.
Journal of the American Chemical Society 2005;127(40):13760-1.
2005: Yamagiwa Noriyuki; Qin Hongbo; Matsunaga Shigeki; Shibasaki Masakatsu
Lewis acid-Lewis acid heterobimetallic cooperative catalysis: mechanistic studies and application in enantioselective aza-Michael reaction.
Journal of the American Chemical Society 2005;127(38):13419-27.
2005: Horiuchi Yoshihiro; Gnanadesikan Vijay; Ohshima Takashi; Masu Hyuma; Katagiri Kosuke; Sei Yoshihisa; Yamaguchi Kentaro; Shibasaki Masakatsu
Dynamic structural change of the self-assembled lanthanum complex induced by lithium triflate for direct catalytic asymmetric aldol-Tishchenko reaction.
Chemistry (Weinheim an der Bergstrasse, Germany) 2005;11(18):5195-204.
2005: Suto Yutaka; Tsuji Riichiro; Kanai Motomu; Shibasaki Masakatsu
Cu(I)-catalyzed direct enantioselective cross aldol-type reaction of acetonitrile.
Organic letters 2005;7(17):3757-60.
2005: Mita Tsuyoshi; Fujimori Ikuo; Wada Reiko; Wen Jianfeng; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective desymmetrization of meso-N-acylaziridines with TMSCN.
Journal of the American Chemical Society 2005;127(32):11252-3.
2005: Kumagai Naoya; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic chemoselective addition of acetonitrile to enolizable aldehydes with cationic Ru complex/DBU combination.
Chemical communications (Cambridge, England) 2005;(28):3600-2.
2005: Okada Akihiro; Shibuguchi Tomoyuki; Ohshima Takashi; Masu Hyuma; Yamaguchi Kentaro; Shibasaki Masakatsu
Enantio- and diastereoselective catalytic Mannich-type reaction of a glycine schiff base using a chiral two-center phase-transfer catalyst.
Angewandte Chemie (International ed. in English) 2005;44(29):4564-7.
2005: Harada Shinji; Handa Shinya; Matsunaga Shigeki; Shibasaki Masakatsu
Direct catalytic asymmetric Mannich-type reactions of N-(2-hydroxyacetyl)pyrrole as an ester-equivalent donor.
Angewandte Chemie (International ed. in English) 2005;44(28):4365-8.
2005: Kakei Hiroyuki; Tsuji Riichiro; Ohshima Takashi; Shibasaki Masakatsu
Catalytic asymmetric epoxidation of alpha,beta-unsaturated esters using an yttrium-biphenyldiol complex.
Journal of the American Chemical Society 2005;127(25):8962-3.
2005: Suzuki Masato; Kato Nobuki; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective synthesis of key intermediates for triazole antifungal agents.
Organic letters 2005;7(13):2527-30.
2005: Yoshida Takamasa; Morimoto Hiroyuki; Kumagai Naoya; Matsunaga Shigeki; Shibasaki Masakatsu
Non-C2-symmetric, chirally economical, and readily tunable linked-binols: design and application in a direct catalytic asymmetric mannich-type reaction.
Angewandte Chemie (International ed. in English) 2005;44(22):3470-4.
2005: Takita Ryo; Fukuta Yuhei; Tsuji Riichiro; Ohshima Takashi; Shibasaki Masakatsu
A new entry in catalytic alkynylation of aldehydes and ketones: dual activation of soft nucleophiles and hard electrophiles by an indium(III) catalyst.
Organic letters 2005;7(7):1363-6.
2005: Tomita Daisuke; Wada Reiko; Kanai Motomu; Shibasaki Masakatsu
Enantioselective alkenylation and phenylation catalyzed by a chiral CuF complex.
Journal of the American Chemical Society 2005;127(12):4138-9.
2005: Yamagiwa Noriyuki; Tian Jun; Matsunaga Shigeki; Shibasaki Masakatsu
Catalytic asymmetric cyano-ethoxycarbonylation reaction of aldehydes using a YLi3 tris(binaphthoxide) (YLB) complex: mechanism and roles of achiral additives.
Journal of the American Chemical Society 2005;127(10):3413-22.
