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Scott Denmark

This is a preview profile on BiomedExperts - the first literature-based scientific social network. It brings the right researchers together and allows them to collaborate online. Collexis and Dell provide the BiomedExperts network of +1.5 Million pre-calculated profiles free of charge to researchers worldwide.

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Co-Publications
Name
6
Fu, Jiping
6
Sweis, Ramzi
5
Beutner, Gregory
5
Heemstra, John
4
Montgomery, Justin
4
Baird, John
4
Fan, Yu
3
Fujimori, Shinji
3
Pham, Son
3
Kallemeyn, Jeffrey
3
Tymonko, Steven
3
Wynn, Thomas
3
Yang, Shyh-Ming
2
Butler, Christopher
2
Stavenger, Robert

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Publications

TOP 3
Denmark Scott E; Vogler Thomas
Synthesis and reactivity of enantiomerically enriched thiiranium ions.
Denmark Scott E; Liu Jack Hung-Chang; Muhuhi Joseck M
Total syntheses of isodomoic acids G and H.
Denmark Scott E; Eklov Brian M; Yao Peter J; Eastgate Martin D
On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR.

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All Publications

2009: Denmark Scott E; Vogler Thomas
Synthesis and reactivity of enantiomerically enriched thiiranium ions.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(43):11737-45.
2009: Denmark Scott E; Liu Jack Hung-Chang; Muhuhi Joseck M
Total syntheses of isodomoic acids G and H.
Journal of the American Chemical Society 2009;131(40):14188-9.
2009: Denmark Scott E; Eklov Brian M; Yao Peter J; Eastgate Martin D
On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR.
Journal of the American Chemical Society 2009;131(33):11770-87.
2009: Denmark Scott E
The interplay of invention, discovery, development, and application in organic synthetic methodology: a case study.
The Journal of organic chemistry 2009;74(8):2915-27.
2009: Denmark Scott E; Collins William R; Cullen Matthew D
Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes.
Journal of the American Chemical Society 2009;131(10):3490-2.
2009: Denmark Scott E; Smith Russell C; Chang Wen-Tau T; Muhuhi Joseck M
Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides.
Journal of the American Chemical Society 2009;131(8):3104-18.
2009: Denmark Scott E; Nguyen Son T
Catalytic, nucleophilic allylation of aldehydes with allyl acetate.
Organic letters 2009;11(3):781-4.
2008: Denmark Scott E; Werner Nathan S
Cross-coupling of aromatic bromides with allylic silanolate salts.
Journal of the American Chemical Society 2008;130(48):16382-93.
2008: Denmark Scott E; Ares Jeffrey J
Stereoselective alkylations of chiral nitro imine and nitro hydrazone dianions. Synthesis of enantiomerically enriched 3-substituted 1-nitrocyclohexenes.
The Journal of organic chemistry 2008;73(24):9647-56.
2008: Denmark Scott E; Regens Christopher S
Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods.
Accounts of chemical research 2008;41(11):1486-99.
2008: Denmark Scott E; Chung Won-Jin
Lewis base activation of Lewis acids: catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes.
The Journal of organic chemistry 2008;73(12):4582-95.
2008: Denmark Scott E; Butler Christopher R
Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols.
Journal of the American Chemical Society 2008;130(11):3690-704.
2008: Denmark Scott E; Baird John D; Regens Christopher S
Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates.
The Journal of organic chemistry 2008;73(4):1440-55.
2008: Denmark Scott E; Lee Wheeseong
Investigations into transition-state geometry in the Mukaiyama directed aldol reaction.
Chemistry, an Asian journal 2008;3(2):327-41.
2008: Denmark Scott E; Beutner Gregory L
Lewis base catalysis in organic synthesis.
Angewandte Chemie (International ed. in English) 2008;47(9):1560-638.
2008: Denmark Scott E; Chung Won-jin
Lewis base activation of Lewis acids: catalytic enantioselective glycolate aldol reactions.
Angewandte Chemie (International ed. in English) 2008;47(10):1890-2.
