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John Hartwig

This is a preview profile on BiomedExperts - the first literature-based scientific social network. It brings the right researchers together and allows them to collaborate online. Collexis and Dell provide the BiomedExperts network of +1.5 Million pre-calculated profiles free of charge to researchers worldwide.

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Co-Publications
Name
12
Incarvito, Christopher
10
Stambuli, James
8
Utsunomiya, Masaru
7
Shekhar, Shashank
7
Leitner, Andreas
5
Shen, Qilong
5
Shu, Chutian
5
Lee, Sunwoo
5
Culkin, Darcy
5
Zhao, Pinjing
4
Ishiyama, Tatsuo
4
Johns, Adam
4
Kawatsura, Motoi
4
Stauffer, Shaun
4
Roy, Amy

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Publications

TOP 3
Tye Jesse W; Hartwig John F
Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium.
Liskey Carl W; Wei Carolyn S; Pahls Dale R; Hartwig John F
Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds.
Pouy Mark J; Stanley Levi M; Hartwig John F
Enantioselective, iridium-catalyzed monoallylation of ammonia.

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All Publications

2009: Tye Jesse W; Hartwig John F
Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium.
Journal of the American Chemical Society 2009;131(41):14703-12.
2009: Liskey Carl W; Wei Carolyn S; Pahls Dale R; Hartwig John F
Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds.
Chemical communications (Cambridge, England) 2009;(37):5603-5.
2009: Pouy Mark J; Stanley Levi M; Hartwig John F
Enantioselective, iridium-catalyzed monoallylation of ammonia.
Journal of the American Chemical Society 2009;131(32):11312-3.
2009: Vo Giang D; Hartwig John F
Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines.
Journal of the American Chemical Society 2009;131(31):11049-61.
2009: Weix Daniel J; Markovic Dean; Ueda Mitsuhiro; Hartwig John F
Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines.
Organic letters 2009;11(13):2944-7.
2009: Stanley Levi M; Hartwig John F
Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes.
Journal of the American Chemical Society 2009;131(25):8971-83.
2009: Barrios-Landeros Fabiola; Carrow Brad P; Hartwig John F
Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes.
Journal of the American Chemical Society 2009;131(23):8141-54.
2009: Alvaro Elsa; Hartwig John F
Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium.
Journal of the American Chemical Society 2009;131(22):7858-68.
2009: Madrahimov Sherzod T; Markovic Dean; Hartwig John F
The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions.
Journal of the American Chemical Society 2009;131(21):7228-9.
2009: Fernández-Rodríguez Manuel A; Hartwig John F
A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides.
The Journal of organic chemistry 2009;74(4):1663-72.
2009: Stanley Levi M; Hartwig John F
Iridium-catalyzed regio- and enantioselective N-allylation of indoles.
Angewandte Chemie (International ed. in English) 2009;48(42):7841-4.
2008: Herzon Seth B; Hartwig John F
Hydroaminoalkylation of unactivated olefins with dialkylamines.
Journal of the American Chemical Society 2008;130(45):14940-1.
2008: Hartwig John F
Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides.
Accounts of chemical research 2008;41(11):1534-44.
2008: Ogata Tokutaro; Hartwig John F
Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature.
Journal of the American Chemical Society 2008;130(42):13848-9.
2008: Hartwig John F
Carbon-heteroatom bond formation catalysed by organometallic complexes.
Nature 2008;455(7211):314-22.
2008: Tye Jesse W; Weng Zhiqiang; Johns Adam M; Incarvito Christopher D; Hartwig John F
Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides.
Journal of the American Chemical Society 2008;130(30):9971-83.
2008: Shen Qilong; Ogata Tokutaro; Hartwig John F
Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships.
Journal of the American Chemical Society 2008;130(20):6586-96.
2008: Barrios-Landeros Fabiola; Carrow Brad P; Hartwig John F
Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br).
Journal of the American Chemical Society 2008;130(18):5842-3.
2008: Hama Takuo; Hartwig John F
Palladium-catalyzed alpha-arylation of esters with chloroarenes.
Organic letters 2008;10(8):1549-52.
2008: Hama Takuo; Hartwig John F
Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2.
Organic letters 2008;10(8):1545-8.
2008: Liu Zhijian; Hartwig John F
Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.
Journal of the American Chemical Society 2008;130(5):1570-1.
2008: Liao Xuebin; Weng Zhiqiang; Hartwig John F
Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.
Journal of the American Chemical Society 2008;130(1):195-200.
2008: Zhou Jianrong; Hartwig John F
Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization.
