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James Mayer

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Alexander J M Miller; D Michael Heinekey; James M Mayer; Karen I Goldberg
Catalytic disproportionation of formic acid to generate methanol.
Todd F Markle; Antonio G DiPasquale; Werner Kaminsky; Tristan A Tronic; James M Mayer
Effect of basic site substituents on concerted proton-electron transfer in hydrogen-bonded pyridyl-phenols.
Benjamin D Matson; Simone Raugei; Amber Von Ruden; Jenny Y Yang; Colin T Carver; James M Mayer
Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water.

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All Publications

2013: Alexander J M Miller; D Michael Heinekey; James M Mayer; Karen I Goldberg
Catalytic disproportionation of formic acid to generate methanol.
Angewandte Chemie (International ed. in English) 2013;52(14):3981-4.
2012: Todd F Markle; Antonio G DiPasquale; Werner Kaminsky; Tristan A Tronic; James M Mayer
Effect of basic site substituents on concerted proton-electron transfer in hydrogen-bonded pyridyl-phenols.
The journal of physical chemistry. A 2012;116(50):12249-59.
2012: Benjamin D Matson; Simone Raugei; Amber Von Ruden; Jenny Y Yang; Colin T Carver; James M Mayer
Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water.
Chemical communications (Cambridge, England) 2012;48(90):11100-2.
2012: Joel N Schrauben; Carolyn N Valdez; Miles Braten; Lila Fridley; Rebecca Hayoun; James M Mayer
Titanium and zinc oxide nanoparticles are proton-coupled electron transfer agents.
Science (New York, N.Y.) 2012;336(6086):1298-301.
2012: Shoshanna M Barnett; Karen I Goldberg; James M Mayer
A soluble copper-bipyridine water-oxidation electrocatalyst.
Nature chemistry 2012;4(6):498-502.
2011: Tristan A Tronic; Mary Rakowski DuBois; Michael K Coggins; Werner Kaminsky; Tianbiao Liu; James M Mayer
Directing protons to the dioxygen ligand of a ruthenium(II) complex with pendent amines in the second coordination sphere.
Angewandte Chemie (International ed. in English) 2011;50(46):10936-9.
2011: Todd F Markle; Ian J Rhile; James M Mayer
Kinetic effects of increased proton transfer distance on proton-coupled oxidations of phenol-amines.
Journal of the American Chemical Society 2011;133(43):17341-52.
2011: Rebecca Hayoun; Kelly M Whitaker; Daniel R Gamelin; James M Mayer
Electron transfer between colloidal ZnO nanocrystals.
Journal of the American Chemical Society 2011;133(12):4228-31.
2011: James M Mayer
Understanding hydrogen atom transfer: from bond strengths to Marcus theory.
Accounts of chemical research 2011;44(1):36-46.
2010: Jeffrey J Warren; Tristan A Tronic; James M Mayer
Thermochemistry of proton-coupled electron transfer reagents and its implications.
Chemical reviews 2010;110(12):6961-7001.
2010: Jeffrey J Warren; James M Mayer
Tuning of the thermochemical and kinetic properties of ascorbate by its local environment: solution chemistry and biochemical implications.
Journal of the American Chemical Society 2010;132(22):7784-93.
2010: Elizabeth A Mader; James M Mayer
The importance of precursor and successor complex formation in a bimolecular proton-electron transfer reaction.
Inorganic chemistry 2010;49(8):3685-7.
2010: Jessica M Hoover; Antonio G DiPasquale; James M Mayer; Forrest E Michael
Platinum-catalyzed intramolecular hydrohydrazination: evidence for alkene insertion into a Pt-N bond.
Journal of the American Chemical Society 2010;132(14):5043-53.
2010: Jeffrey J Warren; James M Mayer
Predicting organic hydrogen atom transfer rate constants using the Marcus cross relation.
Proceedings of the National Academy of Sciences of the United States of America 2010;107(12):5282-7.
2010: Christopher R Waidmann; Antonio G DiPasquale; James M Mayer
Synthesis and reactivity of oxo-peroxo-vanadium(V) bipyridine compounds.
Inorganic chemistry 2010;49(5):2383-91.
2009: Michael P Lanci; Matthew S Remy; Werner Kaminsky; James M Mayer; Melanie S Sanford
Oxidatively induced reductive elimination from ((t)Bu2bpy)Pd(Me)2: palladium(IV) intermediates in a one-electron oxidation reaction.
Journal of the American Chemical Society 2009;131(43):15618-20.
2009: Adam Wu; Elizabeth A Mader; Ayan Datta; David A Hrovat; Weston Thatcher Borden; James M Mayer
Nitroxyl radical plus hydroxylamine pseudo self-exchange reactions: tunneling in hydrogen atom transfer.