2008: Denmark Scott E; Eklov Brian M
Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures.
Chemistry (Weinheim an der Bergstrasse, Germany) 2008;14(1):234-9.
2007: Denmark Scott E; Ahmad Moballigh
Carbonylative ring opening of terminal epoxides at atmospheric pressure.
The Journal of organic chemistry 2007;72(25):9630-4.
2007: Denmark Scott E; Wilson Tyler W; Burk Matthew T; Heemstra John R
Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes.
Journal of the American Chemical Society 2007;129(48):14864-5.
2007: Denmark Scott E; Collins William R
Lewis base activation of Lewis acids: development of a Lewis base catalyzed selenolactonization.
Organic letters 2007;9(19):3801-4.
2007: Denmark Scott E; Xie Min
Lewis acid-promoted conjugate addition of dienol silyl ethers to nitroalkenes: synthesis of 3-substituted azepanes.
The Journal of organic chemistry 2007;72(18):7050-3.
2007: Denmark Scott E; Heemstra John R
Lewis base activation of Lewis acids: catalytic, enantioselective vinylogous aldol addition reactions.
The Journal of organic chemistry 2007;72(15):5668-88.
2007: Denmark Scott E; Liu Jack Hung-Chang
Sequential silylcarbocyclization/silicon-based cross-coupling reactions.
Journal of the American Chemical Society 2007;129(12):3737-44.
2007: Denmark Scott E; Regens Christopher S; Kobayashi Tetsuya
Total synthesis of papulacandin D.
Journal of the American Chemical Society 2007;129(10):2774-6.
2006: Denmark Scott E; Kallemeyn Jeffrey M
Stereospecific palladium-catalyzed cross-coupling of (E)- and (Z)-alkenylsilanolates with aryl chlorides.
Journal of the American Chemical Society 2006;128(50):15958-9.
2006: Denmark Scott E; Neuville Luc; Christy Matthew E L; Tymonko Steven A
A qualitative examination of the effects of silicon substituents on the efficiency of cross-coupling reactions.
The Journal of organic chemistry 2006;71(22):8500-9.
2006: Denmark Scott E; Edwards Michael G
On the mechanism of the selenolactonization reaction with selenenyl halides.
The Journal of organic chemistry 2006;71(19):7293-306.
2006: Denmark Scott E
Organic chemistry: catalysts break symmetry.
Nature 2006;443(7107):40-1.
2006: Denmark Scott E; Montgomery Justin I; Kramps Laurenz A
Synthesis, X-ray crystallography, and computational analysis of 1-azafenestranes.
Journal of the American Chemical Society 2006;128(35):11620-30.
2006: Denmark Scott E; Montgomery Justin I
A general synthesis of N-vinyl nitrones.
The Journal of organic chemistry 2006;71(16):6211-20.
2006: Denmark Scott E; Baird John D
Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions.
Chemistry (Weinheim an der Bergstrasse, Germany) 2006;12(19):4954-63.
2006: Denmark Scott E; Chung Won-Jin
Lewis base catalyzed addition of trimethylsilyl cyanide to aldehydes.
The Journal of organic chemistry 2006;71(10):4002-5.
2006: Denmark Scott E; Pham Son M; Stavenger Robert A; Su Xiping; Wong Ken-Tsung; Nishigaichi Yutaka
Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects.
The Journal of organic chemistry 2006;71(10):3904-22.
2006: Denmark Scott E; Venkatraman Srikanth
On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis.
The Journal of organic chemistry 2006;71(4):1668-76.
2006: Denmark Scott E; Fu Jiping; Lawler Michael J
Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides.
The Journal of organic chemistry 2006;71(4):1523-36.
2006: Denmark Scott E; Fu Jiping; Coe Diane M; Su Xiping; Pratt Norman E; Griedel Brian D
Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides.
The Journal of organic chemistry 2006;71(4):1513-22.
2006: Denmark Scott E; Baird John D
Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides.
Organic letters 2006;8(4):793-5.