Angewandte Chemie (International ed. in English) 2008;47(31):5783-7.
2008: Vo Giang D; Hartwig John F
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos.
Angewandte Chemie (International ed. in English) 2008;47(11):2127-30.
2008: Ueno Satoshi; Hartwig John F
Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols.
Angewandte Chemie (International ed. in English) 2008;47(10):1928-31.
2007: Murphy Jaclyn M; Liao Xuebin; Hartwig John F
Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation.
Journal of the American Chemical Society 2007;129(50):15434-5.
2007: Pouy Mark J; Leitner Andreas; Weix Daniel J; Ueno Satoshi; Hartwig John F
Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates.
Organic letters 2007;9(20):3949-52.
2007: Markovic Dean; Hartwig John F
Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes.
Journal of the American Chemical Society 2007;129(38):11680-1.
2007: Shen Qilong; Hartwig John F
Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides.
Journal of the American Chemical Society 2007;129(25):7734-5.
2007: Weix Daniel J; Hartwig John F
Regioselective and enantioselective iridium-catalyzed allylation of enamines.
Journal of the American Chemical Society 2007;129(25):7720-1.
2007: Yamashita Yasuhiro; Gopalarathnam Apsara; Hartwig John F
Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids.
Journal of the American Chemical Society 2007;129(24):7508-9.
2007: Herzon Seth B; Hartwig John F
Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines.
Journal of the American Chemical Society 2007;129(21):6690-1.
2007: Hartwig John F
Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes.
Inorganic chemistry 2007;46(6):1936-47.
2007: Murphy Jaclyn M; Tzschucke C Christoph; Hartwig John F
One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes.
Organic letters 2007;9(5):757-60.
2007: Tzschucke C Christoph; Murphy Jaclyn M; Hartwig John F
Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling.
Organic letters 2007;9(5):761-4.
2007: Zhao Pinjing; Incarvito Christopher D; Hartwig John F
Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates.
Journal of the American Chemical Society 2007;129(7):1876-7.
2007: Stambuli James P; Weng Zhiqiang; Incarvito Christopher D; Hartwig John F
Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides.
Angewandte Chemie (International ed. in English) 2007;46(40):7674-7.
2007: Johns Adam M; Liu Zhijian; Hartwig John F
Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives.
Angewandte Chemie (International ed. in English) 2007;46(38):7259-61.
2006: Johns Adam M; Tye Jesse W; Hartwig John F
Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium.
Journal of the American Chemical Society 2006;128(50):16010-1.
2006: Takemiya Akihiro; Hartwig John F
Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent.
Journal of the American Chemical Society 2006;128(46):14800-1.
2006: Murphy Jaclyn M; Lawrence Joshua D; Kawamura Kazumori; Incarvito Christopher; Hartwig John F
Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds.
Journal of the American Chemical Society 2006;128(42):13684-5.
2006: Fernández-Rodríguez Manuel A; Shen Qilong; Hartwig John F
Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols.
Chemistry (Weinheim an der Bergstrasse, Germany) 2006;12(30):7782-96.
2006: Rosenfeld Devon C; Shekhar Shashank; Takemiya Akihiro; Utsunomiya Masaru; Hartwig John F
Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.
Organic letters 2006;8(19):4179-82.
2006: Shekhar Shashank; Trantow Brian; Leitner Andreas; Hartwig John F
Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products.
Journal of the American Chemical Society 2006;128(36):11770-1.
2006: Shen Qilong; Hartwig John F
Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides.
Journal of the American Chemical Society 2006;128(31):10028-9.
2006: Zhao Pinjing; Incarvito Christopher D; Hartwig John F
Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide.
Journal of the American Chemical Society 2006;128(30):9642-3.
2006: Johns Adam M; Sakai Norio; Ridder André; Hartwig John F
Direct measurement of the thermodynamics of vinylarene hydroamination.
Journal of the American Chemical Society 2006;128(29):9306-7.
2006: Fujita Ken-ichi; Yamashita Makoto; Puschmann Florian; Alvarez-Falcon Miguel Martinez; Incarvito Christopher D; Hartwig John F
Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II).
Journal of the American Chemical Society 2006;128(28):9044-5.
2006: Sakai Norio; Ridder André; Hartwig John F
Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene.
Journal of the American Chemical Society 2006;128(25):8134-5.
2006: Takemiya Akihiro; Hartwig John F
Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines.
Journal of the American Chemical Society 2006;128(18):6042-3.
2006: Hama Takuo; Culkin Darcy A; Hartwig John F
Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions.
Journal of the American Chemical Society 2006;128(15):4976-85.
