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Antonio De Lacey

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Moustafa Malki; F Javier Palomares; Cristina Vaz-Domínguez; Marisela Velez; Ricardo Amils; Renaud Caillard; Santiago Casado; Angel Cuesta; Antonio L De Lacey; Víctor M Fernández; José A Martín Gago; María Francisca López; David Olea
Physicochemical Characterization of Acidiphilium sp. Biofilms.
Oscar Gutiérrez-Sanz; Marta C Marques; Inês A C Pereira; Claudio M Soares; Carla S A Baltazar; Víctor M Fernández; Antonio L De Lacey
Influence of the protein structure surrounding the active site on the catalytic activity of [NiFeSe] hydrogenases.
Diana M Mate; Marcos Pita; Sergey Shleev; Antonio L De Lacey; Magnus Falk; David Gonzalez-Perez; Roman Kittl; Roland Ludwig; Miguel Alcalde
Blood tolerant laccase by directed evolution.

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All Publications

2013: Moustafa Malki; F Javier Palomares; Cristina Vaz-Domínguez; Marisela Velez; Ricardo Amils; Renaud Caillard; Santiago Casado; Angel Cuesta; Antonio L De Lacey; Víctor M Fernández; José A Martín Gago; María Francisca López; David Olea
Physicochemical Characterization of Acidiphilium sp. Biofilms.
Chemphyschem : a European journal of chemical physics and physical chemistry 2013;14(6):1237-44.
2013: Oscar Gutiérrez-Sanz; Marta C Marques; Inês A C Pereira; Claudio M Soares; Carla S A Baltazar; Víctor M Fernández; Antonio L De Lacey
Influence of the protein structure surrounding the active site on the catalytic activity of [NiFeSe] hydrogenases.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2013;18(4):419-27.
2013: Diana M Mate; Marcos Pita; Sergey Shleev; Antonio L De Lacey; Magnus Falk; David Gonzalez-Perez; Roman Kittl; Roland Ludwig; Miguel Alcalde
Blood tolerant laccase by directed evolution.
Chemistry & biology 2013;20(2):223-31.
2013: Abbas Abou Hamdan; Carole Baffert; Bénédicte Burlat; Antonio L De Lacey; Bruno Guigliarelli; Oscar Gutiérrez-Sanz; Christophe Léger; Pierre-Pol Liebgott; marc rousset; Sébastien Dementin
O2-independent formation of the inactive states of NiFe hydrogenase.
Nature chemical biology 2013;9(1):15-7.
2012: Abbas Abou Hamdan; Antonio L De Lacey; Sébastien Dementin; Vincent Fourmond; Oscar Gutiérrez-Sanz; Pascale Infossi; Pierre-Pol Liebgott; marc rousset; Christophe Léger
Relation between anaerobic inactivation and oxygen tolerance in a large series of NiFe hydrogenase mutants.
Proceedings of the National Academy of Sciences of the United States of America 2012;109(49):19916-21.
2012: Cristina Gutiérrez-Sánchez; Marcos Pita; Sergey Shleev; Cristina Vaz-Domínguez; Antonio L De Lacey
Gold nanoparticles as electronic bridges for laccase-based biocathodes.
Journal of the American Chemical Society 2012;134(41):17212-20.
2012: Abbas Abou Hamdan; Patrick Bertrand; Laurent Cournac; Antonio L De Lacey; Sébastien Dementin; Oscar Gutierrez-Sanz; Pierre-Pol Liebgott; Pierre Richaud; marc rousset; Christophe Léger
Understanding and tuning the catalytic bias of hydrogenase.
Journal of the American Chemical Society 2012;134(20):8368-71.
2011: Johannes Fritsch; Holger Dau; Antonio L De Lacey; Bärbel Friedrich; Oliver Lenz; Simone Löscher; Marcus Ludwig; Oliver Sanganas; Elisabeth Siebert; Matthias Stein; Ingo Zebger; Michael Haumann
[NiFe] and [FeS] cofactors in the membrane-bound hydrogenase of Ralstonia eutropha investigated by X-ray absorption spectroscopy: insights into O(2)-tolerant H(2) cleavage.
