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Edward Solomon

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TOP 3
Michael K Coggins; Yeonju Kwak; Elena Rybak-Akimova; Edward I Solomon; Xianru Sun; Julie A Kovacs
Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.
Kiyoung Park; Lawrence Que; Makina Saito; Makoto Seto; E Ercan Alp; Caleb B Bell; Yasuhiro Kobayashi; Yeonju Kwak; Kenneth M Light; Lei V Liu; Takehiro Ohta; Dong Wang; Shaun D Wong; Genqiang Xue; Yoshitaka Yoda; Jiyong Zhao; Edward I Solomon
Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.
Lei V Liu; Wonwoo Nam; Jaeheung Cho; Seungwoo Hong; Edward I Solomon
Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities.

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2013: Michael K Coggins; Yeonju Kwak; Elena Rybak-Akimova; Edward I Solomon; Xianru Sun; Julie A Kovacs
Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species.
Journal of the American Chemical Society 2013;135(15):5631-40.
2013: Kiyoung Park; Lawrence Que; Makina Saito; Makoto Seto; E Ercan Alp; Caleb B Bell; Yasuhiro Kobayashi; Yeonju Kwak; Kenneth M Light; Lei V Liu; Takehiro Ohta; Dong Wang; Shaun D Wong; Genqiang Xue; Yoshitaka Yoda; Jiyong Zhao; Edward I Solomon
Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.
Proceedings of the National Academy of Sciences of the United States of America 2013;110(16):6275-80.
2013: Lei V Liu; Wonwoo Nam; Jaeheung Cho; Seungwoo Hong; Edward I Solomon
Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities.
Journal of the American Chemical Society 2013;135(8):3286-99.
2013: Samuel A Wilson; Richard DECREAU; Britt Hedman; Rosalie K Hocking; Keith O Hodgson; Thomas Kroll; Marcus Lundberg; Edward I Solomon
Iron L-edge X-ray absorption spectroscopy of oxy-picket fence porphyrin: experimental insight into Fe-O2 bonding.
Journal of the American Chemical Society 2013;135(3):1124-36.
2013: Kiyoung Park; Makina Saito; Makoto Seto; Hideki Furutachi; Yasuhiro Kobayashi; Masayuki Kurokuzu; Yeonju Kwak; Lei V Liu; Masatatsu Suzuki; Tomohiro Tsugawa; Shaun D Wong; Yoshitaka Yoda; Edward I Solomon
Nuclear resonance vibrational spectroscopy and DFT study of peroxo-bridged biferric complexes: structural insight into peroxo intermediates of binuclear non-heme iron enzymes.
Angewandte Chemie (International ed. in English) 2013;52(4):1294-8.
2012: Ryan G Hadt; Britt Hedman; Keith O Hodgson; Yi Lu; Nicholas M Marshall; Ning Sun; Edward I Solomon
Spectroscopic and DFT studies of second-sphere variants of the type 1 copper site in azurin: covalent and nonlocal electrostatic contributions to reduction potentials.
Journal of the American Chemical Society 2012;134(40):16701-16.
2012: Ryan G Hadt; Isabel Moura; Sofia pauleta; Xiangjin Xie; Edward I Solomon
Analysis of resonance Raman data on the blue copper site in pseudoazurin: excited state π and σ charge transfer distortions and their relation to ground state reorganization energy.
Journal of inorganic biochemistry 2012;115():155-62.
2012: Martin Srnec; Shaun D Wong; Jason England; Lawrence Que; Edward I Solomon
π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity.
Proceedings of the National Academy of Sciences of the United States of America 2012;109(36):14326-31.
2012: Samuel A Wilson; Junying Chen; Martin Clémancey; Ricardo Garcia-Serres; Britt Hedman; Keith O Hodgson; Seungwoo Hong; Jean-Marc Latour; Yong-Min Lee; Wonwoo Nam; Takashi Nomura; Takashi Ogura; Edward I Solomon
[Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.
Journal of the American Chemical Society 2012;134(28):11791-806.
2012: Jake W Ginsbach; Matthew T Kieber-Emmons; Akio Noguchi; Ryohei Nomoto; Yasuo Ohnishi; Edward I Solomon
Structure/function correlations among coupled binuclear copper proteins through spectroscopic and reactivity studies of NspF.
Proceedings of the National Academy of Sciences of the United States of America 2012;109(27):10793-7.
2012: Ga Young Park; Munzarin F Qayyum; Edward I Solomon; Julia Woertink; Britt Hedman; Keith O Hodgson; Amy A Narducci Sarjeant; Kenneth D Karlin
Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.
Journal of the American Chemical Society 2012;134(20):8513-24.
2012: Fabien Durand; Sébastien Gounel; Ryan G Hadt; Christian Hauge Kjaergaard; Edward I Solomon; Emmanuel Suraniti; Nicolas Mano
Bilirubin oxidase from Bacillus pumilus: a promising enzyme for the elaboration of efficient cathodes in biofuel cells.
Biosensors & bioelectronics 2012;35(1):140-6.
2012: Christian H Kjaergaard; Nicolas Mano; Munzarin F Qayyum; Fabien Durand; Sébastien Gounel; Britt Hedman; Keith O Hodgson; Brice Kauffmann; Emmanuel Suraniti; Federico Tasca; Edward I Solomon
Spectroscopic and crystallographic characterization of "alternative resting" and "resting oxidized" enzyme forms of bilirubin oxidase: implications for activity and electrochemical behavior of multicopper oxidases.
Journal of the American Chemical Society 2012;134(12):5548-51.
2012: Adam L Tenderholt; Britt Hedman; Keith O Hodgson; Richard H Holm; Edward I Solomon
Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites.
Inorganic chemistry 2012;51(6):3436-42.
2012: Ane B Tomter; Giorgio Zoppellaro; Niels H Andersen; Anne-Laure Barra; Caleb B Bell; Edward I Solomon; K Kristoffer Andersson
Spectroscopic studies of the iron and manganese reconstituted tyrosyl radical in Bacillus cereus ribonucleotide reductase R2 protein.
PloS one 2012;7(3):e33436.
2011: Abhishek Dey; Britt Hedman; Keith O Hodgson; Yi Peng; Joan B Broderick; William E Broderick; Edward I Solomon
S K-edge XAS and DFT calculations on SAM dependent pyruvate formate-lyase activating enzyme: nature of interaction between the Fe4S4 cluster and SAM and its role in reactivity.
Journal of the American Chemical Society 2011;133(46):18656-62.
2011: Matthew T Kieber-Emmons; Yuqi Li; Zakaria Halime; Kenneth D Karlin; Edward I Solomon
Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity.
Inorganic chemistry 2011;50(22):11777-86.
2011: Adrienne R Diebold; Graham R Moran; Michael L Neidig; June M Brownlee; Christina D Brown-Marshall; Edward I Solomon
Activation of α-keto acid-dependent dioxygenases: application of an {FeNO}7/{FeO2}8 methodology for characterizing the initial steps of O2 activation.
Journal of the American Chemical Society 2011;133(45):18148-60.
2011: Patrick J Donoghue; Ritimukta Sarangi; Edward I Solomon; Jacqui Tehranchi; Christopher J Cramer; William B Tolman
Rapid C-H bond activation by a monocopper(III)-hydroxide complex.
Journal of the American Chemical Society 2011;133(44):17602-5.
2011: Jaeheung Cho; Britt Hedman; Keith O Hodgson; Sujin Jeon; Eun A Kang; Mi Hee Lim; Lei V Liu; Edward I Solomon; Joan Selverstone Valentine; Samuel A Wilson; Joseph J Braymer; Wonwoo Nam
Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex.
Nature 2011;478(7370):502-5.
2011: Adrienne R Diebold; Grit D Straganz; Edward I Solomon
Spectroscopic and computational studies of α-keto acid binding to Dke1: understanding the role of the facial triad and the reactivity of β-diketones.
Journal of the American Chemical Society 2011;133(40):15979-91.
2011: Shaun D Wong; Caleb B Bell; Lei V Liu; Yeonju Kwak; Jason England; E Ercan Alp; Jiyong Zhao; Lawrence Que; Edward I Solomon
Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity.
Angewandte Chemie (International ed. in English) 2011;50(14):3215-8.
2011: Ryan L Peterson; Maxime A Siegler; Edward I Solomon; Tomoyoshi Suenobu; Li Tian; Shunichi Fukuzumi; Richard A Himes; Hiroaki Kotani; Kenneth D Karlin
Cupric superoxo-mediated intermolecular C-H activation chemistry.
Journal of the American Chemical Society 2011;133(6):1702-5.
2011: Edward I Solomon; Jake W Ginsbach; David E Heppner; Matthew T Kieber-Emmons; Christian H Kjaergaard; Pieter J Smeets; Li Tian; Julia S Woertink
Copper dioxygen (bio)inorganic chemistry.
Faraday discussions 2011;148():11-39; discussion 97-108.
2010: Lei V Liu; Caleb B Bell; Shaun D Wong; Samuel A Wilson; Yeonju Kwak; Marina S Chow; Jiyong Zhao; Keith O Hodgson; Britt Hedman; Edward I Solomon
Definition of the intermediates and mechanism of the anticancer drug bleomycin using nuclear resonance vibrational spectroscopy and related methods.
Proceedings of the National Academy of Sciences of the United States of America 2010;107(52):22419-24.
