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Tamio Hayashi

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Co-Publications
Name
38
Shintani, Ryo
16
Nishimura, Takahiro
13
Tokunaga, Norihito
12
Sakai, Fukumi
11
Okamoto, Kazuhiro
9
Ogasawara, Masamichi
8
Shimada, Toyoshi
8
Shirakawa, Eiji
7
Kina, Asato
6
Nagano, Takashi
6
Nakai, T
6
Duan, Wei-Liang
6
Tonouchi, Naoto
6
Tsuchida, Takayasu
6
Ueyama, Kazuhito

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Publications

TOP 3
Nishimura Takahiro; Kumamoto Hana; Nagaosa Makoto; Hayashi Tamio
The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes.
Shintani Ryo; Tsutsumi Yosuke; Nagaosa Makoto; Nishimura Takahiro; Hayashi Tamio
Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters.
Shintani Ryo; Nakatsu Hiroki; Takatsu Keishi; Hayashi Tamio
Rhodium-catalyzed asymmetric [5+2] cycloaddition of alkyne-vinylcyclopropanes.

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All Publications

2009: Nishimura Takahiro; Kumamoto Hana; Nagaosa Makoto; Hayashi Tamio
The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes.
Chemical communications (Cambridge, England) 2009;(38):5713-5.
2009: Shintani Ryo; Tsutsumi Yosuke; Nagaosa Makoto; Nishimura Takahiro; Hayashi Tamio
Sodium tetraarylborates as effective nucleophiles in rhodium/diene-catalyzed 1,4-addition to beta,beta-disubstituted alpha,beta-unsaturated ketones: catalytic asymmetric construction of quaternary carbon stereocenters.
Journal of the American Chemical Society 2009;131(38):13588-9.
2009: Shintani Ryo; Nakatsu Hiroki; Takatsu Keishi; Hayashi Tamio
Rhodium-catalyzed asymmetric [5+2] cycloaddition of alkyne-vinylcyclopropanes.
Chemistry (Weinheim an der Bergstrasse, Germany) 2009;15(35):8692-4.
2009: Okamoto Kazuhiro; Hayashi Tamio; Rawal Viresh H
Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines.
Chemical communications (Cambridge, England) 2009;(32):4815-7.
2009: Shintani Ryo; Hayashi Shin-ya; Murakami Masataka; Takeda Momotaro; Hayashi Tamio
Stereoselective synthesis of spirooxindoles by palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with isatins.
Organic letters 2009;11(16):3754-6.
2009: Nishimura Takahiro; Tokuji Sumito; Sawano Takahiro; Hayashi Tamio
Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols.
Organic letters 2009;11(15):3222-5.
2009: Kawamoto Takahiro; Hirabayashi Sho; Guo Xun-Xiang; Nishimura Takahiro; Hayashi Tamio
Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes.
Chemical communications (Cambridge, England) 2009;(24):3528-30.
2009: Shirakawa Eiji; Ikeda Daiji; Ozawa Tsubasa; Watanabe Shogo; Hayashi Tamio
Iron-catalyzed carbolithiation of alkynes having no heteroatoms.
Chemical communications (Cambridge, England) 2009;(14):1885-7.
2009: Shintani Ryo; Murakami Masataka; Hayashi Tamio
Stereoselective synthesis of nipecotic acid derivatives via palladium-catalyzed decarboxylative cyclization of gamma-methylidene-delta-valerolactones with imines.
Organic letters 2009;11(2):457-9.
2009: Shintani Ryo; Ichikawa Yoshitaka; Takatsu Keishi; Chen Fu-Xue; Hayashi Tamio
Tuning the chiral environment of C2-symmetric diene ligands: development of 3,7-disubstituted bicyclo[3.3.1]nona-2,6-dienes.
The Journal of organic chemistry 2009;74(2):869-73.
2009: Nishimura Takahiro; Sawano Takahiro; Hayashi Tamio
Asymmetric synthesis of beta-alkynyl aldehydes by rhodium-catalyzed conjugate alkynylation.
