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Kenneth Karlin

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Saya Kakuda; Kenneth D Karlin; Kei Ohkubo; Ryan L Peterson; Shunichi Fukuzumi
Enhanced Catalytic Four-Electron Dioxygen (O2) and Two-Electron Hydrogen Peroxide (H2O2) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group.
Sunghee Kim; Claudio Saracini; Maxime A Siegler; Natalia Drichko; Kenneth D Karlin
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.
Shabnam Hematian; Maxime A Siegler; Kenneth D Karlin
Heme/copper assembly mediated nitrite and nitric oxide interconversion.

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All Publications

2013: Saya Kakuda; Kenneth D Karlin; Kei Ohkubo; Ryan L Peterson; Shunichi Fukuzumi
Enhanced Catalytic Four-Electron Dioxygen (O2) and Two-Electron Hydrogen Peroxide (H2O2) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group.
Journal of the American Chemical Society 2013;135(17):6513-22.
2012: Sunghee Kim; Claudio Saracini; Maxime A Siegler; Natalia Drichko; Kenneth D Karlin
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.
Inorganic chemistry 2012;51(23):12603-5.
2012: Shabnam Hematian; Maxime A Siegler; Kenneth D Karlin
Heme/copper assembly mediated nitrite and nitric oxide interconversion.
Journal of the American Chemical Society 2012;134(46):18912-5.
2012: Shunichi Fukuzumi; Akinori Itoh; Kei Ohkubo; Tomoyoshi Suenobu; Yusuke Yamada; Kaoru Doi; Kenneth D Karlin
Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity.
Proceedings of the National Academy of Sciences of the United States of America 2012;109(39):15572-7.
2012: Yusuke Yamada; Kenneth D Karlin; Kazuki Maeda; Kei Ohkubo; Shunichi Fukuzumi
Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex.
Physical chemistry chemical physics : PCCP 2012;14(27):9654-9.
2012: Ga Young Park; Munzarin F Qayyum; Edward I Solomon; Julia Woertink; Britt Hedman; Keith O Hodgson; Amy A Narducci Sarjeant; Kenneth D Karlin
Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage.
Journal of the American Chemical Society 2012;134(20):8513-24.
2011: Matthew T Kieber-Emmons; Yuqi Li; Zakaria Halime; Kenneth D Karlin; Edward I Solomon
Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity.
Inorganic chemistry 2011;50(22):11777-86.
2011: Zakaria Halime; Hiroaki Kotani; Yuqi Li; Shunichi Fukuzumi; Kenneth D Karlin
Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights.
Proceedings of the National Academy of Sciences of the United States of America 2011;108(34):13990-4.
2011: Ryan L Peterson; Maxime A Siegler; Edward I Solomon; Tomoyoshi Suenobu; Li Tian; Shunichi Fukuzumi; Richard A Himes; Hiroaki Kotani; Kenneth D Karlin
Cupric superoxo-mediated intermolecular C-H activation chemistry.
Journal of the American Chemical Society 2011;133(6):1702-5.
2010: Julia S Woertink; Li Tian; Debabrata Maiti; Heather R Lucas; Richard A Himes; Kenneth D Karlin; Frank Neese; Christian Würtele; Max C Holthausen; Eckhard Bill; Jörg Sundermeyer; Siegfried Schindler; Edward I Solomon
Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state.
Inorganic chemistry 2010;49(20):9450-9.
2010: Yunho Lee; Dong-Heon Lee; Ga Young Park; Heather R Lucas; Amy A Narducci Sarjeant; Matthew T Kieber-Emmons; Michael A Vance; Ashley E Milligan; Edward I Solomon; Kenneth D Karlin
Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.
Inorganic chemistry 2010;49(19):8873-85.
2010: Heather R Lucas; Gerald J Meyer; Kenneth D Karlin
CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism.
Journal of the American Chemical Society 2010;132(37):12927-40.
2010: Richard A Himes; Kevin Barnese; Kenneth D Karlin
One is lonely and three is a crowd: two coppers are for methane oxidation.
Angewandte Chemie (International ed. in English) 2010;49(38):6714-6.
2010: Kenneth D Karlin
Bioinorganic chemistry: Redox control of oxoiron(IV).
Nature chemistry 2010;2(9):711-2.
