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John Hartwig

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Carl W Liskey; John F Hartwig
Iridium-catalyzed C-H borylation of cyclopropanes.
Patrick S Fier; Jingwei Luo; John F Hartwig
Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex.
Wenyong Chen; John F Hartwig
Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion.

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All Publications

2013: Carl W Liskey; John F Hartwig
Iridium-catalyzed C-H borylation of cyclopropanes.
Journal of the American Chemical Society 2013;135(9):3375-8.
2013: Patrick S Fier; Jingwei Luo; John F Hartwig
Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex.
Journal of the American Chemical Society 2013;135(7):2552-9.
2013: Wenyong Chen; John F Hartwig
Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion.
Journal of the American Chemical Society 2013;135(6):2068-71.
2013: Patrick S Fier; John F Hartwig
Synthesis of difluoromethyl ethers with difluoromethyltriflate.
Angewandte Chemie (International ed. in English) 2013;52(7):2092-5.
2013: Daniel W Robbins; John F Hartwig
Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation.
Angewandte Chemie (International ed. in English) 2013;52(3):933-7.
2013: Benjamin M Partridge; John F Hartwig
Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation.
Organic letters 2013;15(1):140-3.
2012: Alexey G Sergeev; Jonathan D Webb; John F Hartwig
A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation.
Journal of the American Chemical Society 2012;134(50):20226-9.
2012: Shaozhong Ge; John F Hartwig
Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides.
Angewandte Chemie (International ed. in English) 2012;51(51):12837-41.
2012: Wenyong Chen; John F Hartwig
Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran.
Journal of the American Chemical Society 2012;134(37):15249-52.
2012: Patrick S Hanley; Thomas R Cundari; Seth L Marquard; John F Hartwig
Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes.
Journal of the American Chemical Society 2012;134(37):15281-4.
2012: Daniel W Robbins; John F Hartwig
A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates.
Organic letters 2012;14(16):4266-9.
2012: Carl W Liskey; John F Hartwig
Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers.
Journal of the American Chemical Society 2012;134(30):12422-5.
2012: Patrick S Fier; John F Hartwig
Copper-mediated fluorination of aryl iodides.
Journal of the American Chemical Society 2012;134(26):10795-8.
2012: John F Hartwig
Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations.
Accounts of chemical research 2012;45(6):864-73.
2012: Sherzod T Madrahimov; John F Hartwig
Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes.
Journal of the American Chemical Society 2012;134(19):8136-47.
2012: Jessica L Klinkenberg; John F Hartwig
Reductive elimination from arylpalladium cyanide complexes.
Journal of the American Chemical Society 2012;134(13):5758-61.
2012: Patrick S Fier; John F Hartwig
Copper-mediated difluoromethylation of aryl and vinyl iodides.
Journal of the American Chemical Society 2012;134(12):5524-7.
2012: Eric M Simmons; John F Hartwig
On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes.
Angewandte Chemie (International ed. in English) 2012;51(13):3066-72.
2012: Eric M Simmons; John F Hartwig
Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol.
Nature 2012;483(7387):70-3.
2012: Yichen Tan; Fabiola Barrios-Landeros; John F Hartwig
Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers.
Journal of the American Chemical Society 2012;134(8):3683-6.
2012: Zheng Huang; John F Hartwig
Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism.
Angewandte Chemie (International ed. in English) 2012;51(4):1028-32.
2012: Nichole D Litvinas; Patrick S Fier; John F Hartwig
A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)].
Angewandte Chemie (International ed. in English) 2012;51(2):536-9.
2011: Shaozhong Ge; John F Hartwig
Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions.
Journal of the American Chemical Society 2011;133(41):16330-3.
2011: Patrick S Hanley; John F Hartwig
Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion.
Journal of the American Chemical Society 2011;133(39):15661-73.
2011: Daniel W Robbins; John F Hartwig
A simple, multidimensional approach to high-throughput discovery of catalytic reactions.
Science (New York, N.Y.) 2011;333(6048):1423-7.
2011: Seth L Marquard; John F Hartwig
C(sp3)-O bond-forming reductive elimination of ethers from bisphosphine-ligated benzylpalladium(II) aryloxide complexes.
Angewandte Chemie (International ed. in English) 2011;50(31):7119-23.
2011: Alexey G Sergeev; John F Hartwig
Selective, nickel-catalyzed hydrogenolysis of aryl ethers.