2010: Jennifer K Schwartz; Xiaofeng S Liu; Takehiko Tosha; Adrienne Diebold; Elizabeth C Theil; Edward I Solomon
CD and MCD spectroscopic studies of the two Dps miniferritin proteins from Bacillus anthracis: role of O2 and H2O2 substrates in reactivity of the diiron catalytic centers.
Biochemistry 2010;49(49):10516-25.
2010: Peng Kang; Elena Bobyr; John Dustman; Keith O Hodgson; Britt Hedman; Edward I Solomon; T Daniel P Stack
Bis(μ-oxo) dicopper(III) species of the simplest peralkylated diamine: enhanced reactivity toward exogenous substrates.
Inorganic chemistry 2010;49(23):11030-8.
2010: Jaeheung Cho; Ritimukta Sarangi; Hye Yeon Kang; Jung Yoon Lee; Minoru Kubo; Takashi Ogura; Edward I Solomon; Wonwoo Nam
Synthesis, structural, and spectroscopic characterization and reactivities of mononuclear cobalt(III)-peroxo complexes.
Journal of the American Chemical Society 2010;132(47):16977-86.
2010: Pieter J Smeets; Ryan G Hadt; Julia S Woertink; Pieter Vanelderen; Robert A Schoonheydt; Bert F Sels; Edward I Solomon
Oxygen precursor to the reactive intermediate in methanol synthesis by Cu-ZSM-5.
Journal of the American Chemical Society 2010;132(42):14736-8.
2010: Julia S Woertink; Li Tian; Debabrata Maiti; Heather R Lucas; Richard A Himes; Kenneth D Karlin; Frank Neese; Christian Würtele; Max C Holthausen; Eckhard Bill; Jörg Sundermeyer; Siegfried Schindler; Edward I Solomon
Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state.
Inorganic chemistry 2010;49(20):9450-9.
2010: Yunho Lee; Dong-Heon Lee; Ga Young Park; Heather R Lucas; Amy A Narducci Sarjeant; Matthew T Kieber-Emmons; Michael A Vance; Ashley E Milligan; Edward I Solomon; Kenneth D Karlin
Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.
Inorganic chemistry 2010;49(19):8873-85.
2010: Ning Sun; Abhishek Dey; Zhiguang Xiao; Anthony G Wedd; Keith O Hodgson; Britt Hedman; Edward I Solomon
Solvation effects on S K-edge XAS spectra of Fe-S proteins: normal and inverse effects on WT and mutant rubredoxin.
Journal of the American Chemical Society 2010;132(36):12639-47.
2010: Adrienne R Diebold; Michael L Neidig; Graham R Moran; Grit D Straganz; Edward I Solomon
The three-his triad in Dke1: comparisons to the classical facial triad.
Biochemistry 2010;49(32):6945-52.
2010: Adam L Tenderholt; Jun-Jieh Wang; Robert K Szilagyi; Richard H Holm; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues.
Journal of the American Chemical Society 2010;132(24):8359-71.
2010: Steven Vancoillie; Jakub Chalupský; Ulf Ryde; Edward I Solomon; Kristine Pierloot; Frank Neese; Lubomír Rulísek
Multireference ab initio calculations of g tensors for trinuclear copper clusters in multicopper oxidases.
The journal of physical chemistry. B 2010;114(22):7692-702.
2010: Anthony J Augustine; Christian Kjaergaard; Munzarin Qayyum; Lynn Ziegler; Daniel J Kosman; Keith O Hodgson; Britt Hedman; Edward I Solomon
Systematic perturbation of the trinuclear copper cluster in the multicopper oxidases: the role of active site asymmetry in its reduction of O2 to H2O.
Journal of the American Chemical Society 2010;132(17):6057-67.
2010: Zakaria Halime; Matthew T Kieber-Emmons; Munzarin F Qayyum; Biplab Mondal; Thirumanavelan Gandhi; Simona C Puiu; Eduardo E Chufán; Amy A Narducci Sarjeant; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.
Inorganic chemistry 2010;49(8):3629-45.
2010: Pieter J Smeets; Julia S Woertink; Bert F Sels; Edward I Solomon; Robert A Schoonheydt
Transition-metal ions in zeolites: coordination and activation of oxygen.
Inorganic chemistry 2010;49(8):3573-83.
2010: William B Tolman; Edward I Solomon
Preface: Forum on dioxygen activation and reduction.
Inorganic chemistry 2010;49(8):3555-6.
2010: Rosalie K Hocking; Serena DeBeer George; Kenneth N Raymond; Keith O Hodgson; Britt Hedman; Edward I Solomon
Fe L-edge X-ray absorption spectroscopy determination of differential orbital covalency of siderophore model compounds: electronic structure contributions to high stability constants.
Journal of the American Chemical Society 2010;132(11):4006-15.
2010: Christina D Brown-Marshall; Adrienne R Diebold; Edward I Solomon
Reaction coordinate of isopenicillin N synthase: oxidase versus oxygenase activity.
Biochemistry 2010;49(6):1176-82.
2010: Ga Young Park; Yunho Lee; Dong-Heon Lee; Julia S Woertink; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.
Chemical communications (Cambridge, England) 2010;46(1):91-3.
2009: Yunho Lee; Ga Young Park; Heather R Lucas; Peter L Vajda; Kaliappan Kamaraj; Michael A Vance; Ashley E Milligan; Julia S Woertink; Maxime A Siegler; Amy A Narducci Sarjeant; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species.
Inorganic chemistry 2009;48(23):11297-309.
2009: Julia S Woertink; Pieter J Smeets; Marijke H Groothaert; Michael A Vance; Bert F Sels; Robert A Schoonheydt; Edward I Solomon
A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanol.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(45):18908-13.
2009: Ga Young Park; Subramanian Deepalatha; Simona C Puiu; Dong-Heon Lee; Biplab Mondal; Amy A Narducci Sarjeant; Diego del Rio; Monita Y M Pau; Edward I Solomon; Kenneth D Karlin
A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2009;14(8):1301-11.
2009: Jaeheung Cho; Ritimukta Sarangi; Jamespandi Annaraj; Sung Yeon Kim; Minoru Kubo; Takashi Ogura; Edward I Solomon; Wonwoo Nam
Geometric and electronic structure and reactivity of a mononuclear "side-on" nickel(III)-peroxo complex.
Nature chemistry 2009;1(7):568-72.
2009: Xiangjin Xie; Ryan G Hadt; Sofia pauleta; Pablo J González; Sun Un; Isabel Moura; Edward I Solomon
A variable temperature spectroscopic study on Paracoccuspantotrophus pseudoazurin: protein constraints on the blue Cu site.
Journal of inorganic biochemistry 2009;103(10):1307-13.
2009: Debabrata Maiti; Julia S Woertink; Reza A Ghiladi; Edward I Solomon; Kenneth D Karlin
Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.
Inorganic chemistry 2009;48(17):8342-56.
2009: Marina S Chow; Bekir E Eser; Samuel A Wilson; Keith O Hodgson; Britt Hedman; Paul F Fitzpatrick; Edward I Solomon
Spectroscopy and kinetics of wild-type and mutant tyrosine hydroxylase: mechanistic insight into O2 activation.
Journal of the American Chemical Society 2009;131(22):7685-98.
2009: Abhishek Dey; Yonging Jiang; Paul Ortiz de Montellano; Keith O Hodgson; Britt Hedman; Edward I Solomon
S K-edge XAS and DFT calculations on cytochrome P450: covalent and ionic contributions to the cysteine-Fe bond and their contribution to reactivity.
Journal of the American Chemical Society 2009;131(22):7869-78.
2009: Bryan T Op't Holt; Michael A Vance; Liviu M Mirica; David E Heppner; T Daniel P Stack; Edward I Solomon
Reaction coordinate of a functional model of tyrosinase: spectroscopic and computational characterization.
Journal of the American Chemical Society 2009;131(18):6421-38.
2009: Jungjoo Yoon; Satoshi Fujii; Edward I Solomon
Geometric and electronic structure differences between the type 3 copper sites of the multicopper oxidases and hemocyanin/tyrosinase.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(16):6585-90.
2009: Somdatta Ghosh; Xiangjin Xie; Abhishek Dey; Yan Sun; Charles P Scholes; Edward I Solomon
Thermodynamic equilibrium between blue and green copper sites and the role of the protein in controlling function.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(13):4969-74.
2009: Heather R Lucas; Lei Li; Amy A Narducci Sarjeant; Michael A Vance; Edward I Solomon; Kenneth D Karlin
Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.
Journal of the American Chemical Society 2009;131(9):3230-45.
2009: Rosalie K Hocking; Serena DeBeer George; Zeev Gross; F Ann Walker; Keith O Hodgson; Britt Hedman; Edward I Solomon
Fe L- and K-edge XAS of low-spin ferric corrole: bonding and reactivity relative to low-spin ferric porphyrin.
Inorganic chemistry 2009;48(4):1678-88.
2009: Edward I Solomon; Shaun D Wong; Lei V Liu; Andrea Decker; Marina S Chow
Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites.
Current opinion in chemical biology 2009;13(1):99-113.
2009: Somdatta Ghosh; Abhishek Dey; Yan Sun; Charles P Scholes; Edward I Solomon
Spectroscopic and computational studies of nitrite reductase: proton induced electron transfer and backbonding contributions to reactivity.
Journal of the American Chemical Society 2009;131(1):277-88.
