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Christopher Cummins

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Anthony F Cozzolino; Christopher C Cummins; Xiaochen Cai; Burjor Captain; Subhojit Majumdar; Taryn D Palluccio; Elena V Rybak-Akimova; Manuel Temprado; Daniel Tofan; Carl D Hoff
Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex.
Alexandra Velian; Christopher C Cummins
Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene.
Matthew A Rankin; Christopher C Cummins
Terminal phosphinidene formation via tantalaziridine complexes.

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All Publications

2012: Anthony F Cozzolino; Christopher C Cummins; Xiaochen Cai; Burjor Captain; Subhojit Majumdar; Taryn D Palluccio; Elena V Rybak-Akimova; Manuel Temprado; Daniel Tofan; Carl D Hoff
Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex.
Journal of the American Chemical Society 2012;134(44):18249-52.
2012: Alexandra Velian; Christopher C Cummins
Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene.
Journal of the American Chemical Society 2012;134(34):13978-81.
2012: Matthew A Rankin; Christopher C Cummins
Terminal phosphinidene formation via tantalaziridine complexes.
Dalton transactions (Cambridge, England : 2003) 2012;41(32):9615-8.
2012: Alexander R Fox; Christopher C Cummins
A highly reduced cyanogen ligand derived from cyanide reductive coupling.
Chemical communications (Cambridge, England) 2012;48(25):3061-3.
2012: Paula L Diaconescu; Christopher C Cummins
μ-η6,η6-Arene-bridged diuranium hexakisketimide complexes isolable in two states of charge.
Inorganic chemistry 2012;51(5):2902-16.
2012: Nazario Lopez; Robert McGuire; Glen E Alliger; Christopher C Cummins; Daniel J Graham; Yang Shao-Horn; Daniel G Nocera
Reversible reduction of oxygen to peroxide facilitated by molecular recognition.
Science (New York, N.Y.) 2012;335(6067):450-3.
2011: Diego Solis-Ibarra; Vojtech Jancik; Jared S Silvia; Christopher C Cummins
Facile synthesis of zero-, one-, and two-dimensional vanadyl pyrophosphates.
Inorganic chemistry 2011;50(20):9980-4.
2011: Xiaochen Cai; Burjor Captain; Christopher R Clough; Christopher C Cummins; George C Fortman; Luis Manuel Frutos; Meaghan E Germain; Subhojit Majumdar; Taryn Palluccio; Elena V Rybak-Akimova; Manuel Temprado; Carl D Hoff
Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex.
Inorganic chemistry 2011;50(19):9620-30.
2011: Christoph Schwarzmaier; Alexey Y Timoshkin; Manfred Zabel; Brandi M Cossairt; Christopher C Cummins; Germund Glatz; Rhett Kempe; Awal Noor; Manfred Scheer
Formation of cyclo-E4(2-) units (E4 =P4, As4, AsP3) by a complex with a Cr-Cr quintuple bond.
Angewandte Chemie (International ed. in English) 2011;50(32):7283-6.
2011: Glen E Alliger; Christopher C Cummins; Loi Do; Peter Müller; Daniel G Nocera
Family of cofacial bimetallic complexes of a hexaanionic carboxamide cryptand.
Inorganic chemistry 2011;50(9):4107-15.
2011: John J Curley; Anthony F Cozzolino; Christopher C Cummins
Nitrogen fixation to cyanide at a molybdenum center.
Dalton transactions (Cambridge, England : 2003) 2011;40(11):2429-32.
2011: Michael Montag; Christopher R Clough; Peter Müller; Christopher C Cummins
Cyclophosphates as ligands for cobalt(III) in water.
Chemical communications (Cambridge, England) 2011;47(2):662-4.
2010: Brandi M Cossairt; Christopher C Cummins
Molecular gallium arsenide phosphide clusters prepared from AsP(3), P(4), and [{GaC(SiMe(3))(3)}(4)].
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(42):12603-8.
2010: Daniel Tofan; Christopher C Cummins
Photochemical incorporation of diphosphorus units into organic molecules.
Angewandte Chemie (International ed. in English) 2010;49(41):7516-8.
2010: Alexander R Fox; Sidney E Creutz; Christopher C Cummins
A bimetallic uranium mu-dicarbide complex: synthesis, X-ray crystal structure, and bonding.
Dalton transactions (Cambridge, England : 2003) 2010;39(29):6632-4.
2010: Matthew A Rankin; Christopher C Cummins
Carbon dioxide reduction by terminal tantalum hydrides: formation and isolation of bridging methylene diolate complexes.