Science (New York, N.Y.) 2011;332(6028):439-43.
2011: Hiroyuki Morimoto; Tetsu Tsubogo; Nichole D Litvinas; John F Hartwig
A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides.
Angewandte Chemie (International ed. in English) 2011;50(16):3793-8.
2011: John F Hartwig
Regioselectivity of the borylation of alkanes and arenes.
Chemical Society reviews 2011;40(4):1992-2002.
2011: Yichen Tan; John F Hartwig
Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species.
Journal of the American Chemical Society 2011;133(10):3308-11.
2011: Zhijian Liu; Hideaki Yamamichi; Sherzod T Madrahimov; John F Hartwig
Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes.
Journal of the American Chemical Society 2011;133(8):2772-82.
2011: Brad P Carrow; John F Hartwig
Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions.
Journal of the American Chemical Society 2011;133(7):2116-9.
2011: Xuebin Liao; Levi M Stanley; John F Hartwig
Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation.
Journal of the American Chemical Society 2011;133(7):2088-91.
2011: John F Hartwig
Hydrocarbon synthesis: Ringing the chains.
Nature chemistry 2011;3(2):99-101.
2011: Jessica L Klinkenberg; John F Hartwig
Catalytic organometallic reactions of ammonia.
Angewandte Chemie (International ed. in English) 2011;50(1):86-95.
2010: John F Hartwig; Levi M Stanley
Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.
Accounts of chemical research 2010;43(12):1461-75.
2010: Eric M Simmons; John F Hartwig
Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.
Journal of the American Chemical Society 2010;132(48):17092-5.
2010: Ramesh Giri; John F Hartwig
Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI.
Journal of the American Chemical Society 2010;132(45):15860-3.
2010: Lisa D Julian; John F Hartwig
Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex.
Journal of the American Chemical Society 2010;132(39):13813-22.
2010: Jessica L Klinkenberg; John F Hartwig
Slow reductive elimination from arylpalladium parent amido complexes.
Journal of the American Chemical Society 2010;132(34):11830-3.
2010: Carl W Liskey; Xuebin Liao; John F Hartwig
Cyanation of arenes via iridium-catalyzed borylation.
Journal of the American Chemical Society 2010;132(33):11389-91.
2010: Zheng Huang; Jianrong Steve Zhou; John F Hartwig
N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes.
Journal of the American Chemical Society 2010;132(33):11458-60.
2010: David S Huang; John F Hartwig
Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals.
Angewandte Chemie (International ed. in English) 2010;49(33):5757-61.
2010: Levi M Stanley; Chen Bai; Mitsuhiro Ueda; John F Hartwig
Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates.
Journal of the American Chemical Society 2010;132(26):8918-20.
2010: Patrick S Hanley; Dean Marković; John F Hartwig
Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate.
Journal of the American Chemical Society 2010;132(18):6302-3.
2010: Daniel W Robbins; Timothy A Boebel; John F Hartwig
Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles.
Journal of the American Chemical Society 2010;132(12):4068-9.
2010: Yichen Tan; John F Hartwig
Palladium-catalyzed amination of aromatic C-H bonds with oxime esters.
Journal of the American Chemical Society 2010;132(11):3676-7.
2010: Jesse W Tye; Zhiqiang Weng; Ramesh Giri; John F Hartwig
Copper(I) phenoxide complexes in the etherification of aryl halides.
Angewandte Chemie (International ed. in English) 2010;49(12):2185-9.
2010: Carolyn S Wei; Carlos A Jiménez-Hoyos; Marcelo F Videa; John F Hartwig; Michael B Hall
Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes.
Journal of the American Chemical Society 2010;132(9):3078-91.
2010: Manuel A Fernández-Rodríguez; John F Hartwig
One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate.
Chemistry (Weinheim an der Bergstrasse, Germany) 2010;16(8):2355-9.
2010: Karma R Sawyer; James F Cahoon; Jennifer E Shanoski; Elizabeth A Glascoe; Matthias F Kling; Jacob P Schlegel; Matthew C Zoerb; Marko Hapke; John F Hartwig; Charles Edwin Webster; Charles B Harris
Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin).
Journal of the American Chemical Society 2010;132(6):1848-59.
2010: Brad P Carrow; John F Hartwig
Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction.
Journal of the American Chemical Society 2010;132(1):79-81.
2010: Seth L Marquard; Devon C Rosenfeld; John F Hartwig
C(sp(3))-N bond-forming reductive elimination of amines: reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes.
