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Derek Boyd

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Derek R Boyd; Vera Ljubez; Peter K M McGeehin; Narain D Sharma; Paul J Stevenson; Marine Blain; Christopher C R Allen
Chemoenzymatic synthesis of monocyclic arene oxides and arene hydrates from substituted benzene substrates.
Derek R Boyd; Ian N Brannigan; Timothy A Evans; Simon A Haughey; John F Malone; Peter B A McIntyre; Brian T McMurray; Narain D Sharma; Paul J Stevenson; Christopher C R Allen
Toluene dioxygenase-catalyzed cis-dihydroxylation of benzo[b]thiophenes and benzo[b]furans: synthesis of benzo[b]thiophene 2,3-oxide.
Derek R Boyd; Christopher C R Allen; Marcin Kwit; John F Malone; Peter B A McIntyre; Narain D Sharma; Paul J Stevenson; Jacek Gawronski
Structure, stereochemistry and synthesis of enantiopure cyclohexenone cis-diol bacterial metabolites derived from phenols.

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All Publications

2013: Derek R Boyd; Vera Ljubez; Peter K M McGeehin; Narain D Sharma; Paul J Stevenson; Marine Blain; Christopher C R Allen
Chemoenzymatic synthesis of monocyclic arene oxides and arene hydrates from substituted benzene substrates.
Organic & biomolecular chemistry 2013;11(18):3020-9.
2012: Derek R Boyd; Ian N Brannigan; Timothy A Evans; Simon A Haughey; John F Malone; Peter B A McIntyre; Brian T McMurray; Narain D Sharma; Paul J Stevenson; Christopher C R Allen
Toluene dioxygenase-catalyzed cis-dihydroxylation of benzo[b]thiophenes and benzo[b]furans: synthesis of benzo[b]thiophene 2,3-oxide.
Organic & biomolecular chemistry 2012;10(36):7292-304.
2012: Derek R Boyd; Christopher C R Allen; Marcin Kwit; John F Malone; Peter B A McIntyre; Narain D Sharma; Paul J Stevenson; Jacek Gawronski
Structure, stereochemistry and synthesis of enantiopure cyclohexenone cis-diol bacterial metabolites derived from phenols.
Organic & biomolecular chemistry 2012;10(30):6217-29.
2012: Derek R Boyd; Magdalena Kaik; Peter B A McIntyre; Narain D Sharma; Paul J Stevenson; Christopher C R Allen
Chemoenzymatic formal synthesis of (-)- and (+)-epibatidine.
Organic & biomolecular chemistry 2012;10(14):2774-9.
2012: Derek R Boyd; Katherine S Dunne; Brian Kelly; John F Malone; Paul J Stevenson; Mark Bell; Christopher C R Allen
Chemoenzymatic synthesis of a mixed phosphine-phosphine oxide catalyst and its application to asymmetric allylation of aldehydes and hydrogenation of alkenes.
Organic & biomolecular chemistry 2012;10(7):1388-95.
2011: Derek R Boyd; Narain D Sharma; Paul J Stevenson; Marine Blain; Colin McRoberts; John T G Hamilton; José M Argudo; Harpinder Mundi; Leonid A Kulakov; Christopher C R Allen
Dioxygenase-catalysed cis-dihydroxylation of meta-substituted phenols to yield cyclohexenone cis-diol and derived enantiopure cis-triol metabolites.
Organic & biomolecular chemistry 2011;9(5):1479-90.
2010: Marcin Kwit; Jacek Gawronski; Derek R Boyd; Narain D Sharma; Magdalena Kaik
Circular dichroism, optical rotation and absolute configuration of 2-cyclohexenone-cis-diol type phenol metabolites: redefining the role of substituents and 2-cyclohexenone conformation in electronic circular dichroism spectra.
Organic & biomolecular chemistry 2010;8(24):5635-45.
2010: Derek R Boyd; Narain D Sharma; Carmen A Acaru; John F Malone; Colin R O'Dowd; Christopher C R Allen; Paul J Stevenson
Chemoenzymatic synthesis of carbasugars (+)-pericosines A-C from diverse aromatic cis-dihydrodiol precursors.
Organic letters 2010;12(10):2206-9.