2009: Caleb B Bell; Jennifer R Calhoun; Elena Bobyr; Pin-Pin Wei; Britt Hedman; Keith O Hodgson; William F Degrado; Edward I Solomon
Spectroscopic definition of the biferrous and biferric sites in de novo designed four-helix bundle DFsc peptides: implications for O2 reactivity of binuclear non-heme iron enzymes.
Biochemistry 2009;48(1):59-73.
2009: Jihae Yoon; Samuel A Wilson; Yu Kyeong Jang; Mi Sook Seo; Kasi Nehru; Britt Hedman; Keith O Hodgson; Eckhard Bill; Edward I Solomon; Wonwoo Nam
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts.
Angewandte Chemie (International ed. in English) 2009;48(7):1257-60.
2008: Ritimukta Sarangi; Rosalie K Hocking; Michael L Neidig; Maurizio Benfatto; Theodore R. Holman; Edward I Solomon; Keith O Hodgson; Britt Hedman
Geometric structure determination of N694C lipoxygenase: a comparative near-edge X-ray absorption spectroscopy and extended X-ray absorption fine structure study.
Inorganic chemistry 2008;47(24):11543-50.
2008: James P Collman; Abhishek Dey; Ying Yang; Richard DECREAU; Takehiro Ohta; Edward I Solomon
Intermediates involved in the two electron reduction of NO to N2O by a functional synthetic model of heme containing bacterial NO reductase.
Journal of the American Chemical Society 2008;130(49):16498-9.
2008: Somdatta Ghosh; Jordi Cirera; Michael A Vance; Tetsuya Ono; Kiyoshi Fujisawa; Edward I Solomon
Spectroscopic and electronic structure studies of phenolate Cu(II) complexes: phenolate ring orientation and activation related to cofactor biogenesis.
Journal of the American Chemical Society 2008;130(48):16262-73.
2008: Ane B Tomter; Caleb B Bell; Asmund K Røhr; K Kristoffer Andersson; Edward I Solomon
Circular dichroism and magnetic circular dichroism studies of the biferrous site of the class Ib ribonucleotide reductase from Bacillus cereus: comparison to the class Ia enzymes.
Biochemistry 2008;47(43):11300-9.
2008: James P Collman; Ying Yang; Abhishek Dey; Richard DECREAU; Somdatta Ghosh; Takehiro Ohta; Edward I Solomon
A functional nitric oxide reductase model.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(41):15660-5.
2008: Marina S Chow; Lei V Liu; Edward I Solomon
Further insights into the mechanism of the reaction of activated bleomycin with DNA.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(36):13241-5.
2008: Edward I Solomon; Anthony J Augustine; Jungjoo Yoon
O2 reduction to H2O by the multicopper oxidases.
Dalton transactions (Cambridge, England : 2003) 2008;(30):3921-32.
2008: Natasa Mitić; Jennifer K Schwartz; Brian J Brazeau; John D Lipscomb; Edward I Solomon
CD and MCD studies of the effects of component B variant binding on the biferrous active site of methane monooxygenase.
Biochemistry 2008;47(32):8386-97.
2008: Jennifer K Schwartz; Xiaofeng S Liu; Takehiko Tosha; Elizabeth C Theil; Edward I Solomon
Spectroscopic definition of the ferroxidase site in M ferritin: comparison of binuclear substrate vs cofactor active sites.
Journal of the American Chemical Society 2008;130(29):9441-50.
2008: James P Collman; Abhishek Dey; Richard DECREAU; Ying Yang; Ali Hosseini; Edward I Solomon; Todd A Eberspacher
Interaction of nitric oxide with a functional model of cytochrome c oxidase.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(29):9892-6.
2008: Adam L Tenderholt; Robert K Szilagyi; Richard H Holm; Keith O Hodgson; Britt Hedman; Edward I Solomon
Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study.
Inorganic chemistry 2008;47(14):6382-92.
2008: Jennifer K Schwartz; Pin-Pin Wei; Kevin H Mitchell; Brian G Fox; Edward I Solomon
Geometric and electronic structure studies of the binuclear nonheme ferrous active site of toluene-4-monooxygenase: parallels with methane monooxygenase and insight into the role of the effector proteins in O2 activation.
Journal of the American Chemical Society 2008;130(22):7098-109.
2008: Debabrata Maiti; Dong-Heon Lee; Amy A Narducci Sarjeant; Monita Y M Pau; Edward I Solomon; Katya Gaoutchenova; Jörg Sundermeyer; Kenneth D Karlin
Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species.
Journal of the American Chemical Society 2008;130(21):6700-1.
2008: Debabrata Maiti; Julia S Woertink; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent.
Inorganic chemistry 2008;47(9):3787-800.
2008: Xiangjin Xie; Serge I Gorelsky; Ritimukta Sarangi; Dewain K Garner; Hee Jung Hwang; Keith O Hodgson; Britt Hedman; Yi Lu; Edward I Solomon
Perturbations to the geometric and electronic structure of the CuA site: factors that influence delocalization and their contributions to electron transfer.
Journal of the American Chemical Society 2008;130(15):5194-205.
2008: Edward I Solomon; Xiangjin Xie; Abhishek Dey
Mixed valent sites in biological electron transfer.
Chemical Society reviews 2008;37(4):623-38.
2008: Ritimukta Sarangi; Serge I Gorelsky; Lipika Basumallick; Hee Jung Hwang; Russell C Pratt; T Daniel P Stack; Yi Lu; Keith O Hodgson; Britt Hedman; Edward I Solomon
Spectroscopic and density functional theory studies of the blue-copper site in M121SeM and C112SeC azurin: Cu-Se versus Cu-S bonding.
Journal of the American Chemical Society 2008;130(12):3866-77.
2008: Anthony J Augustine; Mads Emil Kragh; Ritimukta Sarangi; Satoshi Fujii; Barry D Liboiron; Christopher S Stoj; Daniel J Kosman; Keith O Hodgson; Britt Hedman; Edward I Solomon
Spectroscopic studies of perturbed T1 Cu sites in the multicopper oxidases Saccharomyces cerevisiae Fet3p and Rhus vernicifera laccase: allosteric coupling between the T1 and trinuclear Cu sites.
Biochemistry 2008;47(7):2036-45.
2008: Takehiro Ohta; Sarmistha Chakrabarty; John D Lipscomb; Edward I Solomon
Near-IR MCD of the nonheme ferrous active site in naphthalene 1,2-dioxygenase: correlation to crystallography and structural insight into the mechanism of Rieske dioxygenases.
Journal of the American Chemical Society 2008;130(5):1601-10.
2008: Ritimukta Sarangi; John T York; Matthew E Helton; Kiyoshi Fujisawa; Kenneth D Karlin; William B Tolman; Keith O Hodgson; Britt Hedman; Edward I Solomon
X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding.
Journal of the American Chemical Society 2008;130(2):676-86.
2008: Caleb B Bell; Shaun D Wong; Yuming Xiao; Eric J Klinker; Adam L Tenderholt; Matt C Smith; Jan-Uwe Rohde; Lawrence Que; Stephen P Cramer; Edward I Solomon
A combined NRVS and DFT study of Fe(IV)=O model complexes: a diagnostic method for the elucidation of non-heme iron enzyme intermediates.
Angewandte Chemie (International ed. in English) 2008;47(47):9071-4.
2007: Andrea Decker; Jan-Uwe Rohde; Eric J Klinker; Shaun D Wong; Lawrence Que; Edward I Solomon
Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity.
Journal of the American Chemical Society 2007;129(51):15983-96.
2007: Abhishek Dey; Francis E Jenney; Michael W W Adams; Elena Babini; Yasuhiro Takahashi; Keiichi Fukuyama; Keith O Hodgson; Britt Hedman; Edward I Solomon
Solvent tuning of electrochemical potentials in the active sites of HiPIP versus ferredoxin.
Science (New York, N.Y.) 2007;318(5855):1464-8.
2007: Michael L Neidig; Christina D Brown; Kenneth M Light; Danica Galonic Fujimori; Elizabeth M Nolan; John C Price; Eric W Barr; J Martin Bollinger; Carsten Krebs; Christopher T Walsh; Edward I Solomon
CD and MCD of CytC3 and taurine dioxygenase: role of the facial triad in alpha-KG-dependent oxygenases.
Journal of the American Chemical Society 2007;129(46):14224-31.
2007: Monita Y M Pau; John D Lipscomb; Edward I Solomon
Substrate activation for O2 reactions by oxidized metal centers in biology.
Proceedings of the National Academy of Sciences of the United States of America 2007;104(47):18355-62.
2007: Abhishek Dey; Kayla N Green; Roxanne M Jenkins; Stephen P Jeffrey; Marcetta Y Darensbourg; Keith O Hodgson; Britt Hedman; Edward I Solomon
S K-edge XAS and DFT calculations on square-planar NiII-thiolate complexes: effects of active and passive H-bonding.
Inorganic chemistry 2007;46(23):9655-60.
2007: Adam L Tenderholt; Robert K Szilagyi; Richard H Holm; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes.
Journal of inorganic biochemistry 2007;101(11-12):1594-600.
2007: Juyoung Yoon; Edward I Solomon
Electronic structure of the peroxy intermediate and its correlation to the native intermediate in the multicopper oxidases: insights into the reductive cleavage of the o-o bond.
Journal of the American Chemical Society 2007;129(43):13127-36.
2007: Anthony J Augustine; Liliana Quintanar; Christopher S Stoj; Daniel J Kosman; Edward I Solomon
Spectroscopic and kinetic studies of perturbed trinuclear copper clusters: the role of protons in reductive cleavage of the O-O bond in the multicopper oxidase Fet3p.