Angewandte Chemie (International ed. in English) 2010;49(4):793-6.
2010: Mitsuhiro Ueda; John F Hartwig
Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates.
Organic letters 2010;12(1):92-4.
2009: Jesse W Tye; John F Hartwig
Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium.
Journal of the American Chemical Society 2009;131(41):14703-12.
2009: Carl W Liskey; Carolyn S Wei; Dale R Pahls; John F Hartwig
Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds.
Chemical communications (Cambridge, England) 2009;(37):5603-5.
2009: Mark J Pouy; Levi M Stanley; John F Hartwig
Enantioselective, iridium-catalyzed monoallylation of ammonia.
Journal of the American Chemical Society 2009;131(32):11312-3.
2009: Giang D Vo; John F Hartwig
Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines.
Journal of the American Chemical Society 2009;131(31):11049-61.
2009: Daniel J Weix; Dean Marković; Mitsuhiro Ueda; John F Hartwig
Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines.
Organic letters 2009;11(13):2944-7.
2009: Levi M Stanley; John F Hartwig
Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes.
Journal of the American Chemical Society 2009;131(25):8971-83.
2009: Fabiola Barrios-Landeros; Brad P Carrow; John F Hartwig
Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes.
Journal of the American Chemical Society 2009;131(23):8141-54.
2009: Elsa Alvaro; John F Hartwig
Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium.
Journal of the American Chemical Society 2009;131(22):7858-68.
2009: Sherzod T Madrahimov; Dean Markovic; John F Hartwig
The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions.
Journal of the American Chemical Society 2009;131(21):7228-9.
2009: Manuel A Fernández-Rodríguez; John F Hartwig
A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides.
The Journal of organic chemistry 2009;74(4):1663-72.
2009: Levi M Stanley; John F Hartwig
Iridium-catalyzed regio- and enantioselective N-allylation of indoles.
Angewandte Chemie (International ed. in English) 2009;48(42):7841-4.
2008: John F Hartwig
Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.
Accounts of chemical research 2008;41(11):1534-44.
2008: Seth B Herzon; John F Hartwig
Hydroaminoalkylation of unactivated olefins with dialkylamines.
Journal of the American Chemical Society 2008;130(45):14940-1.
2008: Tokutaro Ogata; John F Hartwig
Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature.
Journal of the American Chemical Society 2008;130(42):13848-9.
2008: John F Hartwig
Carbon-heteroatom bond formation catalysed by organometallic complexes.
Nature 2008;455(7211):314-22.
2008: Jesse W Tye; Zhiqiang Weng; Adam M Johns; Christopher D Incarvito; John F Hartwig
Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides.
Journal of the American Chemical Society 2008;130(30):9971-83.
2008: Qilong Shen; Tokutaro Ogata; John F Hartwig
Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships.
Journal of the American Chemical Society 2008;130(20):6586-96.
2008: Fabiola Barrios-Landeros; Brad P Carrow; John F Hartwig
Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br).
Journal of the American Chemical Society 2008;130(18):5842-3.
2008: Takuo Hama; John F Hartwig
Palladium-catalyzed alpha-arylation of esters with chloroarenes.
Organic letters 2008;10(8):1549-52.
2008: Takuo Hama; John F Hartwig
Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2.
Organic letters 2008;10(8):1545-8.
2008: Zhijian Liu; John F Hartwig
Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.
Journal of the American Chemical Society 2008;130(5):1570-1.
2008: Xuebin Liao; Zhiqiang Weng; John F Hartwig
Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.
Journal of the American Chemical Society 2008;130(1):195-200.
2008: Jianrong Zhou; John F Hartwig
Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization.
Angewandte Chemie (International ed. in English) 2008;47(31):5783-7.
2008: Giang D Vo; John F Hartwig
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos.
Angewandte Chemie (International ed. in English) 2008;47(11):2127-30.
2008: Satoshi Ueno; John F Hartwig
Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.
Angewandte Chemie (International ed. in English) 2008;47(10):1928-31.
2007: Jaclyn M Murphy; Xuebin Liao; John F Hartwig
Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation.
Journal of the American Chemical Society 2007;129(50):15434-5.
2007: Mark J Pouy; Andreas Leitner; Daniel J Weix; Satoshi Ueno; John F Hartwig
Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates.
Organic letters 2007;9(20):3949-52.
2007: Dean Marković; John F Hartwig
Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes.