Angewandte Chemie (International ed. in English) 2009;48(43):8057-9.
2008: Shintani Ryo; Park Soyoung; Shirozu Fumitaka; Murakami Masataka; Hayashi Tamio
Palladium-catalyzed asymmetric decarboxylative lactamization of gamma-methylidene-delta-valerolactones with isocyanates: conversion of racemic lactones to enantioenriched lactams.
Journal of the American Chemical Society 2008;130(48):16174-5.
2008: Okamoto Kazuhiro; Hayashi Tamio; Rawal Viresh H
Simple chiral diene ligands provide high enantioselectivities in transition-metal-catalyzed conjugate addition reactions.
Organic letters 2008;10(19):4387-9.
2008: Nishimura Takahiro; Guo Xun-Xiang; Hayashi Tamio
Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes.
Chemistry, an Asian journal 2008;3(8-9):1505-10.
2008: Shirakawa Eiji; Ikeda Daiji; Yamaguchi Shigeru; Hayashi Tamio
Fe-Cu cooperative catalysis in the isomerization of alkyl Grignard reagents.
Chemical communications (Cambridge, England) 2008;(10):1214-6.
2008: Shintani Ryo; Takatsu Keishi; Hayashi Tamio
Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage.
Organic letters 2008;10(6):1191-3.
2008: Sörgel Sebastian; Tokunaga Norihito; Sasaki Keigo; Okamoto Kazuhiro; Hayashi Tamio
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates.
Organic letters 2008;10(4):589-92.
2008: Nishimura Takahiro; Guo Xun-Xiang; Uchiyama Nanase; Katoh Taisuke; Hayashi Tamio
Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones.
Journal of the American Chemical Society 2008;130(5):1576-7.
2008: Shintani Ryo; Takatsu Keishi; Katoh Taisuke; Nishimura Takahiro; Hayashi Tamio
Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones.
Angewandte Chemie (International ed. in English) 2008;47(8):1447-9.
2007: Shintani Ryo; Park Soyoung; Hayashi Tamio
Palladium-catalyzed synthesis of spiro[2.4]heptanes: ligand-dependent position control in the nucleophilic attack to a pi-allylpalladium intermediate.
Journal of the American Chemical Society 2007;129(48):14866-7.
2007: Okamoto Kazuhiro; Hayashi Tamio
Platinum-catalyzed addition of dimethylsilylene to beta-methyl alpha,beta-unsaturated ketones: gamma-silylation forming 1-oxa-2-silacyclohex-5-enes.
Organic letters 2007;9(24):5067-9.
2007: Shirakawa Eiji; Sato Takahiro; Imazaki Yusuke; Kimura Takahiro; Hayashi Tamio
Cobalt-catalyzed cross-coupling of alkynyl Grignard reagents with alkenyl triflates.
Chemical communications (Cambridge, England) 2007;(43):4513-5.
2007: Nishimura Takahiro; Katoh Taisuke; Takatsu Keishi; Shintani Ryo; Hayashi Tamio
Rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols: synthetic equivalent to asymmetric conjugate alkynylation of enones.
Journal of the American Chemical Society 2007;129(46):14158-9.
2007: Shintani Ryo; Ichikawa Yoshitaka; Hayashi Tamio; Chen Jinshui; Nakao Yoshiaki; Hiyama Tamejiro
Catalytic asymmetric synthesis of allylsilanes through rhodium/chiral diene-catalyzed 1,4-addition of alkenyl[2-(hydroxymethyl)phenyl]dimethylsilanes.
Organic letters 2007;9(22):4643-5.
2007: Shintani Ryo; Murakami Masataka; Hayashi Tamio
Gamma-methylidene-delta-valerolactones as a coupling partner for cycloaddition: palladium-catalyzed [4 + 3] cycloaddition with nitrones.
Journal of the American Chemical Society 2007;129(41):12356-7.
