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Shannon Stahl

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Alireza Rahimi; John Ralph; Ali Azarpira; Hoon Kim; Shannon S Stahl
Chemoselective metal-free aerobic alcohol oxidation in lignin.
Yusuke Izawa; Changwu Zheng; Shannon S Stahl
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.
James B Gerken; Ilia A Guzei; Robert J Hamers; Riviam J Pérez-Rodríguez; Matthew L Rigsby; Rose E Ruther; Shannon S Stahl
Modular synthesis of alkyne-substituted ruthenium polypyridyl complexes suitable for "click" coupling.

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All Publications

2013: Alireza Rahimi; John Ralph; Ali Azarpira; Hoon Kim; Shannon S Stahl
Chemoselective metal-free aerobic alcohol oxidation in lignin.
Journal of the American Chemical Society 2013;135(17):6415-8.
2013: Yusuke Izawa; Changwu Zheng; Shannon S Stahl
Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.
Angewandte Chemie (International ed. in English) 2013;52(13):3672-5.
2013: James B Gerken; Ilia A Guzei; Robert J Hamers; Riviam J Pérez-Rodríguez; Matthew L Rigsby; Rose E Ruther; Shannon S Stahl
Modular synthesis of alkyne-substituted ruthenium polypyridyl complexes suitable for "click" coupling.
Inorganic chemistry 2013;52(6):2796-8.
2013: Xuan Ye; Paul B White; Shannon S Stahl
Mechanistic studies of Wacker-type amidocyclization of alkenes catalyzed by (IMes)Pd(TFA)2(H2O): kinetic and stereochemical implications of proton transfer.
The Journal of organic chemistry 2013;78(5):2083-90.
2013: Jessica M Hoover; Bradford L Ryland; Shannon S Stahl
Mechanism of copper(I)/TEMPO-catalyzed aerobic alcohol oxidation.
Journal of the American Chemical Society 2013;135(6):2357-67.
2012: Adam B Weinstein; Shannon S Stahl
Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations.
Angewandte Chemie (International ed. in English) 2012;51(46):11505-9.
2012: Tianning Diao; Ilia Guzei; Paul White; Shannon S Stahl
Characterization of DMSO coordination to palladium(II) in solution and insights into the aerobic oxidation catalyst, Pd(DMSO)2(TFA)2.
Inorganic chemistry 2012;51(21):11898-909.
2012: Changwu Zheng; Dian Wang; Shannon S Stahl
Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative Heck reactions.
Journal of the American Chemical Society 2012;134(40):16496-9.
2012: James B Gerken; Robert C Massé; Adam B Powell; Jamie Y C Chen; Shannon S Stahl
Development of an O2-sensitive fluorescence-quenching assay for the combinatorial discovery of electrocatalysts for water oxidation.
Angewandte Chemie (International ed. in English) 2012;51(27):6676-80.
2012: Alison N Campbell; Shannon S Stahl
Overcoming the "oxidant problem": strategies to use O2 as the oxidant in organometallic C-H oxidation reactions catalyzed by Pd (and Cu).
Accounts of chemical research 2012;45(6):851-63.
2012: Jessica M Hoover; Janelle E Steves; Shannon S Stahl
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air.
Nature protocols 2012;7(6):1161-6.
2012: Alison E Wendlandt; Shannon S Stahl
Chemoselective organocatalytic aerobic oxidation of primary amines to secondary imines.
Organic letters 2012;14(11):2850-3.
2012: Alison E Wendlandt; Shannon S Stahl
Copper(II)-mediated oxidative cyclization of enamides to oxazoles.
Organic & biomolecular chemistry 2012;10(19):3866-70.
2012: Zhan Lu; Shannon S Stahl
Intramolecular Pd(II)-catalyzed aerobic oxidative amination of alkenes: synthesis of six-membered N-heterocycles.
Organic letters 2012;14(5):1234-7.
2012: Joanne E Redford; Matthew L Rigsby; Richard I McDonald; Joshua D Wiensch; Shannon S Stahl
Stereoselective synthesis of cis-2,5-disubstituted pyrrolidines via Wacker-type aerobic oxidative cyclization of alkenes with tert-butanesulfinamide nucleophiles.
