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Edward Solomon

This is a preview profile on BiomedExperts - the first literature-based scientific social network. It brings the right researchers together and allows them to collaborate online. Collexis and Dell provide the BiomedExperts network of +1.5 Million pre-calculated profiles free of charge to researchers worldwide.

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Co-Publications
Name
62
Hodgson, Keith
59
Hedman, Britt
20
Dey, Abhishek
19
Karlin, Kenneth
17
Sarangi, Ritimukta
14
Vance, Michael
12
Decker, Andrea
11
Chen, Peng
11
Neidig, Michael
11
Szilagyi, Robert
10
Kosman, Daniel
10
Gorelsky, Serge
10
Ghosh, Somdatta
9
DeBeer George, Serena
9
Que, Lawrence

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Publications

TOP 3
Woertink Julia S; Smeets Pieter J; Groothaert Marijke H; Vance Michael A; Sels Bert F; Schoonheydt Robert A; Solomon Edward I
A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol.
Park Ga Young; Deepalatha Subramanian; Puiu Simona C; Lee Dong-Heon; Mondal Biplab; Narducci Sarjeant Amy A; del Rio Diego; Pau Monita Y M; Solomon Edward I; Karlin Kenneth D
A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.
Xie Xiangjin; Hadt Ryan G; Pauleta Sofia R; González Pablo J; Un Sun; Moura Isabel; Solomon Edward I
A variable temperature spectroscopic study on Paracoccuspantotrophus pseudoazurin: protein constraints on the blue Cu site.

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All Publications

2009: Woertink Julia S; Smeets Pieter J; Groothaert Marijke H; Vance Michael A; Sels Bert F; Schoonheydt Robert A; Solomon Edward I
A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(45):18908-13.
2009: Park Ga Young; Deepalatha Subramanian; Puiu Simona C; Lee Dong-Heon; Mondal Biplab; Narducci Sarjeant Amy A; del Rio Diego; Pau Monita Y M; Solomon Edward I; Karlin Kenneth D
A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2009;14(8):1301-11.
2009: Xie Xiangjin; Hadt Ryan G; Pauleta Sofia R; González Pablo J; Un Sun; Moura Isabel; Solomon Edward I
A variable temperature spectroscopic study on Paracoccuspantotrophus pseudoazurin: protein constraints on the blue Cu site.
Journal of inorganic biochemistry 2009;103(10):1307-13.
2009: Maiti Debabrata; Woertink Julia S; Ghiladi Reza A; Solomon Edward I; Karlin Kenneth D
Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.
Inorganic chemistry 2009;48(17):8342-56.
2009: Chow Marina S; Eser Bekir E; Wilson Samuel A; Hodgson Keith O; Hedman Britt; Fitzpatrick Paul F; Solomon Edward I
Spectroscopy and kinetics of wild-type and mutant tyrosine hydroxylase: mechanistic insight into O2 activation.
Journal of the American Chemical Society 2009;131(22):7685-98.
2009: Dey Abhishek; Jiang Yonging; Ortiz de Montellano Paul; Hodgson Keith O; Hedman Britt; Solomon Edward I
S K-edge XAS and DFT calculations on cytochrome P450: covalent and ionic contributions to the cysteine-Fe bond and their contribution to reactivity.
Journal of the American Chemical Society 2009;131(22):7869-78.
2009: Op't Holt Bryan T; Vance Michael A; Mirica Liviu M; Heppner David E; Stack T Daniel P; Solomon Edward I
Reaction coordinate of a functional model of tyrosinase: spectroscopic and computational characterization.
Journal of the American Chemical Society 2009;131(18):6421-38.
2009: Yoon Jungjoo; Fujii Satoshi; Solomon Edward I
Geometric and electronic structure differences between the type 3 copper sites of the multicopper oxidases and hemocyanin/tyrosinase.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(16):6585-90.
2009: Ghosh Somdatta; Xie Xiangjin; Dey Abhishek; Sun Yan; Scholes Charles P; Solomon Edward I
Thermodynamic equilibrium between blue and green copper sites and the role of the protein in controlling function.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(13):4969-74.
2009: Lucas Heather R; Li Lei; Sarjeant Amy A Narducci; Vance Michael A; Solomon Edward I; Karlin Kenneth D
Toluene and Ethylbenzene Aliphatic C-H Bond Oxidations Initiated by a Dicopper(II)-mu-1,2-Peroxo Complex.
Journal of the American Chemical Society 2009;131(9):3230-45.
2009: Solomon Edward I; Wong Shaun D; Liu Lei V; Decker Andrea; Chow Marina S
Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites.
Current opinion in chemical biology 2009;13(1):99-113.
2009: Hocking Rosalie K; George Serena Debeer; Gross Zeev; Walker F Ann; Hodgson Keith O; Hedman Britt; Solomon Edward I
Fe L- and K-edge XAS of Low-Spin Ferric Corrole: Bonding and Reactivity Relative to Low-Spin Ferric Porphyrin.
Inorganic chemistry 2009;48(4):1678-88.
2009: Bell Caleb B; Calhoun Jennifer R; Bobyr Elena; Wei Pin-Pin; Hedman Britt; Hodgson Keith O; Degrado William F; Solomon Edward I
Spectroscopic definition of the biferrous and biferric sites in de novo designed four-helix bundle DFsc peptides: implications for O2 reactivity of binuclear non-heme iron enzymes.
Biochemistry 2009;48(1):59-73.
2009: Ghosh Somdatta; Dey Abhishek; Sun Yan; Scholes Charles P; Solomon Edward I
Spectroscopic and computational studies of nitrite reductase: proton induced electron transfer and backbonding contributions to reactivity.
Journal of the American Chemical Society 2009;131(1):277-88.
2009: Yoon Jihae; Wilson Samuel A; Jang Yu Kyeong; Seo Mi Sook; Nehru Kasi; Hedman Britt; Hodgson Keith O; Bill Eckhard; Solomon Edward I; Nam Wonwoo
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
Angewandte Chemie (International ed. in English) 2009;48(7):1257-60.
2008: Collman James P; Dey Abhishek; Yang Ying; Decréau Richard A; Ohta Takehiro; Solomon Edward I
Intermediates involved in the two electron reduction of NO to N2O by a functional synthetic model of heme containing bacterial NO reductase.
Journal of the American Chemical Society 2008;130(49):16498-9.
2008: Ghosh Somdatta; Cirera Jordi; Vance Michael A; Ono Tetsuya; Fujisawa Kiyoshi; Solomon Edward I
Spectroscopic and electronic structure studies of phenolate Cu(II) complexes: phenolate ring orientation and activation related to cofactor biogenesis.
Journal of the American Chemical Society 2008;130(48):16262-73.
2008: Sarangi Ritimukta; Hocking Rosalie K; Neidig Michael L; Benfatto Maurizio; Holman Theodore R; Solomon Edward I; Hodgson Keith O; Hedman Britt
Geometric structure determination of N694C lipoxygenase: a comparative near-edge X-ray absorption spectroscopy and extended X-ray absorption fine structure study.
Inorganic chemistry 2008;47(24):11543-50.
2008: Collman James P; Yang Ying; Dey Abhishek; Decréau Richard A; Ghosh Somdatta; Ohta Takehiro; Solomon Edward I
A functional nitric oxide reductase model.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(41):15660-5.
2008: Tomter Ane B; Bell Caleb B; Røhr Asmund K; Andersson K Kristoffer; Solomon Edward I
Circular dichroism and magnetic circular dichroism studies of the biferrous site of the class Ib ribonucleotide reductase from Bacillus cereus: comparison to the class Ia enzymes.
Biochemistry 2008;47(43):11300-9.
2008: Chow Marina S; Liu Lei V; Solomon Edward I
Further insights into the mechanism of the reaction of activated bleomycin with DNA.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(36):13241-5.