Journal of the American Chemical Society 2010;132(29):10021-3.
2010: Brandi M Cossairt; Nicholas A Piro; Christopher C Cummins
Early-transition-metal-mediated activation and transformation of white phosphorus.
Chemical reviews 2010;110(7):4164-77.
2010: Brandi M Cossairt; Christopher C Cummins; Ashley R Head; Dennis L Lichtenberger; Raphael J F Berger; Stuart A Hayes; Norbert W Mitzel; Gang Wu
On the molecular and electronic structures of AsP3 and P4.
Journal of the American Chemical Society 2010;132(24):8459-65.
2010: Glen E Alliger; Peter Müller; Christopher C Cummins; Daniel G Nocera
Cofacial dicobalt complex of a binucleating hexacarboxamide cryptand ligand.
Inorganic chemistry 2010;49(8):3697-9.
2010: Alexander R Fox; Polly L Arnold; Christopher C Cummins
Uranium-nitrogen multiple bonding: isostructural anionic, neutral, and cationic uranium nitride complexes featuring a linear U=N=U core.
Journal of the American Chemical Society 2010;132(10):3250-1.
2010: Jared S Silvia; Christopher C Cummins
Ligand-based reduction of CO(2) to CO mediated by an anionic niobium nitride complex.
Journal of the American Chemical Society 2010;132(7):2169-71.
2010: Brandi M Cossairt; Christopher C Cummins
Shuttling P3 from niobium to rhodium: the synthesis and use of Ph3SnP3(C6H8) as a P3- synthon.
Angewandte Chemie (International ed. in English) 2010;49(9):1595-8.
2009: Heather A Spinney; Nicholas A Piro; Christopher C Cummins
Triple-bond reactivity of an AsP complex intermediate: synthesis stemming from molecular arsenic, As(4).
Journal of the American Chemical Society 2009;131(44):16233-43.
2009: Brandi M Cossairt; Christopher C Cummins
Properties and reactivity patterns of AsP(3): an experimental and computational study of group 15 elemental molecules.
Journal of the American Chemical Society 2009;131(42):15501-11.
2009: John J Curley; Nicholas A Piro; Christopher C Cummins
A terminal molybdenum arsenide complex synthesized from yellow arsenic.
Inorganic chemistry 2009;48(20):9599-601.
2009: John J Curley; Tetsuro Murahashi; Christopher C Cummins
Synthesis and reversible reductive coupling of cationic, dinitrogen-derived diazoalkane complexes.
Inorganic chemistry 2009;48(15):7181-93.
2009: Nicholas A Piro; Christopher C Cummins
An unusual P-P double bond formed via phospha-Wittig transformation of a terminal PO complex.
Journal of the American Chemical Society 2009;131(25):8764-5.
2009: Alexander R Fox; Christopher C Cummins
Uranium-nitrogen multiple bonding: the case of a four-coordinate uranium(VI) nitridoborate complex.
Journal of the American Chemical Society 2009;131(16):5716-7.
2009: Brandi M Cossairt; Mariam-Céline Diawara; Christopher C Cummins
Facile synthesis of AsP3.
Science (New York, N.Y.) 2009;323(5914):602.
2009: Jared S Silvia; Christopher C Cummins
Two-electron reduction of a vanadium(V) nitride by CO to release cyanate and open a coordination site.
Journal of the American Chemical Society 2009;131(2):446-7.
2009: Nicholas A Piro; Christopher C Cummins
Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate.
Angewandte Chemie (International ed. in English) 2009;48(5):934-8.
2008: Brandi M Cossairt; Christopher C Cummins
Phosphaalkenes as long-lived phosphorus cluster surface functional groups: intramolecular P=C addition to a niobium-supported P7 cage.
Inorganic chemistry 2008;47(20):9363-71.
2008: Manuel Temprado; James E McDonough; Arjun Mendiratta; Yi-Chou Tsai; George C Fortman; Christopher C Cummins; Elena V Rybak-Akimova; Carl D Hoff
Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3.
Inorganic chemistry 2008;47(20):9380-9.
2008: Alexander R Fox; Suzanne C Bart; Karsten Meyer; Christopher C Cummins
Towards uranium catalysts.
Nature 2008;455(7211):341-9.
2008: Christopher R Clough; Peter Müller; Christopher C Cummins
6-Coordinate tungsten(VI) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles.
Dalton transactions (Cambridge, England : 2003) 2008;(33):4458-63.
2008: Nicholas A Piro; Christopher C Cummins
P2 addition to terminal phosphide M[triple bond]P triple bonds: a rational synthesis of cyclo-P3 complexes.