2010: Derek R Boyd; Narain D Sharma; Nigel I Bowers; Giorgio Coen; John F Malone; Colin R O'Dowd; Paul J Stevenson; Christopher C R Allen
Chemoenzymatic synthesis of the carbasugars carba-beta-L-galactopyranose, carba-beta-L-talopyranose and carba-alpha-L-talopyranose from methyl benzoate.
Organic & biomolecular chemistry 2010;8(6):1415-23.
2010: Derek R Boyd; Narain D Sharma; L Sbircea; D Murphy; John F Malone; S L James; Christopher C R Allen; John T G Hamilton
Chemoenzymatic synthesis of chiral 2,2'-bipyridine ligands and their N-oxide derivatives: applications in the asymmetric aminolysis of epoxides and asymmetric allylation of aldehydes.
Organic & biomolecular chemistry 2010;8(5):1081-90.
2009: Derek R Boyd; Narain D Sharma; John F Malone; Christopher C R Allen
New families of enantiopure cyclohexenone cis-diol, o-quinol dimer and hydrate metabolites from dioxygenase-catalysed dihydroxylation of phenols.
Chemical communications (Cambridge, England) 2009;(24):3633-5.
2009: Marcin Kwit; Jacek Gawronski; Lenuta Sbircea; Narain D Sharma; Magdalena Kaik; Derek R Boyd
Circular dichroism spectra, optical rotations and absolute configurations of cis-dihydrodiol metabolites of quinoline and derivatives: the role of the nitrogen atom.
Chirality 2009;21 Suppl 1():E37-47.
2008: Lenuta Sbircea; Narain D Sharma; William Clegg; Ross W Harrington; Peter N Horton; Michael B Hursthouse; David C Apperley; Derek R Boyd; Stuart L James
Chemoenzymatic synthesis of chiral 4,4'-bipyridyls and their metal-organic frameworks.
Chemical communications (Cambridge, England) 2008;(43):5538-40.
2008: Derek R Boyd; Narain D Sharma; Lenuta Sbircea; Deirdre Murphy; Tayeb Belhocine; John F Malone; Stuart L James; Christopher C R Allen; John T G Hamilton
Azaarene cis-dihydrodiol-derived 2,2'-bipyridine ligands for asymmetric allylic oxidation and cyclopropanation.
Chemical communications (Cambridge, England) 2008;(43):5535-7.
2008: Derek R Boyd; Narain D Sharma; Giorgio Coen; Francis Hempenstall; Vera Ljubez; John F Malone; Christopher C R Allen; John T G Hamilton
Regioselectivity and stereoselectivity of dioxygenase catalysed cis-dihydroxylation of mono- and tri-cyclic azaarene substrates.
Organic & biomolecular chemistry 2008;6(21):3957-66.
2008: Marcin Kwit; Narain D Sharma; Derek R Boyd; Jacek Gawronski
Determination of absolute configuration of conformationally flexible cis-dihydrodiol metabolites: effect of diene substitution pattern on the circular dichroism spectra and optical rotations.
Chirality 2008;20(5):609-20.
2008: Derek R Boyd; Narain D Sharma; John S Harrison; John F Malone; W Colin McRoberts; John T G Hamilton; David B Harper
Enzyme-catalysed synthesis and reactions of benzene oxide/oxepine derivatives of methyl benzoates.
Organic & biomolecular chemistry 2008;6(7):1251-9.
2007: Derek R Boyd; Narain D Sharma; Pui L Loke; John F Malone; W Colin McRoberts; John T G Hamilton
Synthesis, structure and stereochemistry of quinoline alkaloids from Choisya ternata.
Organic & biomolecular chemistry 2007;5(18):2983-91.
2007: Derek R Boyd; Narain D Sharma; Nuria M Llamas; Colin R O'Dowd; Christopher C R Allen
syn-Benzene dioxides: chemoenzymatic synthesis from 2,3-cis-dihydrodiol derivatives of monosubstituted benzenes and their application in the synthesis of regioisomeric 1,2- and 3,4-cis-dihydrodiols and 1,4-dioxocins.
Organic & biomolecular chemistry 2007;5(14):2267-73.
