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Christopher Pickett

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Joseph A Wright; Lee Webster; Ausra Jablonskyte; Pei Meng Woi; Saad K Ibrahim; Christopher Pickett
Protonation of [FeFe]-hydrogenase sub-site analogues: revealing mechanism using FTIR stopped-flow techniques.
Spyridon Kaziannis; Stefano Santabarbara; Joseph A Wright; Gregory M Greetham; Michael Towrie; Anthony Parker; Christopher Pickett; Neil T Hunt
Femtosecond to microsecond photochemistry of a [FeFe]hydrogenase enzyme model compound.
Andrew I Stewart; Joseph A Wright; Gregory M Greetham; Spiridon Kaziannis; Stefano Santabarbara; Michael Towrie; Anthony Parker; Christopher Pickett; Neil T Hunt
Determination of the photolysis products of [FeFe]hydrogenase enzyme model systems using ultrafast multidimensional infrared spectroscopy.

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All Publications

2011: Joseph A Wright; Lee Webster; Ausra Jablonskyte; Pei Meng Woi; Saad K Ibrahim; Christopher Pickett
Protonation of [FeFe]-hydrogenase sub-site analogues: revealing mechanism using FTIR stopped-flow techniques.
Faraday discussions 2011;148():359-71; discussion 421-41.
2010: Spyridon Kaziannis; Stefano Santabarbara; Joseph A Wright; Gregory M Greetham; Michael Towrie; Anthony Parker; Christopher Pickett; Neil T Hunt
Femtosecond to microsecond photochemistry of a [FeFe]hydrogenase enzyme model compound.
The journal of physical chemistry. B 2010;114(46):15370-9.
2010: Andrew I Stewart; Joseph A Wright; Gregory M Greetham; Spiridon Kaziannis; Stefano Santabarbara; Michael Towrie; Anthony Parker; Christopher Pickett; Neil T Hunt
Determination of the photolysis products of [FeFe]hydrogenase enzyme model systems using ultrafast multidimensional infrared spectroscopy.
Inorganic chemistry 2010;49(20):9563-73.
2009: Joseph A Wright; Christopher Pickett
Protonation of a subsite analogue of [FeFe]-hydrogenase: mechanism of a deceptively simple reaction revealed by time-resolved IR spectroscopy.
Chemical communications (Cambridge, England) 2009;(38):5719-21.
2008: Anna R Ridley; A Ian Stewart; Katrin Adamczyk; Hirendra N Ghosh; Boutheïna Kerkeni; Z Xiao Guo; Erik T J Nibbering; Christopher Pickett; Neil T Hunt
Multiple-timescale photoreactivity of a model compound related to the active site of [FeFe]-hydrogenase.
Inorganic chemistry 2008;47(17):7453-5.
2008: Xiufeng Wang; Zhimei Li; Xirui Zeng; Qiuyan Luo; David J Evans; Christopher Pickett; Xiaoming Liu
The iron centre of the cluster-free hydrogenase (Hmd): low-spin Fe(II) or low-spin Fe(0)?
Chemical communications (Cambridge, England) 2008;(30):3555-7.
2008: A I Stewart; I P Clark; Michael Towrie; S K Ibrahim; Anthony Parker; Christopher Pickett; Neil T Hunt
Structure and vibrational dynamics of model compounds of the [FeFe]-hydrogenase enzyme system via ultrafast two-dimensional infrared spectroscopy.
The journal of physical chemistry. B 2008;112(32):10023-32.
2008: Fenfen Xu; Cédric Tard; Xiufeng Wang; Saad K Ibrahim; David L Hughes; Wei Zhong; Xirui Zeng; Qiuyan Luo; Xiaoming Liu; Christopher Pickett
Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site.
Chemical communications (Cambridge, England) 2008;(5):606-8.
2007: Stephen P Best; Stacey J Borg; Jonathan M White; Mathieu Razavet; Christopher Pickett
On the structure of a proposed mixed-valent analogue of the diiron subsite of [FeFe]-hydrogenase.
Chemical communications (Cambridge, England) 2007;(42):4348-50.
2007: Mun Hon Cheah; Cédric Tard; Stacey J Borg; Xiaoming Liu; Saad K Ibrahim; Christopher Pickett; Stephen P Best
Modeling [Fe-Fe] hydrogenase: evidence for bridging carbonyl and distal iron coordination vacancy in an electrocatalytically competent proton reduction by an iron thiolate assembly that operates through Fe(0)-Fe(II) levels.
Journal of the American Chemical Society 2007;129(36):11085-92.
2007: Saad K Ibrahim; Xiaoming Liu; Cédric Tard; Christopher Pickett
Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies.
Chemical communications (Cambridge, England) 2007;(15):1535-7.
2006: David E Schwab; Cédric Tard; Eric Brecht; John W Peters; Christopher Pickett; Robert K Szilagyi
On the electronic structure of the hydrogenase H-cluster.
Chemical communications (Cambridge, England) 2006;(35):3696-8.