2006: Denmark Scott E; Heemstra John R
Lewis base activation of Lewis acids. Vinylogous aldol addition reactions of conjugated N,O-silyl ketene acetals to aldehydes.
Journal of the American Chemical Society 2006;128(4):1038-9.
2006: Denmark Scott E; Baiazitov Ramil Y
Tandem double-intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. Studies toward a total synthesis of daphnilactone B: piperidine ring construction.
The Journal of organic chemistry 2006;71(2):593-605.
2006: Denmark Scott E; Butler Christopher R
Vinylation of aryl bromides using an inexpensive vinylpolysiloxane.
Organic letters 2006;8(1):63-6.
2005: Denmark Scott E; Fujimori Shinji; Pham Son M
Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates and silyl enol ethers.
The Journal of organic chemistry 2005;70(26):10823-40.
2005: Denmark Scott E; Bui Tommy
Mechanistic insights into the chiral phosphoramide-catalyzed, enantioselective crossed-aldol reactions of aldehydes.
The Journal of organic chemistry 2005;70(25):10393-9.
2005: Denmark Scott E; Baiazitov Ramil Y
Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters.
Organic letters 2005;7(25):5617-20.
2005: Denmark Scott E; Bui Tommy
Lewis base catalyzed enantioselective aldol addition of acetaldehyde-derived silyl enol ether to aldehydes.
The Journal of organic chemistry 2005;70(24):10190-3.
2005: Denmark Scott E; Fan Yu
Catalytic, enantioselective alpha-additions of isocyanides: Lewis base catalyzed Passerini-type reactions.
The Journal of organic chemistry 2005;70(24):9667-76.
2005: Denmark Scott E; Heemstra John R; Beutner Gregory L
Catalytic, enantioselective, vinylogous aldol reactions.
Angewandte Chemie (International ed. in English) 2005;44(30):4682-98.
2005: Denmark Scott E; Fujimori Shinji
Total synthesis of RK-397.
Journal of the American Chemical Society 2005;127(25):8971-3.
2005: Denmark Scott E; Fan Yu; Eastgate Martin D
Lewis base catalyzed, enantioselective aldol addition of methyl trichlorosilyl ketene acetal to ketones.
The Journal of organic chemistry 2005;70(13):5235-48.
2005: Denmark Scott E; Tymonko Steven A
Sequential cross-coupling of 1,4-bissilylbutadienes: synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes.
Journal of the American Chemical Society 2005;127(22):8004-5.
2005: Denmark Scott E; Montgomery Justin I
Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-azafenestrane with discovery of an unexpected dyotropic rearrangement.
Angewandte Chemie (International ed. in English) 2005;44(24):3732-6.
2005: Denmark Scott E; Kallemeyn Jeffrey M
Synthesis of 3,4,5-trisubstituted isoxazoles via sequential [3 + 2] cycloaddition/silicon-based cross-coupling reactions.
The Journal of organic chemistry 2005;70(7):2839-42.
2005: Denmark Scott E; Beutner Gregory L; Wynn Thomas; Eastgate Martin D
Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes.
Journal of the American Chemical Society 2005;127(11):3774-89.
2004: Denmark Scott E; Yang Shyh-Ming
Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction.
Journal of the American Chemical Society 2004;126(39):12432-40.
2004: Denmark Scott E; Baird John D
Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides.
Organic letters 2004;6(20):3649-52.
2004: Denmark Scott E; Sweis Ramzi F
Cross-coupling reactions of alkenylsilanolates. Investigation of the mechanism and identification of key intermediates through kinetic analysis.
Journal of the American Chemical Society 2004;126(15):4876-82.
2004: Denmark Scott E; Sweis Ramzi F; Wehrli Daniel
Fluoride-promoted cross-coupling reactions of alkenylsilanols. Elucidation of the mechanism through spectroscopic and kinetic analysis.
Journal of the American Chemical Society 2004;126(15):4865-75.
2004: Denmark Scott E; Bui Tommy
Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(15):5439-44.