Journal of the American Chemical Society 2007;129(38):11680-1.
2007: Qilong Shen; John F Hartwig
Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides.
Journal of the American Chemical Society 2007;129(25):7734-5.
2007: Daniel J Weix; John F Hartwig
Regioselective and enantioselective iridium-catalyzed allylation of enamines.
Journal of the American Chemical Society 2007;129(25):7720-1.
2007: Yasuhiro Yamashita; Apsara Gopalarathnam; John F Hartwig
Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids.
Journal of the American Chemical Society 2007;129(24):7508-9.
2007: Seth B Herzon; John F Hartwig
Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines.
Journal of the American Chemical Society 2007;129(21):6690-1.
2007: John F Hartwig
Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes.
Inorganic chemistry 2007;46(6):1936-47.
2007: Jaclyn M Murphy; C Christoph Tzschucke; John F Hartwig
One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes.
Organic letters 2007;9(5):757-60.
2007: C Christoph Tzschucke; Jaclyn M Murphy; John F Hartwig
Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling.
Organic letters 2007;9(5):761-4.
2007: Pinjing Zhao; Christopher D Incarvito; John F Hartwig
Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates.
Journal of the American Chemical Society 2007;129(7):1876-7.
2007: James P Stambuli; Zhiqiang Weng; Christopher D Incarvito; John F Hartwig
Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides.
Angewandte Chemie (International ed. in English) 2007;46(40):7674-7.
2007: Adam M Johns; Zhijian Liu; John F Hartwig
Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives.
Angewandte Chemie (International ed. in English) 2007;46(38):7259-61.
2006: Adam M Johns; Jesse W Tye; John F Hartwig
Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium.
Journal of the American Chemical Society 2006;128(50):16010-1.
2006: Akihiro Takemiya; John F Hartwig
Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent.
Journal of the American Chemical Society 2006;128(46):14800-1.
2006: Jaclyn M Murphy; Joshua D Lawrence; Kazumori Kawamura; Christopher D Incarvito; John F Hartwig
Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds.
Journal of the American Chemical Society 2006;128(42):13684-5.
2006: Manuel A Fernández-Rodríguez; Qilong Shen; John F Hartwig
Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols.
Chemistry (Weinheim an der Bergstrasse, Germany) 2006;12(30):7782-96.
2006: Devon C Rosenfeld; Shashank Shekhar; Akihiro Takemiya; Masaru Utsunomiya; John F Hartwig
Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.
Organic letters 2006;8(19):4179-82.
2006: Shashank Shekhar; Brian Trantow; Andreas Leitner; John F Hartwig
Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products.
Journal of the American Chemical Society 2006;128(36):11770-1.
2006: Qilong Shen; John F Hartwig
Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides.
Journal of the American Chemical Society 2006;128(31):10028-9.
2006: Pinjing Zhao; Christopher D Incarvito; John F Hartwig
Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide.
Journal of the American Chemical Society 2006;128(30):9642-3.
2006: Adam M Johns; Norio Sakai; André Ridder; John F Hartwig
Direct measurement of the thermodynamics of vinylarene hydroamination.
Journal of the American Chemical Society 2006;128(29):9306-7.
2006: Ken-ichi Fujita; Makoto Yamashita; Florian Puschmann; Miguel Martinez Alvarez-Falcon; Christopher D Incarvito; John F Hartwig
Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).
Journal of the American Chemical Society 2006;128(28):9044-5.
2006: Norio Sakai; André Ridder; John F Hartwig
Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene.
Journal of the American Chemical Society 2006;128(25):8134-5.
2006: Akihiro Takemiya; John F Hartwig
Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.
Journal of the American Chemical Society 2006;128(18):6042-3.
2006: Takuo Hama; Darcy A Culkin; John F Hartwig
Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions.
Journal of the American Chemical Society 2006;128(15):4976-85.
2006: Shashank Shekhar; Per Ryberg; John F Hartwig; Jinu S Mathew; Donna G Blackmond; Eric R. Strieter; Stephen L Buchwald
Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.
Journal of the American Chemical Society 2006;128(11):3584-91.
2006: Pinjing Zhao; Christopher D Incarvito; John F Hartwig
Direct observation of beta-aryl eliminations from Rh(I) alkoxides.
Journal of the American Chemical Society 2006;128(10):3124-5.
2006: Shashank Shekhar; Per Ryberg; John F Hartwig
Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP).