2008: Solomon Edward I; Augustine Anthony J; Yoon Jungjoo
O2 reduction to H2O by the multicopper oxidases.
Dalton transactions (Cambridge, England : 2003) 2008;(30):3921-32.
2008: Mitic Natasa; Schwartz Jennifer K; Brazeau Brian J; Lipscomb John D; Solomon Edward I
CD and MCD studies of the effects of component B variant binding on the biferrous active site of methane monooxygenase.
Biochemistry 2008;47(32):8386-97.
2008: Collman James P; Dey Abhishek; Decreau Richard A; Yang Ying; Hosseini Ali; Solomon Edward I; Eberspacher Todd A
Interaction of nitric oxide with a functional model of cytochrome c oxidase.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(29):9892-6.
2008: Schwartz Jennifer K; Liu Xiaofeng S; Tosha Takehiko; Theil Elizabeth C; Solomon Edward I
Spectroscopic definition of the ferroxidase site in M ferritin: comparison of binuclear substrate vs cofactor active sites.
Journal of the American Chemical Society 2008;130(29):9441-50.
2008: Tenderholt Adam L; Szilagyi Robert K; Holm Richard H; Hodgson Keith O; Hedman Britt; Solomon Edward I
Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study.
Inorganic chemistry 2008;47(14):6382-92.
2008: Schwartz Jennifer K; Wei Pin-pin; Mitchell Kevin H; Fox Brian G; Solomon Edward I
Geometric and electronic structure studies of the binuclear nonheme ferrous active site of toluene-4-monooxygenase: parallels with methane monooxygenase and insight into the role of the effector proteins in O2 activation.
Journal of the American Chemical Society 2008;130(22):7098-109.
2008: Maiti Debabrata; Lee Dong-Heon; Narducci Sarjeant Amy A; Pau Monita Y M; Solomon Edward I; Gaoutchenova Katya; Sundermeyer Jörg; Karlin Kenneth D
Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species.
Journal of the American Chemical Society 2008;130(21):6700-1.
2008: Maiti Debabrata; Woertink Julia S; Narducci Sarjeant Amy A; Solomon Edward I; Karlin Kenneth D
Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent.
Inorganic chemistry 2008;47(9):3787-800.
2008: Solomon Edward I; Xie Xiangjin; Dey Abhishek
Mixed valent sites in biological electron transfer.
Chemical Society reviews 2008;37(4):623-38.
2008: Xie Xiangjin; Gorelsky Serge I; Sarangi Ritimukta; Garner Dewain K; Hwang Hee Jung; Hodgson Keith O; Hedman Britt; Lu Yi; Solomon Edward I
Perturbations to the geometric and electronic structure of the CuA site: factors that influence delocalization and their contributions to electron transfer.
Journal of the American Chemical Society 2008;130(15):5194-205.
2008: Sarangi Ritimukta; Gorelsky Serge I; Basumallick Lipika; Hwang Hee Jung; Pratt Russell C; Stack T Daniel P; Lu Yi; Hodgson Keith O; Hedman Britt; Solomon Edward I
Spectroscopic and density functional theory studies of the blue-copper site in M121SeM and C112SeC azurin: Cu-Se versus Cu-S bonding.
Journal of the American Chemical Society 2008;130(12):3866-77.
2008: Augustine Anthony J; Kragh Mads Emil; Sarangi Ritimukta; Fujii Satoshi; Liboiron Barry D; Stoj Christopher S; Kosman Daniel J; Hodgson Keith O; Hedman Britt; Solomon Edward I
Spectroscopic studies of perturbed T1 Cu sites in the multicopper oxidases Saccharomyces cerevisiae Fet3p and Rhus vernicifera laccase: allosteric coupling between the T1 and trinuclear Cu sites.
Biochemistry 2008;47(7):2036-45.
2008: Ohta Takehiro; Chakrabarty Sarmistha; Lipscomb John D; Solomon Edward I
Near-IR MCD of the nonheme ferrous active site in naphthalene 1,2-dioxygenase: correlation to crystallography and structural insight into the mechanism of Rieske dioxygenases.
Journal of the American Chemical Society 2008;130(5):1601-10.
2008: Sarangi Ritimukta; York John T; Helton Matthew E; Fujisawa Kiyoshi; Karlin Kenneth D; Tolman William B; Hodgson Keith O; Hedman Britt; Solomon Edward I
X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding.
Journal of the American Chemical Society 2008;130(2):676-86.
2008: Bell Caleb B; Wong Shaun D; Xiao Yuming; Klinker Eric J; Tenderholt Adam L; Smith Matt C; Rohde Jan-Uwe; Que Lawrence; Cramer Stephen P; Solomon Edward I
A combined NRVS and DFT study of Fe(IV)=O model complexes: a diagnostic method for the elucidation of non-heme iron enzyme intermediates.
Angewandte Chemie (International ed. in English) 2008;47(47):9071-4.
2007: Decker Andrea; Rohde Jan-Uwe; Klinker Eric J; Wong Shaun D; Que Lawrence; Solomon Edward I
Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity.
Journal of the American Chemical Society 2007;129(51):15983-96.
2007: Dey Abhishek; Jenney Francis E; Adams Michael W W; Babini Elena; Takahashi Yasuhiro; Fukuyama Keiichi; Hodgson Keith O; Hedman Britt; Solomon Edward I
Solvent tuning of electrochemical potentials in the active sites of HiPIP versus ferredoxin.
Science (New York, N.Y.) 2007;318(5855):1464-8.
2007: Pau Monita Y M; Lipscomb John D; Solomon Edward I
Substrate activation for O2 reactions by oxidized metal centers in biology.
Proceedings of the National Academy of Sciences of the United States of America 2007;104(47):18355-62.
2007: Neidig Michael L; Brown Christina D; Light Kenneth M; Fujimori Danica Galonic; Nolan Elizabeth M; Price John C; Barr Eric W; Bollinger J Martin; Krebs Carsten; Walsh Christopher T; Solomon Edward I
CD and MCD of CytC3 and taurine dioxygenase: role of the facial triad in alpha-KG-dependent oxygenases.
Journal of the American Chemical Society 2007;129(46):14224-31.
2007: Dey Abhishek; Green Kayla N; Jenkins Roxanne M; Jeffrey Stephen P; Darensbourg Marcetta; Hodgson Keith O; Hedman Britt; Solomon Edward I
S K-edge XAS and DFT calculations on square-planar NiII-thiolate complexes: effects of active and passive H-bonding.
Inorganic chemistry 2007;46(23):9655-60.
2007: Tenderholt Adam L; Szilagyi Robert K; Holm Richard H; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes.
Journal of inorganic biochemistry 2007;101(11-12):1594-600.
2007: Yoon Jungjoo; Solomon Edward I
Electronic structure of the peroxy intermediate and its correlation to the native intermediate in the multicopper oxidases: insights into the reductive cleavage of the o-o bond.
Journal of the American Chemical Society 2007;129(43):13127-36.
2007: Augustine Anthony J; Quintanar Liliana; Stoj Christopher S; Kosman Daniel J; Solomon Edward I
Spectroscopic and kinetic studies of perturbed trinuclear copper clusters: the role of protons in reductive cleavage of the O-O bond in the multicopper oxidase Fet3p.
Journal of the American Chemical Society 2007;129(43):13118-26.
2007: Yano Junko; Robblee John; Pushkar Yulia; Marcus Matthew A; Bendix Jesper; Workman José M; Collins Terrence J; Solomon Edward I; George Serena Debeer; Yachandra Vittal K
Polarized X-ray absorption spectroscopy of single-crystal Mn(V) complexes relevant to the oxygen-evolving complex of photosystem II.
Journal of the American Chemical Society 2007;129(43):12989-3000.