2007: Derek R Boyd; Narain D Sharma; Nuria M Llamas; Giorgio Coen; Peter K M McGeehin; Christopher C R Allen
Chemoenzymatic synthesis of trans-dihydrodiol derivatives of monosubstituted benzenes from the corresponding cis-dihydrodiol isomers.
Organic & biomolecular chemistry 2007;5(3):514-22.
2007: Derek R Boyd; Narain D Sharma; Giorgio Coen; Peter J Gray; John F Malone; Jacek Gawronski
Enzyme-catalysed synthesis and absolute configuration assignments of cis-dihydrodiol metabolites from 1,4-disubstituted benzenes.
Chemistry (Weinheim an der Bergstrasse, Germany) 2007;13(20):5804-11.
2007: Marcin Kwit; Narain D Sharma; Derek R Boyd; Jacek Gawronski
Absolute configuration of conformationally flexible cis-dihydrodiol metabolites by the method of confrontation of experimental and calculated electronic CD spectra and optical rotations.
Chemistry (Weinheim an der Bergstrasse, Germany) 2007;13(20):5812-21.
2006: Derek R Boyd; Narain D Sharma; Tayeb Belhocine; John F Malone; Stuart McGregor; Christopher C R Allen
Dioxygenase-catalysed dihydroxylation of arene cis-dihydrodiols and acetonide derivatives: a new approach to the synthesis of enantiopure tetraoxygenated bioproducts from arenes.
Chemical communications (Cambridge, England) 2006;(47):4934-6.
2006: Derek R Boyd; Narain D Sharma; Nigel I Bowers; Howard Dalton; Mark D Garrett; John S Harrison; Gary N Sheldrake
Dioxygenase-catalysed oxidation of disubstituted benzene substrates: benzylic monohydroxylation versus aryl cis-dihydroxylation and the meta effect.
Organic & biomolecular chemistry 2006;4(17):3343-9.
2006: Derek R Boyd; Narain D Sharma; Nuria M Llamas; Colin R O'Dowd; Christopher C R Allen
Chemoenzymatic synthesis of the trans-dihydrodiol isomers of monosubstituted benzenes via anti-benzene dioxides.
Organic & biomolecular chemistry 2006;4(11):2208-17.
2006: Derek R Boyd; Timothy D H Bugg
Arene cis-dihydrodiol formation: from biology to application.
Organic & biomolecular chemistry 2006;4(2):181-92.
2005: Derek R Boyd; Narain D Sharma; Colin R O'Dowd; Jonathan G Carroll; Pui L Loke; Christopher C R Allen
cis-Dihydrodiol, arene oxide and phenol metabolites of dictamnine: key intermediates in the biodegradation and biosynthesis of furoquinoline alkaloids.
Chemical communications (Cambridge, England) 2005;(31):3989-91.
2005: Derek R Boyd; Narain D Sharma; Nuria M Llamas; John F Malone; Colin R O'Dowd; Christopher C R Allen
Chemoenzymatic synthesis of carbasugars from iodobenzene.
Organic & biomolecular chemistry 2005;3(10):1953-63.
2005: Jacek Gawronski; Marcin Kwit; Derek R Boyd; Narain D Sharma; John F Malone; Alex F Drake
Absolute configuration, conformation, and circular dichroism of monocyclic arene dihydrodiol metabolites: it is all due to the heteroatom substituents.
Journal of the American Chemical Society 2005;127(12):4308-19.
2004: Heather R Luckarift; Howard Dalton; Narain D Sharma; Derek R Boyd; Robert A Holt
Isolation and characterisation of bacterial strains containing enantioselective DMSO reductase activity: application to the kinetic resolution of racemic sulfoxides.
Applied microbiology and biotechnology 2004;65(6):678-85.
2004: Derek R Boyd; Narain D Sharma; Breige E Byrne; Simon A Haughey; Martina A Kennedy; Christopher C R Allen
Dioxygenase-catalysed oxidation of alkylaryl sulfides: sulfoxidation versus cis-dihydrodiol formation.
Organic & biomolecular chemistry 2004;2(17):2530-7.
