James Collman

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Collman James P; Dey Abhishek; Barile Christopher J; Ghosh Somdatta; Decréau Richard A
Inhibition of electrocatalytic O(2) reduction of functional CcO models by competitive, non-competitive, and mixed inhibitors.
Collman James P; Dey Abhishek; Yang Ying; Ghosh Somdatta; Decréau Richard A
O2 reduction by a functional heme/nonheme bis-iron NOR model complex.
Collman James P; Hosseini Ali; Eberspacher Todd A; Chidsey Christopher E D
Selective anodic desorption for assembly of different thiol monolayers on the individual electrodes of an array.

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2009: Collman James P; Dey Abhishek; Barile Christopher J; Ghosh Somdatta; Decréau Richard A
Inhibition of electrocatalytic O(2) reduction of functional CcO models by competitive, non-competitive, and mixed inhibitors.
Inorganic chemistry 2009;48(22):10528-34.
2009: Collman James P; Dey Abhishek; Yang Ying; Ghosh Somdatta; Decréau Richard A
O2 reduction by a functional heme/nonheme bis-iron NOR model complex.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(26):10528-33.
2009: Collman James P; Hosseini Ali; Eberspacher Todd A; Chidsey Christopher E D
Selective anodic desorption for assembly of different thiol monolayers on the individual electrodes of an array.
Langmuir : the ACS journal of surfaces and colloids 2009;25(11):6517-21.
2009: Collman James P; Decréau Richard A; Lin Hengwei; Hosseini Ali; Yang Ying; Dey Abhishek; Eberspacher Todd A
Role of a distal pocket in the catalytic O2 reduction by cytochrome c oxidase models immobilized on interdigitated array electrodes.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(18):7320-3.
2009: Collman James P; Ghosh Somdatta; Dey Abhishek; Decréau Richard A; Yang Ying
Catalytic reduction of O2 by cytochrome C using a synthetic model of cytochrome C oxidase.
Journal of the American Chemical Society 2009;131(14):5034-5.
2009: Collman James P; Decréau Richard A; Dey Abhishek; Yang Ying
Water may inhibit oxygen binding in hemoprotein models.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(11):4101-5.
2008: Collman James P; Dey Abhishek; Yang Ying; Decréau Richard A; Ohta Takehiro; Solomon Edward I
Intermediates involved in the two electron reduction of NO to N2O by a functional synthetic model of heme containing bacterial NO reductase.
Journal of the American Chemical Society 2008;130(49):16498-9.
2008: Collman James P; Decréau Richard A
Functional biomimetic models for the active site in the respiratory enzyme cytochrome c oxidase.
Chemical communications (Cambridge, England) 2008;(41):5065-76.
2008: Collman James P; Yang Ying; Dey Abhishek; Decréau Richard A; Ghosh Somdatta; Ohta Takehiro; Solomon Edward I
A functional nitric oxide reductase model.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(41):15660-5.
2008: Collman James P; Dey Abhishek; Decreau Richard A; Yang Ying; Hosseini Ali; Solomon Edward I; Eberspacher Todd A
Interaction of nitric oxide with a functional model of cytochrome c oxidase.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(29):9892-6.
2008: Collman James P; Dey Abhishek; Decréau Richard A; Yang Ying
Model studies of azide binding to functional analogues of CcO.
Inorganic chemistry 2008;47(8):2916-8.
2007: Collman James P; Yang Ying; Decréau Richard A
Synthesis of nitric oxide reductase active site models bearing key components at both distal and proximal sites.
Organic letters 2007;9(15):2855-8.
2007: Collman James P; Decréau Richard A; Yan Yilong; Yoon Jungjoo; Solomon Edward I
Intramolecular single-turnover reaction in a cytochrome C oxidase model bearing a Tyr244 mimic.
Journal of the American Chemical Society 2007;129(18):5794-5.
2007: Decréau Richard A; Collman James P; Yang Ying; Yan Yilong; Devaraj Neal K
Syntheses of hemoprotein models that can be covalently attached onto electrode surfaces by click chemistry.
The Journal of organic chemistry 2007;72(8):2794-802.
