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Xumu Zhang

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TOP 3
Tang-Lin Liu; Chun-Jiang Wang; Huiling Geng; Wei Li; Xumu Zhang
Catalytic enantioselective desymmetrization of meso cyclic anhydrides via iridium-catalyzed hydrogenation.
Shengkun Li; Wenjun Wu; Jiwen Zhang; Kexuan Huang; Xumu Zhang
Cascade synthesis of fenpiprane and related pharmaceuticals via rhodium-catalyzed hydroaminomethylation.
Caiyou Chen; Huiling Geng; Yu Qiao; Xumu Zhang
A novel triphosphoramidite ligand for highly regioselective linear hydroformylation of terminal and internal olefins.

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All Publications

2013: Tang-Lin Liu; Chun-Jiang Wang; Huiling Geng; Wei Li; Xumu Zhang
Catalytic enantioselective desymmetrization of meso cyclic anhydrides via iridium-catalyzed hydrogenation.
Organic letters 2013;15(7):1740-3.
2013: Shengkun Li; Wenjun Wu; Jiwen Zhang; Kexuan Huang; Xumu Zhang
Cascade synthesis of fenpiprane and related pharmaceuticals via rhodium-catalyzed hydroaminomethylation.
Organic letters 2013;15(5):1036-9.
2013: Caiyou Chen; Huiling Geng; Yu Qiao; Xumu Zhang
A novel triphosphoramidite ligand for highly regioselective linear hydroformylation of terminal and internal olefins.
Organic letters 2013;15(5):1048-51.
2013: Kexuan Huang; Shengkun Li; Mingxin Chang; Xumu Zhang
Rhodium-catalyzed enantioselective hydrogenation of oxime acetates.
Organic letters 2013;15(3):484-7.
2012: Shengkun Li; Wenjun Wu; Jiwen Zhang; Bonan Cao; Kexuan Huang; Xumu Zhang
Highly enantioselective hydrogenation of β,β-disubstituted nitroalkenes.
Angewandte Chemie (International ed. in English) 2012;51(34):8573-6.
2012: Chaoxian Cai; Bonan Cao; Shichao Yu; Xumu Zhang
New tetraphosphorus ligands for highly linear selective hydroformylation of allyl and vinyl derivatives.
Chemistry (Weinheim an der Bergstrasse, Germany) 2012;18(32):9992-8.
2011: Mingxin Chang; Wei Li; Xumu Zhang
A highly efficient and enantioselective access to tetrahydroisoquinoline alkaloids: asymmetric hydrogenation with an iridium catalyst.
Angewandte Chemie (International ed. in English) 2011;50(45):10679-81.
2011: Kai Gao; Wei Li; Chang-Bin Yu; Yong-Gui Zhou; Xumu Zhang
Synthesis and enantioselective hydrogenation of seven-membered cyclic imines: substituted dibenzo[b,f][1,4]oxazepines.
Chemical communications (Cambridge, England) 2011;47(27):7845-7.
2011: Zheng-Hui Guan; Zhi-Yuan Zhang; Zhi-Hui Ren; Yao-Yu Wang; Xumu Zhang
Synthesis of enamides via CuI-catalyzed reductive acylation of ketoximes with NaHSO3.
The Journal of organic chemistry 2011;76(1):339-41.
2011: Huiling Geng; Kexuan Huang; Tian Sun; Wei Li; Xumu Zhang; Le Zhou; Wenjun Wu; Xumu Zhang
Enantioselective synthesis of optically pure β-amino ketones and γ-aryl amines by Rh-catalyzed asymmetric hydrogenation.
The Journal of organic chemistry 2011;76(1):332-4.
2010: Kexuan Huang; Xumu Zhang; Thomas J Emge; Guohua Hou; Bonan Cao; Xumu Zhang
Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation.
Chemical communications (Cambridge, England) 2010;46(45):8555-7.
2010: Guohua Hou; Wei Li; Miaofeng Ma; Xumu Zhang; Xumu Zhang
Highly efficient iridium-catalyzed asymmetric hydrogenation of unprotected β-enamine esters.
Journal of the American Chemical Society 2010;132(37):12844-6.
2010: Xumu Zhang; Kexuan Huang; Guohua Hou; Bonan Cao; Xumu Zhang
Electron-donating and rigid P-stereogenic bisphospholane ligands for highly enantioselective rhodium-catalyzed asymmetric hydrogenations.
Angewandte Chemie (International ed. in English) 2010;49(36):6421-4.