2003: Tishkov Alexander A; Lesiv Alexey V; Khomutova Yulya A; Strelenko Yury A; Nesterov Ivan D; Antipin Michael Yu; Ioffe Sema L; Denmark Scott E
2-silyloxy-1,2-oxazines, a new type of acetals of conjugated nitroso alkenes.
The Journal of organic chemistry 2003;68(24):9477-80.
2003: Denmark Scott E; Tymonko Steven A
Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate.
The Journal of organic chemistry 2003;68(23):9151-4.
2003: Denmark Scott E; Gomez Laurent
Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. The fused/bridged mode.
The Journal of organic chemistry 2003;68(21):8015-24.
2003: Denmark Scott E; Kallemeyn Jeffrey M
Palladium-catalyzed silylation of aryl bromides leading to functionalized aryldimethylsilanols.
Organic letters 2003;5(19):3483-6.
2003: Denmark Scott E; Amishiro Nobuyoshi
Palladium-catalyzed conjugate addition of organosiloxanes to alpha,beta-unsaturated carbonyl compounds and nitroalkenes.
The Journal of organic chemistry 2003;68(18):6997-7003.
2003: Denmark Scott E; Fu Jiping
Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones.
Chemical reviews 2003;103(8):2763-94.
2003: Denmark Scott E; Fan Yu
The first catalytic, asymmetric alpha-additions of isocyanides. Lewis-base-catalyzed, enantioselective Passerini-type reactions.
Journal of the American Chemical Society 2003;125(26):7825-7.
2003: Denmark Scott E; Beutner Gregory L
Lewis base activation of Lewis acids. Vinylogous aldol reactions.
Journal of the American Chemical Society 2003;125(26):7800-1.
2003: Denmark Scott E; Kobayashi Tetsuya
Tandem intramolecular silylformylation and silicon-assisted cross-coupling reactions. synthesis of geometrically defined alpha,beta-unsaturated aldehydes.
The Journal of organic chemistry 2003;68(13):5153-9.
2003: Denmark Scott E; Pham Son M
Stereoselective aldol additions of achiral ethyl ketone-derived trichlorosilyl enolates.
The Journal of organic chemistry 2003;68(13):5045-55.
2003: Denmark Scott E; Heemstra John R
Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes.
Organic letters 2003;5(13):2303-6.
2003: Denmark Scott E; Ober Michael H
Cross-coupling reactions of arylsilanols with substituted aryl halides.
Organic letters 2003;5(8):1357-60.
2003: Denmark Scott E; Pan Weitao
Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols.
Organic letters 2003;5(7):1119-22.
2003: Denmark Scott E; Fu Jiping
Understanding the correlation of structure and selectivity in the chiral-phosphoramide-catalyzed enantioselective allylation reactions: solution and solid-state structural studies of bisphosphoramide.SnCl(4) complexes.
Journal of the American Chemical Society 2003;125(8):2208-16.
2003: Denmark Scott E; Fu Jiping
Catalytic enantioselective allylation with chiral Lewis bases.
Chemical communications (Cambridge, England) 2003;(2):167-70.
2002: Denmark Scott Eric; Sweis Ramzi Farah
Cross-coupling reactions of organosilicon compounds: new concepts and recent advances.
Chemical & pharmaceutical bulletin 2002;50(12):1531-41.
2002: Denmark Scott E; Yang Shyh-Ming
Intramolecular silicon-assisted cross-coupling: total synthesis of (+)-brasilenyne.
Journal of the American Chemical Society 2002;124(51):15196-7.
2002: Denmark Scott E; Pan Weitao
Intramolecular anti-hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted homoallylic alcohols.
Organic letters 2002;4(23):4163-6.
2002: Denmark Scott E; Wynn Thomas; Beutner Gregory L
Lewis base activation of lewis acids. Addition of silyl ketene acetals to aldehydes.
Journal of the American Chemical Society 2002;124(45):13405-7.
2002: Denmark Scott E; Kramps Laurenz A; Montgomery Justin I
Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-azafenestrane.
Angewandte Chemie (International ed. in English) 2002;41(21):4122-5.