Journal of the American Chemical Society 2007;129(43):13118-26.
2007: Junko Yano; John H Robblee; Yulia Pushkar; Matthew A Marcus; Jesper Bendix; José M Workman; Terrence J Collins; Edward I Solomon; Serena DeBeer George; Vittal K Yachandra
Polarized X-ray absorption spectroscopy of single-crystal Mn(V) complexes relevant to the oxygen-evolving complex of photosystem II.
Journal of the American Chemical Society 2007;129(43):12989-3000.
2007: Abhishek Dey; Francis E Jenney; Michael W W Adams; Michael K Johnson; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on superoxide reductase: role of the axial thiolate in reactivity.
Journal of the American Chemical Society 2007;129(41):12418-31.
2007: Somdatta Ghosh; Abhishek Dey; Oleg M Usov; Yan Sun; Vladimir M Grigoryants; Charles P Scholes; Edward I Solomon
Resolution of the spectroscopy versus crystallography issue for NO intermediates of nitrite reductase from Rhodobacter sphaeroides.
Journal of the American Chemical Society 2007;129(34):10310-1.
2007: Juyoung Yoon; Barry D Liboiron; Ritimukta Sarangi; Keith O Hodgson; Britt Hedman; Edward I Solomon
The two oxidized forms of the trinuclear Cu cluster in the multicopper oxidases and mechanism for the decay of the native intermediate.
Proceedings of the National Academy of Sciences of the United States of America 2007;104(34):13609-14.
2007: Natasa Mitić; Michael D Clay; Lana Saleh; J Martin Bollinger; Edward I Solomon
Spectroscopic and electronic structure studies of intermediate X in ribonucleotide reductase R2 and two variants: a description of the FeIV-oxo bond in the FeIII-O-FeIV dimer.
Journal of the American Chemical Society 2007;129(29):9049-65.
2007: Dong-Heon Lee; Lanying Q Hatcher; Michael A Vance; Ritimukta Sarangi; Ashley E Milligan; Amy A Narducci Sarjeant; Christopher D Incarvito; Arnold L Rheingold; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.
Inorganic chemistry 2007;46(15):6056-68.
2007: Debabrata Maiti; Julia S Woertink; Michael A Vance; Ashley E Milligan; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry.
Journal of the American Chemical Society 2007;129(28):8882-92.
2007: Edward I Solomon; Ritimukta Sarangi; Julia S Woertink; Anthony J Augustine; Juyoung Yoon; Somdatta Ghosh
O2 and N2O activation by Bi-, Tri-, and tetranuclear Cu clusters in biology.
Accounts of chemical research 2007;40(7):581-91.
2007: Michael L Neidig; Aaron T Wecksler; Gerhard Schenk; Theodore R. Holman; Edward I Solomon
Kinetic and spectroscopic studies of N694C lipoxygenase: a probe of the substrate activation mechanism of a nonheme ferric enzyme.
Journal of the American Chemical Society 2007;129(24):7531-7.
2007: Christina D Brown; Michael L Neidig; Matthew B Neibergall; John D Lipscomb; Edward I Solomon
VTVH-MCD and DFT studies of thiolate bonding to [FeNO]7/[FeO2]8 complexes of isopenicillin N synthase: substrate determination of oxidase versus oxygenase activity in nonheme Fe enzymes.
Journal of the American Chemical Society 2007;129(23):7427-38.
2007: Abhishek Dey; Stephen P Jeffrey; Marcetta Y Darensbourg; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase.
Inorganic chemistry 2007;46(12):4989-96.
2007: Liliana Quintanar; Christopher S Stoj; Alexander B Taylor; Peter Hart; Daniel J Kosman; Edward I Solomon
Shall we dance? How a multicopper oxidase chooses its electron transfer partner.
Accounts of chemical research 2007;40(6):445-52.
2007: Reza A Ghiladi; Eduardo E Chufan; Diego del Río; Edward I Solomon; Carsten Krebs; Boi Hanh Huynh; Hong-Wei Huang; Pierre Moanne-Loccoz; Susan Kaderli; Marcus Honecker; Andreas D Zuberbühler; Lisa Marzilli; Robert J Cotter; Kenneth D Karlin
Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+.
Inorganic chemistry 2007;46(10):3889-902.
2007: James P Collman; Richard DECREAU; Yilong Yan; Juyoung Yoon; Edward I Solomon
Intramolecular single-turnover reaction in a cytochrome C oxidase model bearing a Tyr244 mimic.
Journal of the American Chemical Society 2007;129(18):5794-5.
2007: Somdatta Ghosh; Serge I Gorelsky; Serena DeBeer George; Jeannine M Chan; Inês Cabrito; David M Dooley; José J G Moura; Isabel Moura; Edward I Solomon
Spectroscopic, computational, and kinetic studies of the mu4-sulfide-bridged tetranuclear CuZ cluster in N2O reductase: pH effect on the edge ligand and its contribution to reactivity.
Journal of the American Chemical Society 2007;129(13):3955-65.
2007: Christopher S Stoj; Anthony J Augustine; Edward I Solomon; Daniel J Kosman
Structure-function analysis of the cuprous oxidase activity in Fet3p from Saccharomyces cerevisiae.
The Journal of biological chemistry 2007;282(11):7862-8.
2007: Ritimukta Sarangi; Serena DeBeer George; Deanne Jackson Rudd; Robert K Szilagyi; Xavi Ribas; Concepció Rovira; Manuel Almeida; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge X-ray absorption spectroscopy as a probe of ligand-metal bond covalency: metal vs ligand oxidation in copper and nickel dithiolene complexes.
Journal of the American Chemical Society 2007;129(8):2316-26.
2007: Monita Y M Pau; Mindy I Davis; Allen M Orville; John D Lipscomb; Edward I Solomon
Spectroscopic and electronic structure study of the enzyme-substrate complex of intradiol dioxygenases: substrate activation by a high-spin ferric non-heme iron site.
Journal of the American Chemical Society 2007;129(7):1944-58.
2007: Woon Ju Song; Mi Sook Seo; Serena DeBeer George; Takehiro Ohta; Rita Song; Min-Jung Kang; Takehiko Tosha; Teizo Kitagawa; Edward I Solomon; Wonwoo Nam
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
Journal of the American Chemical Society 2007;129(5):1268-77.
2007: Debabrata Maiti; H Christopher Fry; Julia S Woertink; Michael A Vance; Edward I Solomon; Kenneth D Karlin
A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols.
Journal of the American Chemical Society 2007;129(2):264-5.
2007: Rosalie K Hocking; Erik C Wasinger; Yi-Lin Yan; Frank M F Degroot; F Ann Walker; Keith O Hodgson; Britt Hedman; Edward I Solomon
Fe L-edge X-ray absorption spectroscopy of low-spin heme relative to non-heme Fe complexes: delocalization of Fe d-electrons into the porphyrin ligand.
Journal of the American Chemical Society 2007;129(1):113-25.
2007: Kallol Ray; Serena DeBeer George; Edward I Solomon; Karl Wieghardt; Frank Neese
Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations.
Chemistry (Weinheim an der Bergstrasse, Germany) 2007;13(10):2783-97.
2006: Serge I Gorelsky; Xiangjin Xie; Ying Chen; James A Fee; Edward I Solomon
The two-state issue in the mixed-valence binuclear CuA center in cytochrome C oxidase and N2O reductase.
Journal of the American Chemical Society 2006;128(51):16452-3.
2006: Lanying Q Hatcher; Dong-Heon Lee; Michael A Vance; Ashley E Milligan; Ritimukta Sarangi; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation.
Inorganic chemistry 2006;45(25):10055-7.
2006: Michael L Neidig; Christina D Brown; Michael Kavana; Oliver W Choroba; Jonathan B Spencer; Graham R Moran; Edward I Solomon
Spectroscopic and electronic structure studies of the role of active site interactions in the decarboxylation reaction of alpha-keto acid-dependent dioxygenases.
Journal of inorganic biochemistry 2006;100(12):2108-16.
2006: Pin-Pin Wei; Ane B Tomter; Asmund K Røhr; K Kristoffer Andersson; Edward I Solomon
Circular dichroism and magnetic circular dichroism studies of the active site of p53R2 from human and mouse: iron binding and nature of the biferrous site relative to other ribonucleotide reductases.
Biochemistry 2006;45(47):14043-51.
2006: Christopher S Stoj; Anthony J Augustine; Lynn Zeigler; Edward I Solomon; Daniel J Kosman
Structural basis of the ferrous iron specificity of the yeast ferroxidase, Fet3p.
Biochemistry 2006;45(42):12741-9.
2006: Edward I Solomon
Spectroscopic methods in bioinorganic chemistry: blue to green to red copper sites.
Inorganic chemistry 2006;45(20):8012-25.
2006: Edward I Solomon; Serge I Gorelsky; Abhishek Dey
Metal-thiolate bonds in bioinorganic chemistry.
Journal of computational chemistry 2006;27(12):1415-28.
2006: Priscilla Lugo-Mas; Abhishek Dey; Liang Xu; Steven D Davin; Jason B Benedict; Werner Kaminsky; Keith O Hodgson; Britt Hedman; Edward I Solomon; Julie A Kovacs
How does single oxygen atom addition affect the properties of an Fe-nitrile hydratase analogue? The compensatory role of the unmodified thiolate.