2007: Collman James P; Devaraj Neal K; Decréau Richard A; Yang Ying; Yan Yi-Long; Ebina Wataru; Eberspacher Todd A; Chidsey Christopher E D
A cytochrome C oxidase model catalyzes oxygen to water reduction under rate-limiting electron flux.
Science (New York, N.Y.) 2007;315(5818):1565-8.
2006: Collman James P; Decréau Richard A; Sunderland Christopher J
Single-turnover intermolecular reaction between a Fe(III)-superoxide-Cu(I) cytochrome c oxidase model and exogeneous Tyr244 mimics.
Chemical communications (Cambridge, England) 2006;(37):3894-6.
2006: Collman James P; Yan Yi-Long; Lei Jianping; Dinolfo Peter H
Active-site models of bacterial nitric oxide reductase featuring tris-histidyl and glutamic acid mimics: influence of a carboxylate ligand on Fe(B) binding and the heme Fe/Fe(B) redox potential.
Inorganic chemistry 2006;45(19):7581-3.
2006: Devaraj Neal K; Decreau Richard A; Ebina Wataru; Collman James P; Chidsey Christopher E D
Rate of interfacial electron transfer through the 1,2,3-triazole linkage.
The journal of physical chemistry. B 2006;110(32):15955-62.
2006: Collman James P; Devaraj Neal K; Eberspacher Todd P A; Chidsey Christopher E D
Mixed azide-terminated monolayers: a platform for modifying electrode surfaces.
Langmuir : the ACS journal of surfaces and colloids 2006;22(6):2457-64.
2006: Collman James P; Yan Yi-Long; Lei Jianping; Dinolfo Peter H
Efficient synthesis of trisimidazole and glutaric acid bearing porphyrins: ligands for active-site models of bacterial nitric oxide reductase.
Organic letters 2006;8(5):923-6.
2006: Devaraj Neal K; Dinolfo Peter H; Chidsey Christopher E D; Collman James P
Selective functionalization of independently addressed microelectrodes by electrochemical activation and deactivation of a coupling catalyst.
Journal of the American Chemical Society 2006;128(6):1794-5.
2006: Collman James P; Kaplun Marina; Decréau Richard A
Metal corroles as electrocatalysts for oxygen reduction.
Dalton transactions (Cambridge, England : 2003) 2006;(4):554-9.
2005: Collman James P; Yan Yi-Long; Eberspacher Todd; Xie Xiangjin; Solomon Edward I
Oxygen binding of water-soluble cobalt porphyrins in aqueous solution.
Inorganic chemistry 2005;44(26):9628-30.
2005: Devaraj Neal K; Miller Gregory P; Ebina Wataru; Kakaradov Boyko; Collman James P; Kool Eric T; Chidsey Christopher E D
Chemoselective covalent coupling of oligonucleotide probes to self-assembled monolayers.
Journal of the American Chemical Society 2005;127(24):8600-1.
2005: Collman James P; Wang Hong J H; Decreau Richard A; Eberspacher Todd A; Sunderland Christopher J
Synthesis and characterization of Rh(III) corroles: unusual reactivity patterns observed during metalation reactions.
Chemical communications (Cambridge, England) 2005;(19):2497-9.
2005: Collman James P; Decréau Richard A
5,10,15-tris(o-aminophenyl) corrole (TAPC) as a versatile synthon for the preparation of corrole-based hemoprotein analogs.
Organic letters 2005;7(6):975-8.
2004: Van Ryswyk Hal; Moore Erin E; Joshi Neel S; Zeni Rebecca J; Eberspacher Todd A; Collman James P
Surface-confined metalloporphyrin oligomers.
Angewandte Chemie (International ed. in English) 2004;43(43):5827-30.
2004: Collman James P; Kaplun Marina; Sunderland Christopher J; Boulatov Roman
Electrocatalytic reduction of ROOH by iron porphyrins.
Journal of the American Chemical Society 2004;126(36):11166-7.
2004: Slaughter LeGrande M; Collman James P; Eberspacher Todd A; Brauman John I
Radical autoxidation and autogenous O2 evolution in manganese-porphyrin catalyzed alkane oxidations with chlorite.
Inorganic chemistry 2004;43(17):5198-204.