Journal of the American Chemical Society 2008;130(29):9524-35.
2008: John J Curley; Timothy R Cook; Steven Y Reece; Peter Müller; Christopher C Cummins
Shining light on dinitrogen cleavage: structural features, redox chemistry, and photochemistry of the key intermediate bridging dinitrogen complex.
Journal of the American Chemical Society 2008;130(29):9394-405.
2008: Theodore A Betley; Yogesh Surendranath; Montana V Childress; Glen E Alliger; Ross Fu; Christopher C Cummins; Daniel G Nocera
A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites.
Philosophical transactions of the Royal Society of London. Series B, Biological sciences 2008;363(1494):1293-303; discussion 1303.
2008: James E McDonough; Arjun Mendiratta; John J Curley; George C Fortman; Serena Fantasia; Christopher C Cummins; Elena V Rybak-Akimova; Steven P Nolan; Carl D Hoff
Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus.
Inorganic chemistry 2008;47(6):2133-41.
2008: Brandi M Cossairt; Christopher C Cummins
A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions.
Angewandte Chemie (International ed. in English) 2008;47(46):8863-6.
2008: Brandi M Cossairt; Christopher C Cummins
A reactive niobium phosphinidene P8 cluster obtained by reductive coupling of white phosphorus.
Angewandte Chemie (International ed. in English) 2008;47(1):169-72.
2007: Nicholas A Piro; Christopher C Cummins
Ethylenebis(triphenylphosphine)platinum as a probe for niobium-mediated diphosphorus chemistry.
Inorganic chemistry 2007;46(18):7387-93.
2007: Paresh Agarwal; Nicholas A Piro; Karsten Meyer; Peter Müller; Christopher C Cummins
An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple.
Angewandte Chemie (International ed. in English) 2007;46(17):3111-4.
2007: Alexander R Fox; Christopher R Clough; Nicholas A Piro; Christopher C Cummins
A terminal nitride-to-phosphide conversion sequence followed by tungsten phosphide functionalization using a diphenylphosphenium synthon.
Angewandte Chemie (International ed. in English) 2007;46(6):973-6.
2006: John J Curley; Emma L Sceats; Christopher C Cummins
A cycle for organic nitrile synthesis via dinitrogen cleavage.
Journal of the American Chemical Society 2006;128(43):14036-7.
2006: Nicholas A Piro; Joshua S Figueroa; Jessica T McKellar; Christopher C Cummins
Triple-bond reactivity of diphosphorus molecules.
Science (New York, N.Y.) 2006;313(5791):1276-9.
2006: James E McDonough; John J Weir; Kengkaj Sukcharoenphon; Carl D Hoff; Olga P Kryatova; Elena V Rybak-Akimova; Brian L Scott; Gregory J Kubas; Arjun Mendiratta; Christopher C Cummins
Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation.
Journal of the American Chemical Society 2006;128(31):10295-303.
2006: Arjun Mendiratta; Christopher C Cummins; F Albert Cotton; Sergey A Ibragimov; Carlos A Murillo; Dino Villagrán
A diamagnetic dititanium(III) paddlewheel complex with no direct metal-metal bond.
Inorganic chemistry 2006;45(11):4328-30.
2006: Joshua S Figueroa; Christopher C Cummins
A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer.
Dalton transactions (Cambridge, England : 2003) 2006;(18):2161-8.
2006: Arjun Mendiratta; Christopher C Cummins; Olga P Kryatova; Elena V Rybak-Akimova; James E McDonough; Carl D Hoff
Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction.
Journal of the American Chemical Society 2006;128(14):4881-91.
2006: Christopher C Cummins
Terminal, anionic carbide, nitride, and phosphide transition-metal complexes as synthetic entries to low-coordinate phosphorus derivatives.
Angewandte Chemie (International ed. in English) 2006;45(6):862-70.
2006: Joshua S Figueroa; Nicholas A Piro; Christopher R Clough; Christopher C Cummins
A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling.
Journal of the American Chemical Society 2006;128(3):940-50.
2005: Frances H Stephens; Marc J A Johnson; Christopher C Cummins; Olga P Kryatova; Sergey V Kryatov; Elena V Rybak-Akimova; James E McDonough; Carl D Hoff
Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: a thermochemical, kinetic, and quantum chemical investigation.
Journal of the American Chemical Society 2005;127(43):15191-200.
2005: Arjun Mendiratta; Christopher C Cummins
Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone.
Inorganic chemistry 2005;44(21):7319-21.
2005: Arjun Mendiratta; Joshua S Figueroa; Christopher C Cummins
Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate.