Journal of the American Chemical Society 2006;128(34):11211-21.
2006: Erika N Segraves; Maksymilian Chruszcz; Michael L Neidig; Viola Ruddat; Jing Zhou; Aaron T Wecksler; Wladek Minor; Edward I Solomon; Theodore R. Holman
Kinetic, spectroscopic, and structural investigations of the soybean lipoxygenase-1 first-coordination sphere mutant, Asn694Gly.
Biochemistry 2006;45(34):10233-42.
2006: Michael L Neidig; Andrea Decker; Oliver W Choroba; Fanglu Huang; Michael Kavana; Graham R Moran; Jonathan B Spencer; Edward I Solomon
Spectroscopic and electronic structure studies of aromatic electrophilic attack and hydrogen-atom abstraction by non-heme iron enzymes.
Proceedings of the National Academy of Sciences of the United States of America 2006;103(35):12966-73.
2006: Rosalie K Hocking; Erik C Wasinger; Frank M F de Groot; Keith O Hodgson; Britt Hedman; Edward I Solomon
Fe L-edge XAS studies of K4[Fe(CN)6] and K3[Fe(CN)6]: a direct probe of back-bonding.
Journal of the American Chemical Society 2006;128(32):10442-51.
2006: Abhishek Dey; Rosalie K Hocking; Peter Larsen; Andrew S Borovik; Keith O Hodgson; Britt Hedman; Edward I Solomon
X-ray absorption spectroscopy and density functional theory studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-): comparison of bonding and hydrogen bonding in oxo and sulfido complexes.
Journal of the American Chemical Society 2006;128(30):9825-33.
2006: Ritimukta Sarangi; Nermeen W Aboelella; Kiyoshi Fujisawa; William B Tolman; Britt Hedman; Keith O Hodgson; Edward I Solomon
X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding.
Journal of the American Chemical Society 2006;128(25):8286-96.
2006: Serena DeBeer George; Kuo-Wei Huang; Robert M Waymouth; Edward I Solomon
Metal and ligand K-edge XAS of titanium-TEMPO complexes: determination of oxidation states and insights into Ti-O bond homolysis.
Inorganic chemistry 2006;45(11):4468-77.
2006: Andrea Decker; Marina S Chow; Jyllian N Kemsley; Nicolai Lehnert; Edward I Solomon
Direct hydrogen-atom abstraction by activated bleomycin: an experimental and computational study.
Journal of the American Chemical Society 2006;128(14):4719-33.
2006: Lanying Q Hatcher; Michael A Vance; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.
Inorganic chemistry 2006;45(7):3004-13.
2006: Andrea Decker; Michael D Clay; Edward I Solomon
Spectroscopy and electronic structures of mono- and binuclear high-valent non-heme iron-oxo systems.
Journal of inorganic biochemistry 2006;100(4):697-706.
2006: D Flemming Hansen; Serge I Gorelsky; Ritimukta Sarangi; Keith O Hodgson; Britt Hedman; Hans E M Christensen; Edward I Solomon; Jens Led
Reinvestigation of the method used to map the electronic structure of blue copper proteins by NMR relaxation.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2006;11(3):277-85.
2006: Liviu M Mirica; Deanne Jackson Rudd; Michael A Vance; Edward I Solomon; Keith O Hodgson; Britt Hedman; T Daniel P Stack
mu-eta2:eta2-peroxodicopper(II) complex with a secondary diamine ligand: a functional model of tyrosinase.
Journal of the American Chemical Society 2006;128(8):2654-65.
2006: Abhishek Dey; Marina Chow; Kayoko Taniguchi; Priscilla Lugo-Mas; Steven Davin; Mizuo Maeda; Julie A Kovacs; Masafumi Odaka; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge XAS and DFT calculations on nitrile hydratase: geometric and electronic structure of the non-heme iron active site.
Journal of the American Chemical Society 2006;128(2):533-41.
2006: Serge I Gorelsky; Somdatta Ghosh; Edward I Solomon
Mechanism of N2O reduction by the mu4-S tetranuclear CuZ cluster of nitrous oxide reductase.
Journal of the American Chemical Society 2006;128(1):278-90.
2005: Ritimukta Sarangi; Maurizio Benfatto; Kuniko Hayakawa; Luigi Bubacco; Edward I Solomon; Keith O Hodgson; Britt Hedman
MXAN analysis of the XANES energy region of a mononuclear copper complex: applications to bioinorganic systems.
Inorganic chemistry 2005;44(26):9652-9.
2005: James P Collman; Yi-Lin Yan; Todd A Eberspacher; Xiangjin Xie; Edward I Solomon
Oxygen binding of water-soluble cobalt porphyrins in aqueous solution.
Inorganic chemistry 2005;44(26):9628-30.
2005: Michael L Neidig; Edward I Solomon
Structure-function correlations in oxygen activating non-heme iron enzymes.
Chemical communications (Cambridge, England) 2005;(47):5843-63.
2005: Michael L Neidig; Andrea Decker; Michael Kavana; Graham R Moran; Edward I Solomon
Spectroscopic and computational studies of NTBC bound to the non-heme iron enzyme (4-hydroxyphenyl)pyruvate dioxygenase: active site contributions to drug inhibition.
Biochemical and biophysical research communications 2005;338(1):206-14.
2005: Pin-Pin Wei; Andrew J Skulan; HERSCHEL WADE; William F DeGrado; Edward I Solomon
Spectroscopic and computational studies of the de novo designed protein DF2t: correlation to the biferrous active site of ribonucleotide reductase and factors that affect O2 reactivity.
Journal of the American Chemical Society 2005;127(46):16098-106.
2005: Abhishek Dey; Cara L Roche; Marc A Walters; Keith O Hodgson; Britt Hedman; Edward I Solomon
Sulfur K-edge XAS and DFT calculations on [Fe4S4]2+ clusters: effects of H-bonding and structural distortion on covalency and spin topology.
Inorganic chemistry 2005;44(23):8349-54.
2005: Lei Li; Amy A Narducci Sarjeant; Michael A Vance; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.
Journal of the American Chemical Society 2005;127(44):15360-1.
2005: Juyoung Yoon; Edward I Solomon
Ground-state electronic and magnetic properties of a mu3-oxo-bridged trinuclear Cu(II) complex: correlation to the native intermediate of the multicopper oxidases.
Inorganic chemistry 2005;44(22):8076-86.
2005: Liliana Quintanar; Juyoung Yoon; Constantino P Aznar; Amy E Palmer; K Kristoffer Andersson; R David Britt; Edward I Solomon
Spectroscopic and electronic structure studies of the trinuclear Cu cluster active site of the multicopper oxidase laccase: nature of its coordination unsaturation.
Journal of the American Chemical Society 2005;127(40):13832-45.
2005: Juyoung Yoon; Liviu M Mirica; T Daniel P Stack; Edward I Solomon
Variable-temperature, variable-field magnetic circular dichroism studies of tris-hydroxy- and mu3-oxo-bridged trinuclear Cu(II) complexes: evaluation of proposed structures of the native intermediate of the multicopper oxidases.
Journal of the American Chemical Society 2005;127(39):13680-93.
2005: Abhishek Dey; Taka-aki Okamura; Norikazu Ueyama; Britt Hedman; Keith O Hodgson; Edward I Solomon
Sulfur K-edge XAS and DFT calculations on P450 model complexes: effects of hydrogen bonding on electronic structure and redox potentials.
Journal of the American Chemical Society 2005;127(34):12046-53.
2005: Diego Del Río; Ritimukta Sarangi; Eduardo E Chufán; Kenneth D Karlin; Britt Hedman; Keith O Hodgson; Edward I Solomon
Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4).
Journal of the American Chemical Society 2005;127(34):11969-78.
2005: Serge I Gorelsky; Lipika Basumallick; Josh Vura-Weis; Ritimukta Sarangi; Keith O Hodgson; Britt Hedman; Kiyoshi Fujisawa; Edward I Solomon
Spectroscopic and DFT investigation of [M{HB(3,5-iPr2pz)3}(SC6F5)] (M = Mn, Fe, Co, Ni, Cu, and Zn) model complexes: periodic trends in metal-thiolate bonding.
Inorganic chemistry 2005;44(14):4947-60.
2005: Liviu M Mirica; Michael Vance; Deanne Jackson Rudd; Britt Hedman; Keith O Hodgson; Edward I Solomon; T Daniel P Stack
Tyrosinase reactivity in a model complex: an alternative hydroxylation mechanism.
Science (New York, N.Y.) 2005;308(5730):1890-2.
2005: Liliana Quintanar; Christopher S Stoj; Tzu-Pin Wang; Daniel J Kosman; Edward I Solomon
Role of aspartate 94 in the decay of the peroxide intermediate in the multicopper oxidase Fet3p.
Biochemistry 2005;44(16):6081-91.
2005: Andrea Decker; Edward I Solomon
Comparison of FeIV=O heme and non-heme species: electronic structures, bonding, and reactivities.
Angewandte Chemie (International ed. in English) 2005;44(15):2252-5.
2005: Andrea Decker; Edward I Solomon
Dioxygen activation by copper, heme and non-heme iron enzymes: comparison of electronic structures and reactivities.
Current opinion in chemical biology 2005;9(2):152-63.
2005: Pierre Kennepohl; Frank Neese; Dirk Schweitzer; Henry L Jackson; Julie A Kovacs; Edward I Solomon
Spectroscopy of non-heme iron thiolate complexes: insight into the electronic structure of the low-spin active site of nitrile hydratase.