Organic letters 2012;14(5):1242-5.
2012: Jihua Zhang; Matthew J Markiewicz; Brendan P Mowery; Shannon S Stahl; Bernard Weisblum; Samuel H Gellman
C-terminal functionalization of nylon-3 polymers: effects of C-terminal groups on antibacterial and hemolytic activities.
Biomacromolecules 2012;13(2):323-31.
2011: Paul B White; Shannon S Stahl
Reversible alkene insertion into the Pd-N bond of Pd(II)-sulfonamidates and implications for catalytic amidation reactions.
Journal of the American Chemical Society 2011;133(46):18594-7.
2011: Alison E Wendlandt; Alison M Suess; Shannon S Stahl
Copper-catalyzed aerobic oxidative C-H functionalizations: trends and mechanistic insights.
Angewandte Chemie (International ed. in English) 2011;50(47):11062-87.
2011: Jessica M Hoover; Shannon S Stahl
Highly practical copper(I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols.
Journal of the American Chemical Society 2011;133(42):16901-10.
2011: Alison N Campbell; Eric B Meyer; Shannon S Stahl
Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands.
Chemical communications (Cambridge, England) 2011;47(37):10257-9.
2011: Tianning Diao; Shannon S Stahl
Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones.
Journal of the American Chemical Society 2011;133(37):14566-9.
2011: Lauren M Huffman; Shannon S Stahl
Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex.
Dalton transactions (Cambridge, England : 2003) 2011;40(35):8959-63.
2011: James B Gerken; J Gregory McAlpin; Matthew L Rigsby; R David Britt; William H Casey; Jamie Y C Chen; Shannon S Stahl
Electrochemical water oxidation with cobalt-based electrocatalysts from pH 0-14: the thermodynamic basis for catalyst structure, stability, and activity.
Journal of the American Chemical Society 2011;133(36):14431-42.
2011: Lauren M Huffman; Xavi Ribas; Mercè Canta; Alicia Casitas; Miquel Costas; Marc Font; Shannon S Stahl
Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles.
Chemistry (Weinheim an der Bergstrasse, Germany) 2011;17(38):10643-50.
2011: Nattawan Decharin; Brian V Popp; Shannon S Stahl
Reaction of O2 with [(-)-sparteine]Pd(H)Cl: evidence for an intramolecular [H-L]+ "reductive elimination" pathway.
Journal of the American Chemical Society 2011;133(34):13268-71.
2011: Michelle C Benson; Lee M Bishop; James B Gerken; Matthew L Rigsby; Rose E Ruther; Shannon S Stahl; Yizheng Tan; Robert J Hamers
Modular "click" chemistry for electrochemically and photoelectrochemically active molecular interfaces to tin oxide surfaces.
ACS applied materials & interfaces 2011;3(8):3110-9.
2011: Yusuke Izawa; Doris Pun; Shannon S Stahl
Palladium-catalyzed aerobic dehydrogenation of substituted cyclohexanones to phenols.
Science (New York, N.Y.) 2011;333(6039):209-13.
2011: Richard I McDonald; Paul B White; Adam B Weinstein; Chun Pong Tam; Shannon S Stahl
Enantioselective Pd(II)-catalyzed aerobic oxidative amidation of alkenes and insights into the role of electronic asymmetry in pyridine-oxazoline ligands.
Organic letters 2011;13(11):2830-3.
2011: Rose E Ruther; Matthew L Rigsby; James B Gerken; Stephanie R Hogendoorn; Elizabeth C Landis; Shannon S Stahl; Robert J Hamers
Highly stable redox-active molecular layers by covalent grafting to conductive diamond.
Journal of the American Chemical Society 2011;133(15):5692-4.
2011: Nattawan Decharin; Shannon S Stahl
Benzoquinone-promoted reaction of O2 with a Pd(II)-hydride.
Journal of the American Chemical Society 2011;133(15):5732-5.
2011: Richard I McDonald; Guosheng Liu; Shannon S Stahl
Palladium(II)-catalyzed alkene functionalization via nucleopalladation: stereochemical pathways and enantioselective catalytic applications.