2006: Shekhar Shashank; Ryberg Per; Hartwig John F; Mathew Jinu S; Blackmond Donna G; Strieter Eric R; Buchwald Stephen L
Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.
Journal of the American Chemical Society 2006;128(11):3584-91.
2006: Zhao Pinjing; Incarvito Christopher D; Hartwig John F
Direct observation of beta-aryl eliminations from Rh(I) alkoxides.
Journal of the American Chemical Society 2006;128(10):3124-5.
2006: Shekhar Shashank; Ryberg Per; Hartwig John F
Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP).
Organic letters 2006;8(5):851-4.
2006: Fernández-Rodríguez Manuel A; Shen Qilong; Hartwig John F
A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols.
Journal of the American Chemical Society 2006;128(7):2180-1.
2006: Johns Adam M; Utsunomiya Masaru; Incarvito Christopher D; Hartwig John F
A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes.
Journal of the American Chemical Society 2006;128(6):1828-39.
2005: Graening Timm; Hartwig John F
Iridium-catalyzed regio- and enantioselective allylation of ketone enolates.
Journal of the American Chemical Society 2005;127(49):17192-3.
2005: Wu Lingyun; Hartwig John F
Mild palladium-catalyzed selective monoarylation of nitriles.
Journal of the American Chemical Society 2005;127(45):15824-32.
2005: Limmert Michael E; Roy Amy H; Hartwig John F
Kumada coupling of aryl and vinyl tosylates under mild conditions.
The Journal of organic chemistry 2005;70(23):9364-70.
2005: Leitner Andreas; Shekhar Shashank; Pouy Mark J; Hartwig John F
A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis.
Journal of the American Chemical Society 2005;127(44):15506-14.
2005: Boller Timothy M; Murphy Jaclyn M; Hapke Marko; Ishiyama Tatsuo; Miyaura Norio; Hartwig John F
Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes.
Journal of the American Chemical Society 2005;127(41):14263-78.
2005: Bae Chulsung; Hartwig John F; Chung Hoyong; Harris Nicole K; Switek Karen A; Hillmyer Marc A
Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups.
Angewandte Chemie (International ed. in English) 2005;44(39):6410-3.
2005: Zhao Pinjing; Krug Christopher; Hartwig John F
Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes.
Journal of the American Chemical Society 2005;127(34):12066-73.
2005: Zhao Pinjing; Hartwig John F
Beta-aryl eliminations from Rh(I) iminyl complexes.
Journal of the American Chemical Society 2005;127(33):11618-9.
2005: Yan X Z; Pawlas J; Goodson T; Hartwig J F
Polaron delocalization in ladder macromolecular systems.
Journal of the American Chemical Society 2005;127(25):9105-16.
2005: Barrios-Landeros Fabiola; Hartwig John F
Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands.
Journal of the American Chemical Society 2005;127(19):6944-5.
2005: Takaya Jun; Hartwig John F
Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through pi-Arene Complexes.
Journal of the American Chemical Society 2005;127(16):5756-7.
2005: Tsukada Naofumi; Hartwig John F
Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds.
Journal of the American Chemical Society 2005;127(14):5022-3.
2005: Lee Dae-Yon; Hartwig John F
Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates.
Organic letters 2005;7(6):1169-72.
2005: Leitner Andreas; Shu Chutian; Hartwig John F
Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides.
Organic letters 2005;7(6):1093-6.
2005: Hartwig John F; Cook Kevin S; Hapke Marko; Incarvito Christopher D; Fan Yubo; Webster Charles Edwin; Hall Michael B
Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes.
Journal of the American Chemical Society 2005;127(8):2538-52.
2005: Zhao Jing; Goldman Alan S; Hartwig John F
Oxidative addition of ammonia to form a stable monomeric amido hydride complex.
Science (New York, N.Y.) 2005;307(5712):1080-2.
2005: Shen Qilong; Shekhar Shashank; Stambuli James P; Hartwig John F
Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles.
Angewandte Chemie (International ed. in English) 2005;44(9):1371-5.
2005: Bae Chulsung; Hartwig John F; Boaen Harris Nicole K; Long Rachael O; Anderson Kelly S; Hillmyer Marc A
Catalytic hydroxylation of polypropylenes.
Journal of the American Chemical Society 2005;127(2):767-76.
2004: Lawrence Joshua D; Takahashi Makoto; Bae Chulsung; Hartwig John F
Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality.
Journal of the American Chemical Society 2004;126(47):15334-5.
2004: Leitner Andreas; Larsen Jens; Steffens Christian; Hartwig John F
Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes.
The Journal of organic chemistry 2004;69(22):7552-7.