Inorganic chemistry 2005;44(6):1826-36.
2005: Lipika Basumallick; Ritimukta Sarangi; Serena DeBeer George; Bradley O Elmore; Alan B Hooper; Britt Hedman; Keith O Hodgson; Edward I Solomon
Spectroscopic and density functional studies of the red copper site in nitrosocyanin: role of the protein in determining active site geometric and electronic structure.
Journal of the American Chemical Society 2005;127(10):3531-44.
2005: Edward I Solomon
Preface forum: "functional insight from physical methods on metalloenzymes".
Inorganic chemistry 2005;44(4):723-6.
2005: Serena DeBeer George; Patrick Brant; Edward I Solomon
Metal and ligand K-edge XAS of organotitanium complexes: metal 4p and 3d contributions to pre-edge intensity and their contributions to bonding.
Journal of the American Chemical Society 2005;127(2):667-74.
2004: Nermeen W Aboelella; Sergey V Kryatov; Benjamin F Gherman; William W Brennessel; Victor G Young; Ritimukta Sarangi; Elena V Rybak-Akimova; Keith O Hodgson; Britt Hedman; Edward I Solomon; Christopher J Cramer; William B Tolman
Dioxygen activation at a single copper site: structure, bonding, and mechanism of formation of 1:1 Cu-O2 adducts.
Journal of the American Chemical Society 2004;126(51):16896-911.
2004: Abhishek Dey; Thorsten Glaser; José J G Moura; Richard H Holm; Britt Hedman; Keith O Hodgson; Edward I Solomon
Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment.
Journal of the American Chemical Society 2004;126(51):16868-78.
2004: Juyoung Yoon; Liviu M Mirica; T Daniel P Stack; Edward I Solomon
Spectroscopic demonstration of a large antisymmetric exchange contribution to the spin-frustrated ground state of a D3 symmetric hydroxy-bridged trinuclear Cu(II) complex: ground-to-excited state superexchange pathways.
Journal of the American Chemical Society 2004;126(39):12586-95.
2004: Peng Chen; Edward I Solomon
O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(36):13105-10.
2004: Peng Chen; Serge I Gorelsky; Somdatta Ghosh; Edward I Solomon
N2O reduction by the mu4-sulfide-bridged tetranuclear CuZ cluster active site.
Angewandte Chemie (International ed. in English) 2004;43(32):4132-40.
2004: Andrew J Skulan; Thomas C Brunold; Jeffrey Baldwin; Lana Saleh; J Martin Bollinger; Edward I Solomon
Nature of the peroxo intermediate of the W48F/D84E ribonucleotide reductase variant: implications for O2 activation by binuclear non-heme iron enzymes.
Journal of the American Chemical Society 2004;126(28):8842-55.
2004: Hong-Chang Liang; Mark J Henson; Lanying Q Hatcher; Michael A Vance; Christiana Xin Zhang; David Lahti; Susan Kaderli; Roger D Sommer; Arnold L Rheingold; Andreas D Zuberbühler; Edward I Solomon; Kenneth D Karlin
Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction.
Inorganic chemistry 2004;43(14):4115-7.
2004: Abhishek Dey; Thorsten Glaser; Manon Couture; Lindsay D Eltis; Richard H Holm; Britt Hedman; Keith O Hodgson; Edward I Solomon
Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox.
Journal of the American Chemical Society 2004;126(26):8320-8.
2004: Liliana Quintanar; Mark Gebhard; Tzu-Pin Wang; Daniel J Kosman; Edward I Solomon
Ferrous binding to the multicopper oxidases Saccharomyces cerevisiae Fet3p and human ceruloplasmin: contributions to ferroxidase activity.
Journal of the American Chemical Society 2004;126(21):6579-89.
2004: P M Jones; J A May; J B Reitz; Edward I Solomon
Photoelectron spectroscopic and electronic structure studies of CH(2)O bonding and reactivity on ZnO surfaces: steps in the methanol synthesis reaction.
Inorganic chemistry 2004;43(11):3349-70.
2004: Peng Chen; Joseph Bell; Betty A Eipper; Edward I Solomon
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate.
Biochemistry 2004;43(19):5735-47.
2004: Andrea Decker; Jan-Uwe Rohde; Lawrence Que; Edward I Solomon
Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex.
Journal of the American Chemical Society 2004;126(17):5378-9.
2004: Peng Chen; Edward I Solomon
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site.
Journal of the American Chemical Society 2004;126(15):4991-5000.
2004: Michael L Neidig; Michael Kavana; Graham R Moran; Edward I Solomon
CD and MCD studies of the non-heme ferrous active site in (4-hydroxyphenyl)pyruvate dioxygenase: correlation between oxygen activation in the extradiol and alpha-KG-dependent dioxygenases.
Journal of the American Chemical Society 2004;126(14):4486-7.
2004: Pin-Pin Wei; Andrew J Skulan; Natasa Mitić; Yi-Shan Yang; Lana Saleh; J Martin Bollinger; Edward I Solomon
Electronic and spectroscopic studies of the non-heme reduced binuclear iron sites of two ribonucleotide reductase variants: comparison to reduced methane monooxygenase and contributions to O2 reactivity.
Journal of the American Chemical Society 2004;126(12):3777-88.
2004: Robert K Szilagyi; Peter A Bryngelson; Michael Maroney; Britt Hedman; Keith O Hodgson; Edward I Solomon
S K-edge X-ray absorption spectroscopic investigation of the Ni-containing superoxide dismutase active site: new structural insight into the mechanism.
Journal of the American Chemical Society 2004;126(10):3018-9.
2004: Edward I Solomon; Robert K Szilagyi; Serena DeBeer George; Lipika Basumallick
Electronic structures of metal sites in proteins and models: contributions to function in blue copper proteins.
Chemical reviews 2004;104(2):419-58.
2004: Gerhard Schenk; Monita Y M Pau; Edward I Solomon
Comparison between the geometric and electronic structures and reactivities of [FeNO]7 and [FeO2]8 complexes: a density functional theory study.
Journal of the American Chemical Society 2004;126(2):505-15.
2003: Somdatta Ghosh; Serge I Gorelsky; Peng Chen; Inês Cabrito; José J G Moura; Isabel Moura; Edward I Solomon
Activation of N2O reduction by the fully reduced micro4-sulfide bridged tetranuclear Cu Z cluster in nitrous oxide reductase.
Journal of the American Chemical Society 2003;125(51):15708-9.
2003: Lipika Basumallick; Robert K Szilagyi; Yiwei Zhao; James P Shapleigh; Charles P Scholes; Edward I Solomon
Spectroscopic studies of the Met182Thr mutant of nitrite reductase: role of the axial ligand in the geometric and electronic structure of blue and green copper sites.
Journal of the American Chemical Society 2003;125(48):14784-92.
2003: Kari R Strand; Yi-Shan Yang; K Kristoffer Andersson; Edward I Solomon
Circular dichroism and magnetic circular dichroism studies of the biferrous form of the R2 subunit of ribonucleotide reductase from mouse: comparison to the R2 from Escherichia coli and other binuclear ferrous enzymes.
Biochemistry 2003;42(42):12223-34.
2003: Erik C Wasinger; Frank M F de Groot; Britt Hedman; Keith O Hodgson; Edward I Solomon
L-edge X-ray absorption spectroscopy of non-heme iron sites: experimental determination of differential orbital covalency.
Journal of the American Chemical Society 2003;125(42):12894-906.
2003: Andrew J Skulan; Melissa A Hanson; Hua-fen Hsu; Yanhong Dong; Lawrence Que; Edward I Solomon
EPR spectroscopy of [Fe2O2(5-Et3-TPA)2]3+: electronic origin of the unique spin-Hamiltonian parameters of the Fe2(III,IV)O2 diamond core.
Inorganic chemistry 2003;42(20):6489-96.
2003: Serena DeBeer George; Lipika Basumallick; Robert K Szilagyi; David W Randall; Michael G Hill; Aram M Nersissian; Joan Selverstone Valentine; Britt Hedman; Keith O Hodgson; Edward I Solomon
Spectroscopic investigation of stellacyanin mutants: axial ligand interactions at the blue copper site.
Journal of the American Chemical Society 2003;125(37):11314-28.
2003: Mindy I Davis; Erik C Wasinger; Andrea Decker; Monita Y M Pau; Frédéric H Vaillancourt; Jeffrey T Bolin; Lindsay D Eltis; Britt Hedman; Keith O Hodgson; Edward I Solomon
Spectroscopic and electronic structure studies of 2,3-dihydroxybiphenyl 1,2-dioxygenase: O2 reactivity of the non-heme ferrous site in extradiol dioxygenases.
Journal of the American Chemical Society 2003;125(37):11214-27.
2003: Natasa Mitić; Lana Saleh; Gerhard Schenk; J Martin Bollinger; Edward I Solomon
Rapid-freeze-quench magnetic circular dichroism of intermediate X in ribonucleotide reductase: new structural insight.
Journal of the American Chemical Society 2003;125(37):11200-1.
2003: Jyllian N Kemsley; Kelly Loeb Zaleski; Marina S Chow; Andrea Decker; Ekaterina Y Shishova; Erik C Wasinger; Britt Hedman; Keith O Hodgson; Edward I Solomon
Spectroscopic studies of the interaction of ferrous bleomycin with DNA.
Journal of the American Chemical Society 2003;125(36):10810-21.