2004: Collman James P; Decréau Richard A; Zhang Chi
Synthesis of cytochrome c oxidase models bearing a Tyr244 mimic.
The Journal of organic chemistry 2004;69(10):3546-9.
2004: Collman James P; Zeng Li; Brauman John I
Donor ligand effect on the nature of the oxygenating species in Mn(III)(salen)-catalyzed epoxidation of olefins: experimental evidence for multiple active oxidants.
Inorganic chemistry 2004;43(8):2672-9.
2004: Collman James P; Decréau Richard A; Costanzo Simona
Appending a tris-imidazole ligand with a Tyr 244 mimic on the distal face of bromoacetamidoporphyrin.
Organic letters 2004;6(6):1033-6.
2004: Collman James P; Devaraj Neal K; Chidsey Christopher E D
"Clicking" functionality onto electrode surfaces.
Langmuir : the ACS journal of surfaces and colloids 2004;20(4):1051-3.
2004: Collman James P; Boulatov Roman; Sunderland Christopher J; Fu Lei
Functional analogues of cytochrome c oxidase, myoglobin, and hemoglobin.
Chemical reviews 2004;104(2):561-88.
2003: Collman James P; Zeng Li; Decréau Richard A
Multiple active oxidants in competitive epoxidations catalyzed by porphyrins and corroles.
Chemical communications (Cambridge, England) 2003;(24):2974-5.
2003: Collman James P; Shiryaeva Irina M; Boulatov Roman
Effect of electron availability on selectivity of O2 reduction by synthetic monometallic Fe porphyrins.
Inorganic chemistry 2003;42(16):4807-9.
2003: Collman James P; Sunderland Christopher J; Berg Katja E; Vance Michael A; Solomon Edward I
Spectroscopic evidence for a heme-superoxide/Cu(I) intermediate in a functional model of cytochrome c oxidase.
Journal of the American Chemical Society 2003;125(22):6648-9.
2003: Collman James P; Fudickar Werner; Shiryaeva Irina
Water-soluble polymer-bound biomimetic analogues of cytochrome C oxidase catalyze 4e- reduction of O2 to water.
Inorganic chemistry 2003;42(11):3384-6.
2003: Shiryaeva Irina M; Collman James P; Boulatov Roman; Sunderland Christopher J
Nonideal electrochemical behavior of biomimetic iron porphyrins: interfacial potential distribution across multilayer films.
Analytical chemistry 2003;75(3):494-502.
2002: Collman James P; Berg Katja E; Sunderland Christopher J; Aukauloo Ally; Vance Michael A; Solomon Edward I
Distal metal effects in cobalt porphyrins related to CcO.
Inorganic chemistry 2002;41(25):6583-96.
2002: Collman James P; Boulatov Roman; Shiryaeva Irina M; Sunderland Christopher J
Distal Cu ion protects synthetic heme/Cu analogues of cytochrome oxidase against inhibition by CO and cyanide.
Angewandte Chemie (International ed. in English) 2002;41(21):4139-42.
2002: Collman James P; Boulatov Roman
Heterodinuclear transition-metal complexes with multiple metal-metal bonds.
Angewandte Chemie (International ed. in English) 2002;41(21):3948-61.
2002: Boulatov Roman; Collman James P; Shiryaeva Irina M; Sunderland Christopher J
Functional analogues of the dioxygen reduction site in cytochrome oxidase: mechanistic aspects and possible effects of Cu(B).
Journal of the American Chemical Society 2002;124(40):11923-35.
2002: Collman James P; Boulatov Roman
Electrocatalytic O2 reduction by synthetic analogues of the heme/Cu site of cytochrome oxidase incorporated in a lipid film.
Angewandte Chemie (International ed. in English) 2002;41(18):3487-9.
2002: Collman James P; Boulatov Roman; Sunderland Christopher J; Shiryaeva Irina M; Berg Katja E
Electrochemical metalloporphyrin-catalyzed reduction of chlorite.
Journal of the American Chemical Society 2002;124(36):10670-1.
2002: Collman James P; Sunderland Christopher J; Boulatov Roman
Biomimetic studies of terminal oxidases: trisimidazole picket metalloporphyrins.
