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Antonio Cupane

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Giorgio Schiró; Francesca Natali; Antonio Cupane
Physical origin of anharmonic dynamics in proteins: new insights from resolution-dependent neutron scattering on homomeric polypeptides.
Matteo Levantino; Giorgio Schirò; Alessandro Spilotros; beatrice vallone; Chiara Ardiccioni; Maurizio Brunori; Marco Cammarata; Antonio Cupane
The Monod-Wyman-Changeux allosteric model accounts for the quaternary transition dynamics in wild type and a recombinant mutant human hemoglobin.
Rosina Noto; Margherita Pezzullo; Stefano Ricagno; Maria Grazia Santangelo; Martino Bolognesi; Antonio Cupane; Matteo Levantino; MR Mangione; Vincenzo Martorana; Mauro Manno
The tempered polymerization of human neuroserpin.

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All Publications

2012: Giorgio Schiró; Francesca Natali; Antonio Cupane
Physical origin of anharmonic dynamics in proteins: new insights from resolution-dependent neutron scattering on homomeric polypeptides.
Physical review letters 2012;109(12):128102.
2012: Matteo Levantino; Giorgio Schirò; Alessandro Spilotros; beatrice vallone; Chiara Ardiccioni; Maurizio Brunori; Marco Cammarata; Antonio Cupane
The Monod-Wyman-Changeux allosteric model accounts for the quaternary transition dynamics in wild type and a recombinant mutant human hemoglobin.
Proceedings of the National Academy of Sciences of the United States of America 2012;109(37):14894-9.
2012: Rosina Noto; Margherita Pezzullo; Stefano Ricagno; Maria Grazia Santangelo; Martino Bolognesi; Antonio Cupane; Matteo Levantino; MR Mangione; Vincenzo Martorana; Mauro Manno
The tempered polymerization of human neuroserpin.
PloS one 2012;7(3):e32444.
2011: Giuseppe Bellavia; Sergio Giuffrida; Grazia Cottone; Antonio Cupane; Lorenzo Cordone
Protein thermal denaturation and matrix glass transition in different protein-trehalose-water systems.
The journal of physical chemistry. B 2011;115(19):6340-6.
2011: Alberto Dessy; Anna Maria Piras; Giorgio Schirò; Matteo Levantino; Antonio Cupane; Federica Chiellini
Hemoglobin loaded polymeric nanoparticles: preparation and characterizations.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences 2011;43(1-2):57-64.
2010: Giorgio Schiró; Chiara Caronna; Francesca Natali; Antonio Cupane
Molecular origin and hydration dependence of protein anharmonicity: an elastic neutron scattering study.
Physical chemistry chemical physics : PCCP 2010;12(35):10215-20.
2010: M Cammarata; Matteo Levantino; Michael Wulff; Antonio Cupane
Unveiling the timescale of the R-T transition in human hemoglobin.
Journal of molecular biology 2010;400(5):951-62.
2010: Alessandro Spilotros; Matteo Levantino; Antonio Cupane
Conformational substates of ferricytochrome c revealed by combined optical absorption and electronic circular dichroism spectroscopy at cryogenic temperature.
Biophysical chemistry 2010;147(1-2):8-12.
2010: Giorgio Schiró; Chiara Caronna; Francesca Natali; Antonio Cupane
Direct evidence of the amino acid side chain and backbone contributions to protein anharmonicity.
Journal of the American Chemical Society 2010;132(4):1371-6.
2009: Giuseppe Bellavia; Grazia Cottone; Sergio Giuffrida; Antonio Cupane; Lorenzo Cordone
Thermal denaturation of myoglobin in water--disaccharide matrixes: relation with the glass transition of the system.
The journal of physical chemistry. B 2009;113(33):11543-9.
2009: Giorgio Schirò; Antonio Cupane; Eugenio Vitrano; Fabio Bruni
Dielectric relaxations in confined hydrated myoglobin.
The journal of physical chemistry. B 2009;113(28):9606-13.
2008: Maria Grazia Santangelo; Matteo Levantino; Antonio Cupane; Gunnar Jeschke
Solvation of a probe molecule by fluid supercooled water in a hydrogel at 200 K.