Organic letters 2006;8(5):851-4.
2006: Manuel A Fernández-Rodríguez; Qilong Shen; John F Hartwig
A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols.
Journal of the American Chemical Society 2006;128(7):2180-1.
2006: Adam M Johns; Masaru Utsunomiya; Christopher D Incarvito; John F Hartwig
A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes.
Journal of the American Chemical Society 2006;128(6):1828-39.
2005: Timm Graening; John F Hartwig
Iridium-catalyzed regio- and enantioselective allylation of ketone enolates.
Journal of the American Chemical Society 2005;127(49):17192-3.
2005: Lingyun Wu; John F Hartwig
Mild palladium-catalyzed selective monoarylation of nitriles.
Journal of the American Chemical Society 2005;127(45):15824-32.
2005: Michael E Limmert; Amy H Roy; John F Hartwig
Kumada coupling of aryl and vinyl tosylates under mild conditions.
The Journal of organic chemistry 2005;70(23):9364-70.
2005: Andreas Leitner; Shashank Shekhar; Mark J Pouy; John F Hartwig
A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis.
Journal of the American Chemical Society 2005;127(44):15506-14.
2005: Timothy M Boller; Jaclyn M Murphy; Marko Hapke; Tatsuo Ishiyama; Norio Miyaura; John F Hartwig
Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes.
Journal of the American Chemical Society 2005;127(41):14263-78.
2005: Chulsung Bae; John F Hartwig; Hoyong Chung; Nicole K Harris; Karen A Switek; Marc A Hillmyer
Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups.
Angewandte Chemie (International ed. in English) 2005;44(39):6410-3.
2005: Pinjing Zhao; Christopher Krug; John F Hartwig
Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes.
Journal of the American Chemical Society 2005;127(34):12066-73.
2005: Pinjing Zhao; John F Hartwig
Beta-aryl eliminations from Rh(I) iminyl complexes.
Journal of the American Chemical Society 2005;127(33):11618-9.
2005: X Z Yan; Jan Pawlas; Theodore Goodson; John F Hartwig
Polaron delocalization in ladder macromolecular systems.
Journal of the American Chemical Society 2005;127(25):9105-16.
2005: Fabiola Barrios-Landeros; John F Hartwig
Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands.
Journal of the American Chemical Society 2005;127(19):6944-5.
2005: Jun Takaya; John F Hartwig
Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes.
Journal of the American Chemical Society 2005;127(16):5756-7.
2005: Naofumi Tsukada; John F Hartwig
Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds.
Journal of the American Chemical Society 2005;127(14):5022-3.
2005: Dae-Yon Lee; John F Hartwig
Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates.
Organic letters 2005;7(6):1169-72.
2005: Andreas Leitner; Chutian Shu; John F Hartwig
Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides.
Organic letters 2005;7(6):1093-6.
2005: John F Hartwig; Kevin S Cook; Marko Hapke; Christopher D Incarvito; Yubo Fan; Charles Edwin Webster; Michael B Hall
Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes.
Journal of the American Chemical Society 2005;127(8):2538-52.
2005: Jing Zhao; Alan S Goldman; John F Hartwig
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
Science (New York, N.Y.) 2005;307(5712):1080-2.
2005: Qilong Shen; Shashank Shekhar; James P Stambuli; John F Hartwig
Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles.
Angewandte Chemie (International ed. in English) 2005;44(9):1371-5.
2005: Chulsung Bae; John F Hartwig; Nicole K Boaen Harris; Rachael O Long; Karen S Anderson; Marc A Hillmyer
Catalytic hydroxylation of polypropylenes.
Journal of the American Chemical Society 2005;127(2):767-76.
2004: Joshua D Lawrence; Makoto Takahashi; Chulsung Bae; John F Hartwig
Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality.
Journal of the American Chemical Society 2004;126(47):15334-5.
2004: Andreas Leitner; Jens Larsen; Christian Steffens; John F Hartwig
Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes.
The Journal of organic chemistry 2004;69(22):7552-7.
2004: Kevin S Cook; Christopher D Incarvito; Charles Edwin Webster; Yubo Fan; Michael B Hall; John F Hartwig
Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen.
Angewandte Chemie (International ed. in English) 2004;43(41):5474-7.
2004: Shashank Shekhar; John F Hartwig
Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes.
Journal of the American Chemical Society 2004;126(40):13016-27.
2004: Chutian Shu; Andreas Leitner; John F Hartwig
Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst.
