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Peng Chen

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Electron Spin Resonance Spectroscopy

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TOP 3
Peng Chen; Edward I Solomon
O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms.
Peng Chen; Serge I Gorelsky; Somdatta Ghosh; Edward I Solomon
N2O reduction by the mu4-sulfide-bridged tetranuclear CuZ cluster active site.
Peng Chen; Joseph Bell; Betty A Eipper; Edward I Solomon
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate.

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All Publications

2004: Peng Chen; Edward I Solomon
O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanisms.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(36):13105-10.
2004: Peng Chen; Serge I Gorelsky; Somdatta Ghosh; Edward I Solomon
N2O reduction by the mu4-sulfide-bridged tetranuclear CuZ cluster active site.
Angewandte Chemie (International ed. in English) 2004;43(32):4132-40.
2004: Peng Chen; Joseph Bell; Betty A Eipper; Edward I Solomon
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Spectroscopic definition of the resting sites and the putative CuIIM-OOH intermediate.
Biochemistry 2004;43(19):5735-47.
2004: Peng Chen; Edward I Solomon
Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site.
Journal of the American Chemical Society 2004;126(15):4991-5000.
2003: Somdatta Ghosh; Serge I Gorelsky; Peng Chen; Inês Cabrito; José J G Moura; Isabel Moura; Edward I Solomon
Activation of N2O reduction by the fully reduced micro4-sulfide bridged tetranuclear Cu Z cluster in nitrous oxide reductase.
Journal of the American Chemical Society 2003;125(51):15708-9.
2003: Peng Chen; Kiyoshi Fujisawa; Matthew E Helton; Kenneth D Karlin; Edward I Solomon
Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.
Journal of the American Chemical Society 2003;125(21):6394-408.
2003: Matthew E Helton; Peng Chen; Partha P Paul; Zoltán Tyeklár; Roger D Sommer; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.
Journal of the American Chemical Society 2003;125(5):1160-1.
2003: Peng Chen; David E Root; Cecelia Campochiaro; Kiyoshi Fujisawa; Edward I Solomon
Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization.
Journal of the American Chemical Society 2003;125(2):466-74.
2002: Peng Chen; Inês Cabrito; José J G Moura; Isabel Moura; Edward I Solomon
Spectroscopic and electronic structure studies of the mu(4)-sulfide bridged tetranuclear Cu(Z) cluster in N(2)O reductase: molecular insight into the catalytic mechanism.
Journal of the American Chemical Society 2002;124(35):10497-507.
2002: Peng Chen; Serena DeBeer George; Inês Cabrito; William E Antholine; José J G Moura; Isabel Moura; Britt Hedman; Keith O Hodgson; Edward I Solomon
Electronic structure description of the mu(4)-sulfide bridged tetranuclear Cu(Z) center in N(2)O reductase.
Journal of the American Chemical Society 2002;124(5):744-5.
2002: Peng Chen; Edward I Solomon
Frontier molecular orbital analysis of Cu(n)-O(2) reactivity.
Journal of inorganic biochemistry 2002;88(3-4):368-74.