The journal of physical chemistry. B 2008;112(49):15546-53.
2008: Marco Cammarata; Matteo Levantino; Friedrich Schotte; Philip A Anfinrud; Friederike Ewald; Jungkweon Choi; Antonio Cupane; Michael Wulff; Hyotcherl Ihee
Tracking the structural dynamics of proteins in solution using time-resolved wide-angle X-ray scattering.
Nature methods 2008;5(10):881-6.
2008: Giorgio Schirò; Michele Sclafani; Francesca Natali; Antonio Cupane
Hydration dependent dynamics in sol-gel encapsulated myoglobin.
European biophysics journal : EBJ 2008;37(5):543-9.
2008: Chiara Caronna; Yuriy Chushkin; Anders Madsen; Antonio Cupane
Dynamics of nanoparticles in a supercooled liquid.
Physical review letters 2008;100(5):055702.
2007: Giorgio Schiro; Antonio Cupane
Quaternary relaxations in sol-gel encapsulated hemoglobin studied via NIR and UV spectroscopy.
Biochemistry 2007;46(41):11568-76.
2007: András Dér; Lóránd Kelemen; L Fábián; SG Taneva; E Fodor; Tibor Páli; Antonio Cupane; M G Cacace; Jeremy J Ramsden
Interfacial water structure controls protein conformation.
The journal of physical chemistry. B 2007;111(19):5344-50.
2006: Reinhard Schweitzer-Stenner; Matteo Levantino; Antonio Cupane; Carmichael Wallace; Monique Laberge; Qing Huang
Functionally relevant electric-field induced perturbations of the prosthetic group of yeast ferrocytochrome c mutants obtained from a vibronic analysis of low-temperature absorption spectra.
The journal of physical chemistry. B 2006;110(24):12155-61.
2006: Marco Cammarata; Maciej Lorenc; Tae Kook Kim; Jae Hyuk Lee; Q Y Kong; E Pontecorvo; M Lo Russo; G Schiró; Antonio Cupane; Michael Wulff; Hyotcherl Ihee
Impulsive solvent heating probed by picosecond x-ray diffraction.
The Journal of chemical physics 2006;124(12):124504.
2005: Antonio Cupane; Marco Cammarata; Lorenzo Cordone; Maurizio Leone; Eugenio Vitrano; Niklas Engler; Fritz G Parak
Spectral broadening of the Soret band in myoglobin: an interpretation by the full spectrum of low-frequency modes from a normal modes analysis.
European biophysics journal : EBJ 2005;34(7):881-9.
2005: Matteo Levantino; Qing Huang; Antonio Cupane; Monique Laberge; Andrew Hagarman; Reinhard Schweitzer-Stenner
The importance of vibronic perturbations in ferrocytochrome c spectra: a reevaluation of spectral properties based on low-temperature optical absorption, resonance Raman, and molecular-dynamics simulations.
The Journal of chemical physics 2005;123(5):054508.
2005: Chiara Caronna; Francesca Natali; Antonio Cupane
Incoherent elastic and quasi-elastic neutron scattering investigation of hemoglobin dynamics.
Biophysical chemistry 2005;116(3):219-25.
2005: Giorgio Schirò; Marco Cammarata; Matteo Levantino; Antonio Cupane
Spectroscopic markers of the T<-->R quaternary transition in human hemoglobin.
Biophysical chemistry 2005;114(1):27-33.
2004: Matteo Levantino; Antonio Cupane; László Zimányi; Pál Ormos
Different relaxations in myoglobin after photolysis.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(40):14402-7.
2004: Gianluca Fiandaca; Eugenio Vitrano; Antonio Cupane
Ferricytochrome c encapsulated in silica nanoparticles: structural stability and functional properties.
Biopolymers 2004;74(1-2):55-9.
2003: Marco Cammarata; Matteo Levantino; Antonio Cupane; A Longo; A Martorana; F Bruni
Structure and dynamics of water confined in silica hydrogels: X-ray scattering and dielectric spectroscopy studies.
The European physical journal. E, Soft matter 2003;12 Suppl 1():S63-6.
2003: Antonio Cupane; Maurizio Leone; Valeria Militello
Conformational substates and dynamic properties of carbonmonoxy hemoglobin.