Angewandte Chemie (International ed. in English) 2004;43(36):4797-800.
2004: Chutian Shu; John F Hartwig
Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans.
Angewandte Chemie (International ed. in English) 2004;43(36):4794-7.
2004: Makoto Yamashita; John F Hartwig
Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes.
Journal of the American Chemical Society 2004;126(17):5344-5.
2004: Xiaoxiang Liu; John F Hartwig
Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives.
Journal of the American Chemical Society 2004;126(16):5182-91.
2004: Andreas Leitner; Chutian Shu; John F Hartwig
Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(16):5830-3.
2004: Masaru Utsunomiya; John F Hartwig
Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes.
Journal of the American Chemical Society 2004;126(9):2702-3.
2004: Christopher Krug; John F Hartwig
Imine insertion into a late metal-carbon bond to form a stable amido complex.
Journal of the American Chemical Society 2004;126(9):2694-5.
2004: James P Stambuli; Christopher D Incarvito; Michael Bühl; John F Hartwig
Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction.
Journal of the American Chemical Society 2004;126(4):1184-94.
2003: Makoto Yamashita; Jose V Cuevas Vicario; John F Hartwig
Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres.
Journal of the American Chemical Society 2003;125(52):16347-60.
2003: Tatsuo Ishiyama; Yusuke Nobuta; John F Hartwig; Norio Miyaura
Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.
Chemical communications (Cambridge, England) 2003;(23):2924-5.
2003: Masaru Utsunomiya; John F Hartwig
Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines.
Journal of the American Chemical Society 2003;125(47):14286-7.
2003: Christoph A Kiener; Chutian Shu; Christopher D Incarvito; John F Hartwig
Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity.
Journal of the American Chemical Society 2003;125(47):14272-3.
2003: Amy H Roy; John F Hartwig
Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes.
Journal of the American Chemical Society 2003;125(46):13944-5.
2003: Takuo Hama; Xiaoxiang Liu; Darcy A Culkin; John F Hartwig
Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions.
Journal of the American Chemical Society 2003;125(37):11176-7.
2003: Amy H Roy; John F Hartwig
Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature.
Journal of the American Chemical Society 2003;125(29):8704-5.
2003: Shaun R Stauffer; John F Hartwig
Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study.
Journal of the American Chemical Society 2003;125(23):6977-85.
2003: James P Stambuli; John F Hartwig
Recent advances in the discovery of organometallic catalysts using high-throughput screening assays.
Current opinion in chemical biology 2003;7(3):420-6.
2003: Xiaoxiang Liu; John F Hartwig
Palladium-catalyzed alpha-arylation of azlactones to form quaternary amino acid derivatives.
Organic letters 2003;5(11):1915-8.
2003: Masaru Utsunomiya; Ryoichi Kuwano; Motoi Kawatsura; John F Hartwig
Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes.
Journal of the American Chemical Society 2003;125(19):5608-9.
2003: Mark W Hooper; Masaru Utsunomiya; John F Hartwig
Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides.
The Journal of organic chemistry 2003;68(7):2861-73.
2003: Darcy A Culkin; John F Hartwig
Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles.
Accounts of chemical research 2003;36(4):234-45.
2003: Fernando López; Toshimichi Ohmura; John F Hartwig
Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides.
Journal of the American Chemical Society 2003;125(12):3426-7.
2003: Charles Edwin Webster; Yubo Fan; Michael B Hall; Doris Kunz; John F Hartwig
Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation.
Journal of the American Chemical Society 2003;125(4):858-9.
2003: Masaru Utsunomiya; Motoi Kawatsura; John F Hartwig
Palladium-catalyzed equilibrium addition of acidic OH groups across dienes.
Angewandte Chemie (International ed. in English) 2003;42(47):5865-8.
2002: Toshimichi Ohmura; John F Hartwig
Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex.
Journal of the American Chemical Society 2002;124(51):15164-5.
2002: James P Stambuli; Ryoichi Kuwano; John F Hartwig
Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature.
Angewandte Chemie (International ed. in English) 2002;41(24):4746-8.
2002: Joanna P Wolkowski; John F Hartwig
Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions.
Angewandte Chemie (International ed. in English) 2002;41(22):4289-91.
2002: Morten Jørgensen; Sunwoo Lee; Xiaoxiang Liu; Joanna P Wolkowski; John F Hartwig
Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates.
Journal of the American Chemical Society 2002;124(42):12557-65.