Chemical reviews 2011;111(4):2981-3019.
2011: Xuan Ye; Guosheng Liu; Brian V Popp; Shannon S Stahl
Mechanistic studies of Wacker-type intramolecular aerobic oxidative amination of alkenes catalyzed by Pd(OAc)2/pyridine.
The Journal of organic chemistry 2011;76(4):1031-44.
2010: Alicia Casitas; Albert Poater; Miquel Solà; Shannon S Stahl; Miquel Costas; Xavi Ribas
Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species.
Dalton transactions (Cambridge, England : 2003) 2010;39(43):10458-63.
2010: Alison N Campbell; Paul B White; Ilia A Guzei; Shannon S Stahl
Allylic C-H acetoxylation with a 4,5-diazafluorenone-ligated palladium catalyst: a ligand-based strategy to achieve aerobic catalytic turnover.
Journal of the American Chemical Society 2010;132(43):15116-9.
2010: James B Gerken; Elizabeth C Landis; Robert J Hamers; Shannon S Stahl
Fluoride-modulated cobalt catalysts for electrochemical oxidation of water under non-alkaline conditions.
ChemSusChem 2010;3(10):1176-9.
2010: Richard I McDonald; Gene W Wong; Ram P Neupane; Shannon S Stahl; Clark R Landis
Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands.
Journal of the American Chemical Society 2010;132(40):14027-9.
2010: Brian V Popp; Christine M Morales; Clark R Landis; Shannon S Stahl
Electronic structural comparison of the reactions of dioxygen and alkenes with nitrogen-chelated palladium(0).
Inorganic chemistry 2010;49(18):8200-7.
2010: Amanda E King; Lauren M Huffman; Alicia Casitas; Miquel Costas; Xavi Ribas; Shannon S Stahl
Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate.
Journal of the American Chemical Society 2010;132(34):12068-73.
2010: Richard I McDonald; Shannon S Stahl
Modular synthesis of 1,2-diamine derivatives by palladium-catalyzed aerobic oxidative cyclization of allylic sulfamides.
Angewandte Chemie (International ed. in English) 2010;49(32):5529-32.
2009: Myung-Ryul Lee; Shannon S Stahl; Samuel H Gellman; Kristyn S Masters
Nylon-3 copolymers that generate cell-adhesive surfaces identified by library screening.
Journal of the American Chemical Society 2009;131(46):16779-89.
2009: Nickeisha A Stephenson; Jiang Zhu; Samuel H Gellman; Shannon S Stahl
Catalytic transamidation reactions compatible with tertiary amide metathesis under ambient conditions.
Journal of the American Chemical Society 2009;131(29):10003-8.
2009: Brendan P Mowery; Alexandra H Lindner; Bernard Weisblum; Shannon S Stahl; Samuel H Gellman
Structure-activity relationships among random nylon-3 copolymers that mimic antibacterial host-defense peptides.
Journal of the American Chemical Society 2009;131(28):9735-45.
2009: Amanda E King; Thomas C Brunold; Shannon S Stahl
Mechanistic study of copper-catalyzed aerobic oxidative coupling of arylboronic esters and methanol: insights into an organometallic oxidase reaction.
Journal of the American Chemical Society 2009;131(14):5044-5.
2009: Christopher C Scarborough; Richard I McDonald; Caroline Hartmann; Graham T Sazama; Ana Bergant; Shannon S Stahl
Steric modulation of chiral biaryl diamines via Pd-catalyzed directed C-H arylation.
The Journal of organic chemistry 2009;74(6):2613-5.
2009: Jihua Zhang; Denis A Kissounko; Sarah E Lee; Samuel H Gellman; Shannon S Stahl
Access to poly-beta-peptides with functionalized side chains and end groups via controlled ring-opening polymerization of beta-lactams.
Journal of the American Chemical Society 2009;131(4):1589-97.
2009: Brian V Popp; Shannon S Stahl
Mechanism of Pd(OAc)2/pyridine catalyst reoxidation by O2: influence of labile monodentate ligands and identification of a biomimetic mechanism for O2 activation.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(12):2915-22.
2008: Lauren M Huffman; Shannon S Stahl
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes.