2007: Dey Abhishek; Jenney Francis E; Adams Michael W W; Johnson Michael K; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on superoxide reductase: role of the axial thiolate in reactivity.
Journal of the American Chemical Society 2007;129(41):12418-31.
2007: Yoon Jungjoo; Liboiron Barry D; Sarangi Ritimukta; Hodgson Keith O; Hedman Britt; Solomon Edward I
The two oxidized forms of the trinuclear Cu cluster in the multicopper oxidases and mechanism for the decay of the native intermediate.
Proceedings of the National Academy of Sciences of the United States of America 2007;104(34):13609-14.
2007: Ghosh Somdatta; Dey Abhishek; Usov Oleg M; Sun Yan; Grigoryants Vladimir M; Scholes Charles P; Solomon Edward I
Resolution of the spectroscopy versus crystallography issue for NO intermediates of nitrite reductase from Rhodobacter sphaeroides.
Journal of the American Chemical Society 2007;129(34):10310-1.
2007: Mitic Natasa; Clay Michael D; Saleh Lana; Bollinger J Martin; Solomon Edward I
Spectroscopic and electronic structure studies of intermediate X in ribonucleotide reductase R2 and two variants: a description of the FeIV-oxo bond in the FeIII-O-FeIV dimer.
Journal of the American Chemical Society 2007;129(29):9049-65.
2007: Maiti Debabrata; Woertink Julia S; Vance Michael A; Milligan Ashley E; Sarjeant Amy A Narducci; Solomon Edward I; Karlin Kenneth D
Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry.
Journal of the American Chemical Society 2007;129(28):8882-92.
2007: Lee Dong-Heon; Hatcher Lanying Q; Vance Michael A; Sarangi Ritimukta; Milligan Ashley E; Sarjeant Amy A Narducci; Incarvito Christopher D; Rheingold Arnold L; Hodgson Keith O; Hedman Britt; Solomon Edward I; Karlin Kenneth D
Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.
Inorganic chemistry 2007;46(15):6056-68.
2007: Solomon Edward I; Sarangi Ritimukta; Woertink Julia S; Augustine Anthony J; Yoon Jungjoo; Ghosh Somdatta
O2 and N2O activation by Bi-, Tri-, and tetranuclear Cu clusters in biology.
Accounts of chemical research 2007;40(7):581-91.
2007: Neidig Michael L; Wecksler Aaron T; Schenk Gerhard; Holman Theodore R; Solomon Edward I
Kinetic and spectroscopic studies of N694C lipoxygenase: a probe of the substrate activation mechanism of a nonheme ferric enzyme.
Journal of the American Chemical Society 2007;129(24):7531-7.
2007: Brown Christina D; Neidig Michael L; Neibergall Matthew B; Lipscomb John D; Solomon Edward I
VTVH-MCD and DFT studies of thiolate bonding to [FeNO]7/[FeO2]8 complexes of isopenicillin N synthase: substrate determination of oxidase versus oxygenase activity in nonheme Fe enzymes.
Journal of the American Chemical Society 2007;129(23):7427-38.
2007: Dey Abhishek; Jeffrey Stephen P; Darensbourg Marcetta; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase.
Inorganic chemistry 2007;46(12):4989-96.
2007: Quintanar Liliana; Stoj Christopher; Taylor Alexander B; Hart P John; Kosman Daniel J; Solomon Edward I
Shall we dance? How a multicopper oxidase chooses its electron transfer partner.
Accounts of chemical research 2007;40(6):445-52.
2007: Ghiladi Reza A; Chufan Eduardo E; del Río Diego; Solomon Edward I; Krebs Carsten; Huynh Boi Hanh; Huang Hong-Wei; Moënne-Loccoz Pierre; Kaderli Susan; Honecker Marcus; Zuberbühler Andreas D; Marzilli Lisa; Cotter Robert J; Karlin Kenneth D
Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+.
Inorganic chemistry 2007;46(10):3889-902.
2007: Collman James P; Decréau Richard A; Yan Yilong; Yoon Jungjoo; Solomon Edward I
Intramolecular single-turnover reaction in a cytochrome C oxidase model bearing a Tyr244 mimic.
Journal of the American Chemical Society 2007;129(18):5794-5.
2007: Ghosh Somdatta; Gorelsky Serge I; George Serena DeBeer; Chan Jeannine M; Cabrito Inês; Dooley David M; Moura José J G; Moura Isabel; Solomon Edward I
Spectroscopic, computational, and kinetic studies of the mu4-sulfide-bridged tetranuclear CuZ cluster in N2O reductase: pH effect on the edge ligand and its contribution to reactivity.
Journal of the American Chemical Society 2007;129(13):3955-65.
2007: Stoj Christopher S; Augustine Anthony J; Solomon Edward I; Kosman Daniel J
Structure-function analysis of the cuprous oxidase activity in Fet3p from Saccharomyces cerevisiae.
The Journal of biological chemistry 2007;282(11):7862-8.
2007: Sarangi Ritimukta; DeBeer George Serena; Rudd Deanne Jackson; Szilagyi Robert K; Ribas Xavi; Rovira Concepció; Almeida Manuel; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.
Journal of the American Chemical Society 2007;129(8):2316-26.
2007: Song Woon Ju; Seo Mi Sook; George Serena Debeer; Ohta Takehiro; Song Rita; Kang Min-Jung; Tosha Takehiko; Kitagawa Teizo; Solomon Edward I; Nam Wonwoo
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
Journal of the American Chemical Society 2007;129(5):1268-77.
2007: Pau Monita Y M; Davis Mindy I; Orville Allen M; Lipscomb John D; Solomon Edward I
Spectroscopic and electronic structure study of the enzyme-substrate complex of intradiol dioxygenases: substrate activation by a high-spin ferric non-heme iron site.
Journal of the American Chemical Society 2007;129(7):1944-58.
2007: Maiti Debabrata; Fry H Christopher; Woertink Julia S; Vance Michael A; Solomon Edward I; Karlin Kenneth D
A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols.
Journal of the American Chemical Society 2007;129(2):264-5.
2007: Hocking Rosalie K; Wasinger Erik C; Yan Yi-Long; Degroot Frank M F; Walker F Ann; Hodgson Keith O; Hedman Britt; Solomon Edward I
Fe L-edge X-ray absorption spectroscopy of low-spin heme relative to non-heme Fe complexes: delocalization of Fe d-electrons into the porphyrin ligand.
Journal of the American Chemical Society 2007;129(1):113-25.
2007: Ray Kallol; Debeer George Serena; Solomon Edward I; Wieghardt Karl; Neese Frank
Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations.
Chemistry (Weinheim an der Bergstrasse, Germany) 2007;13(10):2783-97.
2006: Gorelsky Serge I; Xie Xiangjin; Chen Ying; Fee James A; Solomon Edward I
The two-state issue in the mixed-valence binuclear CuA center in cytochrome C oxidase and N2O reductase.
Journal of the American Chemical Society 2006;128(51):16452-3.
2006: Hatcher Lanying Q; Lee Dong-Heon; Vance Michael A; Milligan Ashley E; Sarangi Ritimukta; Hodgson Keith O; Hedman Britt; Solomon Edward I; Karlin Kenneth D
Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation.
Inorganic chemistry 2006;45(25):10055-7.
2006: Neidig Michael L; Brown Christina D; Kavana Michael; Choroba Oliver W; Spencer Jonathan B; Moran Graham R; Solomon Edward I
Spectroscopic and electronic structure studies of the role of active site interactions in the decarboxylation reaction of alpha-keto acid-dependent dioxygenases.
Journal of inorganic biochemistry 2006;100(12):2108-16.