Inorganic chemistry 2002;41(8):2282-91.
2002: Collman James P; Boulatov Roman; Jameson Geoffrey B; Narang Vipin
High-vacuum pyrolysis of Zr(2,3,7,8,12,13,17,18-octaethylporphyrin)(PhC triple bond CPh) as a route to novel Zr species: X-ray structure of a hetero-triply bridged species, [(OEP)Zr(mu-Cl)](2)(mu-O).
Inorganic chemistry 2002;41(2):416-20.
2001: Collman J P; Zhong M; Costanzo S; Zhang C
New imidazole-based tripodal ligands as Cu(B) site mimics of cytochrome C oxidase.
The Journal of organic chemistry 2001;66(24):8252-6.
2001: Collman J P; Slaughter L M; Eberspacher T A; Strassner T; Brauman J I
Mechanism of dihydrogen cleavage by high-valent metal oxo compounds: experimental and computational studies.
Inorganic chemistry 2001;40(24):6272-80.
2001: Collman J P; Zhong M; Zhang C; Costanzo S
Catalytic activities of Cu(II) complexes with nitrogen-chelating bidentate ligands in the coupling of imidazoles with arylboronic acids.
The Journal of organic chemistry 2001;66(23):7892-7.
2001: Collman J P; Boulatov R
Aromatic and benzylic C-H bond activation in the system bis(dicarbonylrhodium(I))- porphyrinate--hydrocarbon solvent.
Inorganic chemistry 2001;40(10):2461-4.
2001: Jameson G B; Collman J P; Boulatov R
Superimposed saddle and ruffled distortions of the porphyrin in iodo(pyridine-N)(5,10,15,20-tetraphenylporphyrinato-kappa(4)N)rhodium(III) toluene solvate.
Acta crystallographica. Section C, Crystal structure communications 2001;57(Pt 4):406-8.
2001: Collman J P; Zhong M; Zeng L; Costanzo S
The [Cu(OH).TMEDA]2Cl2-catalyzed coupling of arylboronic acids with imidazoles in water.
The Journal of organic chemistry 2001;66(4):1528-31.
2001: Collman J P; Boulatov R
Unexpected reactivity of Rh(TPP)I(CO) toward an alkoxide in CH2Cl2: synthesis and crystal structure of Rh(TPP)(CH2Cl).
Inorganic chemistry 2001;40(3):560-3.
2000: Collman J P; Kendall J L; Chen J L; Collins K A; Marchon J C
Formation of charge-transfer complexes from neutral bis(porphyrin) sandwiches.
Inorganic chemistry 2000;39(8):1661-7.
1999: Collman J P; Zhong M; Wang Z; Rapta M; Rose E
Efficient synthesis of a porphyrin-N-tripod conjugate with covalently linked proximal ligand: toward new-generation active-site models of cytochrome c oxidase.
Organic letters 1999;1(13):2121-4.
1999: Collman J P; Zhong M; Wang Z
A general route to 4-imidazolyl-containing multidentate ligands for biomimetic studies.
Organic letters 1999;1(6):949-51.
1997: Collman J P; Fu L; Herrmann P C; Zhang X
A functional model related to cytochrome c oxidase and its electrocatalytic four-electron reduction of O2.
Science (New York, N.Y.) 1997;275(5302):949-51.
1996: Collman J P
Coupling H2 to electron transfer.
Nature structural biology 1996;3(3):213-7.
1993: Collman J P; Zhang X; Lee V J; Uffelman E S; Brauman J I
Regioselective and enantioselective epoxidation catalyzed by metalloporphyrins.
Science (New York, N.Y.) 1993;261(5127):1404-11.
1984: Collman J P; Brauman J I; Meunier B; Raybuck S A; Kodadek T
Epoxidation of olefins by cytochrome P-450 model compounds: mechanism of oxygen atom transfer.
Proceedings of the National Academy of Sciences of the United States of America 1984;81(10):3245-8.
1983: Collman J P; Kodadek T; Raybuck S A; Meunier B
Oxygenation of hydrocarbons by cytochrome P-450 model compounds: modification of reactivity by axial ligands.
Proceedings of the National Academy of Sciences of the United States of America 1983;80(22):7039-41.

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