2003: Robert K Szilagyi; Booyong S Lim; Thorsten Glaser; Richard H Holm; Britt Hedman; Keith O Hodgson; Edward I Solomon
Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy.
Journal of the American Chemical Society 2003;125(30):9158-69.
2003: Tzu-Pin Wang; Liliana Quintanar; Scott Severance; Edward I Solomon; Daniel J Kosman
Targeted suppression of the ferroxidase and iron trafficking activities of the multicopper oxidase Fet3p from Saccharomyces cerevisiae.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(6):611-20.
2003: Amy E Palmer; Robert K Szilagyi; Joel R Cherry; Aubrey Jones; Feng Xu; Edward I Solomon
Spectroscopic characterization of the Leu513His variant of fungal laccase: effect of increased axial ligand interaction on the geometric and electronic structure of the type 1 Cu site.
Inorganic chemistry 2003;42(13):4006-17.
2003: Gerhard Schenk; Michael L Neidig; Jing Zhou; Theodore R. Holman; Edward I Solomon
Spectroscopic characterization of soybean lipoxygenase-1 mutants: the role of second coordination sphere residues in the regulation of enzyme activity.
Biochemistry 2003;42(24):7294-302.
2003: Andrew J Skulan; Melissa A Hanson; Hua-Fen Hsu; Lawrence Que; Edward I Solomon
Spectroscopic study of [Fe2O2(5-Et3-TPA)2]3+: nature of the Fe2O2 diamond core and its possible relevance to high-valent binuclear non-heme enzyme intermediates.
Journal of the American Chemical Society 2003;125(24):7344-56.
2003: James P Collman; Christopher J Sunderland; Katja E Berg; Michael A Vance; Edward I Solomon
Spectroscopic evidence for a heme-superoxide/Cu(I) intermediate in a functional model of cytochrome c oxidase.
Journal of the American Chemical Society 2003;125(22):6648-9.
2003: Peng Chen; Kiyoshi Fujisawa; Matthew E Helton; Kenneth D Karlin; Edward I Solomon
Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.
Journal of the American Chemical Society 2003;125(21):6394-408.
2003: Jyllian N Kemsley; Erik C Wasinger; Supratim Datta; Natasa Mitić; Tara Acharya; Britt Hedman; John P Caradonna; Keith O Hodgson; Edward I Solomon
Spectroscopic and kinetic studies of PKU-inducing mutants of phenylalanine hydroxylase: Arg158Gln and Glu280Lys.
Journal of the American Chemical Society 2003;125(19):5677-86.
2003: Mark J Henson; Michael A Vance; Christiana Xin Zhang; Hong-Chang Liang; Kenneth D Karlin; Edward I Solomon
Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes.
Journal of the American Chemical Society 2003;125(17):5186-92.
2003: Edward I Solomon; Andrea Decker; Nicolai Lehnert
Non-heme iron enzymes: contrasts to heme catalysis.
Proceedings of the National Academy of Sciences of the United States of America 2003;100(7):3589-94.
2003: Pierre Kennepohl; Edward I Solomon
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 3. Kinetics of electron transfer.
Inorganic chemistry 2003;42(3):696-708.
2003: Pierre Kennepohl; Edward I Solomon
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 2. Reduction potentials.
Inorganic chemistry 2003;42(3):689-95.
2003: Pierre Kennepohl; Edward I Solomon
Electronic structure contributions to electron-transfer reactivity in iron-sulfur active sites: 1. Photoelectron spectroscopic determination of electronic relaxation.
Inorganic chemistry 2003;42(3):679-88.
2003: Matthew E Helton; Peng Chen; Partha P Paul; Zoltán Tyeklár; Roger D Sommer; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.
Journal of the American Chemical Society 2003;125(5):1160-1.
2003: Nicolai Lehnert; Edward I Solomon
Density-functional investigation on the mechanism of H-atom abstraction by lipoxygenase.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(3):294-305.
2003: K Kristoffer Andersson; Peter P Schmidt; Bettina Katterle; Kari R Strand; Amy E Palmer; Sang-Kyu Lee; Edward I Solomon; Astrid Gräslund; Anne-Laure Barra
Examples of high-frequency EPR studies in bioinorganic chemistry.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2003;8(3):235-47.
2003: Nicolai Lehnert; Kiyoshi Fujisawa; Edward I Solomon
Electronic structure and reactivity of high-spin iron--alkyl- and--pterinperoxo complexes.
Inorganic chemistry 2003;42(2):469-81.
2003: Erik C Wasinger; Mindy I Davis; Monita Y M Pau; Allen M Orville; Jeffrey M Zaleski; Britt Hedman; John D Lipscomb; Keith O Hodgson; Edward I Solomon
Spectroscopic studies of the effect of ligand donor strength on the Fe-NO bond intradiol dioxygenases.
Inorganic chemistry 2003;42(2):365-76.
2003: Peng Chen; David E Root; Cecelia Campochiaro; Kiyoshi Fujisawa; Edward I Solomon
Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization.
Journal of the American Chemical Society 2003;125(2):466-74.
2002: James P Collman; Katja E Berg; Christopher J Sunderland; Ally Aukauloo; Michael A Vance; Edward I Solomon
Distal metal effects in cobalt porphyrins related to CcO.
Inorganic chemistry 2002;41(25):6583-96.
2002: Nicolai Lehnert; Frank Neese; Raymond Y N Ho; Lawrence Que; Edward I Solomon
Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin.
Journal of the American Chemical Society 2002;124(36):10810-22.
2002: Peng Chen; Inês Cabrito; José J G Moura; Isabel Moura; Edward I Solomon
Spectroscopic and electronic structure studies of the mu(4)-sulfide bridged tetranuclear Cu(Z) cluster in N(2)O reductase: molecular insight into the catalytic mechanism.
Journal of the American Chemical Society 2002;124(35):10497-507.
2002: Liviu M Mirica; Michael Vance; Deanne Jackson Rudd; Britt Hedman; Keith O Hodgson; Edward I Solomon; T Daniel P Stack
A stabilized mu-eta(2):eta(2) peroxodicopper(II) complex with a secondary diamine ligand and its tyrosinase-like reactivity.
Journal of the American Chemical Society 2002;124(32):9332-3.
2002: Sang-Kyu Lee; Serena DeBeer George; William E Antholine; Britt Hedman; Keith O Hodgson; Edward I Solomon
Nature of the intermediate formed in the reduction of O(2) to H(2)O at the trinuclear copper cluster active site in native laccase.
Journal of the American Chemical Society 2002;124(21):6180-93.
2002: Amy E Palmer; Liliana Quintanar; Scott Severance; Tzu-Pin Wang; Daniel J Kosman; Edward I Solomon
Spectroscopic characterization and O2 reactivity of the trinuclear Cu cluster of mutants of the multicopper oxidase Fet3p.
Biochemistry 2002;41(20):6438-48.
2002: Erik C Wasinger; Natasa Mitić; Britt Hedman; John P Caradonna; Edward I Solomon; Keith O Hodgson
X-ray absorption spectroscopic investigation of the resting ferrous and cosubstrate-bound active sites of phenylalanine hydroxylase.
Biochemistry 2002;41(20):6211-7.
2002: Jing Zhou; Amy M Rocklin; John D Lipscomb; Lawrence Que; Edward I Solomon
Spectroscopic studies of 1-aminocyclopropane-1-carboxylic acid oxidase: molecular mechanism and CO(2) activation in the biosynthesis of ethylene.
Journal of the American Chemical Society 2002;124(17):4602-9.
2002: Hong-Chang Liang; Christiana Xin Zhang; Mark J Henson; Roger D Sommer; Karen R Hatwell; Susan Kaderli; Andreas D Zuberbühler; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.
Journal of the American Chemical Society 2002;124(16):4170-1.
2002: Robert K Szilagyi; Edward I Solomon
Electronic structure and its relation to function in copper proteins.
Current opinion in chemical biology 2002;6(2):250-8.
2002: Peng Chen; Serena DeBeer George; Inês Cabrito; William E Antholine; José J G Moura; Isabel Moura; Britt Hedman; Keith O Hodgson; Edward I Solomon
Electronic structure description of the mu(4)-sulfide bridged tetranuclear Cu(Z) center in N(2)O reductase.
Journal of the American Chemical Society 2002;124(5):744-5.
2002: Peng Chen; Edward I Solomon
Frontier molecular orbital analysis of Cu(n)-O(2) reactivity.
Journal of inorganic biochemistry 2002;88(3-4):368-74.
2002: Mindy I Davis; Allen M Orville; Frank Neese; Jeffrey M Zaleski; John D Lipscomb; Edward I Solomon
Spectroscopic and electronic structure studies of protocatechuate 3,4-dioxygenase: nature of tyrosinate-Fe(III) bonds and their contribution to reactivity.
Journal of the American Chemical Society 2002;124(4):602-14.
2002: Erik C Wasinger; Loeb Zaleski; Britt Hedman; Keith O Hodgson; Edward I Solomon
X-ray absorption spectroscopic investigation of Fe(II)-peplomycin and peplomycin derivatives: the effect of axial ligation on Fe-pyrimidine back-bonding.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2002;7(1-2):157-64.
2001: Nicolai Lehnert; Raymond Y N Ho; Lawrence Que; Edward I Solomon
Electronic structure of high-spin iron(III)-alkylperoxo complexes and its relation to low-spin analogues: reaction coordinate of O-O bond homolysis.
Journal of the American Chemical Society 2001;123(51):12802-16.