2010: Duo-Sheng Wang; Qing-An Chen; Wei Li; Chang-Bin Yu; Yong-Gui Zhou; Xumu Zhang
Pd-catalyzed asymmetric hydrogenation of unprotected indoles activated by Brønsted acids.
Journal of the American Chemical Society 2010;132(26):8909-11.
2010: Wei Li; Guohua Hou; Chunjiang Wang; Yutong Jiang; Xumu Zhang
Asymmetric hydrogenation of ketones catalyzed by a ruthenium(II)-indan-ambox complex.
Chemical communications (Cambridge, England) 2010;46(22):3979-81.
2010: Xumu Zhang; Bonan Cao; Shichao Yu; Xumu Zhang
Rhodium-catalyzed asymmetric hydroformylation of N-allylamides: highly enantioselective approach to beta2-amino aldehydes.
Angewandte Chemie (International ed. in English) 2010;49(24):4047-50.
2010: Miaofeng Ma; Guohua Hou; Tian Sun; Xumu Zhang; Wei Li; Junru Wang; Xumu Zhang
Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of beta-amino acrylonitriles.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(18):5301-4.
2010: Senmiao Xu; Zheng Wang; Yuxue Li; Xumu Zhang; Haiming Wang; Kuiling Ding
Mechanistic investigation of chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanones with H2O2 as the oxidant.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(10):3021-35.
2010: Guohua Hou; Ran Tao; Yongkui Sun; Xumu Zhang; Francis Gosselin
Iridium-monodentate phosphoramidite-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
Journal of the American Chemical Society 2010;132(7):2124-5.
2010: Xumu Zhang; Bonan Cao; Yongjun Yan; Shichao Yu; Baoming Ji; Xumu Zhang
Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: structure-selectivity relationship.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(3):871-7.
2009: Guohua Hou; Francis Gosselin; Wei Li; J Christopher McWilliams; Yongkui Sun; Mark Weisel; Paul D O'Shea; Cheng-yi Chen; Ian W Davies; Xumu Zhang
Enantioselective hydrogenation of N-H imines.
Journal of the American Chemical Society 2009;131(29):9882-3.
2009: Xianfeng Sun; Wei Li; Le Zhou; Xumu Zhang
Matching and mismatching effects of hybrid chiral biaxial bisphosphine ligands in enantioselective hydrogenation of ketoesters.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(30):7302-5.
2009: Wei Li; Xianfeng Sun; Le Zhou; Guohua Hou; Shichao Yu; Xumu Zhang
Highly efficient and highly enantioselective asymmetric hydrogenation of ketones with TunesPhos/1,2-diamine-ruthenium(II) complexes.
The Journal of organic chemistry 2009;74(3):1397-9.
2009: Zheng-Hui Guan; Zhi-Hui Ren; Stephen M Spinella; Shichao Yu; Yong-Min Liang; Xumu Zhang
Rhodium-catalyzed direct oxidative carbonylation of aromatic C-H bond with CO and alcohols.
Journal of the American Chemical Society 2009;131(2):729-33.
2009: Zheng-Hui Guan; Kexuan Huang; Shichao Yu; Xumu Zhang
Synthesis of enamides via Rh/C-catalyzed direct hydroacylation of ketoximes.
Organic letters 2009;11(2):481-3.
2009: Huiling Geng; Weicheng Zhang; Jian Chen; Guohua Hou; Le Zhou; Yaping Zou; Wenjun Wu; Xumu Zhang
Rhodium-catalyzed enantioselective and diastereoselective hydrogenation of beta-ketoenamides: efficient access to anti 1,3-amino alcohols.
Angewandte Chemie (International ed. in English) 2009;48(33):6052-4.
2009: Zhaobin Han; Zheng Wang; Xumu Zhang; Kuiling Ding
Spiro[4,4]-1,6-nonadiene-based phosphine-oxazoline ligands for iridium-catalyzed enantioselective hydrogenation of ketimines.
Angewandte Chemie (International ed. in English) 2009;48(29):5345-9.
2009: Jian Chen; Weicheng Zhang; Huiling Geng; Wei Li; Guohua Hou; Aiwen Lei; Xumu Zhang
Efficient synthesis of chiral beta-arylisopropylamines by using catalytic asymmetric hydrogenation.
Angewandte Chemie (International ed. in English) 2009;48(4):800-2.
2009: Shichao Yu; Yu-ming Chie; Zheng-Hui Guan; Yaping Zou; Wei Li; Xumu Zhang
Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands.
Organic letters 2009;11(1):241-4.
2008: Shichao Yu; Yu-Ming Chie; Zheng-Hui Guan; Xumu Zhang
Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands.