2005: Tosaki Shin-ya; Tsuji Riichiro; Ohshima Takashi; Shibasaki Masakatsu
Dynamic ligand exchange of the lanthanide complex leading to structural and functional transformation: one-pot sequential catalytic asymmetric epoxidation-regioselective epoxide-opening process.
Journal of the American Chemical Society 2005;127(7):2147-55.
2005: Mita Tsuyoshi; Sasaki Kazuki; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective conjugate addition of cyanide to alpha,beta-unsaturated N-acylpyrroles.
Journal of the American Chemical Society 2005;127(2):514-5.
2004: Usuda Hiroyuki; Kuramochi Akiyoshi; Kanai Motomu; Shibasaki Masakatsu
Challenge toward structural complexity using asymmetric catalysis: target-oriented development of catalytic enantioselective Diels-Alder reaction.
Organic letters 2004;6(23):4387-90.
2004: Kumagai Naoya; Matsunaga Shigeki; Shibasaki Masakatsu
Cooperative catalysis of a cationic ruthenium complex, amine base, and na salt: catalytic activation of acetonitrile as a nucleophile.
Journal of the American Chemical Society 2004;126(42):13632-3.
2004: Ichikawa Eiko; Suzuki Masato; Yabu Kazuo; Albert Matthias; Kanai Motomu; Shibasaki Masakatsu
New entries in Lewis acid-Lewis base bifunctional asymmetric catalyst: catalytic enantioselective Reissert reaction of pyridine derivatives.
Journal of the American Chemical Society 2004;126(38):11808-9.
2004: Kato Nobuki; Tomita Daisuke; Maki Keisuke; Kanai Motomu; Shibasaki Masakatsu
Practical synthesis of chiral ligands for catalytic enantioselective cyanosilylation of ketones and ketoimines.
The Journal of organic chemistry 2004;69(18):6128-30.
2004: Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Mechanistic studies of a reaction promoted by the [YLi3[tris(binaphthoxide)]] complex: are three 1,1'-bi-2-naphthol units in a rare-earth-alkali-metal heterobimetallic complex necessary?
Angewandte Chemie (International ed. in English) 2004;43(34):4493-7.
2004: Wada Reiko; Oisaki Kounosuke; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective allylboration of ketones.
Journal of the American Chemical Society 2004;126(29):8910-1.
2004: Matsunaga Shigeki; Yoshida Takamasa; Morimoto Hiroyuki; Kumagai Naoya; Shibasaki Masakatsu
Direct catalytic asymmetric Mannich-type reaction of hydroxyketone using a Et2Zn/linked-BINOL complex: synthesis of either anti- or syn-beta-amino alcohols.
Journal of the American Chemical Society 2004;126(28):8777-85.
2004: Gnanadesikan Vijay; Horiuchi Yoshihiro; Ohshima Takashi; Shibasaki Masakatsu
Direct catalytic asymmetric aldol-Tishchenko reaction.
Journal of the American Chemical Society 2004;126(25):7782-3.
2004: Matsunaga Shigeki; Kinoshita Tomofumi; Okada Shigemitsu; Harada Shinji; Shibasaki Masakatsu
Catalytic asymmetric 1,4-addition reactions using alpha,beta-unsaturated N-acylpyrroles as highly reactive monodentate alpha,beta-unsaturated ester surrogates.
Journal of the American Chemical Society 2004;126(24):7559-70.
2004: Tamaruya Yoko; Suzuki Masato; Kamura Goshu; Kanai Motomu; Hama Kotaro; Shimizu Kumiko; Aoki Junken; Arai Hiroyuki; Shibasaki Masakatsu
Identifying specific conformations by using a carbohydrate scaffold: discovery of subtype-selective LPA-receptor agonists and an antagonist.
Angewandte Chemie (International ed. in English) 2004;43(21):2834-7.
2004: Fukuta Yuhei; Ohshima Takashi; Gnanadesikan Vijay; Shibuguchi Tomoyuki; Nemoto Tetsuhiro; Kisugi Takaya; Okino Tatsufumi; Shibasaki Masakatsu
Enantioselective syntheses and biological studies of aeruginosin 298-A and its analogs: application of catalytic asymmetric phase-transfer reaction.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(15):5433-8.