2007: Nakao Yoshiaki; Chen Jinshui; Imanaka Hidekazu; Hiyama Tamejiro; Ichikawa Yoshitaka; Duan Wei-Liang; Shintani Ryo; Hayashi Tamio
Organo[2-(hydroxymethyl)phenyl]dimethylsilanes as mild and reproducible agents for rhodium-catalyzed 1,4-addition reactions.
Journal of the American Chemical Society 2007;129(29):9137-43.
2007: Nishimura Takahiro; Yasuhara Yuichi; Hayashi Tamio
Iridium-catalyzed [3 + 2] annulation of 1,3-dienes with ortho-carbonylated phenylboronic acids. A catalytic process involving regioselective 1,2-addition.
Journal of the American Chemical Society 2007;129(24):7506-7.
2007: Otsuka Hidehito; Shirakawa Eiji; Hayashi Tamio
Palladium-catalyzed conjugate reduction of enones into alpha,beta-dideuterioketones with hexamethyldisilane and deuterium oxide.
Chemical communications (Cambridge, England) 2007;(18):1819-21.
2007: Yamagami Takafumi; Shintani Ryo; Shirakawa Eiji; Hayashi Tamio
Iron-catalyzed arylmagnesiation of aryl(alkyl)acetylenes in the presence of an N-heterocyclic carbene ligand.
Organic letters 2007;9(6):1045-8.
2007: Nishimura Takahiro; Kawamoto Takahiro; Sasaki Keigo; Tsurumaki Eiji; Hayashi Tamio
Rhodium-catalyzed asymmetric cyclodimerization of oxa- and azabicyclic alkenes.
Journal of the American Chemical Society 2007;129(6):1492-3.
2007: Duan Wei-Liang; Iwamura Hiroshi; Shintani Ryo; Hayashi Tamio
Chiral phosphine-olefin ligands in the rhodium-catalyzed asymmetric 1,4-addition reactions.
Journal of the American Chemical Society 2007;129(7):2130-8.
2007: Shintani Ryo; Hayashi Tamio
Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones.
Nature protocols 2007;2(11):2903-9.
2007: Shintani Ryo; Sannohe Yuta; Tsuji Takaoki; Hayashi Tamio
A cationic rhodium-chiral diene complex as a high-performance catalyst for the intramolecular asymmetric [4+2] cycloaddition of alkyne-1,3-dienes.
Angewandte Chemie (International ed. in English) 2007;46(38):7277-80.
2007: Shintani Ryo; Park Soyoung; Duan Wei-Liang; Hayashi Tamio
Palladium-catalyzed asymmetric [3+3] cycloaddition of trimethylenemethane derivatives with nitrones.
Angewandte Chemie (International ed. in English) 2007;46(31):5901-3.
2007: Nishimura Takahiro; Katoh Taisuke; Hayashi Tamio
Rhodium-catalyzed aryl transfer from trisubstituted aryl methanols to alpha,beta-unsaturated carbonyl compounds.
Angewandte Chemie (International ed. in English) 2007;46(26):4937-9.
2007: Shintani Ryo; Takatsu Keishi; Hayashi Tamio
Rhodium-catalyzed asymmetric synthesis of 3,3-disubstituted 1-indanones.
Angewandte Chemie (International ed. in English) 2007;46(20):3735-7.
2006: Kina Asato; Yasuhara Yuichi; Nishimura Takahiro; Iwamura Hiroshi; Hayashi Tamio
Kinetic studies prove high catalytic activity of a diene-rhodium complex in 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones.
Chemistry, an Asian journal 2006;1(5):707-11.
2006: Berthon-Gelloz Guillaume; Hayashi Tamio
Expanding the C2-symmetric bicyclo[2.2.1]hepta-2,5-diene ligand family: concise synthesis and catalytic activity in rhodium-catalyzed asymmetric addition.
The Journal of organic chemistry 2006;71(23):8957-60.
2006: Shirakawa Eiji; Hironaka Koji; Otsuka Hidehito; Hayashi Tamio
Palladium-catalyzed silylation of alcohols with hexamethyldisilane.
Chemical communications (Cambridge, England) 2006;(37):3927-9.