2006: Saad K Ibrahim; Alexei V Khvostov; Michael F Lappert; Laurent Maron; Lionel Perrin; Christopher Pickett; Andrey V Protchenko
An electrochemical and DFT study on selected beta-diketiminato metal complexes.
Dalton transactions (Cambridge, England : 2003) 2006;(21):2591-6.
2005: Cédric Tard; Xiaoming Liu; Saad K Ibrahim; Maurizio Bruschi; Luca De Gioia; Siân C Davies; Xin Yang; Lai-Sheng Wang; Gary Sawers; Christopher Pickett
Synthesis of the H-cluster framework of iron-only hydrogenase.
Nature 2005;433(7026):610-3.
2005: Stacey J Borg; Mark Bondin; Stephen P Best; Mathieu Razavet; Xiaoming Liu; Christopher Pickett
Electrocatalytic proton reduction by dithiolate-bridged diiron carbonyl complexes: a connection to the H-cluster?
Biochemical Society transactions 2005;33(Pt 1):3-6.
2005: Cédric Tard; Xiaoming Liu; David L Hughes; Christopher Pickett
A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution.
Chemical communications (Cambridge, England) 2005;(1):133-5.
2005: Giuseppe Zampella; Maurizio Bruschi; Piercarlo Fantucci; Mathieu Razavet; Christopher Pickett; Luca De Gioia
Dissecting the intimate mechanism of cyanation of {2Fe3S} complexes related to the active site of all-iron hydrogenases by DFT analysis of energetics, transition states, intermediates and products in the carbonyl substitution pathway.
Chemistry (Weinheim an der Bergstrasse, Germany) 2005;11(2):509-20.
2004: Stacey J Borg; Thomas Behrsing; Stephen P Best; Mathieu Razavet; Xiaoming Liu; Christopher Pickett
Electron transfer at a dithiolate-bridged diiron assembly: electrocatalytic hydrogen evolution.
Journal of the American Chemical Society 2004;126(51):16988-99.
2004: Christopher Pickett; Kylie A Vincent; Saad K Ibrahim; Carol A Gormal; Barry E Smith; Shirley A Fairhurst; Stephen P Best
Synergic binding of carbon monoxide and cyanide to the FeMo cofactor of nitrogenase: relic chemistry of an ancient enzyme?
Chemistry (Weinheim an der Bergstrasse, Germany) 2004;10(19):4770-6.
2004: Vasily S Oganesyan; J Elaine Barclay; Sinead M Hardy; David J Evans; Christopher Pickett; Upali A Jayasooriya
Nuclear inelastic scattering spectroscopy of iron-sulfur cubane compounds.
Chemical communications (Cambridge, England) 2004;(2):214-5.
2003: Xue-Bin Wang; Shuqiang Niu; Xin Yang; Saad K Ibrahim; Christopher Pickett; Toshiko Ichiye; Lai-Sheng Wang
Probing the intrinsic electronic structure of the cubane [4Fe-4S] cluster: nature's favorite cluster for electron transfer and storage.
Journal of the American Chemical Society 2003;125(46):14072-81.
2003: David J Evans; Christopher Pickett
Chemistry and the hydrogenases.
Chemical Society reviews 2003;32(5):268-75.
2003: Christopher Pickett; Kylie A Vincent; Saad K Ibrahim; Carol A Gormal; Barry E Smith; Stephen P Best
Electron-transfer chemistry of the iron-molybdenum cofactor of nitrogenase: delocalized and localized reduced states of FeMoco which allow binding of carbon monoxide to iron and molybdenum.
Chemistry (Weinheim an der Bergstrasse, Germany) 2003;9(1):76-87.
2002: Xin Yang; Xue-Bin Wang; Shuqiang Niu; Christopher Pickett; Toshiko Ichiye; Lai-Sheng Wang
Coulomb- and antiferromagnetic-induced fission in doubly charged cubelike fe-s clusters.
Physical review letters 2002;89(16):163401.
2002: SimonJ George; Zhen Cui; Mathieu Razavet; Christopher Pickett
The di-iron subsite of all-iron hydrogenase: mechanism of cyanation of a synthetic [2Fe3S]-carbonyl assembly.
Chemistry (Weinheim an der Bergstrasse, Germany) 2002;8(17):4037-46.
2002: Nathalie Le Grand; Kenneth W Muir; François Y Pétillon; Christopher Pickett; Philippe Schollhammer; Jean Talarmin
Electrochemical cleavage of N=N bonds at a Mo2(mu-SMe)3 site relevant to the biological reduction of dinitrogen at a bimetallic sulfur centre.
Chemistry (Weinheim an der Bergstrasse, Germany) 2002;8(14):3115-27.
2002: Mathieu Razavet; Stacey J Borg; Simon J George; Stephen P Best; Shirley A Fairhurst; Christopher Pickett
Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence (Fe(I)-Fe(II)) bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase.
Chemical communications (Cambridge, England) 2002;(7):700-1.
2000: Christopher Pickett; Saad K Ibrahim; D L Hughes
Polyferredoxin-based electrode materials.
Faraday discussions 2000;(116):235-44; discussion 257-68.