Biophysical chemistry 2003;104(1):335-44.
2003: Matteo Levantino; Antonio Cupane; László Zimányi
Quaternary structure dependence of kinetic hole burning and conformational substates interconversion in hemoglobin.
Biochemistry 2003;42(15):4499-505.
2003: Maria Grazia Santangelo; Matteo Levantino; Eugenio Vitrano; Antonio Cupane
Ferricytochrome c encapsulated in silica hydrogels: correlation between active site dynamics and solvent structure.
Biophysical chemistry 2003;103(2):99-107.
2003: Maria Grazia Santangelo; Matteo Levantino; Eugenio Vitrano; Antonio Cupane
Ferricytochrome c encapsulated in silica hydrogels: correlation between active site dynamics and solvent structure.
Biophysical chemistry 2003;103(1):67-75.
2002: Valeria Militello; Maurizio Leone; Antonio Cupane; R Santucci; A Desideri
Local dynamic properties of the heme pocket in native and solvent-induced molten-globule-like states of cytochrome c.
Biophysical chemistry 2002;97(2-3):121-8.
2001: M C Piro; Valeria Militello; Maurizio Leone; Zygmunt Gryczynski; Stanley V Smith; William S Brinigar; Antonio Cupane; Fred Friedman; Clara Fronticelli
Heme pocket disorder in myoglobin: reversal by acid-induced soft refolding.
Biochemistry 2001;40(39):11841-50.
2000: V Sanfratello; Alberto Boffi; Antonio Cupane; Maurizio Leone
Heme symmetry, vibronic structure, and dynamics in heme proteins: ferrous nicotinate horse myoglobin and soybean leghemoglobin.
Biopolymers 2000;57(5):291-305.
1998: Michael Karavitis; Clara Fronticelli; William S Brinigar; GB Vasquez; Valeria Militello; Maurizio Leone; Antonio Cupane
Properties of human hemoglobins with increased polarity in the alpha- or beta-heme pocket. Carbonmonoxy derivatives.
The Journal of biological chemistry 1998;273(37):23740-9.
1998: Pál Ormos; S Száraz; Antonio Cupane; G U Nienhaus
Structural factors controlling ligand binding to myoglobin: a kinetic hole-burning study.
Proceedings of the National Academy of Sciences of the United States of America 1998;95(12):6762-7.
1998: Maurizio Leone; Antonio Cupane; Valeria Militello; M E Stroppolo; A Desideri
Fourier transform infrared analysis of the interaction of azide with the active site of oxidized and reduced bovine Cu,Zn superoxide dismutase.
Biochemistry 1998;37(13):4459-64.
1997: Antonio Cupane; Maurizio Leone; Valeria Militello; Fred Friedman; Aditya Koley; GB Vasquez; William S Brinigar; Michael Karavitis; Clara Fronticelli
Modification of alpha-chain or beta-chain heme pocket polarity by Val(E11) --> thr substitution has different effects on the steric, dynamic, and functional properties of human recombinant hemoglobin. Deoxy derivatives.
The Journal of biological chemistry 1997;272(42):26271-8.
1997: Antonio Cupane; C Bologna; O Rizzo; Eugenio Vitrano; Lorenzo Cordone
Local dynamics of DNA probed with optical absorption spectroscopy of bound ethidium bromide.
Biophysical journal 1997;73(2):959-65.
1996: Antonio Cupane; Eugenio Vitrano; Pál Ormos; G Ulrich Nienhaus
Heme geometry in the 10 K photoproduct from sperm whale carbonmonoxymyoglobin.
Biophysical chemistry 1996;60(3):111-7.
1996: B Melchers; Ernst-Walter Knapp; Fritz G Parak; Lorenzo Cordone; Antonio Cupane; Maurizio Leone
Structural fluctuations of myoglobin from normal-modes, Mössbauer, Raman, and absorption spectroscopy.
Biophysical journal 1996;70(5):2092-9.
1996: Maurizio Leone; Antonio Cupane; Lorenzo Cordone
Low temperature optical spectroscopy of low-spin ferric hemeproteins.
European biophysics journal : EBJ 1996;24(3):117-24.