2006: Shintani Ryo; Yamagami Takafumi; Hayashi Tamio
Rhodium-catalyzed multicomponent-coupling reactions involving a carborhodation-cross-coupling sequence.
Organic letters 2006;8(21):4799-801.
2006: Shintani Ryo; Duan Wei-Liang; Park Soyoung; Hayashi Tamio
Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes.
Chemical communications (Cambridge, England) 2006;(34):3646-7.
2006: Nishimura Takahiro; Yasuhara Yuichi; Hayashi Tamio
Highly selective 1,6-addition of aryl boronic acids to alpha,beta,gamma,delta-unsaturated carbonyl compounds catalyzed by an iridium complex.
Angewandte Chemie (International ed. in English) 2006;45(31):5164-6.
2006: Shintani Ryo; Hayashi Tamio
Palladium-catalyzed [3 + 3] cycloaddition of trimethylenemethane with azomethine imines.
Journal of the American Chemical Society 2006;128(19):6330-1.
2006: Shintani Ryo; Duan Wei-Liang; Hayashi Tamio
Rhodium-catalyzed asymmetric construction of quaternary carbon stereocenters: ligand-dependent regiocontrol in the 1,4-addition to substituted maleimides.
Journal of the American Chemical Society 2006;128(17):5628-9.
2006: Shintani Ryo; Inoue Mitsunori; Hayashi Tamio
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins.
Angewandte Chemie (International ed. in English) 2006;45(20):3353-6.
2006: Kina Asato; Iwamura Hiroshi; Hayashi Tamio
A kinetic study on Rh/binap-catalyzed 1,4-addition of phenylboronic acid to enones: negative nonlinear effect caused by predominant homochiral dimer contribution.
Journal of the American Chemical Society 2006;128(12):3904-5.
2006: Shintani Ryo; Yashio Keiji; Nakamura Tomoaki; Okamoto Kazuhiro; Shimada Toyoshi; Hayashi Tamio
Rhodium-catalyzed asymmetric synthesis of indanones: development of a new "axially chiral" bisphosphine ligand.
Journal of the American Chemical Society 2006;128(9):2772-3.
2006: Nishimura Takahiro; Yasuhara Yuichi; Hayashi Tamio
Asymmetric addition of dimethylzinc to N-tosylarylimines catalyzed by a rhodium-diene complex toward the synthesis of chiral 1-arylethylamines.
Organic letters 2006;8(5):979-81.
2006: Nishimura Takahiro; Hirabayashi Sho; Yasuhara Yuichi; Hayashi Tamio
Rhodium-catalyzed asymmetric hydroarylation of diphenylphosphinylallenes with arylboronic acids.
Journal of the American Chemical Society 2006;128(8):2556-7.
2006: Chen Fu-Xue; Kina Asato; Hayashi Tamio
High performance of a chiral diene-rhodium catalyst for the asymmetric 1,4-addition of arylboroxines to alpha,beta-unsaturated ketones.
Organic letters 2006;8(2):341-4.
2005: Kina Asato; Ueyama Kazuhito; Hayashi Tamio
Enantiomerically pure rhodium complexes bearing 1,5-diphenyl-1,5-cyclooctadiene as a chiral diene ligand. Their use as catalysts for asymmetric 1,4-addition of phenylzinc chloride.
Organic letters 2005;7(26):5889-92.
2005: Shirakawa Eiji; Yamagami Takafumi; Kimura Takahiro; Yamaguchi Shigeru; Hayashi Tamio
Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes.
Journal of the American Chemical Society 2005;127(49):17164-5.
2005: Shirakawa Eiji; Otsuka Hidehito; Hayashi Tamio
Reduction of alkynes into 1,2-dideuterioalkenes with hexamethyldisilane and deuterium oxide in the presence of a palladium catalyst.
Chemical communications (Cambridge, England) 2005;(47):5885-6.
2005: Shintani Ryo; Yamagami Takafumi; Kimura Takahiro; Hayashi Tamio
Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane.