2006: Wei Pin-pin; Tomter Ane B; Røhr Asmund K; Andersson K Kristoffer; Solomon Edward I
Circular dichroism and magnetic circular dichroism studies of the active site of p53R2 from human and mouse: iron binding and nature of the biferrous site relative to other ribonucleotide reductases.
Biochemistry 2006;45(47):14043-51.
2006: Stoj Christopher S; Augustine Anthony J; Zeigler Lynn; Solomon Edward I; Kosman Daniel J
Structural basis of the ferrous iron specificity of the yeast ferroxidase, Fet3p.
Biochemistry 2006;45(42):12741-9.
2006: Solomon Edward I
Spectroscopic methods in bioinorganic chemistry: blue to green to red copper sites.
Inorganic chemistry 2006;45(20):8012-25.
2006: Solomon Edward I; Gorelsky Serge I; Dey Abhishek
Metal-thiolate bonds in bioinorganic chemistry.
Journal of computational chemistry 2006;27(12):1415-28.
2006: Lugo-Mas Priscilla; Dey Abhishek; Xu Liang; Davin Steven D; Benedict Jason; Kaminsky Werner; Hodgson Keith O; Hedman Britt; Solomon Edward I; Kovacs Julie A
How does single oxygen atom addition affect the properties of an Fe-nitrile hydratase analogue? The compensatory role of the unmodified thiolate.
Journal of the American Chemical Society 2006;128(34):11211-21.
2006: Segraves Erika N; Chruszcz Maksymilian; Neidig Michael L; Ruddat Viola; Zhou Jing; Wecksler Aaron T; Minor Wladek; Solomon Edward I; Holman Theodore R
Kinetic, spectroscopic, and structural investigations of the soybean lipoxygenase-1 first-coordination sphere mutant, Asn694Gly.
Biochemistry 2006;45(34):10233-42.
2006: Neidig Michael L; Decker Andrea; Choroba Oliver W; Huang Fanglu; Kavana Michael; Moran Graham R; Spencer Jonathan B; Solomon Edward I
Spectroscopic and electronic structure studies of aromatic electrophilic attack and hydrogen-atom abstraction by non-heme iron enzymes.
Proceedings of the National Academy of Sciences of the United States of America 2006;103(35):12966-73.
2006: Hocking Rosalie K; Wasinger Erik C; de Groot Frank M F; Hodgson Keith O; Hedman Britt; Solomon Edward I
Fe L-edge XAS studies of K4[Fe(CN)6] and K3[Fe(CN)6]: a direct probe of back-bonding.
Journal of the American Chemical Society 2006;128(32):10442-51.
2006: Dey Abhishek; Hocking Rosalie K; Larsen Peter; Borovik Andrew S; Hodgson Keith O; Hedman Britt; Solomon Edward I
X-ray absorption spectroscopy and density functional theory studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-): comparison of bonding and hydrogen bonding in oxo and sulfido complexes.
Journal of the American Chemical Society 2006;128(30):9825-33.
2006: Sarangi Ritimukta; Aboelella Nermeen; Fujisawa Kiyoshi; Tolman William B; Hedman Britt; Hodgson Keith O; Solomon Edward I
X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding.
Journal of the American Chemical Society 2006;128(25):8286-96.
2006: Debeer George Serena; Huang Kuo-Wei; Waymouth Robert M; Solomon Edward I
Metal and ligand K-edge XAS of titanium-TEMPO complexes: determination of oxidation states and insights into Ti-O bond homolysis.
Inorganic chemistry 2006;45(11):4468-77.
2006: Decker Andrea; Chow Marina S; Kemsley Jyllian N; Lehnert Nicolai; Solomon Edward I
Direct hydrogen-atom abstraction by activated bleomycin: an experimental and computational study.
Journal of the American Chemical Society 2006;128(14):4719-33.
2006: Hatcher Lanying Q; Vance Michael A; Narducci Sarjeant Amy A; Solomon Edward I; Karlin Kenneth D
Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.
Inorganic chemistry 2006;45(7):3004-13.
2006: Decker Andrea; Clay Michael D; Solomon Edward I
Spectroscopy and electronic structures of mono- and binuclear high-valent non-heme iron-oxo systems.
Journal of inorganic biochemistry 2006;100(4):697-706.
2006: Flemming Hansen D; Gorelsky Serge I; Sarangi Ritimukta; Hodgson Keith O; Hedman Britt; Christensen Hans E M; Solomon Edward I; Led Jens J
Reinvestigation of the method used to map the electronic structure of blue copper proteins by NMR relaxation.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2006;11(3):277-85.
2006: Mirica Liviu M; Rudd Deanne Jackson; Vance Michael A; Solomon Edward I; Hodgson Keith O; Hedman Britt; Stack T Daniel P
mu-eta2:eta2-peroxodicopper(II) complex with a secondary diamine ligand: a functional model of tyrosinase.
Journal of the American Chemical Society 2006;128(8):2654-65.
2006: Dey Abhishek; Chow Marina; Taniguchi Kayoko; Lugo-Mas Priscilla; Davin Steven; Maeda Mizuo; Kovacs Julie A; Odaka Masafumi; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge XAS and DFT calculations on nitrile hydratase: geometric and electronic structure of the non-heme iron active site.
Journal of the American Chemical Society 2006;128(2):533-41.
2006: Gorelsky Serge I; Ghosh Somdatta; Solomon Edward I
Mechanism of N2O reduction by the mu4-S tetranuclear CuZ cluster of nitrous oxide reductase.
Journal of the American Chemical Society 2006;128(1):278-90.
2005: Sarangi Ritimukta; Benfatto Maurizio; Hayakawa Kuniko; Bubacco Luigi; Solomon Edward I; Hodgson Keith O; Hedman Britt
MXAN analysis of the XANES energy region of a mononuclear copper complex: applications to bioinorganic systems.
Inorganic chemistry 2005;44(26):9652-9.
2005: Collman James P; Yan Yi-Long; Eberspacher Todd; Xie Xiangjin; Solomon Edward I
Oxygen binding of water-soluble cobalt porphyrins in aqueous solution.
Inorganic chemistry 2005;44(26):9628-30.
2005: Neidig Michael L; Solomon Edward I
Structure-function correlations in oxygen activating non-heme iron enzymes.
Chemical communications (Cambridge, England) 2005;(47):5843-63.
2005: Neidig Michael L; Decker Andrea; Kavana Michael; Moran Graham R; Solomon Edward I
Spectroscopic and computational studies of NTBC bound to the non-heme iron enzyme (4-hydroxyphenyl)pyruvate dioxygenase: active site contributions to drug inhibition.
Biochemical and biophysical research communications 2005;338(1):206-14.
2005: Wei Pin-Pin; Skulan Andrew J; Wade Herschel; DeGrado William F; Solomon Edward I
Spectroscopic and computational studies of the de novo designed protein DF2t: correlation to the biferrous active site of ribonucleotide reductase and factors that affect O2 reactivity.
Journal of the American Chemical Society 2005;127(46):16098-106.
2005: Dey Abhishek; Roche Cara L; Walters Marc A; Hodgson Keith O; Hedman Britt; Solomon Edward I
Sulfur K-edge XAS and DFT calculations on [Fe4S4]2+ clusters: effects of H-bonding and structural distortion on covalency and spin topology.
Inorganic chemistry 2005;44(23):8349-54.
2005: Li Lei; Narducci Sarjeant Amy A; Vance Michael A; Zakharov Lev N; Rheingold Arnold L; Solomon Edward I; Karlin Kenneth D
Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.
Journal of the American Chemical Society 2005;127(44):15360-1.
2005: Yoon Jungjoo; Solomon Edward I
Ground-state electronic and magnetic properties of a mu3-oxo-bridged trinuclear Cu(II) complex: correlation to the native intermediate of the multicopper oxidases.
Inorganic chemistry 2005;44(22):8076-86.