2002: John F Hartwig
Chemical synthesis. Raising the bar for the "perfect reaction".
Science (New York, N.Y.) 2002;297(5587):1653-4.
2002: Ryoichi Kuwano; Masaru Utsunomiya; John F Hartwig
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
The Journal of organic chemistry 2002;67(18):6479-86.
2002: Tatsuo Ishiyama; Jun Takagi; John F Hartwig; Norio Miyaura
A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature.
Angewandte Chemie (International ed. in English) 2002;41(16):3056-8.
2002: James P Stambuli; Michael Bühl; John F Hartwig
Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand.
Journal of the American Chemical Society 2002;124(32):9346-7.
2002: Darcy A Culkin; John F Hartwig
Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.
Journal of the American Chemical Society 2002;124(32):9330-1.
2002: Noriyasu Kataoka; Quinetta Shelby; James P Stambuli; John F Hartwig
Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings.
The Journal of organic chemistry 2002;67(16):5553-66.
2002: Mahinda I Ranasinghe; Oleg Varnavski; Jan Pawlas; Sheila I Hauck; Janis Louie; John F Hartwig; Theodore Goodson
Femtosecond excitation energy transport in triarylamine dendrimers.
Journal of the American Chemical Society 2002;124(23):6520-1.
2002: Björn Schlummer; John F Hartwig
Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines.
Organic letters 2002;4(9):1471-4.
2002: Jan Pawlas; Yoshiaki Nakao; Motoi Kawatsura; John F Hartwig
A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism.
Journal of the American Chemical Society 2002;124(14):3669-79.
2002: Christopher Krug; John F Hartwig
Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes.
Journal of the American Chemical Society 2002;124(8):1674-9.
2002: Ulrike Nettekoven; John F Hartwig
A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes.
Journal of the American Chemical Society 2002;124(7):1166-7.
2002: Yuichiro Kondo; Domingo García-Cuadrado; John F Hartwig; Nicole K Boaen; Nicole L Wagner; Marc A Hillmyer
Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt.
Journal of the American Chemical Society 2002;124(7):1164-5.
2002: Neil A Beare; John F Hartwig
Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands.
The Journal of organic chemistry 2002;67(2):541-55.
2002: Tatsuo Ishiyama; Jun Takagi; Kousaku Ishida; Norio Miyaura; Natia R Anastasi; John F Hartwig
Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate.
Journal of the American Chemical Society 2002;124(3):390-1.
2001: L M Alcazar-Roman; John F Hartwig
Mechanism of aryl chloride amination: base-induced oxidative addition.
Journal of the American Chemical Society 2001;123(51):12905-6.
2001: K Kawamura; John F Hartwig
Isolated Ir(V) boryl complexes and their reactions with hydrocarbons.
Journal of the American Chemical Society 2001;123(34):8422-3.
2001: Sunwoo Lee; Neil A Beare; John F Hartwig
Palladium-catalyzed alpha-arylation of esters and protected amino acids.
Journal of the American Chemical Society 2001;123(34):8410-1.
2001: Sunwoo Lee; M Jørgensen; John F Hartwig
Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.
Organic letters 2001;3(17):2729-32.
2001: J Zhao; H Hesslink; John F Hartwig
Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands.
Journal of the American Chemical Society 2001;123(30):7220-7.
2001: Darcy A Culkin; John F Hartwig
C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates.
Journal of the American Chemical Society 2001;123(24):5816-7.
2001: Sunwoo Lee; John F Hartwig
Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations.
The Journal of organic chemistry 2001;66(10):3402-15.
2001: Shaun R Stauffer; Neil A Beare; James P Stambuli; John F Hartwig
Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery.
Journal of the American Chemical Society 2001;123(19):4641-2.
2001: O Löber; Motoi Kawatsura; John F Hartwig
Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.
Journal of the American Chemical Society 2001;123(18):4366-7.
2001: James P Stambuli; Shaun R Stauffer; K H Shaughnessy; John F Hartwig
Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions.
Journal of the American Chemical Society 2001;123(11):2677-8.
2001: Amy H Roy; John F Hartwig
Reductive elimination of aryl halides from palladium(II).
Journal of the American Chemical Society 2001;123(6):1232-3.
2000: Shaun R Stauffer; Sunwoo Lee; James P Stambuli; S I Hauck; John F Hartwig
High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.
Organic letters 2000;2(10):1423-6.