Biochemistry 2011;50(26):5858-69.
2011: Juan García-Muñoz; Ricardo Amils; Antonio L De Lacey; Víctor M Fernández; Moustafa Malki
Electricity generation by microorganisms in the sediment-water interface of an extreme acidic microcosm.
International microbiology : the official journal of the Spanish Society for Microbiology 2011;14(2):73-81.
2011: Cristina Gutiérrez-Sánchez; Marta Marques; David Olea; Inês A C Pereira; Marisela Vélez; Victor M Fernández; Antonio L De Lacey
Oriented immobilization of a membrane-bound hydrogenase onto an electrode for direct electron transfer.
Langmuir : the ACS journal of surfaces and colloids 2011;27(10):6449-57.
2011: Pierre-Pol Liebgott; Antonio L De Lacey; Bénédicte Burlat; Laurent Cournac; Pierre Richaud; Myriam Brugna; Victor M Fernandez; Bruno Guigliarelli; marc rousset; Christophe Léger; Sébastien Dementin
Original design of an oxygen-tolerant [NiFe] hydrogenase: major effect of a valine-to-cysteine mutation near the active site.
Journal of the American Chemical Society 2011;133(4):986-97.
2010: Cristina Gutiérrez-Sánchez; Olaf Rüdiger; Víctor M Fernández; Antonio L De Lacey; Marta Marques; Inês A C Pereira
Interaction of the active site of the Ni-Fe-Se hydrogenase from Desulfovibrio vulgaris Hildenborough with carbon monoxide and oxygen inhibitors.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2010;15(8):1285-92.
2010: Sofía Carbajosa; Moustafá Malki; Renaud Caillard; María F Lopez; F Javier Palomares; José A Martín-Gago; Nuria Rodríguez; Ricardo Amils; Victor M Fernández; Antonio L De Lacey
Electrochemical growth of Acidithiobacillus ferrooxidans on a graphite electrode for obtaining a biocathode for direct electrocatalytic reduction of oxygen.
Biosensors & bioelectronics 2010;26(2):877-80.
2010: Anton Ressine; Cristina Vaz-Domínguez; Victor M Fernandez; Antonio L De Lacey; Thomas Laurell; Tautgirdas Ruzgas; Sergey Shleev
Bioelectrochemical studies of azurin and laccase confined in three-dimensional chips based on gold-modified nano-/microstructured silicon.
Biosensors & bioelectronics 2010;25(5):1001-7.
2009: Karolina Haberska; Cristina Vaz-Domínguez; Antonio L De Lacey; Marius Dagys; Curt T Reimann; Sergey Shleev
Direct electron transfer reactions between human ceruloplasmin and electrodes.
Bioelectrochemistry (Amsterdam, Netherlands) 2009;76(1-2):34-41.
2009: Sébastien Dementin; Fanny Leroux; Laurent Cournac; Antonio L De Lacey; Anne Volbeda; Christophe Léger; Bénédicte Burlat; Nicolas Martinez; Stéphanie Champ; Lydie Martin; Oliver Sanganas; Michael Haumann; Víctor M Fernández; Bruno Guigliarelli; Juan C Fontecilla-Camps; marc rousset
Introduction of methionines in the gas channel makes [NiFe] hydrogenase aero-tolerant.
Journal of the American Chemical Society 2009;131(29):10156-64.
2008: Cristina Vaz-Dominguez; Susana Campuzano; Olaf Rüdiger; Marcos Pita; Marina Gorbacheva; Sergey Shleev; Victor M Fernandez; Antonio L De Lacey
Laccase electrode for direct electrocatalytic reduction of O2 to H2O with high-operational stability and resistance to chloride inhibition.
Biosensors & bioelectronics 2008;24(4):531-7.