2004: Derek R Boyd; Narain D Sharma; Alistair W T King; Steven D Shepherd; Christopher C R Allen; Robert A Holt; Heather R Luckarift; Howard Dalton
Stereoselective reductase-catalysed deoxygenation of sulfoxides in aerobic and anaerobic bacteria.
Organic & biomolecular chemistry 2004;2(4):554-61.
2003: R Jeremy H Davies; Clarke Stevenson; Shiv Kumar; Jason Lyle; Lisa Cosby; John F Malone; Derek R Boyd; Narain D Sharma; Ann P Hunter; Bridget K Stein
Oxidation of guanine nucleosides to 4-amidinocarbamoyl-5-hydroxyimidazoles by dimethyldioxirane.
Nucleosides, nucleotides & nucleic acids 2003;22(5-8):1355-7.
2003: Derek R Boyd; Narain D Sharma; Nigel I Bowers; Rosemary Boyle; John S Harrison; Kyoung Lee; Timothy D H Bugg; David T Gibson
Stereochemical and mechanistic aspects of dioxygenase-catalysed benzylic hydroxylation of indene and chromane substrates.
Organic & biomolecular chemistry 2003;1(8):1298-307.
2003: Derek R Boyd; Narain D Sharma; Nimal Gunaratne; Simon A Haughey; Martina A Kennedy; John F Malone; Christopher C R Allen; Howard Dalton
Dioxygenase-catalysed oxidation of monosubstituted thiophenes: sulfoxidation versus dihydrodiol formation.
Organic & biomolecular chemistry 2003;1(6):984-94.
2002: Derek R Boyd; Narain D Sharma; Pui L Loke; John F Malone; W Colin McRoberts; John T G Hamilton
Absolute configuration assignment and enantiopurity determination of chiral alkaloids and coumarins derived from O- and C-prenyl epoxides.
Chemical communications (Cambridge, England) 2002;(24):3070-1.
2002: Derek Fairley; Derek R Boyd; Narain D Sharma; Christopher C R Allen; P Morgan; Michael J Larkin
Aerobic metabolism of 4-hydroxybenzoic acid in Archaea via an unusual pathway involving an intramolecular migration (NIH shift).
Applied and environmental microbiology 2002;68(12):6246-55.
2002: Derek R Boyd; Narain D Sharma; Vera Ljubez; Breige E Byrne; Steven D Shepherd; Christopher C R Allen; Leonid A Kulakov; Michael J Larkin; Howard Dalton
Tandem enzyme-catalysed oxidations of alkyl phenyl sulfides and alkyl benzenes: enantiocomplementary routes to chiral phenols.
Chemical communications (Cambridge, England) 2002;(17):1914-5.
2002: Derek R Boyd; Narain D Sharma; Martina A Kennedy; Steven D Shepherd; John F Malone; André Alves-Areias; Robert Holt; Stig G Allenmark; Malin A Lemurell; Howard Dalton; Heather R Luckarift
Enzyme-catalysed oxygenation and deoxygenation routes to chiral thiosulfinates.
Chemical communications (Cambridge, England) 2002;(14):1452-3.
2001: Derek R Boyd; Narain D Sharma; Christopher C R Allen
Aromatic dioxygenases: molecular biocatalysis and applications.
Current opinion in biotechnology 2001;12(6):564-73.
2000: Rebecca E Parales; SM Resnick; Chi-Li Yu; Derek R Boyd; Narain D Sharma; David T Gibson
Regioselectivity and enantioselectivity of naphthalene dioxygenase during arene cis-dihydroxylation: control by phenylalanine 352 in the alpha subunit.
Journal of bacteriology 2000;182(19):5495-504.
1999: Christopher C R Allen; Derek R Boyd; F Hempenstall; Michael J Larkin; Narain D Sharma
Contrasting effects of a nonionic surfactant on the biotransformation of polycyclic aromatic hydrocarbons to cis-dihydrodiols by soil bacteria.
Applied and environmental microbiology 1999;65(3):1335-9.
1991: Juluri R Rao; Narain D Sharma; John T G Hamilton; Derek R Boyd; J E Cooper
Biotransformation of the Pentahydroxy Flavone Quercetin by Rhizobium loti and Bradyrhizobium Strains (Lotus).
Applied and environmental microbiology 1991;57(5):1563-5.