2002: Denmark Scott E; Sweis Ramzi F
Design and implementation of new, silicon-based, cross-coupling reactions: importance of silicon-oxygen bonds.
Accounts of chemical research 2002;35(10):835-46.
2002: Denmark Scott E; Sweis Ramzi F
Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates.
Organic letters 2002;4(21):3771-4.
2002: Denmark Scott E; Fujimori Shinji
The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates.
Organic letters 2002;4(20):3477-80.
2002: Denmark Scott E; Fujimori Shinji
Diastereoselective aldol additions of chiral beta-hydroxy ethyl ketone enolates catalyzed by Lewis bases.
Organic letters 2002;4(20):3473-6.
2002: Denmark Scott E; Fu Jiping
Asymmetric construction of quaternary centers by enantioselective allylation: application to the synthesis of the serotonin antagonist LY426965.
Organic letters 2002;4(11):1951-3.
2002: Denmark Scott E; Matsuhashi Hayao
Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone.
The Journal of organic chemistry 2002;67(10):3479-86.
2002: Denmark Scott E; Fan Yu
Catalytic, enantioselective aldol additions to ketones.
Journal of the American Chemical Society 2002;124(16):4233-5.
2002: Denmark Scott E; Yang Shyh-Ming
Intramolecular silicon-assisted cross-coupling reactions: general synthesis of medium-sized rings containing a 1,3-cis-cis diene unit.
Journal of the American Chemical Society 2002;124(10):2102-3.
2002: Denmark Scott E; Dorow Roberta L
Stereospecific cleavage of carbon-phosphorus bonds: stereochemical course of the phosphinoyl curtius (Harger) reaction.
Chirality 2002;14(2-3):241-57.
2001: Denmark S E; Fu J
Catalytic, enantioselective addition of substituted allylic trichlorosilanes using a rationally-designed 2,2'-bispyrrolidine-based bisphosphoramide.
Journal of the American Chemical Society 2001;123(38):9488-9.
2001: Denmark S E; Gomez L
Tandem double intramolecular [4 + 2]/[3 + 2] cycloadditions of nitroalkenes.
Organic letters 2001;3(18):2907-10.
2001: Denmark S E; Pham S M
Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis.
Organic letters 2001;3(14):2201-4.
2001: Denmark S E; Sweis R F
Fluoride-free cross-coupling of organosilanols.
Journal of the American Chemical Society 2001;123(26):6439-40.
2001: Denmark S E; Wynn T
Lewis base activation of Lewis acids: catalytic enantioselective allylation and propargylation of aldehydes.
Journal of the American Chemical Society 2001;123(25):6199-200.
2001: Denmark S E; Cottell J J
Synthesis of (+)-1-epiaustraline.
The Journal of organic chemistry 2001;66(12):4276-84.
2001: Denmark S E; Yang S M
Sequential ring-closing metathesis and silicon-assisted cross-coupling reactions: stereocontrolled synthesis of highly substituted unsaturated alcohols.
Organic letters 2001;3(11):1749-52.
2001: Denmark S E; Wang Z
Highly stereoselective hydrocarbation of terminal alkynes via Pt-catalyzed hydrosilylation/Pd-catalyzed cross-coupling reactions.
Organic letters 2001;3(7):1073-6.
2001: Denmark S E; Pan W
Intramolecular hydrosilylation and silicon-assisted cross-coupling: an efficient route to trisubstituted homoallylic alcohols.
Organic letters 2001;3(1):61-4.
2000: Denmark S E; Stavenger R A
Asymmetric catalysis of aldol reactions with chiral lewis bases.
Accounts of chemical research 2000;33(6):432-40.
2000: Denmark S E; Herbert B
Synthesis of (-)-7-epiaustraline and (-)-1-epicastanospermine.
The Journal of organic chemistry 2000;65(10):2887-96.
2000: Denmark S E; Hurd A R
Synthesis of (+)-casuarine.
The Journal of organic chemistry 2000;65(10):2875-86.
1999: Denmark S E; Hurd A R
Synthesis of (+)-casuarine.
Organic letters 1999;1(8):1311-4.

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