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Masanobu Uchiyama

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Chemicals & Drugs

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Chemistry, Organic

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Publications

TOP 3
Shinsuke Komagawa; Yotaro Matsumoto; Ryo Takita; Philip J Harford; Joanna Haywood; Keiichi Hirano; Shinya Usui; Andrew E H Wheatley; Masanobu Uchiyama
Amidocuprates for directed ortho cupration: structural study, mechanistic investigation, and chemical requirements.
Kazuto Takaishi; Masuki Kawamoto; Atsuya Muranaka; Masanobu Uchiyama
Fusion of photochromic reaction and synthetic reaction: photoassisted cyclization to highly strained chiral azobenzenophanes.
Yu Kushida; Kenjiro Hanaoka; Toru Komatsu; Takuya Terai; Masanobu Uchiyama; Tasuku Ueno; Kengo Yoshida; Tetsuo Nagano
Red fluorescent scaffold for highly sensitive protease activity probes.

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2012: Shinsuke Komagawa; Yotaro Matsumoto; Ryo Takita; Philip J Harford; Joanna Haywood; Keiichi Hirano; Shinya Usui; Andrew E H Wheatley; Masanobu Uchiyama
Amidocuprates for directed ortho cupration: structural study, mechanistic investigation, and chemical requirements.
Angewandte Chemie (International ed. in English) 2012;51(48):12081-5.
2012: Kazuto Takaishi; Masuki Kawamoto; Atsuya Muranaka; Masanobu Uchiyama
Fusion of photochromic reaction and synthetic reaction: photoassisted cyclization to highly strained chiral azobenzenophanes.
Organic letters 2012;14(13):3252-5.
2012: Yu Kushida; Kenjiro Hanaoka; Toru Komatsu; Takuya Terai; Masanobu Uchiyama; Tasuku Ueno; Kengo Yoshida; Tetsuo Nagano
Red fluorescent scaffold for highly sensitive protease activity probes.
Bioorganic & medicinal chemistry letters 2012;22(12):3908-11.
2012: Chao Wang; Takashi Ozaki; Ryo Takita; Masanobu Uchiyama
Aryl ether as a Negishi coupling partner: an approach for constructing C-C bonds under mild conditions.
Chemistry (Weinheim an der Bergstrasse, Germany) 2012;18(12):3482-5.
2012: Osamu Matsushita; Atsuya Muranaka; Soji Shimizu; Masanobu Uchiyama; Valentina M Derkacheva; Evgeny A Luk'yanets; Nagao Kobayashi
Rectangular-shaped expanded phthalocyanines with two central metal atoms.
Journal of the American Chemical Society 2012;134(7):3411-8.
2011: Kazuto Takaishi; Masuki Kawamoto; Atsuya Muranaka; Masanobu Uchiyama
Planar chirality of twisted trans-azobenzene structure induced by chiral transfer from binaphthyls.
The Journal of organic chemistry 2011;76(18):7623-8.
2011: Tsuneaki Sakurai; Kentaro Tashiro; Yoshihito Honsho; Akinori Saeki; Shu Seki; Atsuhiro Osuka; Atsuya Muranaka; Masanobu Uchiyama; Jungeun Kim; Sunyeo Ha; Kenichi Kato; Masaki Takata; Takuzo Aida
Electron- or hole-transporting nature selected by side-chain-directed π-stacking geometry: liquid crystalline fused metalloporphyrin dimers.
Journal of the American Chemical Society 2011;133(17):6537-40.
2011: Kazuto Takaishi; Masuki Kawamoto; Kazunori Tsubaki; Taniyuki Furuyama; Atsuya Muranaka; Masanobu Uchiyama
Helical chirality of azobenzenes induced by an intramolecular chiral axis and potential as chiroptical switches.
Chemistry (Weinheim an der Bergstrasse, Germany) 2011;17(6):1778-82.
2010: Mutsumi Sada; Masanobu Uchiyama; Kiitiro Utimoto; Masami Kobata; Shinsuke Komagawa; Tsuyoshi Mizuno; Koichiro Oshima; Seijiro Matsubara
Reaction pathway of methylenation of carbonyl compounds with bis(iodozincio)methane.
Journal of the American Chemical Society 2010;132(49):17452-8.
2010: Yohsuke Yamamoto; Yusuke Hirata; Megumi Kodama; Torahiko Yamaguchi; Shiro Matsukawa; Kin-ya Akiba; Daisuke Hashizume; Fujiko Iwasaki; Atsuya Muranaka; Masanobu Uchiyama; Ping Chen; Karl M Kadish; Nagao Kobayashi
Synthesis, reactions, and electronic properties of 16 pi-electron octaisobutyltetraphenylporphyrin.
Journal of the American Chemical Society 2010;132(36):12627-38.
2010: Atsuya Muranaka; Mitsuhiro Yonehara; Masanobu Uchiyama
Azulenocyanine: a new family of phthalocyanines with intense near-IR absorption.
Journal of the American Chemical Society 2010;132(23):7844-5.
2010: Mitsuhiro Yonehara; Shinji Nakamura; Atsuya Muranaka; Masanobu Uchiyama