2005: Quintanar Liliana; Yoon Jungjoo; Aznar Constantino P; Palmer Amy E; Andersson K Kristoffer; Britt R David; Solomon Edward I
Spectroscopic and electronic structure studies of the trinuclear Cu cluster active site of the multicopper oxidase laccase: nature of its coordination unsaturation.
Journal of the American Chemical Society 2005;127(40):13832-45.
2005: Yoon Jungjoo; Mirica Liviu M; Stack T Daniel P; Solomon Edward I
Variable-temperature, variable-field magnetic circular dichroism studies of tris-hydroxy- and mu3-oxo-bridged trinuclear Cu(II) complexes: evaluation of proposed structures of the native intermediate of the multicopper oxidases.
Journal of the American Chemical Society 2005;127(39):13680-93.
2005: Dey Abhishek; Okamura Taka-aki; Ueyama Norikazu; Hedman Britt; Hodgson Keith O; Solomon Edward I
Sulfur K-edge XAS and DFT calculations on P450 model complexes: effects of hydrogen bonding on electronic structure and redox potentials.
Journal of the American Chemical Society 2005;127(34):12046-53.
2005: Del Río Diego; Sarangi Ritimukta; Chufán Eduardo E; Karlin Kenneth D; Hedman Britt; Hodgson Keith O; Solomon Edward I
Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4).
Journal of the American Chemical Society 2005;127(34):11969-78.
2005: Gorelsky Serge I; Basumallick Lipika; Vura-Weis Josh; Sarangi Ritimukta; Hodgson Keith O; Hedman Britt; Fujisawa Kiyoshi; Solomon Edward I
Spectroscopic and DFT investigation of [M{HB(3,5-iPr2pz)3}(SC6F5)] (M = Mn, Fe, Co, Ni, Cu, and Zn) model complexes: periodic trends in metal-thiolate bonding.
Inorganic chemistry 2005;44(14):4947-60.
2005: Mirica Liviu M; Vance Michael; Rudd Deanne Jackson; Hedman Britt; Hodgson Keith O; Solomon Edward I; Stack T Daniel P
Tyrosinase reactivity in a model complex: an alternative hydroxylation mechanism.
Science (New York, N.Y.) 2005;308(5730):1890-2.
2005: Quintanar Liliana; Stoj Christopher; Wang Tzu-Pin; Kosman Daniel J; Solomon Edward I
Role of aspartate 94 in the decay of the peroxide intermediate in the multicopper oxidase Fet3p.
Biochemistry 2005;44(16):6081-91.
2005: Decker Andrea; Solomon Edward I
Dioxygen activation by copper, heme and non-heme iron enzymes: comparison of electronic structures and reactivities.
Current opinion in chemical biology 2005;9(2):152-63.
2005: Decker Andrea; Solomon Edward I
Comparison of FeIV=O heme and non-heme species: electronic structures, bonding, and reactivities.
Angewandte Chemie (International ed. in English) 2005;44(15):2252-5.
2005: Kennepohl Pierre; Neese Frank; Schweitzer Dirk; Jackson Henry L; Kovacs Julie A; Solomon Edward I
Spectroscopy of non-heme iron thiolate complexes: insight into the electronic structure of the low-spin active site of nitrile hydratase.
Inorganic chemistry 2005;44(6):1826-36.
2005: Basumallick Lipika; Sarangi Ritimukta; DeBeer George Serena; Elmore Brad; Hooper Alan B; Hedman Britt; Hodgson Keith O; Solomon Edward I
Spectroscopic and density functional studies of the red copper site in nitrosocyanin: role of the protein in determining active site geometric and electronic structure.
Journal of the American Chemical Society 2005;127(10):3531-44.
2005: Solomon Edward I
Preface forum: "functional insight from physical methods on metalloenzymes".
Inorganic chemistry 2005;44(4):723-6.
2005: George Serena DeBeer; Brant Patrick; Solomon Edward I
Metal and ligand K-edge XAS of organotitanium complexes: metal 4p and 3d contributions to pre-edge intensity and their contributions to bonding.
Journal of the American Chemical Society 2005;127(2):667-74.
2004: Aboelella Nermeen W; Kryatov Sergey V; Gherman Benjamin F; Brennessel William W; Young Victor G; Sarangi Ritimukta; Rybak-Akimova Elena V; Hodgson Keith O; Hedman Britt; Solomon Edward I; Cramer Christopher J; Tolman William B
Dioxygen activation at a single copper site: structure, bonding, and mechanism of formation of 1:1 Cu-O2 adducts.
Journal of the American Chemical Society 2004;126(51):16896-911.
2004: Dey Abhishek; Glaser Thorsten; Moura Jose J-G; Holm Richard H; Hedman Britt; Hodgson Keith O; Solomon Edward I
Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment.
Journal of the American Chemical Society 2004;126(51):16868-78.
2004: Yoon Jungjoo; Mirica Liviu M; Stack T Daniel P; Solomon Edward I
Spectroscopic demonstration of a large antisymmetric exchange contribution to the spin-frustrated ground state of a D3 symmetric hydroxy-bridged trinuclear Cu(II) complex: ground-to-excited state superexchange pathways.
Journal of the American Chemical Society 2004;126(39):12586-95.
2004: Chen Peng; Solomon Edward I
O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(36):13105-10.
2004: Chen Peng; Gorelsky Serge I; Ghosh Somdatta; Solomon Edward I
N2O reduction by the mu4-sulfide-bridged tetranuclear CuZ cluster active site.
Angewandte Chemie (International ed. in English) 2004;43(32):4132-40.
2004: Skulan Andrew J; Brunold Thomas C; Baldwin Jeffrey; Saleh Lana; Bollinger J Martin; Solomon Edward I
Nature of the peroxo intermediate of the W48F/D84E ribonucleotide reductase variant: implications for O2 activation by binuclear non-heme iron enzymes.
Journal of the American Chemical Society 2004;126(28):8842-55.
2004: Liang Hong-Chang; Henson Mark J; Hatcher Lanying Q; Vance Michael A; Zhang Christiana Xin; Lahti David; Kaderli Susan; Sommer Roger D; Rheingold Arnold L; Zuberbühler Andreas D; Solomon Edward I; Karlin Kenneth D
Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction.
Inorganic chemistry 2004;43(14):4115-7.
2004: Dey Abhishek; Glaser Thorsten; Couture Manon M-J; Eltis Lindsay D; Holm R H; Hedman Britt; Hodgson Keith O; Solomon Edward I
Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox.
Journal of the American Chemical Society 2004;126(26):8320-8.
2004: Quintanar Liliana; Gebhard Mark; Wang Tzu-Pin; Kosman Daniel J; Solomon Edward I
Ferrous binding to the multicopper oxidases Saccharomyces cerevisiae Fet3p and human ceruloplasmin: contributions to ferroxidase activity.
Journal of the American Chemical Society 2004;126(21):6579-89.
2004: Jones P M; May J A; Reitz J B; Solomon Edward I
Photoelectron spectroscopic and electronic structure studies of CH(2)O bonding and reactivity on ZnO surfaces: steps in the methanol synthesis reaction.
Inorganic chemistry 2004;43(11):3349-70.
2004: Chen Peng; Bell Joseph; Eipper Betty A; Solomon Edward I
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate.
Biochemistry 2004;43(19):5735-47.
2004: Decker Andrea; Rohde Jan-Uwe; Que Lawrence; Solomon Edward I
Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex.
Journal of the American Chemical Society 2004;126(17):5378-9.
2004: Chen Peng; Solomon Edward I
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site.
Journal of the American Chemical Society 2004;126(15):4991-5000.
2004: Neidig Michael L; Kavana Michael; Moran Graham R; Solomon Edward I
CD and MCD studies of the non-heme ferrous active site in (4-hydroxyphenyl)pyruvate dioxygenase: correlation between oxygen activation in the extradiol and alpha-KG-dependent dioxygenases.