2010: Mark Paul Schopfer; Jun Wang; Kenneth D Karlin
Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling.
Inorganic chemistry 2010;49(14):6267-82.
2010: Zakaria Halime; Matthew T Kieber-Emmons; Munzarin F Qayyum; Biplab Mondal; Thirumanavelan Gandhi; Simona C Puiu; Eduardo E Chufán; Amy A Narducci Sarjeant; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity.
Inorganic chemistry 2010;49(8):3629-45.
2010: Jun Wang; Mark Paul Schopfer; Simona C Puiu; Amy A Narducci Sarjeant; Kenneth D Karlin
Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes.
Inorganic chemistry 2010;49(4):1404-19.
2010: Ga Young Park; Yunho Lee; Dong-Heon Lee; Julia S Woertink; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.
Chemical communications (Cambridge, England) 2010;46(1):91-3.
2009: Yunho Lee; Ga Young Park; Heather R Lucas; Peter L Vajda; Kaliappan Kamaraj; Michael A Vance; Ashley E Milligan; Julia S Woertink; Maxime A Siegler; Amy A Narducci Sarjeant; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species.
Inorganic chemistry 2009;48(23):11297-309.
2009: Richard A Himes; Kenneth D Karlin
A new copper-oxo player in methane oxidation.
Proceedings of the National Academy of Sciences of the United States of America 2009;106(45):18877-8.
2009: Ga Young Park; Subramanian Deepalatha; Simona C Puiu; Dong-Heon Lee; Biplab Mondal; Amy A Narducci Sarjeant; Diego del Rio; Monita Y M Pau; Edward I Solomon; Kenneth D Karlin
A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2009;14(8):1301-11.
2009: Heather R Lucas; Gerald J Meyer; Kenneth D Karlin
Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems.
Journal of the American Chemical Society 2009;131(39):13924-5.
2009: Debabrata Maiti; Julia S Woertink; Reza A Ghiladi; Edward I Solomon; Kenneth D Karlin
Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex.
Inorganic chemistry 2009;48(17):8342-56.
2009: Mark Paul Schopfer; Biplab Mondal; Dong-Heon Lee; Amy A Narducci Sarjeant; Kenneth D Karlin
Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate.
Journal of the American Chemical Society 2009;131(32):11304-5.
2009: Heather R Lucas; Lei Li; Amy A Narducci Sarjeant; Michael A Vance; Edward I Solomon; Kenneth D Karlin
Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.
Journal of the American Chemical Society 2009;131(9):3230-45.
2009: Richard A Himes; Kenneth D Karlin
Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).
Current opinion in chemical biology 2009;13(1):119-31.
2009: Jun Wang; Mark Paul Schopfer; Amy A Narducci Sarjeant; Kenneth D Karlin
Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO).
Journal of the American Chemical Society 2009;131(2):450-1.
2009: Heather R Lucas; Kenneth D Karlin
Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site.
Metal ions in life sciences 2009;6():295-361.
2008: Debabrata Maiti; Amy A Narducci Sarjeant; Kenneth D Karlin
Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.
Inorganic chemistry 2008;47(19):8736-47.
2008: Debabrata Maiti; Dong-Heon Lee; Amy A Narducci Sarjeant; Monita Y M Pau; Edward I Solomon; Katya Gaoutchenova; Jörg Sundermeyer; Kenneth D Karlin
Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species.
Journal of the American Chemical Society 2008;130(21):6700-1.
2008: Qing Zhu; Yuxiang Lian; Sunita Thyagarajan; Steven E. Rokita; Kenneth D Karlin; Neil V Blough
Hydrogen peroxide and dioxygen activation by dinuclear copper complexes in aqueous solution: hydroxyl radical production initiated by internal electron transfer.
Journal of the American Chemical Society 2008;130(20):6304-5.
2008: Debabrata Maiti; Julia S Woertink; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent.
Inorganic chemistry 2008;47(9):3787-800.
2008: Debabrata Maiti; Amy A Narducci Sarjeant; Shinobu Itoh; Kenneth D Karlin
Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety.
Journal of the American Chemical Society 2008;130(17):5644-5.
2008: Ritimukta Sarangi; John T York; Matthew E Helton; Kiyoshi Fujisawa; Kenneth D Karlin; William B Tolman; Keith O Hodgson; Britt Hedman; Edward I Solomon
X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding.