Regioselective silylzincation of phenylallene derivatives.
Chemistry, an Asian journal 2010;5(3):452-5.
2010: Ching-Yuan Liu; Xuan Wang; Taniyuki Furuyama; Shuji Yasuike; Atsuya Muranaka; Keiji Morokuma; Masanobu Uchiyama
Reaction mechanism for the LiCl-mediated directed zinc insertion: a computational and experimental study.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(6):1780-4.
2009: Shinji Nakamura; Ching-Yuan Liu; Atsuya Muranaka; Masanobu Uchiyama
Theoretical study on the halogen-zinc exchange reaction by using organozincate compounds.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(23):5686-94.
2009: Atsuya Muranaka; Osamu Matsushita; Kengo Yoshida; Shigeki Mori; Masaaki Suzuki; Taniyuki Furuyama; Masanobu Uchiyama; Atsuhiro Osuka; Nagao Kobayashi
Application of the perimeter model to the assignment of the electronic absorption spectra of gold(III) hexaphyrins with [4n+2] and [4n] pi-electron systems.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(15):3744-51.
2008: Hiroshi Naka; James V Morey; Joanna Haywood; Dana J Eisler; Mary McPartlin; Felipe García; Hironaga Kudo; Yoshinori Kondo; Masanobu Uchiyama; Andrew E H Wheatley
Mixed alkylamido aluminate as a kinetically controlled base.
Journal of the American Chemical Society 2008;130(48):16193-200.
2008: Daisuke Nobuto; Masanobu Uchiyama
A new interpretation of the reaction pathway of deprotonative metalation with TMP-Zn-ate/TMEDA Complex [TMEDA.Na(micro-tBu)(micro-TMP)Zn(tBu)].
The Journal of organic chemistry 2008;73(3):1117-20.
2008: Masanobu Uchiyama; Yuri Kobayashi; Taniyuki Furuyama; Shinji Nakamura; Yumiko Kajihara; Tomoko Miyoshi; Takao Sakamoto; Yoshinori Kondo; Keiji Morokuma
Generation and suppression of 3-/4-functionalized benzynes using zinc ate base (TMP-Zn-ate): new approaches to multisubstituted benzenes.
Journal of the American Chemical Society 2008;130(2):472-80.
2008: Taniyuki Furuyama; Mitsuhiro Yonehara; Sho Arimoto; Minoru Kobayashi; Yotaro Matsumoto; Masanobu Uchiyama
Development of highly chemoselective bulky zincate complex, tBu4ZnLi2: design, structure, and practical applications in small-/macromolecular synthesis.
Chemistry (Weinheim an der Bergstrasse, Germany) 2008;14(33):10348-56.
2008: Junko Aimi; Yuka Nagamine; Akihiko Tsuda; Atsuya Muranaka; Masanobu Uchiyama; Takuzo Aida
"Conformational" solvatochromism: spatial discrimination of nonpolar solvents by using a supramolecular box of a pi-conjugated zinc bisporphyrin rotamer.
Angewandte Chemie (International ed. in English) 2008;47(28):5153-6.
2008: Shinji Nakamura; Mitsuhiro Yonehara; Masanobu Uchiyama
Silylmetalation of alkenes.
Chemistry (Weinheim an der Bergstrasse, Germany) 2008;14(4):1068-78.
2007: Shinya Usui; Yuichi Hashimoto; James V Morey; Andrew E H Wheatley; Masanobu Uchiyama
Direct ortho cupration: a new route to regioselectively functionalized aromatics.
Journal of the American Chemical Society 2007;129(49):15102-3.
2007: Masanobu Uchiyama; Shinji Nakamura; Taniyuki Furuyama; Eiichi Nakamura; Keiji Morokuma
Reaction pathway of conjugate addition of lithium organozincates to s-trans-enones.
Journal of the American Chemical Society 2007;129(44):13360-1.
2007: Yoshinori Kondo; James V Morey; Jacqueline C Morgan; Hiroshi Naka; Daisuke Nobuto; Paul R Raithby; Masanobu Uchiyama; Andrew E H Wheatley
On the kinetic and thermodynamic reactivity of lithium di(alkyl)amidozincate bases in directed ortho metalation.
Journal of the American Chemical Society 2007;129(42):12734-8.
2007: Hiroshi Naka; Masanobu Uchiyama; Yotaro Matsumoto; Andrew E H Wheatley; Mary McPartlin; James V Morey; Yoshinori Kondo
An aluminum ate base: its design, structure, function, and reaction mechanism.
Journal of the American Chemical Society 2007;129(7):1921-30.
2007: Shinji Nakamura; Masanobu Uchiyama
Regio- and chemoselective silylmetalation of functionalized terminal alkenes.
Journal of the American Chemical Society 2007;129(1):28-9.
2007: Masanobu Uchiyama; Yotaro Matsumoto; Shinya Usui; Yuichi Hashimoto; Keiji Morokuma
Origin of chemoselectivity of TMP zincate bases and differences between TMP zincate and alkyl lithium reagents: a DFT study on model systems.
Angewandte Chemie (International ed. in English) 2007;46(6):926-9.
