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Jason Halfen

Research Profile

Chemicals & Drugs

Genes & Molecular Sequences

Molecular Structure

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Electrochemistry

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Publications

TOP 3
Aidan R McDonald; Eckard Münck; Wonwoo Nam; Michael R Bukowski; Raymond F De Hont; Erik R Farquhar; Jason A Halfen; Timothy A Jackson; Kevin D Koehntop; Mi Sook Seo; Audria Stubna; Lawrence Que
Sulfur versus iron oxidation in an iron-thiolate model complex.
Katarzyna Grubel; Katarzyna Rudzka; Atta M Arif; Katie L Klotz; Jason A Halfen; Lisa M Berreau
Synthesis, characterization, and ligand exchange reactivity of a series of first row divalent metal 3-hydroxyflavonolate complexes.
Katie L Klotz; Luke M Slominski; Miranda E Riemer; James A Phillips; Jason A Halfen
Mechanism of the iron-mediated alkene aziridination reaction: experimental and computational investigations.

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All Publications

2010: Aidan R McDonald; Eckard Münck; Wonwoo Nam; Michael R Bukowski; Raymond F De Hont; Erik R Farquhar; Jason A Halfen; Timothy A Jackson; Kevin D Koehntop; Mi Sook Seo; Audria Stubna; Lawrence Que
Sulfur versus iron oxidation in an iron-thiolate model complex.
Journal of the American Chemical Society 2010;132(48):17118-29.
2010: Katarzyna Grubel; Katarzyna Rudzka; Atta M Arif; Katie L Klotz; Jason A Halfen; Lisa M Berreau
Synthesis, characterization, and ligand exchange reactivity of a series of first row divalent metal 3-hydroxyflavonolate complexes.
Inorganic chemistry 2010;49(1):82-96.
2009: Katie L Klotz; Luke M Slominski; Miranda E Riemer; James A Phillips; Jason A Halfen
Mechanism of the iron-mediated alkene aziridination reaction: experimental and computational investigations.
Inorganic chemistry 2009;48(3):801-3.
2008: Laurie E Grove; Jason K Hallman; Joseph P Emerson; Jason A Halfen; Thomas C Brunold
Synthesis, X-ray crystallographic characterization, and electronic structure studies of a di-azide iron(III) complex: implications for the azide adducts of iron(III) superoxide dismutase.
Inorganic chemistry 2008;47(13):5762-74.
2008: Yuming Zhou; Xiaopeng Shan; Rubén Mas-Ballesté; Michael R Bukowski; Audria Stubna; Mrinmoy Chakrabarti; Luke Slominski; Jason A Halfen; Eckard Münck; Lawrence Que
Contrasting cis and trans effects on the reactivity of nonheme oxoiron(IV) complexes.
Angewandte Chemie (International ed. in English) 2008;47(10):1896-9.
2007: Chivukula V Sastri; Jimin Lee; Kyungeun Oh; Yoon Jin Lee; Junghyun Lee; Timothy A Jackson; Kallol Ray; Hajime Hirao; Woonsup Shin; Jason A Halfen; Jinheung Kim; Lawrence Que; Sason Shaik; Wonwoo Nam
Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction.
Proceedings of the National Academy of Sciences of the United States of America 2007;104(49):19181-6.
2007: Benjamin M Schmiege; Michael J Carney; Brooke L Small; Deidra L Gerlach; Jason A Halfen
Alternatives to pyridinediimine ligands: syntheses and structures of metal complexes supported by donor-modified alpha-diimine ligands.
Dalton transactions (Cambridge, England : 2003) 2007;(24):2547-62.
2007: Katie L Klotz; Luke M Slominski; Anthony V Hull; Victoria M Gottsacker; Rubén Mas-Ballesté; Lawrence Que; Jason A Halfen
Non-heme iron(II) complexes are efficient olefin aziridination catalysts.
Chemical communications (Cambridge, England) 2007;(20):2063-5.
2006: James A Phillips; Jason A Halfen; John P Wrass; Christopher C Knutson; Christopher J Cramer
Large gas-solid structural differences in complexes of haloacetonitriles with boron trifluoride.
Inorganic chemistry 2006;45(2):722-31.
2005: Michael R Bukowski; Kevin D Koehntop; Audria Stubna; Emile L Bominaar; Jason A Halfen; Eckard Münck; Wonwoo Nam; Lawrence Que
A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450.
Science (New York, N.Y.) 2005;310(5750):1000-2.
2005: James A Phillips; D J Giesen; N P Wells; Jason A Halfen; Christopher C Knutson; J P Wrass
Condensed-phase effects on the structural properties of C6H5CN-BF3 and (CH3)3CCN-BF3: IR spectra, crystallography, and computations.