Journal of the American Chemical Society 2008;130(2):676-86.
2008: H Christopher Fry; Heather R Lucas; Amy A Narducci Sarjeant; Kenneth D Karlin; Gerald J Meyer
Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds.
Inorganic chemistry 2008;47(1):241-56.
2008: Richard A Himes; Ga Young Park; Gnana Sutha Siluvai; Ninian J Blackburn; Kenneth D Karlin
Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes.
Angewandte Chemie (International ed. in English) 2008;47(47):9084-7.
2008: Debabrata Maiti; Dong-Heon Lee; Katya Gaoutchenova; Christian Würtele; Max C Holthausen; Amy A Narducci Sarjeant; Jörg Sundermeyer; Siegfried Schindler; Kenneth D Karlin
Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation.
Angewandte Chemie (International ed. in English) 2008;47(1):82-5.
2007: Yunho Lee; Dong-Heon Lee; Amy A Narducci Sarjeant; Kenneth D Karlin
Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition.
Journal of inorganic biochemistry 2007;101(11-12):1845-58.
2007: Eduardo E Chufán; Biplab Mondal; Thirumanavelan Gandhi; Eunsuk Kim; Nick D Rubie; Pierre Moanne-Loccoz; Kenneth D Karlin
Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity.
Inorganic chemistry 2007;46(16):6382-94.
2007: Dong-Heon Lee; Lanying Q Hatcher; Michael A Vance; Ritimukta Sarangi; Ashley E Milligan; Amy A Narducci Sarjeant; Christopher D Incarvito; Arnold L Rheingold; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.
Inorganic chemistry 2007;46(15):6056-68.
2007: Debabrata Maiti; Julia S Woertink; Michael A Vance; Ashley E Milligan; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry.
Journal of the American Chemical Society 2007;129(28):8882-92.
2007: Eduardo E Chufán; Simona C Puiu; Kenneth D Karlin
Heme-copper/dioxygen adduct formation, properties, and reactivity.
Accounts of chemical research 2007;40(7):563-72.
2007: Debabrata Maiti; Heather R Lucas; Amy A Narducci Sarjeant; Kenneth D Karlin
Aryl hydroxylation from a mononuclear copper-hydroperoxo species.
Journal of the American Chemical Society 2007;129(22):6998-9.
2007: Debabrata Maiti; Amy A Narducci Sarjeant; Kenneth D Karlin
Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry.
Journal of the American Chemical Society 2007;129(21):6720-1.
2007: Reza A Ghiladi; Eduardo E Chufan; Diego del Río; Edward I Solomon; Carsten Krebs; Boi Hanh Huynh; Hong-Wei Huang; Pierre Moanne-Loccoz; Susan Kaderli; Marcus Honecker; Andreas D Zuberbühler; Lisa Marzilli; Robert J Cotter; Kenneth D Karlin
Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+.
Inorganic chemistry 2007;46(10):3889-902.
2007: Richard A Himes; Ga Young Park; Amanda N Barry; Ninian J Blackburn; Kenneth D Karlin
Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry.
Journal of the American Chemical Society 2007;129(17):5352-3.
2007: Eduardo E Chufan; Claudio N Verani; Simona C Puiu; Eva Rentschler; Ulrich Schatzschneider; Christopher D Incarvito; Arnold L Rheingold; Kenneth D Karlin
Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine.
Inorganic chemistry 2007;46(8):3017-26.
2007: Debabrata Maiti; H Christopher Fry; Julia S Woertink; Michael A Vance; Edward I Solomon; Kenneth D Karlin
A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols.
Journal of the American Chemical Society 2007;129(2):264-5.
2006: Yunho Lee; Dong-Heon Lee; Amy A Narducci Sarjeant; Lev N Zakharov; Arnold L Rheingold; Kenneth D Karlin
Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands.
Inorganic chemistry 2006;45(25):10098-107.
2006: Lanying Q Hatcher; Dong-Heon Lee; Michael A Vance; Ashley E Milligan; Ritimukta Sarangi; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation.
Inorganic chemistry 2006;45(25):10055-7.
2006: Lei Li; Amy A Narducci Sarjeant; Kenneth D Karlin
Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions.
Inorganic chemistry 2006;45(18):7160-72.