Journal of the American Chemical Society 2004;126(14):4486-7.
2004: Wei Pin-Pin; Skulan Andrew J; Mitic Natasa; Yang Yi-Shan; Saleh Lana; Bollinger J Martin; Solomon Edward I
Electronic and spectroscopic studies of the non-heme reduced binuclear iron sites of two ribonucleotide reductase variants: comparison to reduced methane monooxygenase and contributions to O2 reactivity.
Journal of the American Chemical Society 2004;126(12):3777-88.
2004: Szilagyi Robert K; Bryngelson Peter A; Maroney Michael J; Hedman Britt; Hodgson Keith O; Solomon Edward I
S K-edge X-ray absorption spectroscopic investigation of the Ni-containing superoxide dismutase active site: new structural insight into the mechanism.
Journal of the American Chemical Society 2004;126(10):3018-9.
2004: Solomon Edward I; Szilagyi Robert K; DeBeer George Serena; Basumallick Lipika
Electronic structures of metal sites in proteins and models: contributions to function in blue copper proteins.
Chemical reviews 2004;104(2):419-58.
2004: Schenk Gerhard; Pau Monita Y M; Solomon Edward I
Comparison between the geometric and electronic structures and reactivities of [FeNO]7 and [FeO2]8 complexes: a density functional theory study.
Journal of the American Chemical Society 2004;126(2):505-15.
2003: Ghosh Somdatta; Gorelsky Serge I; Chen Peng; Cabrito Inês; Moura José J G; Moura Isabel; Solomon Edward I
Activation of N2O reduction by the fully reduced micro4-sulfide bridged tetranuclear Cu Z cluster in nitrous oxide reductase.
Journal of the American Chemical Society 2003;125(51):15708-9.
2003: Basumallick Lipika; Szilagyi Robert K; Zhao Yiwei; Shapleigh James P; Scholes Charles P; Solomon Edward I
Spectroscopic studies of the Met182Thr mutant of nitrite reductase: role of the axial ligand in the geometric and electronic structure of blue and green copper sites.
Journal of the American Chemical Society 2003;125(48):14784-92.
2003: Strand Kari R; Yang Yi-Shan; Andersson K Kristoffer; Solomon Edward I
Circular dichroism and magnetic circular dichroism studies of the biferrous form of the R2 subunit of ribonucleotide reductase from mouse: comparison to the R2 from Escherichia coli and other binuclear ferrous enzymes.
Biochemistry 2003;42(42):12223-34.
2003: Wasinger Erik C; de Groot Frank M F; Hedman Britt; Hodgson Keith O; Solomon Edward I
L-edge X-ray absorption spectroscopy of non-heme iron sites: experimental determination of differential orbital covalency.
Journal of the American Chemical Society 2003;125(42):12894-906.
2003: Skulan Andrew J; Hanson Melissa A; Hsu Hua-fen; Dong Yanhong; Que Lawrence; Solomon Edward I
EPR spectroscopy of [Fe2O2(5-Et3-TPA)2]3+: electronic origin of the unique spin-Hamiltonian parameters of the Fe2(III,IV)O2 diamond core.
Inorganic chemistry 2003;42(20):6489-96.
2003: DeBeer George Serena; Basumallick Lipika; Szilagyi Robert K; Randall David W; Hill Michael G; Nersissian Aram M; Valentine Joan S; Hedman Britt; Hodgson Keith O; Solomon Edward I
Spectroscopic investigation of stellacyanin mutants: axial ligand interactions at the blue copper site.
Journal of the American Chemical Society 2003;125(37):11314-28.
2003: Davis Mindy I; Wasinger Erik C; Decker Andrea; Pau Monita Y M; Vaillancourt Frédéric H; Bolin Jeffrey T; Eltis Lindsay D; Hedman Britt; Hodgson Keith O; Solomon Edward I
Spectroscopic and electronic structure studies of 2,3-dihydroxybiphenyl 1,2-dioxygenase: O2 reactivity of the non-heme ferrous site in extradiol dioxygenases.
Journal of the American Chemical Society 2003;125(37):11214-27.
2003: Mitic Natasa; Saleh Lana; Schenk Gerhard; Bollinger J Martin; Solomon Edward I
Rapid-freeze-quench magnetic circular dichroism of intermediate X in ribonucleotide reductase: new structural insight.
Journal of the American Chemical Society 2003;125(37):11200-1.
2003: Kemsley Jyllian N; Zaleski Kelly Loeb; Chow Marina S; Decker Andrea; Shishova Ekaterina Y; Wasinger Erik C; Hedman Britt; Hodgson Keith O; Solomon Edward I
Spectroscopic studies of the interaction of ferrous bleomycin with DNA.
Journal of the American Chemical Society 2003;125(36):10810-21.
2003: Szilagyi Robert K; Lim Booyong S; Glaser Thorsten; Holm Richard H; Hedman Britt; Hodgson Keith O; Solomon Edward I
Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.
Journal of the American Chemical Society 2003;125(30):9158-69.
2003: Wang Tzu-Pin; Quintanar Liliana; Severance Scott; Solomon Edward I; Kosman Daniel J
Targeted suppression of the ferroxidase and iron trafficking activities of the multicopper oxidase Fet3p from Saccharomyces cerevisiae.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(6):611-20.
2003: Palmer Amy E; Szilagyi Robert K; Cherry Joel R; Jones Aubrey; Xu Feng; Solomon Edward I
Spectroscopic characterization of the Leu513His variant of fungal laccase: effect of increased axial ligand interaction on the geometric and electronic structure of the type 1 Cu site.
Inorganic chemistry 2003;42(13):4006-17.
2003: Schenk Gerhard; Neidig Michael L; Zhou Jing; Holman Theodore R; Solomon Edward I
Spectroscopic characterization of soybean lipoxygenase-1 mutants: the role of second coordination sphere residues in the regulation of enzyme activity.
Biochemistry 2003;42(24):7294-302.
2003: Skulan Andrew J; Hanson Melissa A; Hsu Hua-Fen; Que Lawrence; Solomon Edward I
Spectroscopic study of [Fe2O2(5-Et3-TPA)2]3+: nature of the Fe2O2 diamond core and its possible relevance to high-valent binuclear non-heme enzyme intermediates.
Journal of the American Chemical Society 2003;125(24):7344-56.
2003: Collman James P; Sunderland Christopher J; Berg Katja E; Vance Michael A; Solomon Edward I
Spectroscopic evidence for a heme-superoxide/Cu(I) intermediate in a functional model of cytochrome c oxidase.
Journal of the American Chemical Society 2003;125(22):6648-9.
2003: Chen Peng; Fujisawa Kiyoshi; Helton Matthew E; Karlin Kenneth D; Solomon Edward I
Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.
Journal of the American Chemical Society 2003;125(21):6394-408.
2003: Kemsley Jyllian N; Wasinger Erik C; Datta Supratim; Mitic Natasa; Acharya Tara; Hedman Britt; Caradonna John P; Hodgson Keith O; Solomon Edward I
Spectroscopic and kinetic studies of PKU-inducing mutants of phenylalanine hydroxylase: Arg158Gln and Glu280Lys.
Journal of the American Chemical Society 2003;125(19):5677-86.
2003: Henson Mark J; Vance Michael A; Zhang Christiana Xin; Liang Hong-Chang; Karlin Kenneth D; Solomon Edward I
Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes.
Journal of the American Chemical Society 2003;125(17):5186-92.
2003: Solomon Edward I; Decker Andrea; Lehnert Nicolai
Non-heme iron enzymes: contrasts to heme catalysis.
Proceedings of the National Academy of Sciences of the United States of America 2003;100(7):3589-94.