2004: Tosaki Shin-ya; Horiuchi Yoshihiro; Nemoto Tetsuhiro; Ohshima Takashi; Shibasaki Masakatsu
Strategy for enantio- and diastereoselective syntheses of all possible stereoisomers of 1,3-polyol arrays based on a highly catalyst-controlled epoxidation of alpha,beta-unsaturated morpholinyl amides: application to natural product synthesis.
Chemistry (Weinheim an der Bergstrasse, Germany) 2004;10(6):1527-44.
2004: Kumagai Naoya; Matsunaga Shigeki; Shibasaki Masakatsu
An efficient synthesis of bicyclic amidines by intramolecular cyclization.
Angewandte Chemie (International ed. in English) 2004;43(4):478-82.
2004: Kakei Hiroyuki; Nemoto Tetsuhiro; Ohshima Takashi; Shibasaki Masakatsu
Efficient synthesis of chiral alpha- and beta-hydroxy amides: application to the synthesis of (R)-fluoxetine.
Angewandte Chemie (International ed. in English) 2004;43(3):317-20.
2003: Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Heterobimetallic catalysis in asymmetric 1,4-addition of O-alkylhydroxylamine to enones.
Journal of the American Chemical Society 2003;125(52):16178-9.
2003: Majima Keisuke; Takita Ryo; Okada Akihiro; Ohshima Takashi; Shibasaki Masakatsu
Catalytic asymmetric Michael reaction of beta-keto esters: effects of the linker heteroatom in linked-BINOL.
Journal of the American Chemical Society 2003;125(51):15837-45.
2003: Funabashi Ken; Jachmann Markus; Kanai Motomu; Shibasaki Masakatsu
Multicenter strategy for the development of catalytic enantioselective nucleophilic alkylation of ketones: Me2Zn addition to alpha-ketoesters.
Angewandte Chemie (International ed. in English) 2003;42(44):5489-92.
2003: Kinoshita Tomofumi; Okada Shigemitsu; Park Sun-Ryung; Matsunaga Shigeki; Shibasaki Masakatsu
Sequential Wittig olefination-catalytic asymmetric epoxidation with reuse of waste Ph3P(O): application of alpha,beta-unsaturated N-acyl pyrroles as ester surrogates.
Angewandte Chemie (International ed. in English) 2003;42(38):4680-4.
2003: Ohshima Takashi; Gnanadesikan Vijay; Shibuguchi Tomoyuki; Fukuta Yuhei; Nemoto Tetsuhiro; Shibasaki Masakatsu
Enantioselective syntheses of aeruginosin 298-A and its analogues using a catalytic asymmetric phase-transfer reaction and epoxidation.
Journal of the American Chemical Society 2003;125(37):11206-7.
2003: Suto Yutaka; Kumagai Naoya; Matsunaga Shigeki; Kanai Motomu; Shibasaki Masakatsu
Direct catalytic aldol-type reactions using RCH2CN.
Organic letters 2003;5(17):3147-50.
2003: Tian Jun; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
Efficient two-step conversion of alpha,beta-unsaturated aldehydes to optically active gamma-oxy-alpha,beta-unsaturated nitriles and its application to the total synthesis of (+)-patulolide C.
Organic letters 2003;5(17):3021-4.
2003: Oisaki Kounosuke; Suto Yutaka; Kanai Motomu; Shibasaki Masakatsu
A new method for the catalytic aldol reaction to ketones.
Journal of the American Chemical Society 2003;125(19):5644-5.
2003: Masumoto Shuji; Usuda Hiroyuki; Suzuki Masato; Kanai Motomu; Shibasaki Masakatsu
Catalytic enantioselective Strecker reaction of ketoimines.
Journal of the American Chemical Society 2003;125(19):5634-5.
2003: Nemoto Tetsuhiro; Tosaki Shin-Ya; Ohshima Takashi; Shibasaki Masakatsu
Unique reactivity of alpha,beta-unsaturated carboxylic acid imidazolides: catalytic asymmetric synthesis of alpha,beta-epoxy esters and alpha,beta-epoxy carboxylic acid derivatives.
Chirality 2003;15(4):306-11.
2003: Matsunaga Shigeki; Kumagai Naoya; Harada Shinji; Shibasaki Masakatsu
anti-Selective direct catalytic asymmetric Mannich-type reaction of hydroxyketone providing beta-amino alcohols.