Organic letters 2008;10(16):3469-72.
2008: Zheng Lu; Suqing Zheng; Xumu Zhang; Xiyan Lu
An unexpected phosphine-catalyzed [3 + 2] annulation. Synthesis of highly functionalized cyclopentenes.
Organic letters 2008;10(15):3267-70.
2008: Jian Chen; Qiang Liu; Weicheng Zhang; Stephen Spinella; Aiwen Lei; Xumu Zhang
A convenient synthesis and the asymmetric hydrogenation of N-phthaloyl dehydroamino acid esters.
Organic letters 2008;10(14):3033-6.
2008: Xianfeng Sun; Le Zhou; Wei Li; Xumu Zhang
Convenient divergent strategy for the synthesis of TunePhos-type chiral diphosphine ligands and their applications in highly enantioselective Ru-catalyzed hydrogenations.
The Journal of organic chemistry 2008;73(3):1143-6.
2008: Senmiao Xu; Zheng Wang; Xumu Zhang; Xue Zhang; Kuiling Ding
Chiral Brønsted acid catalyzed asymmetric Baeyer-Villiger reaction of 3-substituted cyclobutanones by using aqueous H2O2.
Angewandte Chemie (International ed. in English) 2008;47(15):2840-3.
2007: Weicheng Zhang; Yongxiang Chi; Xumu Zhang
Developing chiral ligands for asymmetric hydrogenation.
Accounts of chemical research 2007;40(12):1278-90.
2007: Miao Yang; Xumu Zhang; Xiyan Lu
Cationic palladium(II)-catalyzed highly enantioselective [3+2] annulation of 2-acylarylboronic acids with substituted alkynes.
Organic letters 2007;9(24):5131-3.
2007: Fei Liu; Qiang Liu; Minsheng He; Xumu Zhang; Aiwen Lei
Rh-catalyzed highly enantioselective formation of functionalized cyclopentanes and cyclopentanones.
Organic & biomolecular chemistry 2007;5(21):3531-4.
2007: Weicheng Zhang; Xumu Zhang
Highly enantioselective hydrogenation of alpha-dehydroamino esters and itaconates with triphosphorous bidentate ligands and the unprecedented solvent effect thereof.
The Journal of organic chemistry 2007;72(3):1020-3.
2007: Gao Shang; Duan Liu; Scott E Allen; Qin Yang; Xumu Zhang
Asymmetric hydrogenation of alpha-primary and secondary amino ketones: efficient asymmetric syntheses of (-)-arbutamine and (-)-denopamine.
Chemistry (Weinheim an der Bergstrasse, Germany) 2007;13(27):7780-4.
2007: Xianfeng Sun; Le Zhou; Chun-Jiang Wang; Xumu Zhang
Rh-catalyzed highly enantioselective synthesis of 3-arylbutanoic acids.
Angewandte Chemie (International ed. in English) 2007;46(15):2623-6.
2006: Weicheng Zhang; Shulin Wu; Zhaoguo Zhang; Hemant Yennawar; Xumu Zhang
Practical synthesis of chiral 9,9'-spirobixanthene-1,1'-diol.
Organic & biomolecular chemistry 2006;4(24):4474-7.
2006: Yongjun Yan; Xumu Zhang; Xumu Zhang
A tetraphosphorus ligand for highly regioselective isomerization-hydroformylation of internal olefins.
Journal of the American Chemical Society 2006;128(50):16058-61.
2006: Gao Shang; Qin Yang; Xumu Zhang
Rh-catalyzed asymmetric hydrogenation of alpha-aryl imino esters: an efficient enantioselective synthesis of aryl glycine derivatives.
Angewandte Chemie (International ed. in English) 2006;45(38):6360-2.
2006: Weicheng Zhang; Xumu Zhang
Synthesis of triphosphorous bidentate phosphine-phosphoramidite ligands: application in the highly enantioselective hydrogenation of ortho-substituted aryl enamides.
Angewandte Chemie (International ed. in English) 2006;45(33):5515-8.
2006: Yongjun Yan; Xumu Zhang
A hybrid phosphorus ligand for highly enantioselective asymmetric hydroformylation.
Journal of the American Chemical Society 2006;128(22):7198-202.
2006: Qin Yang; Gao Shang; Wenzhong Gao; Jingen Deng; Xumu Zhang
A highly enantioselective, Pd-TangPhos-catalyzed hydrogenation of N-tosylimines.
Angewandte Chemie (International ed. in English) 2006;45(23):3832-5.