2003: Lehnert Nicolai; Solomon Edward I
Density-functional investigation on the mechanism of H-atom abstraction by lipoxygenase.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(3):294-305.
2003: Andersson K Kristoffer; Schmidt Peter P; Katterle Bettina; Strand Kari R; Palmer Amy E; Lee Sang-Kyu; Solomon Edward I; Gräslund Astrid; Barra Anne-Laure
Examples of high-frequency EPR studies in bioinorganic chemistry.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(3):235-47.
2003: Kennepohl Pierre; Solomon Edward I
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 3. Kinetics of electron transfer.
Inorganic chemistry 2003;42(3):696-708.
2003: Kennepohl Pierre; Solomon Edward I
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 2. Reduction potentials.
Inorganic chemistry 2003;42(3):689-95.
2003: Kennepohl Pierre; Solomon Edward I
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 1. Photoelectron spectroscopic determination of electronic relaxation.
Inorganic chemistry 2003;42(3):679-88.
2003: Helton Matthew E; Chen Peng; Paul Partha P; Tyeklár Zoltán; Sommer Roger D; Zakharov Lev N; Rheingold Arnold L; Solomon Edward I; Karlin Kenneth D
Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.
Journal of the American Chemical Society 2003;125(5):1160-1.
2003: Lehnert Nicolai; Fujisawa Kiyoshi; Solomon Edward I
Electronic structure and reactivity of high-spin iron--alkyl- and--pterinperoxo complexes.
Inorganic chemistry 2003;42(2):469-81.
2003: Wasinger Erik C; Davis Mindy I; Pau Monita Y M; Orville Allen M; Zaleski Jeffrey M; Hedman Britt; Lipscomb John D; Hodgson Keith O; Solomon Edward I
Spectroscopic studies of the effect of ligand donor strength on the Fe-NO bond intradiol dioxygenases.
Inorganic chemistry 2003;42(2):365-76.
2003: Chen Peng; Root David E; Campochiaro Cecelia; Fujisawa Kiyoshi; Solomon Edward I
Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization.
Journal of the American Chemical Society 2003;125(2):466-74.
2002: Collman James P; Berg Katja E; Sunderland Christopher J; Aukauloo Ally; Vance Michael A; Solomon Edward I
Distal metal effects in cobalt porphyrins related to CcO.
Inorganic chemistry 2002;41(25):6583-96.
2002: Lehnert Nicolai; Neese Frank; Ho Raymond Y N; Que Lawrence; Solomon Edward I
Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin.
Journal of the American Chemical Society 2002;124(36):10810-22.
2002: Chen Peng; Cabrito Inês; Moura José J G; Moura Isabel; Solomon Edward I
Spectroscopic and electronic structure studies of the mu(4)-sulfide bridged tetranuclear Cu(Z) cluster in N(2)O reductase: molecular insight into the catalytic mechanism.
Journal of the American Chemical Society 2002;124(35):10497-507.
2002: Mirica Liviu M; Vance Michael; Rudd Deanne Jackson; Hedman Britt; Hodgson Keith O; Solomon Edward I; Stack T D P
A stabilized mu-eta(2):eta(2) peroxodicopper(II) complex with a secondary diamine ligand and its tyrosinase-like reactivity.
Journal of the American Chemical Society 2002;124(32):9332-3.
2002: Lee Sang-Kyu; George Serena DeBeer; Antholine William E; Hedman Britt; Hodgson Keith O; Solomon Edward I
Nature of the intermediate formed in the reduction of O(2) to H(2)O at the trinuclear copper cluster active site in native laccase.
Journal of the American Chemical Society 2002;124(21):6180-93.
2002: Palmer Amy E; Quintanar Liliana; Severance Scott; Wang Tzu-Pin; Kosman Daniel J; Solomon Edward I
Spectroscopic characterization and O2 reactivity of the trinuclear Cu cluster of mutants of the multicopper oxidase Fet3p.
Biochemistry 2002;41(20):6438-48.
2002: Wasinger Erik C; Mitic Natasa; Hedman Britt; Caradonna John; Solomon Edward I; Hodgson Keith O
X-ray absorption spectroscopic investigation of the resting ferrous and cosubstrate-bound active sites of phenylalanine hydroxylase.
Biochemistry 2002;41(20):6211-7.
2002: Zhou Jing; Rocklin Amy M; Lipscomb John D; Que Lawrence; Solomon Edward I
Spectroscopic studies of 1-aminocyclopropane-1-carboxylic acid oxidase: molecular mechanism and CO(2) activation in the biosynthesis of ethylene.
Journal of the American Chemical Society 2002;124(17):4602-9.
2002: Szilagyi Robert K; Solomon Edward I
Electronic structure and its relation to function in copper proteins.
Current opinion in chemical biology 2002;6(2):250-8.
2002: Liang Hong-Chang; Zhang Christiana Xin; Henson Mark J; Sommer Roger D; Hatwell Karen R; Kaderli Susan; Zuberbühler Andreas D; Rheingold Arnold L; Solomon Edward I; Karlin Kenneth D
Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.
Journal of the American Chemical Society 2002;124(16):4170-1.
2002: Chen Peng; Solomon Edward I
Frontier molecular orbital analysis of Cu(n)-O(2) reactivity.
Journal of inorganic biochemistry 2002;88(3-4):368-74.
2002: Chen Peng; DeBeer George Serena; Cabrito Inês; Antholine William E; Moura José J G; Moura Isabel; Hedman Britt; Hodgson Keith O; Solomon Edward I
Electronic structure description of the mu(4)-sulfide bridged tetranuclear Cu(Z) center in N(2)O reductase.
Journal of the American Chemical Society 2002;124(5):744-5.
2002: Wasinger Erik C; Zaleski Loeb; Hedman Britt; Hodgson Keith O; Solomon Edward I
X-ray absorption spectroscopic investigation of Fe(II)-peplomycin and peplomycin derivatives: the effect of axial ligation on Fe-pyrimidine back-bonding.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2002;7(1-2):157-64.
2002: Davis Mindy I; Orville Allen M; Neese Frank; Zaleski Jeffrey M; Lipscomb John D; Solomon Edward I
Spectroscopic and electronic structure studies of protocatechuate 3,4-dioxygenase: nature of tyrosinate-Fe(III) bonds and their contribution to reactivity.
Journal of the American Chemical Society 2002;124(4):602-14.
2001: Lehnert N; Ho R Y; Que L; Solomon E I
Electronic structure of high-spin iron(III)-alkylperoxo complexes and its relation to low-spin analogues: reaction coordinate of O-O bond homolysis.
Journal of the American Chemical Society 2001;123(51):12802-16.
2001: Henson M J; Mahadevan V; Stack T D; Solomon E I
A new Cu(II) side-on peroxo model clarifies the assignment of the oxyhemocyanin Raman spectrum.
Inorganic chemistry 2001;40(20):5068-9.
2001: Lehnert N; Ho R Y; Que L; Solomon E I
Spectroscopic properties and electronic structure of low-spin Fe(III)-alkylperoxo complexes: homolytic cleavage of the O-O bond.
Journal of the American Chemical Society 2001;123(34):8271-90.
2001: Zhou J; Kelly W L; Bachmann B O; Gunsior M; Townsend C A; Solomon E I
Spectroscopic studies of substrate interactions with clavaminate synthase 2, a multifunctional alpha-KG-dependent non-heme iron enzyme: correlation with mechanisms and reactivities.
Journal of the American Chemical Society 2001;123(30):7388-98.
2001: Solomon E I
Invited award contribution for ACS Award in Inorganic Chemistry. Geometric and electronic structure contributions to function in bioinorganic chemistry: active sites in non-heme iron enzymes.
Inorganic chemistry 2001;40(15):3656-69.