Journal of the American Chemical Society 2009;131(33):11985-97.
2009: Virginia W Manner; James M Mayer
Concerted proton-electron transfer in a ruthenium terpyridyl-benzoate system with a large separation between the redox and basic sites.
Journal of the American Chemical Society 2009;131(29):9874-5.
2009: Christopher R Waidmann; Xin Zhou; Erin A Tsai; Werner Kaminsky; David A Hrovat; Weston Thatcher Borden; James M Mayer
Slow hydrogen atom transfer reactions of oxo- and hydroxo-vanadium compounds: the importance of intrinsic barriers.
Journal of the American Chemical Society 2009;131(13):4729-43.
2009: Elizabeth A Mader; Virginia W Manner; Todd F Markle; Adam Wu; James A Franz; James M Mayer
Trends in ground-state entropies for transition metal based hydrogen atom transfer reactions.
Journal of the American Chemical Society 2009;131(12):4335-45.
2009: Lisa S Park-Gehrke; John Freudenthal; Werner Kaminsky; Antonio G DiPasquale; James M Mayer
Synthesis and oxidation of CpIrIII compounds: functionalization of a Cp methyl group.
Dalton transactions (Cambridge, England : 2003) 2009;(11):1972-83.
2009: Jennifer L Look; Douglas D Wick; James M Mayer; Karen I Goldberg
Autoxidation of platinum(IV) hydrocarbyl hydride complexes to form platinum(IV) hydrocarbyl hydroperoxide complexes.
Inorganic chemistry 2009;48(4):1356-69.
2008: D Bridget Williams; Werner Kaminsky; James M Mayer; Karen I Goldberg
Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding.
Chemical communications (Cambridge, England) 2008;(35):4195-7.
2008: Todd F Markle; Ian J Rhile; Antonio G DiPasquale; James M Mayer
Probing concerted proton-electron transfer in phenol-imidazoles.
Proceedings of the National Academy of Sciences of the United States of America 2008;105(24):8185-90.
2008: Virginia W Manner; Antonio G DiPasquale; James M Mayer
Facile concerted proton-electron transfers in a ruthenium terpyridine-4'-carboxylate complex with a long distance between the redox and basic sites.
Journal of the American Chemical Society 2008;130(23):7210-1.
2008: Jeffrey J Warren; James M Mayer
Hydrogen atom transfer reactions of iron-porphyrin-imidazole complexes as models for histidine-ligated heme reactivity.
Journal of the American Chemical Society 2008;130(9):2774-6.
2008: Antonio G DiPasquale; James M Mayer
Hydrogen peroxide: a poor ligand to gallium tetraphenylporphyrin.
Journal of the American Chemical Society 2008;130(6):1812-3.
2008: Virginia W Manner; Todd F Markle; John H Freudenthal; Justine P Roth; James M Mayer
The first crystal structure of a monomeric phenoxyl radical: 2,4,6-tri-tert-butylphenoxyl radical.
Chemical communications (Cambridge, England) 2008;(2):256-8.
2008: Todd F Markle; James M Mayer
Concerted proton-electron transfer in pyridylphenols: the importance of the hydrogen bond.
Angewandte Chemie (International ed. in English) 2008;47(4):738-40.
2007: Adam Wu; Joshua Masland; Rodney D Swartz; Werner Kaminsky; James M Mayer
Synthesis and characterization of ruthenium bis(beta-diketonato) pyridine-imidazole complexes for hydrogen atom transfer.
Inorganic chemistry 2007;46(26):11190-201.
2007: Karine Valliant-Saunders; Erica Gunn; G Robert Shelton; David A Hrovat; Weston Thatcher Borden; James M Mayer
Oxidation of tertiary silanes by osmium tetroxide.
Inorganic chemistry 2007;46(13):5212-9.
2007: Elizabeth A Mader; Ernest R Davidson; James M Mayer
Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexes.
Journal of the American Chemical Society 2007;129(16):5153-66.
2006: Takao Osako; Eric J Watson; Ahmad Dehestani; Brian C Bales; James M Mayer
Methane oxidation by aqueous osmium tetroxide and sodium periodate: inhibition of methanol oxidation by methane.
Angewandte Chemie (International ed. in English) 2006;45(44):7433-6.
2006: Ian J Rhile; Todd F Markle; Hirotaka Nagao; Antonio G DiPasquale; Oanh P Lam; Mark A Lockwood; Katrina Rotter; James M Mayer
Concerted proton-electron transfer in the oxidation of hydrogen-bonded phenols.