2006: Qian Dai; Wenzhong Gao; Duan Liu; Lea M Kapes; Xumu Zhang
Triazole-based monophosphine ligands for palladium-catalyzed cross-coupling reactions of aryl chlorides.
The Journal of organic chemistry 2006;71(10):3928-34.
2005: Qian Dai; Weiran Yang; Xumu Zhang
Efficient rhodium-catalyzed asymmetric hydrogenation for the synthesis of a new class of N-aryl beta-amino acid derivatives.
Organic letters 2005;7(23):5343-5.
2005: Duan Liu; Wenzhong Gao; Qian Dai; Xumu Zhang
Triazole-based monophosphines for Suzuki-Miyaura coupling and amination reactions of aryl chlorides.
Organic letters 2005;7(22):4907-10.
2005: Wenzhong Gao; Xumu Zhang; Malati Raghunath
Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates.
Organic letters 2005;7(19):4241-4.
2005: Chun-Jiang Wang; Xianfeng Sun; Xumu Zhang
Enantioselective hydrogenation of allylphthalimides: an efficient method for the synthesis of beta-methyl chiral amines.
Angewandte Chemie (International ed. in English) 2005;44(31):4933-5.
2005: Duan Liu; Wenzhong Gao; Chunjiang Wang; Xumu Zhang
Practical synthesis of enantiopure gamma-amino alcohols by rhodium-catalyzed asymmetric hydrogenation of beta-secondary-amino ketones.
Angewandte Chemie (International ed. in English) 2005;44(11):1687-9.
2004: Shulin Wu; Weicheng Zhang; Zhaoguo Zhang; Xumu Zhang
Synthesis of new monodentate spiro phosphoramidite ligand and its application in Rh-catalyzed asymmetric hydrogenation reactions.
Organic letters 2004;6(20):3565-7.
2004: Xiaofeng Tong; Dao Li; Zhaoguo Zhang; Xumu Zhang
Rhodium-catalyzed cycloisomerization of 1,6-enynes with an intramolecular halogen shift: reaction scope and mechanism.
Journal of the American Chemical Society 2004;126(24):7601-7.
2004: Duan Liu; Wenjun Tang; Xumu Zhang
Synthesis of a new class of conformationally rigid phosphino-oxazolines: highly enantioselective ligands for Ir-catalyzed asymmetric hydrogenation.
Organic letters 2004;6(4):513-6.
2004: Aiwen Lei; Shulin Wu; Minsheng He; Xumu Zhang
Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.
Journal of the American Chemical Society 2004;126(6):1626-7.
2003: Aiwen Lei; Minsheng He; Xumu Zhang
Rh-catalyzed kinetic resolution of enynes and highly enantioselective formation of 4-alkenyl-2,3-disubstituted tetrahydrofurans.
Journal of the American Chemical Society 2003;125(38):11472-3.
2003: Wenjun Tang; Shulin Wu; Xumu Zhang
Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.
Journal of the American Chemical Society 2003;125(32):9570-1.
2003: Wenjun Tang; Weimin Wang; Yongxiang Chi; Xumu Zhang
A bisphosphepine ligand with stereogenic phosphorus centers for the practical synthesis of beta-aryl-beta-amino acids by asymmetric hydrogenation.
Angewandte Chemie (International ed. in English) 2003;42(30):3509-11.
2003: Wenjun Tang; Xumu Zhang
New chiral phosphorus ligands for enantioselective hydrogenation.
Chemical reviews 2003;103(8):3029-70.
2003: Xiaofeng Tong; Zhaoguo Zhang; Xumu Zhang
Novel rhodium-catalyzed cycloisomerization of 1,6-enynes with an intramolecular halogen shift.
Journal of the American Chemical Society 2003;125(21):6370-1.
2003: Yongxiang Chi; Yong-Gui Zhou; Xumu Zhang
Highly enantioselective reductive amination of simple aryl ketones catalyzed by Ir-f-Binaphane in the presence of titanium(IV) isopropoxide and iodine.
The Journal of organic chemistry 2003;68(10):4120-2.
2003: Wenjun Tang; Weimin Wang; Xumu Zhang
Phospholane-oxazoline ligands for Ir-catalyzed asymmetric hydrogenation.
Angewandte Chemie (International ed. in English) 2003;42(8):943-6.
2003: Wenjun Tang; Duan Liu; Xumu Zhang
Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst.
Organic letters 2003;5(2):205-7.
2002: Shulin Wu; Weimin Wang; Wenjun Tang; Min Lin; Xumu Zhang
Highly enantioselective hydrogenation of enol acetates catalyzed by Ru-TunaPhos complexes.