The journal of physical chemistry. A 2005;109(36):8199-208.
2005: Adam T Fiedler; Heather L Halfen; Jason A Halfen; Thomas C Brunold
Synthesis, structure determination, and spectroscopic/computational characterization of a series of Fe(II)-thiolate model complexes: implications for Fe-S bonding in superoxide reductases.
Journal of the American Chemical Society 2005;127(6):1675-89.
2005: Michael R Bukowski; Heather L Halfen; Tieme A van den Berg; Jason A Halfen; Lawrence Que
Spin-state rationale for the peroxo-stabilizing role of the thiolate ligand in superoxide reductase.
Angewandte Chemie (International ed. in English) 2005;44(4):584-7.
2004: Kyle J Tubbs; Ewa Szajna; Brian Bennett; Jason A Halfen; Rex W Watkins; Atta M Arif; Lisa M Berreau
Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: structural, EPR, paramagnetic 1H NMR, and electrochemical investigations.
Dalton transactions (Cambridge, England : 2003) 2004;(16):2398-9.
2004: Olivier Horner; Jean-Marie Mouesca; Jean-Louis Oddou; Claudine Jeandey; Vincent Nivière; Tony A Mattioli; Christelle Mathé; Marc Fontecave; Pascale Maldivi; Pierre Bonville; Jason A Halfen; Jean-Marc Latour
Mössbauer characterization of an unusual high-spin side-on peroxo-Fe3+ species in the active site of superoxide reductase from Desulfoarculus Baarsii. Density functional calculations on related models.
Biochemistry 2004;43(27):8815-25.
2004: Derek C Fox; Adam T Fiedler; Heather L Halfen; Thomas C Brunold; Jason A Halfen
Electronic structure control of the nucleophilicity of transition metal-thiolate complexes: an experimental and theoretical study.
Journal of the American Chemical Society 2004;126(24):7627-38.
2004: Laurent Coue; Luciano Cuesta; Dolores Morales; Jason A Halfen; Julio Pérez; Lucía Riera; Víctor Riera; Daniel Miguel; Neil G Connelly; Supakorn Boonyuen
A neutral organometallic fluoro complex can be a good ligand.
Chemistry (Weinheim an der Bergstrasse, Germany) 2004;10(8):1906-12.
2003: Jason A Halfen; Victor G Young
Efficient preparation of 1,4,8-trimethylcyclam and its conversion into a thioalkyl-pendant pentadentate chelate.
Chemical communications (Cambridge, England) 2003;(23):2894-5.
2003: Magdalena M Makowska-Grzyska; Ewa Szajna; Crystal Shipley; Atta M Arif; Michael H Mitchell; Jason A Halfen; Lisa M Berreau
First row divalent transition metal complexes of aryl-appended tris((pyridyl)methyl)amine ligands: syntheses, structures, electrochemistry, and hydroxamate binding properties.
Inorganic chemistry 2003;42(23):7472-88.
2003: Nicholas J Robertson; Michael J Carney; Jason A Halfen
Chromium(II) and chromium(III) complexes supported by tris(2-pyridylmethyl)amine: synthesis, structures, and reactivity.
Inorganic chemistry 2003;42(21):6876-85.
2002: Jason A Halfen; Heather L Moore; Derek C Fox
Synthetic models of the reduced active site of superoxide reductase.
Inorganic chemistry 2002;41(15):3935-43.
2001: Jason A Halfen; Derek C Fox; M P Mehn; Lawrence Que
Enhanced reactivity of copper catalysts for olefin aziridination by manipulation of ligand denticity.
Inorganic chemistry 2001;40(20):5060-1.
2001: D A Krogstad; Jason A Halfen; T J Terry; Victor G Young
Synthesis and characterization of iridium 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. X-ray crystal and molecular structures of [Ir(PTA)4(CO)]Cl and [Ir(PTAH)3(PTAH2)(H)2]Cl6.
Inorganic chemistry 2001;40(3):463-71.
2000: Jason A Halfen; J M Uhan; Derek C Fox; M P Mehn; Lawrence Que
Copper(II) complexes of pyridyl-appended diazacycloalkanes: synthesis, characterization, and application to catalytic olefin aziridination.
Inorganic chemistry 2000;39(21):4913-20.
2000: B M Lam; Jason A Halfen; Victor G Young; J R Hagadorn; Patrick L Holland; Agustí Lledós; L Cucurull-Sánchez; J J Novoa; Santiago Alvarez; William B Tolman
Ligand macrocycle structural effects on copper-dioxygen reactivity.
Inorganic chemistry 2000;39(18):4059-72.
1997: H Zhu; Jason A Halfen; Victor G Young; Brian E Padden; Eric J Munson; V Menon; David J W Grant
Physicochemical characterization of nedocromil bivalent metal salt hydrates. 3. Nedocromil calcium.
Journal of pharmaceutical sciences 1997;86(12):1439-47.