Journal of the American Chemical Society 2008;130(29):9196-7.
2008: Michael M Konnick; Shannon S Stahl
Reaction of molecular oxygen with a Pd(II)-hydride to produce a Pd(II)-hydroperoxide: experimental evidence for an HX-reductive-elimination pathway.
Journal of the American Chemical Society 2008;130(17):5753-62.
2008: Tetsuya Hamada; Xuan Ye; Shannon S Stahl
Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides.
Journal of the American Chemical Society 2008;130(3):833-5.
2008: Justin M Hoerter; Karin M Otte; Samuel H Gellman; Qiang Cui; Shannon S Stahl
Discovery and mechanistic study of Al(III)-catalyzed transamidation of tertiary amides.
Journal of the American Chemical Society 2008;130(2):647-54.
2007: Brendan P Mowery; Sarah E Lee; Denis A Kissounko; Raquel F Epand; Richard M Epand; Bernard Weisblum; Shannon S Stahl; Samuel H Gellman
Mimicry of antimicrobial host-defense peptides by random copolymers.
Journal of the American Chemical Society 2007;129(50):15474-6.
2007: Michelle M Rogers; Vasily Kotov; Jaruwan Chatwichien; Shannon S Stahl
Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent.
Organic letters 2007;9(21):4331-4.
2007: Guosheng Liu; Shannon S Stahl
Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular aza-Wacker reactions.
Journal of the American Chemical Society 2007;129(19):6328-35.
2007: Brian V Popp; Shannon S Stahl
Insertion of molecular oxygen into a palladium-hydride bond: computational evidence for two nearly isoenergetic pathways.
Journal of the American Chemical Society 2007;129(14):4410-22.
2007: Vasily Kotov; Christopher C Scarborough; Shannon S Stahl
Palladium-catalyzed aerobic oxidative amination of alkenes: development of intra- and intermolecular aza-Wacker reactions.
Inorganic chemistry 2007;46(6):1910-23.
2007: Denis A Kissounko; Justin M Hoerter; Ilia A Guzei; Qiang Cui; Samuel H Gellman; Shannon S Stahl
TiIV-mediated reactions between primary amines and secondary carboxamides: amidine formation versus transamidation.
Journal of the American Chemical Society 2007;129(6):1776-83.
2007: Christen M Bell; Denis A Kissounko; Samuel H Gellman; Shannon S Stahl
Catalytic metathesis of simple secondary amides.
Angewandte Chemie (International ed. in English) 2007;46(5):761-3.
2007: Brian V Popp; Johanna E Wendlandt; Clark R Landis; Shannon S Stahl
Reaction of molecular oxygen with an NHC-coordinated Pd0 complex: computational insights and experimental implications.
Angewandte Chemie (International ed. in English) 2007;46(4):601-4.
2006: Christopher C Scarborough; Shannon S Stahl
Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides.
Organic letters 2006;8(15):3251-4.
2006: Guosheng Liu; Shannon S Stahl
Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation.
Journal of the American Chemical Society 2006;128(22):7179-81.
2006: Michelle M Rogers; Johanna E Wendlandt; Ilia A Guzei; Shannon S Stahl
Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes.
Organic letters 2006;8(11):2257-60.
2006: Michael M Konnick; Bhavesh A Gandhi; Ilia A Guzei; Shannon S Stahl
Reaction of molecular oxygen with a PdII- hydride to produce a PdII-hydroperoxide: acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions.
Angewandte Chemie (International ed. in English) 2006;45(18):2904-7.
2006: Justin M Hoerter; Karin M Otte; Samuel H Gellman; Shannon S Stahl
Mechanism of Al(III)-catalyzed transamidation of unactivated secondary carboxamides.
Journal of the American Chemical Society 2006;128(15):5177-83.
2006: Bradley A Steinhoff; Shannon S Stahl
Mechanism of Pd(OAc)2/DMSO-catalyzed aerobic alcohol oxidation: mass-transfer-limitation effects and catalyst decomposition pathways.
Journal of the American Chemical Society 2006;128(13):4348-55.
2006: Brian V Popp; Shannon S Stahl
"Oxidatively induced" reductive elimination of dioxygen from an eta2-peroxopalladium(II) complex promoted by electron-deficient alkenes.