2004: Cook Kevin S; Incarvito Christopher D; Webster Charles Edwin; Fan Yubo; Hall Michael B; Hartwig John F
Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen.
Angewandte Chemie (International ed. in English) 2004;43(41):5474-7.
2004: Shekhar Shashank; Hartwig John F
Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes.
Journal of the American Chemical Society 2004;126(40):13016-27.
2004: Shu Chutian; Leitner Andreas; Hartwig John F
Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst.
Angewandte Chemie (International ed. in English) 2004;43(36):4797-800.
2004: Shu Chutian; Hartwig John F
Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans.
Angewandte Chemie (International ed. in English) 2004;43(36):4794-7.
2004: Yamashita Makoto; Hartwig John F
Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes.
Journal of the American Chemical Society 2004;126(17):5344-5.
2004: Liu Xiaoxiang; Hartwig John F
Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives.
Journal of the American Chemical Society 2004;126(16):5182-91.
2004: Leitner Andreas; Shu Chutian; Hartwig John F
Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(16):5830-3.
2004: Utsunomiya Masaru; Hartwig John F
Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes.
Journal of the American Chemical Society 2004;126(9):2702-3.
2004: Krug Christopher; Hartwig John F
Imine insertion into a late metal-carbon bond to form a stable amido complex.
Journal of the American Chemical Society 2004;126(9):2694-5.
2004: Stambuli James P; Incarvito Christopher D; Bühl Michael; Hartwig John F
Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction.
Journal of the American Chemical Society 2004;126(4):1184-94.
2003: Yamashita Makoto; Cuevas Vicario Jose V; Hartwig John F
Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres.
Journal of the American Chemical Society 2003;125(52):16347-60.
2003: Ishiyama Tatsuo; Nobuta Yusuke; Hartwig John F; Miyaura Norio
Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.
Chemical communications (Cambridge, England) 2003;(23):2924-5.
2003: Utsunomiya Masaru; Hartwig John F
Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines.
Journal of the American Chemical Society 2003;125(47):14286-7.
2003: Kiener Christoph A; Shu Chutian; Incarvito Christopher; Hartwig John F
Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity.
Journal of the American Chemical Society 2003;125(47):14272-3.
2003: Roy Amy H; Hartwig John F
Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes.
Journal of the American Chemical Society 2003;125(46):13944-5.
2003: Hama Takuo; Liu Xiaoxiang; Culkin Darcy A; Hartwig John F
Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions.
Journal of the American Chemical Society 2003;125(37):11176-7.
2003: Roy Amy H; Hartwig John F
Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature.
Journal of the American Chemical Society 2003;125(29):8704-5.
2003: Stambuli James P; Hartwig John F
Recent advances in the discovery of organometallic catalysts using high-throughput screening assays.
Current opinion in chemical biology 2003;7(3):420-6.
2003: Stauffer Shaun R; Hartwig John F
Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study.
Journal of the American Chemical Society 2003;125(23):6977-85.
2003: Liu Xiaoxiang; Hartwig John F
Palladium-catalyzed alpha-arylation of azlactones to form quaternary amino acid derivatives.
Organic letters 2003;5(11):1915-8.
2003: Utsunomiya Masaru; Kuwano Ryoichi; Kawatsura Motoi; Hartwig John F
Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes.
Journal of the American Chemical Society 2003;125(19):5608-9.
2003: Culkin Darcy A; Hartwig John F
Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles.
Accounts of chemical research 2003;36(4):234-45.
2003: Hooper Mark W; Utsunomiya Masaru; Hartwig John F
Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides.
The Journal of organic chemistry 2003;68(7):2861-73.
2003: López Fernando; Ohmura Toshimichi; Hartwig John F
Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides.
Journal of the American Chemical Society 2003;125(12):3426-7.
2003: Webster Charles Edwin; Fan Yubo; Hall Michael B; Kunz Doris; Hartwig John F
Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation.
Journal of the American Chemical Society 2003;125(4):858-9.
2003: Utsunomiya Masaru; Kawatsura Motoi; Hartwig John F
Palladium-catalyzed equilibrium addition of acidic OH groups across dienes.
Angewandte Chemie (International ed. in English) 2003;42(47):5865-8.
2002: Ohmura Toshimichi; Hartwig John F
Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex.
Journal of the American Chemical Society 2002;124(51):15164-5.
2002: Stambuli James P; Kuwano Ryoichi; Hartwig John F
Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature.
Angewandte Chemie (International ed. in English) 2002;41(24):4746-8.
2002: Wolkowski Joanna P; Hartwig John F
Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions.