Organic letters 2005;7(23):5317-9.
2005: Shintani Ryo; Okamoto Kazuhiro; Hayashi Tamio
Carbon-carbon bond-forming enantioselective synthesis of chiral organosilicon compounds by rhodium/chiral diene-catalyzed asymmetric 1,4-addition reaction.
Organic letters 2005;7(21):4757-9.
2005: Shintani Ryo; Duan Wei-Liang; Nagano Takashi; Okada Atsushi; Hayashi Tamio
Chiral phosphine-olefin bidentate ligands in asymmetric catalysis: rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to maleimides.
Angewandte Chemie (International ed. in English) 2005;44(29):4611-4.
2005: Shintani Ryo; Kimura Takahiro; Hayashi Tamio
Rhodium/diene-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated Weinreb amides.
Chemical communications (Cambridge, England) 2005;(25):3213-4.
2005: Hayashi Tamio; Yamamoto Shohei; Tokunaga Norihito
Rhodium-catalyzed asymmetric 1,6-addition of aryl zinc reagents to dienones.
Angewandte Chemie (International ed. in English) 2005;44(27):4224-7.
2005: Shintani Ryo; Tsurusaki Akihiro; Okamoto Kazuhiro; Hayashi Tamio
Highly chemo- and enantioselective arylative cyclization of alkyne-tethered electron-deficient olefins catalyzed by rhodium complexes with chiral dienes.
Angewandte Chemie (International ed. in English) 2005;44(25):3909-12.
2005: Chen Gang; Tokunaga Norihito; Hayashi Tamio
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine.
Organic letters 2005;7(11):2285-8.
2005: Shintani Ryo; Hayashi Tamio
Rhodium-catalyzed addition of arylzinc reagents to aryl alkynyl ketones: synthesis of beta,beta-disubstituted indanones.
Organic letters 2005;7(10):2071-3.
2005: Otomaru Yusuke; Okamoto Kazuhiro; Shintani Ryo; Hayashi Tamio
Preparation of C2-symmetric bicyclo[2.2.2]octa-2,5-diene ligands and their use for rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids.
The Journal of organic chemistry 2005;70(7):2503-8.
2005: Shintani Ryo; Okamoto Kazuhiro; Hayashi Tamio
Rhodium-catalyzed isomerization of alpha-arylpropargyl alcohols to indanones: involvement of an unexpected reaction cascade.
Journal of the American Chemical Society 2005;127(9):2872-3.
2005: Nagano Takashi; Hayashi Tamio
Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents.
Organic letters 2005;7(3):491-3.
2005: Otomaru Yusuke; Tokunaga Norihito; Shintani Ryo; Hayashi Tamio
C2-symmetric bicyclo[3.3.1]nonadiene as a chiral ligand for rhodium-catalyzed asymmetric arylation of N-(4-nitrobenzenesulfonyl)arylimines.
Organic letters 2005;7(2):307-10.
2005: Shintani Ryo; Okamoto Kazuhiro; Otomaru Yusuke; Ueyama Kazuhito; Hayashi Tamio
Catalytic asymmetric arylative cyclization of alkynals: phosphine-free rhodium/diene complexes as efficient catalysts.
Journal of the American Chemical Society 2005;127(1):54-5.
2004: Hayashi Tamio; Kawai Masahiro; Tokunaga Norihito
Asymmetric synthesis of diarylmethyl amines by rhodium-catalyzed asymmetric addition of aryl titanium reagents to imines.
Angewandte Chemie (International ed. in English) 2004;43(45):6125-8.
2004: Tokunaga Norihito; Otomaru Yusuke; Okamoto Kazuhiro; Ueyama Kazuhito; Shintani Ryo; Hayashi Tamio
C2-symmetric bicyclo[2.2.2]octadienes as chiral ligands: their high performance in rhodium-catalyzed asymmetric arylation of N-tosylarylimines.
Journal of the American Chemical Society 2004;126(42):13584-5.
2004: Shintani Ryo; Ueyama Kazuhito; Yamada Ichiro; Hayashi Tamio
Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds.