Journal of the American Chemical Society 2006;128(9):2804-5.
2006: Bradley A Steinhoff; Amanda E King; Shannon S Stahl
Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation.
The Journal of organic chemistry 2006;71(5):1861-8.
2005: Vitaliy I Timokhin; Shannon S Stahl
Brønsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium.
Journal of the American Chemical Society 2005;127(50):17888-93.
2005: Shannon S Stahl
Chemistry. Palladium-catalyzed oxidation of organic chemicals with O2.
Science (New York, N.Y.) 2005;309(5742):1824-6.
2005: Christopher C Scarborough; Michael J W Grady; Ilia A Guzei; Bhavesh A Gandhi; Emilio E Bunel; Shannon S Stahl
PdII complexes possessing a seven-membered N-heterocyclic carbene ligand.
Angewandte Chemie (International ed. in English) 2005;44(33):5269-72.
2005: Sarah E Eldred; Margaret R Pancost; Karin M Otte; David B Rozema; Shannon S Stahl; Samuel H Gellman
Effects of side chain configuration and backbone spacing on the gene delivery properties of lysine-derived cationic polymers.
Bioconjugate chemistry 2005;16(3):694-9.
2005: Jodie L Brice; Jenna E Harang; Vitaliy I Timokhin; Natia R Anastasi; Shannon S Stahl
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium.
Journal of the American Chemical Society 2005;127(9):2868-9.
2004: Clark R Landis; Christine M Morales; Shannon S Stahl
Insights into the spin-forbidden reaction between L2Pd0 and molecular oxygen.
Journal of the American Chemical Society 2004;126(50):16302-3.
2004: Brian V Popp; Joseph L Thorman; Christine M Morales; Clark R Landis; Shannon S Stahl
"Inverse-electron-demand" ligand substitution: experimental and computational insights into olefin exchange at palladium(0).
Journal of the American Chemical Society 2004;126(45):14832-42.
2004: Bradley A Steinhoff; Ilia A Guzei; Shannon S Stahl
Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence.
Journal of the American Chemical Society 2004;126(36):11268-78.
2004: Michael M Konnick; Ilia A Guzei; Shannon S Stahl
Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0).
Journal of the American Chemical Society 2004;126(33):10212-3.
2004: Shannon S Stahl
Palladium oxidase catalysis: selective oxidation of organic chemicals by direct dioxygen-coupled turnover.
Angewandte Chemie (International ed. in English) 2004;43(26):3400-20.
2004: Jodie L Brice; James E Meerdink; Shannon S Stahl
Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles.
Organic letters 2004;6(11):1845-8.
2003: Vitaliy I Timokhin; Natia R Anastasi; Shannon S Stahl
Dioxygen-coupled oxidative amination of styrene.
Journal of the American Chemical Society 2003;125(43):12996-7.
2003: Sarah E Eldred; David A Stone; Samuel H Gellman; Shannon S Stahl
Catalytic transamidation under moderate conditions.
Journal of the American Chemical Society 2003;125(12):3422-3.
2003: Shannon S Stahl; Joseph L Thorman; Namal de Silva; Ilia A Guzei; Robert W Clark
"Inverse-electron-demand" ligand substitution in palladium(0)-olefin complexes.
Journal of the American Chemical Society 2003;125(1):12-3.
2002: Bradley A Steinhoff; Shannon S Stahl
Ligand-modulated palladium oxidation catalysis: mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system.
Organic letters 2002;4(23):4179-81.
2002: Bradley A Steinhoff; Shannon R Fix; Shannon S Stahl
Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O(2)/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts.
Journal of the American Chemical Society 2002;124(5):766-7.
2002: Shannon R Fix; Jodie L Brice; Shannon S Stahl
Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis.
Angewandte Chemie (International ed. in English) 2002;41(1):164-6.
2001: Shannon S Stahl; Joseph L Thorman; R C Nelson; M A Kozee
Oxygenation of nitrogen-coordinated palladium(0): synthetic, structural, and mechanistic studies and implications for aerobic oxidation catalysis.
Journal of the American Chemical Society 2001;123(29):7188-9.