1995: Antonio Cupane; Maurizio Leone; Valeria Militello; Maria Elena Stroppolo; Fabio Polticelli; Alessandro Desideri
Low-temperature optical spectroscopy of cobalt in Cu,Co superoxide dismutase: a structural dynamics study of the solvent-unaccessible metal site.
Biochemistry 1995;34(50):16313-9.
1995: Valeria Militello; Antonio Cupane; Maurizio Leone; William S Brinigar; A-Lien Lu-Chang; Clara Fronticelli
Dynamic properties of some beta-chain mutant hemoglobins.
Proteins 1995;22(1):12-9.
1995: Antonio Cupane; Maurizio Leone; Eugenio Vitrano; Lorenzo Cordone
Low temperature optical absorption spectroscopy: an approach to the study of stereodynamic properties of hemeproteins.
European biophysics journal : EBJ 1995;23(6):385-98.
1994: Antonio Cupane; Maurizio Leone; Valeria Militello; Maria Elena Stroppolo; Fabio Polticelli; Alessandro Desideri
Low-temperature optical spectroscopy of native and azide-reacted bovine Cu,Zn superoxide dismutase. A structural dynamics study.
Biochemistry 1994;33(50):15103-9.
1994: Alberto Boffi; Daniela Verzili; Emilia Chiancone; Maurizio Leone; Antonio Cupane; Valeria Militello; Eugenio Vitrano; Lorenzo Cordone; W Yu; E E Di Iorio
Stereodynamic properties of the cooperative homodimeric Scapharca inaequivalvis hemoglobin studied through optical absorption spectroscopy and ligand rebinding kinetics.
Biophysical journal 1994;67(4):1713-23.
1994: Maurizio Leone; Antonio Cupane; Valeria Militello; Lorenzo Cordone
Thermal broadening of the Soret band in heme complexes and in heme-proteins: role of iron dynamics.
European biophysics journal : EBJ 1994;23(5):349-52.
1993: Antonio Cupane; Maurizio Leone; Eugenio Vitrano; Lorenzo Cordone; U R Hiltpold; Kaspar Winterhalter; W Yu; E E Di Iorio
Structure-dynamics-function relationships in Asian elephant (Elephas maximus) myoglobin. An optical spectroscopy and flash photolysis study on functionally important motions.
Biophysical journal 1993;65(6):2461-72.
1993: Antonio Cupane; Maurizio Leone; Eugenio Vitrano
Protein dynamics: conformational disorder, vibrational coupling and anharmonicity in deoxy-hemoglobin and myoglobin.
European biophysics journal : EBJ 1993;21(6):385-91.
1992: Lorenzo Cordone; Antonio Cupane; Maurizio Leone; Valeria Militello; Eugenio Vitrano
Oxygenation of partially oxidized human hemoglobin.
Biophysical journal 1992;63(6):1678-82.
1992: A Di Pace; Antonio Cupane; Maurizio Leone; Eugenio Vitrano; Lorenzo Cordone
Protein dynamics. Vibrational coupling, spectral broadening mechanisms, and anharmonicity effects in carbonmonoxy heme proteins studied by the temperature dependence of the Soret band lineshape.
Biophysical journal 1992;63(2):475-84.
1992: Maurizio Leone; Antonio Cupane; Eugenio Vitrano; Lorenzo Cordone
Strong vibronic coupling in heme proteins.
Biophysical chemistry 1992;42(2):111-5.
1991: E E Di Iorio; U R Hiltpold; D Filipovic; Kaspar Winterhalter; E Gratton; Eugenio Vitrano; Antonio Cupane; Maurizio Leone; Lorenzo Cordone
Protein dynamics. Comparative investigation on heme-proteins with different physiological roles.
Biophysical journal 1991;59(3):742-54.
1991: Valeria Militello; Eugenio Vitrano; Antonio Cupane
The effect of organic cosolvents on the oxygen affinity of fetal hemoglobin. Relevance of protein-solvent interactions to the functional properties.
Biophysical chemistry 1991;39(2):161-9.
1990: Lorenzo Cordone; Antonio Cupane; Maurizio Leone; Valeria Militello; Eugenio Vitrano
Oxygen binding to partially oxidized hemoglobin. Analysis in terms of an allosteric model.