Angewandte Chemie (International ed. in English) 2002;41(22):4289-91.
2002: Jørgensen Morten; Lee Sunwoo; Liu Xiaoxiang; Wolkowski Joanna P; Hartwig John F
Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates.
Journal of the American Chemical Society 2002;124(42):12557-65.
2002: Hartwig John F
Chemical synthesis. Raising the bar for the "perfect reaction".
Science (New York, N.Y.) 2002;297(5587):1653-4.
2002: Kuwano Ryoichi; Utsunomiya Masaru; Hartwig John F
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
The Journal of organic chemistry 2002;67(18):6479-86.
2002: Ishiyama Tatsuo; Takagi Jun; Hartwig John F; Miyaura Norio
A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature.
Angewandte Chemie (International ed. in English) 2002;41(16):3056-8.
2002: Stambuli James P; Bühl Michael; Hartwig John F
Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand.
Journal of the American Chemical Society 2002;124(32):9346-7.
2002: Culkin Darcy A; Hartwig John F
Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.
Journal of the American Chemical Society 2002;124(32):9330-1.
2002: Kataoka Noriyasu; Shelby Quinetta; Stambuli James P; Hartwig John F
Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings.
The Journal of organic chemistry 2002;67(16):5553-66.
2002: Ranasinghe Mahinda I; Varnavski Oleg P; Pawlas Jan; Hauck Sheila I; Louie Janis; Hartwig John F; Goodson Theodore
Femtosecond excitation energy transport in triarylamine dendrimers.
Journal of the American Chemical Society 2002;124(23):6520-1.
2002: Schlummer Björn; Hartwig John F
Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines.
Organic letters 2002;4(9):1471-4.
2002: Pawlas Jan; Nakao Yoshiaki; Kawatsura Motoi; Hartwig John F
A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism.
Journal of the American Chemical Society 2002;124(14):3669-79.
2002: Krug Christopher; Hartwig John F
Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes.
Journal of the American Chemical Society 2002;124(8):1674-9.
2002: Nettekoven Ulrike; Hartwig John F
A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes.
Journal of the American Chemical Society 2002;124(7):1166-7.
2002: Kondo Yuichiro; García-Cuadrado Domingo; Hartwig John F; Boaen Nicole K; Wagner Nicole L; Hillmyer Marc A
Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt.
Journal of the American Chemical Society 2002;124(7):1164-5.
2002: Beare Neil A; Hartwig John F
Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands.
The Journal of organic chemistry 2002;67(2):541-55.
2002: Ishiyama Tatsuo; Takagi Jun; Ishida Kousaku; Miyaura Norio; Anastasi Natia R; Hartwig John F
Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate.
Journal of the American Chemical Society 2002;124(3):390-1.
2001: Alcazar-Roman L M; Hartwig J F
Mechanism of aryl chloride amination: base-induced oxidative addition.
Journal of the American Chemical Society 2001;123(51):12905-6.
2001: Kawamura K; Hartwig J F
Isolated Ir(V) boryl complexes and their reactions with hydrocarbons.
Journal of the American Chemical Society 2001;123(34):8422-3.
2001: Lee S; Beare N A; Hartwig J F
Palladium-catalyzed alpha-arylation of esters and protected amino acids.
Journal of the American Chemical Society 2001;123(34):8410-1.
2001: Lee S; Jørgensen M; Hartwig J F
Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.
Organic letters 2001;3(17):2729-32.
2001: Zhao J; Hesslink H; Hartwig J F
Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands.
Journal of the American Chemical Society 2001;123(30):7220-7.
2001: Culkin D A; Hartwig J F
C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates.
Journal of the American Chemical Society 2001;123(24):5816-7.
2001: Stauffer S R; Beare N A; Stambuli J P; Hartwig J F
Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery.
Journal of the American Chemical Society 2001;123(19):4641-2.
2001: Löber O; Kawatsura M; Hartwig J F
Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.
Journal of the American Chemical Society 2001;123(18):4366-7.
2001: Lee S; Hartwig J F
Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations.
The Journal of organic chemistry 2001;66(10):3402-15.
2001: Stambuli J P; Stauffer S R; Shaughnessy K H; Hartwig J F
Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions.
Journal of the American Chemical Society 2001;123(11):2677-8.
2001: Roy A H; Hartwig J F
Reductive elimination of aryl halides from palladium(II).
Journal of the American Chemical Society 2001;123(6):1232-3.
2000: Stauffer S R; Lee S; Stambuli J P; Hauck S I; Hartwig J F
High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.
Organic letters 2000;2(10):1423-6.

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