2006: Lei Li; Narasimha N Murthy; Joshua Telser; Lev N Zakharov; Glenn P A Yap; Arnold L Rheingold; Kenneth D Karlin; Steven E. Rokita
Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions.
Inorganic chemistry 2006;45(18):7144-59.
2006: Sunita Thyagarajan; Narasimha N Murthy; Amy A Narducci Sarjeant; Kenneth D Karlin; Steven E. Rokita
Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species.
Journal of the American Chemical Society 2006;128(21):7003-8.
2006: Lanying Q Hatcher; Michael A Vance; Amy A Narducci Sarjeant; Edward I Solomon; Kenneth D Karlin
Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects.
Inorganic chemistry 2006;45(7):3004-13.
2006: Yunho Lee; Amy A Narducci Sarjeant; Kenneth D Karlin
A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands.
Chemical communications (Cambridge, England) 2006;(6):621-3.
2006: Matthew E Helton; Debabrata Maiti; Lev N Zakharov; Arnold L Rheingold; John A Porco; Kenneth D Karlin
A mu-eta2:eta2-disulfide dicopper(II) complex from reaction of S8 with a copper(I) precursor: reactivity of the bound disulfur moiety.
Angewandte Chemie (International ed. in English) 2006;45(7):1138-41.
2005: Lei Li; Amy A Narducci Sarjeant; Michael A Vance; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex.
Journal of the American Chemical Society 2005;127(44):15360-1.
2005: Takeo Ito; Sunita Thyagarajan; Kenneth D Karlin; Steven E. Rokita
Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex.
Chemical communications (Cambridge, England) 2005;(38):4812-4.
2005: Eunsuk Kim; Matthew E Helton; Shen Lu; Pierre Moanne-Loccoz; Christopher D Incarvito; Arnold L Rheingold; Susan Kaderli; Andreas D Zuberbühler; Kenneth D Karlin
Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes.
Inorganic chemistry 2005;44(20):7014-29.
2005: Diego Del Río; Ritimukta Sarangi; Eduardo E Chufán; Kenneth D Karlin; Britt Hedman; Keith O Hodgson; Edward I Solomon
Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4).
Journal of the American Chemical Society 2005;127(34):11969-78.
2005: H Christopher Fry; Andrew D Cohen; John P Toscano; Gerald J Meyer; Kenneth D Karlin
Photoinduced carbon monoxide migration in a synthetic heme-copper complex.
Journal of the American Chemical Society 2005;127(17):6225-30.
2005: Jason Shearer; Christiana Xin Zhang; Lev N Zakharov; Arnold L Rheingold; Kenneth D Karlin
Substrate oxidation by copper-dioxygen adducts: mechanistic considerations.
Journal of the American Chemical Society 2005;127(15):5469-83.
2005: Ian M Wasser; Hong-Wei Huang; Pierre Moanne-Loccoz; Kenneth D Karlin
Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase.
Journal of the American Chemical Society 2005;127(10):3310-20.
2005: Eunsuk Kim; Kaliappan Kamaraj; Benedikt Galliker; Nick D Rubie; Pierre Moanne-Loccoz; Susan Kaderli; Andreas D Zuberbühler; Kenneth D Karlin
Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link.
Inorganic chemistry 2005;44(5):1238-47.
2005: Lei Li; Kenneth D Karlin; Steven E. Rokita
Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex.
Journal of the American Chemical Society 2005;127(2):520-1.
2005: Reza A Ghiladi; Hong-Wei Huang; Pierre Moanne-Loccoz; Jay Stasser; Ninian J Blackburn; Amina S Woods; Robert J Cotter; Christopher D Incarvito; Arnold L Rheingold; Kenneth D Karlin
Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O2(2-))-CuII]+.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2005;10(1):63-77.
2004: H Christopher Fry; Paul G Hoertz; Ian M Wasser; Kenneth D Karlin; Gerald J Meyer
Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes.
Journal of the American Chemical Society 2004;126(51):16712-3.
2004: Ian M Wasser; H Christopher Fry; Paul G Hoertz; Gerald J Meyer; Kenneth D Karlin
Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex.
Inorganic chemistry 2004;43(26):8272-81.
2004: Eunsuk Kim; Jason Shearer; Shen Lu; Pierre Moanne-Loccoz; Matthew E Helton; Susan Kaderli; Andreas D Zuberbühler; Kenneth D Karlin
Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation.