Journal of the American Chemical Society 2003;125(16):4712-3.
2003: Fujii Kunihiko; Maki Keisuke; Kanai Motomu; Shibasaki Masakatsu
Formal catalytic asymmetric total synthesis of fostriecin.
Organic letters 2003;5(5):733-6.
2003: Harada Shinji; Kumagai Naoya; Kinoshita Tomofumi; Matsunaga Shigeki; Shibasaki Masakatsu
Direct catalytic asymmetric Michael reaction of hydroxyketones: asymmetric Zn catalysis with a Et2Zn/linked-BINOL complex.
Journal of the American Chemical Society 2003;125(9):2582-90.
2003: Kumagai Naoya; Matsunaga Shigeki; Kinoshita Tomofumi; Harada Shinji; Okada Shigemitsu; Sakamoto Shigeru; Yamaguchi Kentaro; Shibasaki Masakatsu
Direct catalytic asymmetric aldol reaction of hydroxyketones: asymmetric Zn catalysis with a Et(2)Zn/linked-BINOL complex.
Journal of the American Chemical Society 2003;125(8):2169-78.
2003: Tosaki Shin-Ya; Nemoto Tetsuhiro; Ohshima Takashi; Shibasaki Masakatsu
Catalytic asymmetric synthesis of both syn- and anti-3,5-dihydroxy esters: application to 1,3-polyol/alpha-pyrone natural product synthesis.
Organic letters 2003;5(4):495-8.
2002: Mizutani Takashi; Honzawa Shinobu; Tosaki Shin-ya; Shibasaki Masakatsu
Total synthesis of (+/-)-wortmannin.
Angewandte Chemie (International ed. in English) 2002;41(24):4680-2.
2002: Ohshima Takashi; Xu Youjun; Takita Ryo; Shimizu Satoshi; Zhong Dafang; Shibasaki Masakatsu
Enantioselective total synthesis of (-)-strychnine using the catalytic asymmetric Michael reaction and tandem cyclization.
Journal of the American Chemical Society 2002;124(49):14546-7.
2002: Nemoto Tetsuhiro; Kakei Hiroyuki; Gnanadesikan Vijay; Tosaki Shin-Ya; Ohshima Takashi; Shibasaki Masakatsu
Catalytic asymmetric epoxidation of alpha,beta-unsaturated amides: efficient synthesis of beta-aryl alpha-hydroxy amides using a one-pot tandem catalytic asymmetric epoxidation-Pd-catalyzed epoxide opening process.
Journal of the American Chemical Society 2002;124(49):14544-5.
2002: Tian Jun; Yamagiwa Noriyuki; Matsunaga Shigeki; Shibasaki Masakatsu
An asymmetric cyanation reaction and sequential asymmetric cyanation-nitroaldol reaction using a [YLi(3)[tris(binaphthoxide)]] single catalyst component: catalyst tuning with achiral additives.
Angewandte Chemie (International ed. in English) 2002;41(19):3636-8, 3517.
2002: Shibasaki Masakatsu; Kanai Motomu; Funabashi Ken
Recent progress in asymmetric two-center catalysis.
Chemical communications (Cambridge, England) 2002;(18):1989-99.
2002: Wada Reiko; Suto Yutaka; Kanai Motomu; Shibasaki Masakatsu
Dramatic switching of protein kinase C agonist/antagonist activity by modifying the 12-ester side chain of phorbol esters.
Journal of the American Chemical Society 2002;124(36):10658-9.
2002: Shibasaki Masakatsu; Yoshikawa Naoki
Lanthanide complexes in multifunctional asymmetric catalysis.
Chemical reviews 2002;102(6):2187-210.
2002: Yamasaki Shingo; Fujii Kunihiko; Wada Reiko; Kanai Motomu; Shibasaki Masakatsu
A general catalytic allylation using allyltrimethoxysilane.
Journal of the American Chemical Society 2002;124(23):6536-7.
2002: Yoshikawa Naoki; Suzuki Takeyuki; Shibasaki Masakatsu
Diastereo- and enantioselective direct catalytic aldol reaction of 2-hydroxyacetophenones with aldehydes promoted by a heteropolymetallic complex: catalytic asymmetric synthesis of anti-1,2-diols.