2006: Masanobu Uchiyama; Hiroki Ozawa; Kazuya Takuma; Yotaro Matsumoto; Mitsuhiro Yonehara; Kou Hiroya; Takao Sakamoto
Regiocontrolled intramolecular cyclizations of carboxylic acids to carbon-carbon triple bonds promoted by acid or base catalyst.
Organic letters 2006;8(24):5517-20.
2006: Masanobu Uchiyama; Yotaro Matsumoto; Daisuke Nobuto; Taniyuki Furuyama; Kentaro Yamaguchi; Keiji Morokuma
Structure and reaction pathway of TMP-Zincate: amido base or alkyl base?
Journal of the American Chemical Society 2006;128(27):8748-50.
2006: Masanobu Uchiyama; Taniyuki Furuyama; Minoru Kobayashi; Yotaro Matsumoto; Kentaro Tanaka
Toward a protecting-group-free halogen-metal exchange reaction: practical, chemoselective metalation of functionalized aromatic halides using dianion-type zincate, tBu4ZnLi2.
Journal of the American Chemical Society 2006;128(26):8404-5.
2005: Shinji Nakamura; Masanobu Uchiyama; Tomohiko Ohwada
Cp2TiCl2-catalyzed regio- and chemoselective one-step synthesis of gamma-substituted allylsilanes from terminal alkenes using dianion-type zincate (SiSiNOL-Zn-ate).
Journal of the American Chemical Society 2005;127(38):13116-7.
2005: Ryuji Sugi; Akihiro Yokoyama; Taniyuki Furuyama; Masanobu Uchiyama; Tsutomu Yokozawa
Inductive effect-assisted chain-growth polycondensation. synthetic development from para- to meta-substituted aromatic polyamides with low polydispersities.
Journal of the American Chemical Society 2005;127(29):10172-3.
2004: Shinji Nakamura; Masanobu Uchiyama; Tomohiko Ohwada
Chemoselective silylzincation of functionalized terminal alkynes using dianion-type zincate (SiBNOL-Zn-ate): regiocontrolled synthesis of vinylsilanes.
Journal of the American Chemical Society 2004;126(36):11146-7.
2004: Masanobu Uchiyama; Shinji Nakamura; Tomohiko Ohwada; Masaharu Nakamura; Eiichi Nakamura
Mechanism and ligand-transfer selectivity of 1,2-addition of organozincate complexes to aldehyde.
Journal of the American Chemical Society 2004;126(35):10897-903.
2004: Masanobu Uchiyama; Hiroshi Naka; Yotaro Matsumoto; Tomohiko Ohwada
Regio- and chemoselective direct generation of functionalized aromatic aluminum compounds using aluminum ate base.
Journal of the American Chemical Society 2004;126(34):10526-7.
2004: Masanobu Uchiyama; Yotaro Matsumoto; Shinji Nakamura; Tomohiko Ohwada; Nagao Kobayashi; Natsuno Yamashita; Atsushi Matsumiya; Takao Sakamoto
Development of a catalytic electron transfer system mediated by transition metal ate complexes: applicability and tunability of electron-releasing potential for organic transformations.
Journal of the American Chemical Society 2004;126(28):8755-9.
2003: Yuko Otani; Osamu Nagae; Yuji Naruse; Satoshi Inagaki; Masashi Ohno; Kentaro Yamaguchi; Gaku Yamamoto; Masanobu Uchiyama; Tomohiko Ohwada
An evaluation of amide group planarity in 7-azabicyclo[2.2.1]heptane amides. Low amide bond rotation barrier in solution.
Journal of the American Chemical Society 2003;125(49):15191-9.
2003: Satoshi Nakamura; Masaru Tanaka; Tooru Taniguchi; Masanobu Uchiyama; Tomohiko Ohwada
Stereoselectivity of superacid-catalyzed Pictet-Spengler cyclization reactions.
Organic letters 2003;5(12):2087-90.
2003: Satoshi Nakamura; Masanobu Uchiyama; Tomohiko Ohwada
4H-1,2-benzoxazines with electron-withdrawing substituents on the benzene ring: synthesis and application as potent intermediates for oxygen-functionalized aromatic compounds.
Journal of the American Chemical Society 2003;125(18):5282-3.
2002: Masanobu Uchiyama; Tomoko Miyoshi; Yumiko Kajihara; Takao Sakamoto; Yuko Otani; Tomohiko Ohwada; Yoshinori Kondo
Generation of functionalized asymmetric benzynes with TMP-zincates. Effects of ligands on selectivity and reactivity of zincates.
Journal of the American Chemical Society 2002;124(29):8514-5.
2002: Masanobu Uchiyama
[Molecular design and function of ate complexes].
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 2002;122(1):29-46.
2001: Yoshinori Kondo; M Asai; T Miura; Masanobu Uchiyama; Takao Sakamoto
Mesityllithium as a reagent for chemoselective halogen-lithium exchange reaction.
Organic letters 2001;3(1):13-5.
2000: Masanobu Uchiyama
[Molecular design and control of functional expression of ate complexes].
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 2000;120(2):183-96.