Organic letters 2004;6(19):3425-7.
2004: Otomaru Yusuke; Senda Taichi; Hayashi Tamio
Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water.
Organic letters 2004;6(19):3357-9.
2004: Cho Yong-Hwan; Kina Asato; Shimada Toyoshi; Hayashi Tamio
Asymmetric synthesis of axially chiral biaryls by nickel-catalyzed grignard cross-coupling of dibenzothiophenes.
The Journal of organic chemistry 2004;69(11):3811-23.
2004: Shintani Ryo; Tokunaga Norihito; Doi Hidenori; Hayashi Tamio
A new entry of nucleophiles in rhodium-catalyzed asymmetric 1,4-addition reactions: addition of organozinc reagents for the synthesis of 2-aryl-4-piperidones.
Journal of the American Chemical Society 2004;126(20):6240-1.
2004: Nagano Takashi; Hayashi Tamio
Iron-catalyzed Grignard cross-coupling with alkyl halides possessing beta-hydrogens.
Organic letters 2004;6(8):1297-9.
2004: Tokunaga Norihito; Yoshida Kazuhiro; Hayashi Tamio
Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to alpha,beta-unsaturated ketones.
Proceedings of the National Academy of Sciences of the United States of America 2004;101(15):5445-9.
2004: Hayashi Tamio; Yamasaki Kaori; Mimura Michihiro; Uozumi Yasuhiro
Deuterium-labeling studies establishing stereochemistry at the oxypalladation step in Wacker-type oxidative cyclization of an o-allylphenol.
Journal of the American Chemical Society 2004;126(10):3036-7.
2004: Hayashi Tamio; Tokunaga Norihito; Inoue Kazuya
Rhodium-catalyzed asymmetric 1,6-addition of aryltitanates to enynones giving axially chiral allenes.
Organic letters 2004;6(2):305-7.
2003: Hayashi Tamio; Ueyama Kazuhito; Tokunaga Norihito; Yoshida Kazuhiro
A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition.
Journal of the American Chemical Society 2003;125(38):11508-9.
2003: Hayashi Tamio; Yamasaki Kaori
Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions.
Chemical reviews 2003;103(8):2829-44.
2003: Shimada Toyoshi; Kina Asato; Hayashi Tamio
A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes.
The Journal of organic chemistry 2003;68(16):6329-37.
2003: Hayashi Tamio; Okada Atsushi; Suzuka Toshimasa; Kawatsura Motoi
High enantioselectivity in rhodium-catalyzed allylic alkylation of 1-substituted 2-propenyl acetates.
Organic letters 2003;5(10):1713-5.
2003: Shimada Toyoshi; Aoki Kazuko; Shinoda Yo; Nakamura Tomoaki; Tokunaga Norihito; Inagaki Shinji; Hayashi Tamio
Functionalization on silica gel with allylsilanes. A new method of covalent attachment of organic functional groups on silica gel.
Journal of the American Chemical Society 2003;125(16):4688-9.
2003: Yoshida Kazuhiro; Hayashi Tamio
A new cine-substitution of alkenyl sulfones with aryltitanium reagents catalyzed by rhodium: mechanistic studies and catalytic asymmetric synthesis of allylarenes.
Journal of the American Chemical Society 2003;125(10):2872-3.
2003: Yoshida Kazuhiro; Ogasawara Masamichi; Hayashi Tamio
Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones.
The Journal of organic chemistry 2003;68(5):1901-5.
2003: Ogasawara Masamichi; Ueyama Kazuhito; Nagano Takashi; Mizuhata Yoshiyuki; Hayashi Tamio
Palladium-catalyzed asymmetric synthesis of axially chiral (allenylmethyl)silanes and chirality transfer to stereogenic carbon centers in S(E)' reactions.
Organic letters 2003;5(2):217-9.
2002: Shimada Toyoshi; Cho Yong-Hwan; Hayashi Tamio
Nickel-catalyzed asymmetric grignard cross-coupling of dinaphthothiophene giving axially chiral 1,1'-binaphthyls.