The Journal of organic chemistry 2002;67(8):2556-65.
2002: Usuda Hiroyuki; Kanai Motomu; Shibasaki Masakatsu
Studies toward the total synthesis of garsubellin A: a concise synthesis of the 18-epi-tricyclic core.
Organic letters 2002;4(5):859-62.
2001: Kumagai N; Matsunaga S; Shibasaki M
Enantioselective 1,4-addition of unmodified ketone catalyzed by a bimetallic Zn-Zn-linked-BINOL complex.
Organic letters 2001;3(26):4251-4.
2001: Yamasaki S; Kanai M; Shibasaki M
Zirconium alkoxides in catalysis.
Chemistry (Weinheim an der Bergstrasse, Germany) 2001;7(19):4066-72.
2001: Funabashi K; Ratni H; Kanai M; Shibasaki M
Enantioselective construction of quaternary stereocenter through a Reissert-type reaction catalyzed by an electronically tuned bifunctional catalyst: efficient synthesis of various biologically significant compounds.
Journal of the American Chemical Society 2001;123(43):10784-5.
2001: Yabu K; Masumoto S; Yamasaki S; Hamashima Y; Kanai M; Du W; Curran D P; Shibasaki M
Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones.
Journal of the American Chemical Society 2001;123(40):9908-9.
2001: Nemoto T; Ohshima T; Shibasaki M
Catalytic asymmetric synthesis of alpha,beta-epoxy esters, aldehydes, amides, and gamma,delta-epoxy beta-keto esters: unique reactivity of alpha,beta-unsaturated carboxylic acid imidazolides.
Journal of the American Chemical Society 2001;123(38):9474-5.
2001: Takamura M; Funabashi K; Kanai M; Shibasaki M
Catalytic enantioselective Reissert-type reaction: development and application to the synthesis of a potent NMDA receptor antagonist (-)-L-689,560 using a solid-supported catalyst.
Journal of the American Chemical Society 2001;123(28):6801-8.
2001: Kumagai N; Matsunaga S; Yoshikawa N; Ohshima T; Shibasaki M
Direct catalytic enantio- and diastereoselective aldol reaction using a Zn-Zn-linked-BINOL complex: a practical synthesis of syn-1,2-diols.
Organic letters 2001;3(10):1539-42.
2001: Shibasaki M; Kanai M
Multifunctional asymmetric catalysis.
Chemical & pharmaceutical bulletin 2001;49(5):511-24.
2001: Nemoto T; Ohshima T; Yamaguchi K; Shibasaki M
Catalytic asymmetric epoxidation of enones using La-BINOL-triphenylarsine oxide complex: structural determination of the asymmetric catalyst.
Journal of the American Chemical Society 2001;123(12):2725-32.
2001: Yoshikawa N; Kumagai N; Matsunaga S; Moll G; Ohshima T; Suzuki T; Shibasaki M
Direct catalytic asymmetric aldol reaction: synthesis of either syn- or anti-alpha,beta-dihydroxy ketones.
Journal of the American Chemical Society 2001;123(10):2466-7.
2001: Yamasaki S; Kanai M; Shibasaki M
Novel multiaction of Zr catalyst: one-pot synthesis of beta-cyanohydrins from olefins.
Journal of the American Chemical Society 2001;123(6):1256-7.
2000: Takamura M; Hamashima Y; Usuda H; Kanai M; Shibasaki M
A catalytic asymmetric strecker-type reaction promoted by Lewis acid-Lewis base bifunctional catalyst.
Chemical & pharmaceutical bulletin 2000;48(10):1586-92.
2000: Ohori K; Shimizu S; Ohshima T; Shibasaki M
Catalytic asymmetric synthesis of 19,20-dihydroakuammicine.
Chirality 2000;12(5-6):400-3.
2000: Shibasaki M
[Phorbols: chemical synthesis and chemical biology]
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 2000;120(1):76-90.
2000: Shibasaki M
Multifunctional asymmetric catalysis.
Ernst Schering Research Foundation workshop 2000;(32):287-314.
1998: Uotsu K; Sodeoka M; Shibasaki M
Photoaffinity labeling of PKC isozymes by phorbol ester derivatives.
Bioorganic & medicinal chemistry 1998;6(7):1117-26.

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