Chemical communications (Cambridge, England) 2005;(27):3403-5.
2005: Joshua S Figueroa; Christopher C Cummins
Triatomic EP2 triangles (E=Ge, Sn, Pb) as mu2:eta3,eta3-bridging ligands.
Angewandte Chemie (International ed. in English) 2005;44(29):4592-6.
2005: James E McDonough; John J Weir; Matthew J Carlson; Carl D Hoff; Olga P Kryatova; Elena V Rybak-Akimova; Christopher R Clough; Christopher C Cummins
Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths.
Inorganic chemistry 2005;44(9):3127-36.
2005: Tetsuro Murahashi; Christopher R Clough; Joshua S Figueroa; Christopher C Cummins
A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex.
Angewandte Chemie (International ed. in English) 2005;44(17):2560-3.
2004: Joshua S Figueroa; Christopher C Cummins
Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: a recyclable niobium phosphide (P(3-)) reagent that effects C-P triple-bond formation.
Journal of the American Chemical Society 2004;126(43):13916-7.
2004: Han Sen Soo; Joshua S Figueroa; Christopher C Cummins
A homoleptic molybdenum(IV) enolate complex: synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI).
Journal of the American Chemical Society 2004;126(36):11370-6.
2004: Christopher R Clough; Jane B Greco; Joshua S Figueroa; Paula L Diaconescu; William M Davis; Christopher C Cummins
Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex.
Journal of the American Chemical Society 2004;126(25):7742-3.
2004: Joshua S Figueroa; Christopher C Cummins
Diorganophosphanylphosphinidenes as complexed ligands: synthesis via an anionic terminal phosphide of niobium.
Angewandte Chemie (International ed. in English) 2004;43(8):984-8.
2003: Arjun Mendiratta; Christopher C Cummins; Olga P Kryatova; Elena V Rybak-Akimova; James E McDonough; Carl D Hoff
Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh (E = S, Se, and Te) elimination.
Inorganic chemistry 2003;42(26):8621-3.
2003: Frances H Stephens; Joshua S Figueroa; Paula L Diaconescu; Christopher C Cummins
Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex.
Journal of the American Chemical Society 2003;125(31):9264-5.
2003: Joshua S Figueroa; Christopher C Cummins
The niobaziridine-hydride functional group: synthesis and divergent reactivity.
Journal of the American Chemical Society 2003;125(14):4020-1.
2002: Paula L Diaconescu; Christopher C Cummins
Diuranium inverted sandwiches involving naphthalene and cyclooctatetraene.
Journal of the American Chemical Society 2002;124(26):7660-1.
2002: Justin K Brask; Víctor Durà-Vilà; Paula L Diaconescu; Christopher C Cummins
Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide.
Chemical communications (Cambridge, England) 2002;(8):902-3.
2002: Theodor Agapie; Paula L Diaconescu; Christopher C Cummins
Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex.
Journal of the American Chemical Society 2002;124(11):2412-3.
2001: J P Cherry; Frances H Stephens; Marc J A Johnson; Paula L Diaconescu; Christopher C Cummins
Terminal phosphide and dinitrogen molybdenum compounds obtained from pnictide-bridged precursors.
Inorganic chemistry 2001;40(27):6860-2.
2001: J K Brask; M G Fickes; P Sangtrirutnugul; V Durà-Vilà; A L Odom; Christopher C Cummins
Niobium and vanadium iminophosphinimide complexes.
Chemical communications (Cambridge, England) 2001;(17):1676-7.
2001: J P Cherry; A R Johnson; L M Baraldo; Y C Tsai; Christopher C Cummins; Sergey V Kryatov; Elena V Rybak-Akimova; Kenneth B Capps; Carl D Hoff; C M Haar; Steven P Nolan
On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes.
Journal of the American Chemical Society 2001;123(30):7271-86.
2001: M V Barybin; Paula L Diaconescu; Christopher C Cummins
Coordination chemistry of a chelating amidoximato ligand.
Inorganic chemistry 2001;40(12):2892-7.
2001: J B Greco; J C Peters; T A Baker; William M Davis; Christopher C Cummins; G Wu
Atomic carbon as a terminal ligand: studies of a carbidomolybdenum anion featuring solid-state (13)C NMR data and proton-transfer self-exchange kinetics.
Journal of the American Chemical Society 2001;123(21):5003-13.
2000: Theodor Agapie; A L Odom; Christopher C Cummins
In pursuit of the molybdenum(III) tris(thiolate) fragment: unusual structure of a dimolybdenum mu-nitrido complex.
Inorganic chemistry 2000;39(2):174-9.