2008: Antonio L De Lacey; Cristina Gutiérrez-Sánchez; Víctor M Fernández; Isabel Pacheco; Inês A C Pereira
FTIR spectroelectrochemical characterization of the Ni-Fe-Se hydrogenase from Desulfovibrio vulgaris Hildenborough.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2008;13(8):1315-20.
2008: Vasile Coman; Cristina Vaz-Domínguez; Roland Ludwig; Wolfgang Harreither; Dietmar Haltrich; Antonio L De Lacey; Tautgirdas Ruzgas; Lo Gorton; Sergey Shleev
A membrane-, mediator-, cofactor-less glucose/oxygen biofuel cell.
Physical chemistry chemical physics : PCCP 2008;10(40):6093-6.
2008: Manuel Ferrer; Olga V Golyshina; Ana Beloqui; Lars H Böttger; José M Andreu; Julio Polaina; Antonio L De Lacey; Alfred X Trautwein; Kenneth N Timmis; Peter N Golyshin
A purple acidophilic di-ferric DNA ligase from Ferroplasma.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(26):8878-83.
2008: Moustafa Malki; Antonio L De Lacey; Nuria Rodríguez; Ricardo Amils; Victor M Fernandez
Preferential use of an anode as an electron acceptor by an acidophilic bacterium in the presence of oxygen.
Applied and environmental microbiology 2008;74(14):4472-6.
2007: Antonio L De Lacey; Victor M Fernandez; marc rousset; Richard Cammack
Activation and inactivation of hydrogenase function and the catalytic cycle: spectroelectrochemical studies.
Chemical reviews 2007;107(10):4304-30.
2007: Alejandro Pardo; Antonio L De Lacey; Víctor M Fernández; Yubo Fan; Michael B Hall
Characterization of the active site of catalytically inactive forms of [NiFe] hydrogenases by density functional theory.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2007;12(6):751-60.
2007: M Asunción Alonso Lomillo; Olaf Rüdiger; Angel Maroto-Valiente; Marisela Velez; Inmaculada Rodríguez-Ramos; F Javier Muñoz; Víctor M Fernández; Antonio L De Lacey
Hydrogenase-coated carbon nanotubes for efficient H2 oxidation.
Nano letters 2007;7(6):1603-8.
2007: Antje Gebler; Tanja Burgdorf; Antonio L De Lacey; Olaf Rüdiger; Arturo Martinez-Arias; Oliver Lenz; Bärbel Friedrich
Impact of alterations near the [NiFe] active site on the function of the H(2) sensor from Ralstonia eutropha.
The FEBS journal 2007;274(1):74-85.
2006: Sébastien Dementin; Valérie Belle; Patrick Bertrand; Bruno Guigliarelli; Géraldine Adryanczyk-Perrier; Antonio L De Lacey; Victor M Fernandez; marc rousset; Christophe Léger
Changing the ligation of the distal [4Fe4S] cluster in NiFe hydrogenase impairs inter- and intramolecular electron transfers.
Journal of the American Chemical Society 2006;128(15):5209-18.
2006: Alejandro Pardo; Antonio L De Lacey; Víctor M Fernández; Hua-Jun Fan; Yubo Fan; Michael B Hall
Density functional study of the catalytic cycle of nickel-iron [NiFe] hydrogenases and the involvement of high-spin nickel(II).
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2006;11(3):286-306.
2006: Eddy van der Linden; Tanja Burgdorf; Antonio L De Lacey; Thorsten Buhrke; Marcel Scholte; Victor M Fernandez; Bärbel Friedrich; Simon P J Albracht
An improved purification procedure for the soluble [NiFe]-hydrogenase of Ralstonia eutropha: new insights into its (in)stability and spectroscopic properties.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2006;11(2):247-60.
2006: Winfried Roseboom; Antonio L De Lacey; Victor M Fernandez; E Claude Hatchikian; Simon P J Albracht
The active site of the [FeFe]-hydrogenase from Desulfovibrio desulfuricans. II. Redox properties, light sensitivity and CO-ligand exchange as observed by infrared spectroscopy.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2006;11(1):102-18.