Journal of the American Chemical Society 2002;124(45):13396-7.
2002: Hayashi Tamio; Tokunaga Norihito; Yoshida Kazuhiro; Han Jin Wook
Rhodium-catalyzed asymmetric 1,4-addition of aryltitanium reagents generating chiral titanium enolates: isolation as silyl enol ethers.
Journal of the American Chemical Society 2002;124(41):12102-3.
2002: Yoshida Kazuhiro; Ogasawara Masamichi; Hayashi Tamio
A new type of catalytic tandem 1,4-addition-aldol reaction which proceeds through an (oxa-pi-allyl)rhodium intermediate.
Journal of the American Chemical Society 2002;124(37):10984-5.
2002: Shimada Toyoshi; Kina Asato; Ikeda Syushiro; Hayashi Tamio
A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst.
Organic letters 2002;4(16):2799-801.
2002: Ogasawara Masamichi; Nagano Takashi; Hayashi Tamio
Metathesis route to bridged metallocenes.
Journal of the American Chemical Society 2002;124(31):9068-9.
2002: Suzuka Toshimasa; Ogasawara Masamichi; Hayashi Tamio
Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene.
The Journal of organic chemistry 2002;67(10):3355-9.
2002: Hayashi Tamio; Takahashi Makoto; Takaya Yoshiaki; Ogasawara Masamichi
Catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of organoboronic acids. Arylrhodium, oxa-pi-allylrhodium, and hydroxorhodium intermediates.
Journal of the American Chemical Society 2002;124(18):5052-8.
2002: Shimada Toyoshi; Mukaide Kotaro; Shinohara Akihiro; Han Jin Wook; Hayashi Tamio
Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step.
Journal of the American Chemical Society 2002;124(8):1584-5.
2001: Shimada T; Kurushima H; Cho Y H; Hayashi T
Preparation of enantiomerically pure 2'-substituted 2-diphenylphosphino-1,1'-binaphthyls by reductive cleavage of the carbon-phosphorus bond in a borane complex of 2-diphenylphosphino-2'-diphenylphosphinyl-1,1'-binaphthyl.
The Journal of organic chemistry 2001;66(26):8854-8.
2001: Han J W; Tokunaga N; Hayashi T
Palladium-catalyzed asymmetric hydrosilylation of 4-substituted 1-buten-3-ynes. Catalytic asymmetric synthesis of axially chiral allenylsilanes.
Journal of the American Chemical Society 2001;123(51):12915-6.
2001: Senda T; Ogasawara M; Hayashi T
Rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents to 5,6-dihydro-2(1H)-pyridinones. Asymmetric synthesis of 4-aryl-2-piperidinones.
The Journal of organic chemistry 2001;66(21):6852-6.
2001: Hayashi T; Inoue K; Taniguchi N; Ogasawara M
Rhodium-catalyzed hydroarylation of alkynes with arylboronic acids: 1,4-shift of rhodium from 2-aryl-1-alkenylrhodium to 2-alkenylarylrhodium intermediate.
Journal of the American Chemical Society 2001;123(40):9918-9.
2001: Ogasawara M; Ikeda H; Nagano T; Hayashi T
Chloroprene as a source of fine chemicals: palladium-catalyzed synthesis of terminal allenes.
Organic letters 2001;3(16):2615-7.
2001: Hayashi T; Hirate S; Kitayama K; Tsuji H; Torii A; Uozumi Y
Asymmetric hydrosilylation of styrenes catalyzed by palladium-MOP complexes: ligand modification and mechanistic studies.
The Journal of organic chemistry 2001;66(4):1441-9.
2000: Ohmiya Y; Samejima M; Shiroishi M; Amano Y; Kanda T; Sakai F; Hayashi T
Evidence that endo-1,4-beta-glucanases act on cellulose in suspension-cultured poplar cells.
The Plant journal : for cell and molecular biology 2000;24(2):147-58.
2000: Hayashi T
Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions.