Journal of the American Chemical Society 2004;126(40):12716-7.
2004: Baldo Lucchese; Kristi J Humphreys; Dong-Heon Lee; Christopher D Incarvito; Roger D Sommer; Arnold L Rheingold; Kenneth D Karlin
Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform.
Inorganic chemistry 2004;43(19):5987-98.
2004: Lanying Q Hatcher; Kenneth D Karlin
Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2004;9(6):669-83.
2004: Hong-Chang Liang; Mark J Henson; Lanying Q Hatcher; Michael A Vance; Christiana Xin Zhang; David Lahti; Susan Kaderli; Roger D Sommer; Arnold L Rheingold; Andreas D Zuberbühler; Edward I Solomon; Kenneth D Karlin
Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction.
Inorganic chemistry 2004;43(14):4115-7.
2004: Eunsuk Kim; Eduardo E Chufán; Kaliappan Kamaraj; Kenneth D Karlin
Synthetic models for heme-copper oxidases.
Chemical reviews 2004;104(2):1077-133.
2004: Ian M Wasser; Constantinus F Martens; Claudio N Verani; Eva Rentschler; Hong-Wei Huang; Pierre Moanne-Loccoz; Lev N Zakharov; Arnold L Rheingold; Kenneth D Karlin
Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase.
Inorganic chemistry 2004;43(2):651-62.
2003: Eduardo E Chufán; Kenneth D Karlin
An iron-peroxo porphyrin complex: new synthesis and reactivity toward a Cu(II) complex giving a heme-peroxo-copper adduct.
Journal of the American Chemical Society 2003;125(52):16160-1.
2003: Jason Shearer; Christiana Xin Zhang; Lanying Q Hatcher; Kenneth D Karlin
Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects.
Journal of the American Chemical Society 2003;125(42):12670-1.
2003: H Christopher Fry; Donald V Scaltrito; Kenneth D Karlin; Gerald J Meyer
The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes.
Journal of the American Chemical Society 2003;125(39):11866-71.
2003: David W Thompson; Ryan M Kretzer; Estelle L Lebeau; Donald V Scaltrito; Reza A Ghiladi; Kin-Chung Lam; Arnold L Rheingold; Kenneth D Karlin; Gerald J Meyer
Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex.
Inorganic chemistry 2003;42(17):5211-8.
2003: Peng Chen; Kiyoshi Fujisawa; Matthew E Helton; Kenneth D Karlin; Edward I Solomon
Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues.
Journal of the American Chemical Society 2003;125(21):6394-408.
2003: Kaliappan Kamaraj; Eunsuk Kim; Benedikt Galliker; Lev N Zakharov; Arnold L Rheingold; Andreas D Zuberbühler; Kenneth D Karlin
Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity.
Journal of the American Chemical Society 2003;125(20):6028-9.
2003: Ryan M Kretzer; Reza A Ghiladi; Estelle L Lebeau; Hong-Chang Liang; Kenneth D Karlin
Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species.
Inorganic chemistry 2003;42(9):3016-25.
2003: Mark J Henson; Michael A Vance; Christiana Xin Zhang; Hong-Chang Liang; Kenneth D Karlin; Edward I Solomon
Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes.
Journal of the American Chemical Society 2003;125(17):5186-92.
2003: Eunsuk Kim; Matthew E Helton; Ian M Wasser; Kenneth D Karlin; Shen Lu; Hong-Wei Huang; Pierre Moenne-Loccoz; Christopher D Incarvito; Arnold L Rheingold; Marcus Honecker; Susan Kaderli; Andreas D Zuberbuhler
Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models.
Proceedings of the National Academy of Sciences of the United States of America 2003;100(7):3623-8.
2003: Christiana Xin Zhang; Susan Kaderli; Miguel Costas; Eun-Il Kim; Yorck-Michael Neuhold; Kenneth D Karlin; Andreas D Zuberbühler
Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations.
Inorganic chemistry 2003;42(6):1807-24.
2003: Matthew E Helton; Peng Chen; Partha P Paul; Zoltán Tyeklár; Roger D Sommer; Lev N Zakharov; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry.
Journal of the American Chemical Society 2003;125(5):1160-1.