Organic letters 2002;4(25):4495-7.
2002: Duan Liu; Wenge Li; Xumu Zhang
A novel chiral ferrocenyl phosphine ligand from sugar: applications in Rh-catalyzed asymmetric hydrogenation reactions.
Organic letters 2002;4(25):4471-4.
2002: Aiwen Lei; Jason P Waldkirch; Minsheng He; Xumu Zhang
Highly enantioselective cycloisomerization of enynes catalyzed by rhodium for the preparation of functionalized lactams.
Angewandte Chemie (International ed. in English) 2002;41(23):4526-9.
2002: Wenjun Tang; Xumu Zhang
Highly efficient synthesis of chiral beta-amino acid derivatives via asymmetric hydrogenation.
Organic letters 2002;4(23):4159-61.
2002: James M Longmire; Bin Wang; Xumu Zhang
Highly enantioselective Ag(i)-catalyzed [3 + 2] cycloaddition of azomethine ylides.
Journal of the American Chemical Society 2002;124(45):13400-1.
2002: Wenge Li; Jason P Waldkirch; Xumu Zhang
Chiral C(2)-symmetric ligands with 1,4-dioxane backbone derived from tartrates: syntheses and applications in asymmetric hydrogenation.
The Journal of organic chemistry 2002;67(22):7618-23.
2002: Aiwen Lei; Minsheng He; Shulin Wu; Xumu Zhang
Highly enantioselective Rh-catalyzed intramolecular Alder-ene reactions for the syntheses of chiral tetrahydrofurans.
Angewandte Chemie (International ed. in English) 2002;41(18):3457-60.
2002: Aiwen Lei; Minsheng He; Xumu Zhang
Highly enantioselective syntheses of functionalized alpha-methylene-gamma-butyrolactones via Rh(I)-catalyzed intramolecular Alder ene reaction: application to formal synthesis of (+)-pilocarpine.
Journal of the American Chemical Society 2002;124(28):8198-9.
2002: Aiwen Lei; Xumu Zhang
Palladium-catalyzed homocoupling reactions between two Csp(3)-Csp(3) centers.
Organic letters 2002;4(14):2285-8.
2002: Yong-Gui Zhou; Xumu Zhang
Synthesis of novel BINOL-derived chiral bisphosphorus ligands and their application in catalytic asymmetric hydrogenation.
Chemical communications (Cambridge, England) 2002;(10):1124-5.
2002: Wenjun Tang; Yongxiang Chi; Xumu Zhang
An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides.
Organic letters 2002;4(10):1695-8.
2002: Yong-Gui Zhou; Wenjun Tang; Wen-Bo Wang; Wenge Li; Xumu Zhang
Highly effective chiral ortho-substituted BINAPO ligands (o-BINAPO): applications in Ru-catalyzed asymmetric hydrogenations of beta-aryl-substituted beta-(acylamino)acrylates and beta-keto esters.
Journal of the American Chemical Society 2002;124(18):4952-3.
2002: Wenjun Tang; Xumu Zhang
A chiral 1,2-bisphospholane ligand with a novel structural motif: applications in highly enantioselective Rh-catalyzed hydrogenations.
Angewandte Chemie (International ed. in English) 2002;41(9):1612-4.
2002: Aiwen Lei; Manisha Srivastava; Xumu Zhang
Transmetalation of palladium enolate and its application in palladium-catalyzed homocoupling of alkynes: a room-temperature, highly efficient route to make diynes.
The Journal of organic chemistry 2002;67(6):1969-71.
2000: Zhaoguo Zhang; H Qian; J Longmire; Xumu Zhang
Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.
The Journal of organic chemistry 2000;65(19):6223-6.
2000: Wenge Li; Xumu Zhang
Synthesis of 3, 4-O-isopropylidene- (3S,4S)-dihydroxy-(2R,5R)- bis(diphenylphosphino)hexane and its application in Rh-catalyzed highly enantioselective hydrogenation of enamides.
The Journal of organic chemistry 2000;65(18):5871-4.
2000: Wenge Li; Zhaoguo Zhang; D Xiao; Xumu Zhang
Synthesis of chiral hydroxyl phospholanes from D-mannitol and their use in asymmetric catalytic reactions.
The Journal of organic chemistry 2000;65(11):3489-96.
1999: D Xiao; Zhaoguo Zhang; Xumu Zhang
Synthesis of a novel chiral binaphthyl phospholane and its application in the highly enantioselective hydrogenation of enamides.
Organic letters 1999;1(10):1679-81.