Biophysical chemistry 1990;37(1-3):171-81.
1990: Lorenzo Cordone; Antonio Cupane; Maurizio Leone; Eugenio Vitrano
Thermal behavior of the 760-nm absorption band in photodissociated sperm whale carbonmonoxymyoglobin at cryogenic temperature: dependence on external medium.
Biopolymers 1990;29(3):639-43.
1988: Antonio Cupane; Maurizio Leone; Eugenio Vitrano; Lorenzo Cordone
Structural and dynamic properties of the heme pocket in myoglobin probed by optical spectroscopy.
Biopolymers 1988;27(12):1977-97.
1988: Lorenzo Cordone; Antonio Cupane; Maurizio Leone; Eugenio Vitrano; donatella bulone
Interaction between external medium and haem pocket in myoglobin probed by low-temperature optical spectroscopy.
Journal of molecular biology 1988;199(1):213-8.
1987: Maurizio Leone; Antonio Cupane; Eugenio Vitrano; Lorenzo Cordone
Dynamic properties of oxy- and carbonmonoxyhemoglobin probed by optical spectroscopy in the temperature range of 300-20 K.
Biopolymers 1987;26(10):1769-79.
1986: Antonio Cupane; Eugenio Vitrano
The interaction of sodium maleate with human haemoglobin.
Biochimica et biophysica acta 1986;873(1):1-5.
1986: Lorenzo Cordone; Antonio Cupane; Maurizio Leone; Eugenio Vitrano
Optical absorption spectra of deoxy- and oxyhemoglobin in the temperature range 300-20 K. Relation with protein dynamics.
Biophysical chemistry 1986;24(3):259-75.
1986: Lorenzo Cordone; Antonio Cupane; Eugenio Vitrano
Effects of organic co-solvents on the oxygen equilibrium of N-ethylmaleimide-treated human haemoglobin.
Journal of molecular biology 1986;189(2):353-9.
1986: Antonio Cupane; Eugenio Vitrano; Lorenzo Cordone
Effect of organic co-solvents on the dimer/tetramer equilibrium of human haemoglobin.
Journal of molecular biology 1986;189(2):343-51.
1984: Eugenio Vitrano; Antonio Cupane; Lorenzo Cordone
Oxygen affinity of bovine haemoglobin. Relevance of electrostatic and hydrophobic interactions.
Journal of molecular biology 1984;180(4):1157-71.
1983: Lorenzo Cordone; Antonio Cupane; S L Fornili
Conformational and functional properties of hemoglobin in perturbed solvent: kinetics of O2 release.
Biopolymers 1983;22(7):1677-96.
1983: donatella bulone; Antonio Cupane; Lorenzo Cordone
Conformational and functional properties of hemoglobin in water-organic cosolvent mixtures: effect of ethylene glycol and glycerol on oxygen affinity.
Biopolymers 1983;22(1):119-23.
1982: Antonio Cupane; D Giacomazza; Lorenzo Cordone
Kinetics of thermal denaturation of met-hemoglobin in perturbed solvent: relevance of bulk-electrostatic and hydrophobic interactions.
Biopolymers 1982;21(6):1081-92.
1981: Lorenzo Cordone; Antonio Cupane
Effects of some organic cosolvents on the functional properties of hemoglobin: kinetics of O2 displacement by CO.
Biopolymers 1981;20(10):2137-42.
1981: Lorenzo Cordone; Antonio Cupane; PIER LUIGI SAN BIAGIO; Eugenio Vitrano
Temperature dependence of the effects of some monohydric alcohols on the oxygen affinity of hemoglobin: determination and analysis of thermodynamic parameters.
Biopolymers 1981;20(1):53-63.
1981: Lorenzo Cordone; Antonio Cupane; PIER LUIGI SAN BIAGIO; Eugenio Vitrano
Effect of some organic cosolvents on the reaction of hemoglobin with oxygen.
Biopolymers 1981;20(1):39-51.
1980: Antonio Cupane; Eugenio Vitrano; P L San Biago; F Madonia; MU Palma
Thermal stability of poly(A) and poly(U) complexes in H2O and D2O: isotopic effects on critical temperatures and transition widths.
Nucleic acids research 1980;8(18):4283-303.