2003: Christiana Xin Zhang; Hong-Chang Liang; Eun-Il Kim; Jason Shearer; Matthew E Helton; Eunsuk Kim; Susan Kaderli; Christopher D Incarvito; Andreas D Zuberbühler; Arnold L Rheingold; Kenneth D Karlin
Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics.
Journal of the American Chemical Society 2003;125(3):634-5.
2002: Kristi J Humphreys; Anne E Johnson; Kenneth D Karlin; Steven E. Rokita
Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2002;7(7-8):835-42.
2002: Kristi J Humphreys; Kenneth D Karlin; Steven E. Rokita
Targeted strand scission of DNA substrates by a tricopper(II) coordination complex.
Journal of the American Chemical Society 2002;124(27):8055-66.
2002: Kristi J Humphreys; Kenneth D Karlin; Steven E. Rokita
Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties.
Journal of the American Chemical Society 2002;124(21):6009-19.
2002: Reza A Ghiladi; Kenneth D Karlin
Low-temperature UV-visible and NMR spectroscopic investigations of O(2) binding to ((6)L)Fe(II), a ferrous heme bearing covalently tethered axial pyridine ligands.
Inorganic chemistry 2002;41(9):2400-7.
2002: Hong-Chang Liang; Christiana Xin Zhang; Mark J Henson; Roger D Sommer; Karen R Hatwell; Susan Kaderli; Andreas D Zuberbühler; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.
Journal of the American Chemical Society 2002;124(16):4170-1.
2002: Hong-Chang Liang; Eunsuk Kim; Christopher D Incarvito; Arnold L Rheingold; Kenneth D Karlin
A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+).
Inorganic chemistry 2002;41(8):2209-12.
2002: Ian M Wasser; Simon de Vries; Pierre Moanne-Loccoz; Imke Schröder; Kenneth D Karlin
Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry.
Chemical reviews 2002;102(4):1201-34.
2001: Reza A Ghiladi; Ryan M Kretzer; I Guzei; Arnold L Rheingold; Yorck-Michael Neuhold; Karen R Hatwell; Andreas D Zuberbühler; Kenneth D Karlin
(F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation.
Inorganic chemistry 2001;40(23):5754-67.
2001: Donald V Scaltrito; H Christopher Fry; Brett M Showalter; David W Thompson; Hong-Chang Liang; Christiana Xin Zhang; Ryan M Kretzer; Eunsuk Kim; John P Toscano; Kenneth D Karlin; Gerald J Meyer
Reversible carbon monoxide photodissociation from Cu(I) coordination compounds.
Inorganic chemistry 2001;40(18):4514-5.
2001: Reza A Ghiladi; Karen R Hatwell; Kenneth D Karlin; Hong-Wei Huang; Pierre Moanne-Loccoz; C Krebs; Boi Hanh Huynh; L A Marzilli; Robert J Cotter; Susan Kaderli; Andreas D Zuberbühler
Dioxygen reactivity of mononuclear heme and copper components yielding a high-spin heme-peroxo-cu complex.
Journal of the American Chemical Society 2001;123(25):6183-4.
2001: K J Humphreys; Kenneth D Karlin; Steven E. Rokita
Recognition and strand scission at junctions between single- and double-stranded DNA by a trinuclear copper complex.
Journal of the American Chemical Society 2001;123(23):5588-9.
2001: F C Rhames; N N Murthy; Kenneth D Karlin; Ninian J Blackburn
Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc).
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 2001;6(5-6):567-77.
2001: Markus Schatz; M Becker; F Thaler; Frank Hampel; Siegfried Schindler; R R Jacobson; Zoltán Tyeklár; N N Murthy; P Ghosh; Q Chen; J Zubieta; Kenneth D Karlin
Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands.
Inorganic chemistry 2001;40(10):2312-22.
2001: Narasimha N Murthy; M Mahroof-Tahir; Kenneth D Karlin
Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities.
Inorganic chemistry 2001;40(4):628-35.
2000: Hong-Chang Liang; Kenneth D Karlin; R Dyson; Susan Kaderli; B Jung; Andreas D Zuberbühler
Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts.
Inorganic chemistry 2000;39(26):5884-94.
1997: Samuel Karlin; ZY Zhu; Kenneth D Karlin
The extended environment of mononuclear metal centers in protein structures.
Proceedings of the National Academy of Sciences of the United States of America 1997;94(26):14225-30.