2001: Palmer A E; Lee S K; Solomon E I
Decay of the peroxide intermediate in laccase: reductive cleavage of the O-O bond.
Journal of the American Chemical Society 2001;123(27):6591-9.
2001: DeBeer George S; Metz M; Szilagyi R K; Wang H; Cramer S P; Lu Y; Tolman W B; Hedman B; Hodgson K O; Solomon E I
A quantitative description of the ground-state wave function of Cu(A) by X-ray absorption spectroscopy: comparison to plastocyanin and relevance to electron transfer.
Journal of the American Chemical Society 2001;123(24):5757-67.
2001: Machonkin T E; Quintanar L; Palmer A E; Hassett R; Severance S; Kosman D J; Solomon E I
Spectroscopy and reactivity of the type 1 copper site in Fet3p from Saccharomyces cerevisiae: correlation of structure with reactivity in the multicopper oxidases.
Journal of the American Chemical Society 2001;123(23):5507-17.
2001: Anxolabéhère-Mallart E; Glaser T; Frank P; Aliverti A; Zanetti G; Hedman B; Hodgson K O; Solomon E I
Sulfur K-edge X-ray absorption spectroscopy of 2Fe-2S ferredoxin: covalency of the oxidized and reduced 2Fe forms and comparison to model complexes.
Journal of the American Chemical Society 2001;123(23):5444-52.
2001: Metz M; Solomon E I
Dioxygen binding to deoxyhemocyanin: electronic structure and mechanism of the spin-forbidden two-electron reduction of o(2).
Journal of the American Chemical Society 2001;123(21):4938-50.
2001: Glaser T; Bertini I; Moura J J; Hedman B; Hodgson K O; Solomon E I
Protein effects on the electronic structure of the [Fe4S4]2+ cluster in ferredoxin and HiPIP.
Journal of the American Chemical Society 2001;123(20):4859-60.
2001: Hirsch J; DeBeer George S; Solomon E I; Hedman B; Hodgson K O; Burstyn J N
Raman and extended X-ray absorption fine structure characterization of a sulfur-ligated Cu(I) ethylene complex: modeling the proposed ethylene binding site of Arabidopsis thaliana ETR1.
Inorganic chemistry 2001;40(10):2439-41.
2001: Lehnert N; George S D; Solomon E I
Recent advances in bioinorganic spectroscopy.
Current opinion in chemical biology 2001;5(2):176-87.
2001: Glaser T; Rose K; Shadle S E; Hedman B; Hodgson K O; Solomon E I
S K-edge X-ray absorption studies of tetranuclear iron-sulfur clusters: mu-sulfide bonding and its contribution to electron delocalization.
Journal of the American Chemical Society 2001;123(3):442-54.
2000: Glaser T; Hedman B; Hodgson K O; Solomon E I
Ligand K-edge X-ray absorption spectroscopy: a direct probe of ligand-metal covalency.
Accounts of chemical research 2000;33(12):859-68.
2000: Randall D W; Gamelin D R; LaCroix L B; Solomon E I
Electronic structure contributions to electron transfer in blue Cu and Cu(A).
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2000;5(1):16-29.
1999: Machonkin T E; Musci G; Zhang H H; Bonaccorsi di Patti M C; Calabrese L; Hedman B; Hodgson K O; Solomon E I
Investigation of the anomalous spectroscopic features of the copper sites in chicken ceruloplasmin: comparison to human ceruloplasmin.
Biochemistry 1999;38(34):11093-102.
1998: Machonkin T E; Zhang H H; Hedman B; Hodgson K O; Solomon E I
Spectroscopic and magnetic studies of human ceruloplasmin: identification of a redox-inactive reduced Type 1 copper site.
Biochemistry 1998;37(26):9570-8.
1997: Solomon E I; Zhou J; Neese F; Pavel E G
New insights from spectroscopy into the structure/function relationships of lipoxygenases.
Chemistry & biology 1997;4(11):795-808.
1996: Cole A P; Root D E; Mukherjee P; Solomon E I; Stack T D
A trinuclear intermediate in the copper-mediated reduction of O2: four electrons from three coppers.
Science (New York, N.Y.) 1996;273(5283):1848-50.
1995: Solomon E I; Kirk M L; Gamelin D R; Pulver S
Bioinorganic spectroscopy.
Methods in enzymology 1995;246():71-110.
1994: Pavel E G; Martins L J; Ellis W R; Solomon E I
Magnetic circular dichroism studies of exogenous ligand and substrate binding to the non-heme ferrous active site in phthalate dioxygenase.
Chemistry & biology 1994;1(3):173-83.
1993: Solomon E I; Lowery M D
Electronic structure contributions to function in bioinorganic chemistry.
Science (New York, N.Y.) 1993;259(5101):1575-81.
1993: Solomon E I; Lowery M D; LaCroix L B; Root D E
Electronic absorption spectroscopy of copper proteins.
Methods in enzymology 1993;226():1-33.
1988: Solomon E I
Coupled binuclear copper proteins: catalytic mechanisms and structure-reactivity correlations.
Progress in clinical and biological research 1988;274():309-29.
1987: Deaton J C; Solomon E I; Watt G D; Wetherbee P J; Durfor C N
Electron paramagnetic resonance studies of the tungsten-containing formate dehydrogenase from Clostridium thermoaceticum.
Biochemical and biophysical research communications 1987;149(2):424-30.
1985: Allendorf M D; Spira D J; Solomon E I
Low-temperature magnetic circular dichroism studies of native laccase: spectroscopic evidence for exogenous ligand bridging at a trinuclear copper active site.
Proceedings of the National Academy of Sciences of the United States of America 1985;82(10):3063-7.
1984: Deaton J C; Solomon E I; Durfor C N; Wetherbee P J; Burgess B K; Jacobs D B
Activation of nit-1 nitrate reductase by W-formate dehydrogenase.
Biochemical and biophysical research communications 1984;121(3):1042-7.
1984: Penner-Hahn J E; Hedman B; Hodgson K O; Spira D J; Solomon E I
On the spectral features associated with peroxide reactivity of the coupled binuclear copper active site in type 2 depleted and native Rhus laccase.
Biochemical and biophysical research communications 1984;119(2):567-74.
1983: Durfor C N; Wetherbee P J; Deaton J C; Solomon E I
Characterization and spectroscopic properties of reduced Mo and W formate dehydrogenase from C. thermoaceticum.
Biochemical and biophysical research communications 1983;115(1):61-7.
1983: Spira D J; Solomon E I
Nitrite reactivity of the binuclear copper site in T2D Rhus laccase: preparation of half met-NO2- T2D laccase and its correlation to half met-NO2- hemocyanin and tyrosinase.
Biochemical and biophysical research communications 1983;112(2):729-36.
1983: Spira D J; Co M S; Solomon E I; Hodgson K O
EXAFS investigation of the binuclear cupric site in met T2D Rhus laccase and its azide bound derivative.
Biochemical and biophysical research communications 1983;112(2):746-53.
1983: Hahn J E; Co M S; Spira D J; Hodgson K O; Solomon E I
Quantitative Cu(I) determination using X-ray absorption edge spectroscopy: oxidation of the reduced binuclear copper site in type 2 depleted Rhus laccase.
Biochemical and biophysical research communications 1983;112(2):737-45.
1982: Winkler M E; Spira D J; LuBein C D; Thamann T J; Solomon E I
Anion binding to oxidized type 2 depleted and native laccase: a spectroscopically effective model for exogenous ligand binding to the type 3--type 2 active site.
Biochemical and biophysical research communications 1982;107(2):727-34.
1982: Spira D J; Winkler M E; Solomon E I
Preparation and characterization of a stable half met derivative of type 2 depleted Rhus laccase: exogenous ligand binding to the type 3 site.
Biochemical and biophysical research communications 1982;107(2):721-6.

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