Accounts of chemical research 2000;33(6):354-62.
2000: Takeda T; Sakai F; Hayashi T
A homologue of EGL1 encoding endo-1,4-beta-glucanase in elongating pea stems.
Bioscience, biotechnology, and biochemistry 2000;64(3):636-40.
1999: Nakai T; Tonouchi N; Konishi T; Kojima Y; Tsuchida T; Yoshinaga F; Sakai F; Hayashi T
Enhancement of cellulose production by expression of sucrose synthase in Acetobacter xylinum.
Proceedings of the National Academy of Sciences of the United States of America 1999;96(1):14-8.
1998: Nakai T; Konishi T; Zhang X Q; Chollet R; Tonouchi N; Tsuchida T; Yoshinaga F; Mori H; Sakai F; Hayashi T
An increase in apparent affinity for sucrose of mung bean sucrose synthase is caused by in vitro phosphorylation or directed mutagenesis of Ser11.
Plant & cell physiology 1998;39(12):1337-41.
1998: Hirai N; Sonobe S; Hayashi T
In situ synthesis of beta-glucan microfibrils on tobacco plasma membrane sheets.
Proceedings of the National Academy of Sciences of the United States of America 1998;95(25):15102-6.
1998: Nakai T; Moriya A; Tonouchi N; Tsuchida T; Yoshinaga F; Horinouchi S; Sone Y; Mori H; Sakai F; Hayashi T
Control of expression by the cellulose synthase (bcsA) promoter region from Acetobacter xylinum BPR 2001.
Gene 1998;213(1-2):93-100.
1997: Hayashi T
[Xyloglucan]
Seikagaku. The Journal of Japanese Biochemical Society 1997;69(12):1392-7.
1997: Nakai T; Tonouchi N; Tsuchida T; Mori H; Sakai F; Hayashi T
Synthesis of asymmetrically labeled sucrose by a recombinant sucrose synthase.
Bioscience, biotechnology, and biochemistry 1997;61(11):1955-6.
1997: Tonouchi N; Tahara N; Kojima Y; Nakai T; Sakai F; Hayashi T; Tsuchida T; Yoshinaga F
A beta-glucosidase gene downstream of the cellulose synthase operon in cellulose-producing Acetobacter.
Bioscience, biotechnology, and biochemistry 1997;61(10):1789-90.
1997: Nakai T; Tonouchi N; Tsuchida T; Mori H; Sakai F; Hayashi T
Expression and characterization of sucrose synthase from mung bean seedlings in Escherichia coli.
Bioscience, biotechnology, and biochemistry 1997;61(9):1500-3.
1997: Shimizu Y; Aotsuka S; Hasegawa O; Kawada T; Sakuno T; Sakai F; Hayashi T
Changes in levels of mRNAs for cell wall-related enzymes in growing cotton fiber cells.
Plant & cell physiology 1997;38(3):375-8.
1996: Takeda T; Mitsuishi Y; Sakai F; Hayashi T
Xyloglucan endotransglycosylation in suspension-cultured poplar cells.
Bioscience, biotechnology, and biochemistry 1996;60(12):1950-5.
1995: Nakamura S; Mori H; Sakai F; Hayashi T
Cloning and sequencing of a cDNA for poplar endo-1,4-beta-glucanase.
Plant & cell physiology 1995;36(7):1229-35.
1995: Ohmiya Y; Takeda T; Nakamura S; Sakai F; Hayashi T
Purification and properties of wall-bound endo-1, 4-beta-glucanase from suspension-cultured poplar cells.
Plant & cell physiology 1995;36(4):607-14.
1994: Hayashi T; Takeda T; Ogawa K; Mitsuishi Y
Effects of the degree of polymerization on the binding of xyloglucans to cellulose.
Plant & cell physiology 1994;35(6):893-9.
1994: Hayashi T; Takeda T
Compositional analysis of the oligosaccharide units of xyloglucans from suspension-cultured poplar cells.
Bioscience, biotechnology, and biochemistry 1994;58(9):1707-8.

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