2001: Mark J Henson; Viswanath Mahadevan; T Daniel P Stack; Edward I Solomon
A new Cu(II) side-on peroxo model clarifies the assignment of the oxyhemocyanin Raman spectrum.
Inorganic chemistry 2001;40(20):5068-9.
2001: Nicolai Lehnert; Raymond Y N Ho; Lawrence Que; Edward I Solomon
Spectroscopic properties and electronic structure of low-spin Fe(III)-alkylperoxo complexes: homolytic cleavage of the O-O bond.
Journal of the American Chemical Society 2001;123(34):8271-90.
2001: Jing Zhou; Wendy Kelly; Brian O Bachmann; Michele Gunsior; Craig A Townsend; Edward I Solomon
Spectroscopic studies of substrate interactions with clavaminate synthase 2, a multifunctional alpha-KG-dependent non-heme iron enzyme: correlation with mechanisms and reactivities.
Journal of the American Chemical Society 2001;123(30):7388-98.
2001: Edward I Solomon
Invited award contribution for ACS Award in Inorganic Chemistry. Geometric and electronic structure contributions to function in bioinorganic chemistry: active sites in non-heme iron enzymes.
Inorganic chemistry 2001;40(15):3656-69.
2001: Amy E Palmer; Sang-Kyu Lee; Edward I Solomon
Decay of the peroxide intermediate in laccase: reductive cleavage of the O-O bond.
Journal of the American Chemical Society 2001;123(27):6591-9.
2001: Serena DeBeer George; M Metz; Robert K Szilagyi; H Wang; Stephen P Cramer; Yuerui Lu; William B Tolman; Britt Hedman; Keith O Hodgson; Edward I Solomon
A quantitative description of the ground-state wave function of Cu(A) by X-ray absorption spectroscopy: comparison to plastocyanin and relevance to electron transfer.
Journal of the American Chemical Society 2001;123(24):5757-67.
2001: TE Machonkin; Liliana Quintanar; Amy E Palmer; RF Hassett; Scott Severance; Daniel J Kosman; Edward I Solomon
Spectroscopy and reactivity of the type 1 copper site in Fet3p from Saccharomyces cerevisiae: correlation of structure with reactivity in the multicopper oxidases.
Journal of the American Chemical Society 2001;123(23):5507-17.
2001: Elodie Anxolabéhère-Mallart; Thorsten Glaser; Patrick Frank; A Aliverti; G Zanetti; Britt Hedman; Keith O Hodgson; Edward I Solomon
Sulfur K-edge X-ray absorption spectroscopy of 2Fe-2S ferredoxin: covalency of the oxidized and reduced 2Fe forms and comparison to model complexes.
Journal of the American Chemical Society 2001;123(23):5444-52.
2001: M Metz; Edward I Solomon
Dioxygen binding to deoxyhemocyanin: electronic structure and mechanism of the spin-forbidden two-electron reduction of o(2).
Journal of the American Chemical Society 2001;123(21):4938-50.
2001: Thorsten Glaser; I Bertini; José J G Moura; Britt Hedman; Keith O Hodgson; Edward I Solomon
Protein effects on the electronic structure of the [Fe4S4]2+ cluster in ferredoxin and HiPIP.
Journal of the American Chemical Society 2001;123(20):4859-60.
2001: J Hirsch; Serena DeBeer George; Edward I Solomon; Britt Hedman; Keith O Hodgson; Judith N Burstyn
Raman and extended X-ray absorption fine structure characterization of a sulfur-ligated Cu(I) ethylene complex: modeling the proposed ethylene binding site of Arabidopsis thaliana ETR1.
Inorganic chemistry 2001;40(10):2439-41.
2001: Nicolai Lehnert; Serena DeBeer George; Edward I Solomon
Recent advances in bioinorganic spectroscopy.
Current opinion in chemical biology 2001;5(2):176-87.
2001: Thorsten Glaser; K Rose; S E Shadle; Britt Hedman; Keith O Hodgson; Edward I Solomon
S K-edge X-ray absorption studies of tetranuclear iron-sulfur clusters: mu-sulfide bonding and its contribution to electron delocalization.
Journal of the American Chemical Society 2001;123(3):442-54.
2000: T Glaser; Britt Hedman; Keith O Hodgson; Edward I Solomon
Ligand K-edge X-ray absorption spectroscopy: a direct probe of ligand-metal covalency.
Accounts of chemical research 2000;33(12):859-68.
2000: D W Randall; D R Gamelin; L B LaCroix; Edward I Solomon
Electronic structure contributions to electron transfer in blue Cu and Cu(A).
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2000;5(1):16-29.
1999: TE Machonkin; Giovanni Musci; H H Zhang; Maria Carmela Bonaccorsi di Patti; Lilia Calabrese; Britt Hedman; Keith O Hodgson; Edward I Solomon
Investigation of the anomalous spectroscopic features of the copper sites in chicken ceruloplasmin: comparison to human ceruloplasmin.
Biochemistry 1999;38(34):11093-102.
1998: TE Machonkin; H H Zhang; Britt Hedman; Keith O Hodgson; Edward I Solomon
Spectroscopic and magnetic studies of human ceruloplasmin: identification of a redox-inactive reduced Type 1 copper site.
Biochemistry 1998;37(26):9570-8.
1997: Edward I Solomon; Jing Zhou; F Neese; E G Pavel
New insights from spectroscopy into the structure/function relationships of lipoxygenases.
Chemistry & biology 1997;4(11):795-808.
1996: A P Cole; D E Root; P Mukherjee; Edward I Solomon; T D Stack
A trinuclear intermediate in the copper-mediated reduction of O2: four electrons from three coppers.
Science (New York, N.Y.) 1996;273(5283):1848-50.
1995: Edward I Solomon; M L Kirk; D R Gamelin; S Pulver
Bioinorganic spectroscopy.
Methods in enzymology 1995;246():71-110.
1994: E G Pavel; L J Martins; Walther R Ellis; Edward I Solomon
Magnetic circular dichroism studies of exogenous ligand and substrate binding to the non-heme ferrous active site in phthalate dioxygenase.
Chemistry & biology 1994;1(3):173-83.
1993: Edward I Solomon; M D Lowery
Electronic structure contributions to function in bioinorganic chemistry.
Science (New York, N.Y.) 1993;259(5101):1575-81.
1993: Edward I Solomon; M D Lowery; L B LaCroix; D E Root
Electronic absorption spectroscopy of copper proteins.
Methods in enzymology 1993;226():1-33.
1988: Edward I Solomon
Coupled binuclear copper proteins: catalytic mechanisms and structure-reactivity correlations.
Progress in clinical and biological research 1988;274():309-29.
1987: J C Deaton; Edward I Solomon; G D Watt; P J Wetherbee; C N Durfor
Electron paramagnetic resonance studies of the tungsten-containing formate dehydrogenase from Clostridium thermoaceticum.
Biochemical and biophysical research communications 1987;149(2):424-30.
1985: M D Allendorf; D J Spira; Edward I Solomon
Low-temperature magnetic circular dichroism studies of native laccase: spectroscopic evidence for exogenous ligand bridging at a trinuclear copper active site.
Proceedings of the National Academy of Sciences of the United States of America 1985;82(10):3063-7.
1984: J C Deaton; Edward I Solomon; C N Durfor; P J Wetherbee; B K Burgess; D B Jacobs
Activation of nit-1 nitrate reductase by W-formate dehydrogenase.
Biochemical and biophysical research communications 1984;121(3):1042-7.
1984: James Penner-Hahn; Britt Hedman; Keith O Hodgson; D J Spira; Edward I Solomon
On the spectral features associated with peroxide reactivity of the coupled binuclear copper active site in type 2 depleted and native Rhus laccase.
Biochemical and biophysical research communications 1984;119(2):567-74.
1983: C N Durfor; P J Wetherbee; J C Deaton; Edward I Solomon
Characterization and spectroscopic properties of reduced Mo and W formate dehydrogenase from C. thermoaceticum.
Biochemical and biophysical research communications 1983;115(1):61-7.
1983: D J Spira; Edward I Solomon
Nitrite reactivity of the binuclear copper site in T2D Rhus laccase: preparation of half met-NO2- T2D laccase and its correlation to half met-NO2- hemocyanin and tyrosinase.
Biochemical and biophysical research communications 1983;112(2):729-36.
1983: D J Spira; M S Co; Edward I Solomon; Keith O Hodgson
EXAFS investigation of the binuclear cupric site in met T2D Rhus laccase and its azide bound derivative.
Biochemical and biophysical research communications 1983;112(2):746-53.
1983: J E Hahn; M S Co; D J Spira; Keith O Hodgson; Edward I Solomon
Quantitative Cu(I) determination using X-ray absorption edge spectroscopy: oxidation of the reduced binuclear copper site in type 2 depleted Rhus laccase.
Biochemical and biophysical research communications 1983;112(2):737-45.
1982: M E Winkler; D J Spira; C D LuBein; T J Thamann; Edward I Solomon
Anion binding to oxidized type 2 depleted and native laccase: a spectroscopically effective model for exogenous ligand binding to the type 3--type 2 active site.
Biochemical and biophysical research communications 1982;107(2):727-34.
1982: D J Spira; M E Winkler; Edward I Solomon
Preparation and characterization of a stable half met derivative of type 2 depleted Rhus laccase: exogenous ligand binding to the type 3 site.
Biochemical and biophysical research communications 1982;107(2):721-6.