2005: Olaf Rüdiger; Jose M Abad; E Claude Hatchikian; Victor M Fernandez; Antonio L De Lacey
Oriented immobilization of Desulfovibrio gigas hydrogenase onto carbon electrodes by covalent bonds for nonmediated oxidation of H2.
Journal of the American Chemical Society 2005;127(46):16008-9.
2004: Boris Bleijlevens; Fleur A van Broekhuizen; Antonio L De Lacey; Winfried Roseboom; Victor M Fernandez; Simon P J Albracht
The activation of the [NiFe]-hydrogenase from Allochromatium vinosum. An infrared spectro-electrochemical study.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2004;9(6):743-52.
2004: Antonio L De Lacey; Alejandro Pardo; Víctor M Fernández; Sébastien Dementin; Géraldine Adryanczyk-Perrier; E Claude Hatchikian; marc rousset
FTIR spectroelectrochemical study of the activation and inactivation processes of [NiFe] hydrogenases: effects of solvent isotope replacement and site-directed mutagenesis.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2004;9(5):636-42.
2004: Sébastien Dementin; Bénédicte Burlat; Antonio L De Lacey; Alejandro Pardo; Géraldine Adryanczyk-Perrier; Bruno Guigliarelli; Victor M Fernandez; marc rousset
A glutamate is the essential proton transfer gate during the catalytic cycle of the [NiFe] hydrogenase.
The Journal of biological chemistry 2004;279(11):10508-13.
2002: Tanja Burgdorf; Antonio L De Lacey; Bärbel Friedrich
Functional analysis by site-directed mutagenesis of the NAD(+)-reducing hydrogenase from Ralstonia eutropha.
Journal of bacteriology 2002;184(22):6280-8.
2002: Christian Stadler; Antonio L De Lacey; Yael Montet; Anne Volbeda; Juan C Fontecilla-Camps; Jose C Conesa; Víctor M Fernández
Density functional calculations for modeling the active site of nickel-iron hydrogenases. 2. Predictions for the unready and ready States and the corresponding activation processes.
Inorganic chemistry 2002;41(17):4424-34.
2002: Christian Stadler; Antonio L De Lacey; Belén Hernández; Víctor M Fernández; Jose C Conesa
Density functional calculations for modeling the oxidized states of the active site of nickel-iron hydrogenases. 1. Verification of the method with paramagnetic Ni and Co complexes.
Inorganic chemistry 2002;41(17):4417-23.
2002: Antonio L De Lacey; Christian Stadler; Victor M Fernandez; E Claude Hatchikian; Hua-Jun Fan; Shuhua Li; Michael B Hall
IR spectroelectrochemical study of the binding of carbon monoxide to the active site of Desulfovibrio fructosovorans Ni-Fe hydrogenase.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2002;7(3):318-26.
2001: Michael Bernhard; Thorsten Buhrke; Boris Bleijlevens; Antonio L De Lacey; Victor M Fernandez; Simon P J Albracht; Bärbel Friedrich
The H2 sensor of Ralstonia eutropha. Biochemical characteristics, spectroscopic properties, and its interaction with a histidine protein kinase.
The Journal of biological chemistry 2001;276(19):15592-7.
2001: Yvain Nicolet; Antonio L De Lacey; Xavier Vernède; Victor M Fernandez; E Claude Hatchikian; Juan C Fontecilla-Camps
Crystallographic and FTIR spectroscopic evidence of changes in Fe coordination upon reduction of the active site of the Fe-only hydrogenase from Desulfovibrio desulfuricans.
Journal of the American Chemical Society 2001;123(8):1596-601.
2000: Antonio L De Lacey; E Santamaria; E Claude Hatchikian; Victor M Fernandez
Kinetic characterization of Desulfovibrio gigas hydrogenase upon selective chemical modification of amino acid groups as a tool for structure-function relationships.
Biochimica et biophysica acta 2000;1481(2):371-80.