Journal of the American Chemical Society 2006;128(18):6075-88.
2006: James M Mayer; Ian J Rhile; Frank B Larsen; Elizabeth A Mader; Todd F Markle; Antonio G DiPasquale
Models for proton-coupled electron transfer in photosystem II.
Photosynthesis research 2006;87(1):3-20.
2005: Christine M Isborn; David A Hrovat; Weston Thatcher Borden; James M Mayer; Barry K Carpenter
Factors controlling the barriers to degenerate hydrogen atom transfers.
Journal of the American Chemical Society 2005;127(16):5794-5.
2005: Takashi Matsuo; James M Mayer
Oxidations of NADH analogues by cis-[RuIV(bpy)2(py)(O)]2+ occur by hydrogen-atom transfer rather than by hydride transfer.
Inorganic chemistry 2005;44(7):2150-8.
2005: Ahmad Dehestani; Wai Han Lam; David A Hrovat; Ernest R Davidson; Weston Thatcher Borden; James M Mayer
Ligand-assisted reduction of osmium tetroxide with molecular hydrogen via a [3+2] mechanism.
Journal of the American Chemical Society 2005;127(10):3423-32.
2005: Brian C Bales; Peter Brown; Ahmad Dehestani; James M Mayer
Alkane oxidation by osmium tetroxide.
Journal of the American Chemical Society 2005;127(9):2832-3.
2005: Ian J Rhile; James M Mayer
Comments on "How single and bifurcated hydrogen bonds influence proton-migration rate constants, redox, and electronic properties of phenoxyl radicals".
Angewandte Chemie (International ed. in English) 2005;44(11):1598-9.
2004: Ian J Rhile; James M Mayer
One-electron oxidation of a hydrogen-bonded phenol occurs by concerted proton-coupled electron transfer.
Journal of the American Chemical Society 2004;126(40):12718-9.
2004: Jake D Soper; Erik Saganic; David Weinberg; David A Hrovat; Jason B Benedict; Werner Kaminsky; James M Mayer
Nucleophilic aromatic substitution on aryl-amido ligands promoted by oxidizing osmium(IV) centers.
Inorganic chemistry 2004;43(19):5804-15.
2004: Elizabeth A Mader; Anna S Larsen; James M Mayer
Hydrogen atom transfer from iron(II)-tris[2,2'-bi(tetrahydropyrimidine)] to TEMPO: a negative enthalpy of activation predicted by the Marcus equation.
Journal of the American Chemical Society 2004;126(26):8066-7.
2004: James M Mayer; Ian J Rhile
Thermodynamics and kinetics of proton-coupled electron transfer: stepwise vs. concerted pathways.
Biochimica et biophysica acta 2004;1655(1-3):51-8.
2004: Jasmine R Bryant; Takashi Matsuo; James M Mayer
Cumene oxidation by cis-[RuIV(bpy)2(py)(O)]2+, revisited.
Inorganic chemistry 2004;43(4):1587-92.
2004: James M Mayer
Proton-coupled electron transfer: a reaction chemist's view.
Annual review of physical chemistry 2004;55():363-90.
2003: Jake D Soper; James M Mayer
Slow hydrogen atom self-exchange between Os(IV) anilide and Os(III) aniline complexes: relationships with electron and proton transfer self-exchange.
Journal of the American Chemical Society 2003;125(40):12217-29.
2003: Takayoshi Suzuki; Antonio G DiPasquale; James M Mayer
Nitrogen atom insertion into Ir-S and C-S bonds initiated by photolysis of iridium(III)-azido-dithiocarbamato complexes.
Journal of the American Chemical Society 2003;125(35):10514-5.
2003: Jasmine R Bryant; James M Mayer
Oxidation of C-H bonds by [(bpy)2(py)RuIVO]2+ occurs by hydrogen atom abstraction.
Journal of the American Chemical Society 2003;125(34):10351-61.
2003: Brian K Bennett; Erik Saganic; Scott Lovell; Werner Kaminsky; Amanda Samuel; James M Mayer
Osmium phosphiniminato complexes: synthesis, protonation, structure, and redox-coupled hydrolytic scission of N-p bonds.
Inorganic chemistry 2003;42(13):4127-34.
2003: Jeffrey C Yoder; Justine P Roth; Emily M Gussenhoven; Anna S Larsen; James M Mayer
Electron and hydrogen-atom self-exchange reactions of iron and cobalt coordination complexes.
Journal of the American Chemical Society 2003;125(9):2629-40.
2003: Ahmad Dehestani; Werner Kaminsky; James M Mayer
Tuning the properties of the osmium nitrido group in TpOs(N)X2 by changing the ancillary ligand.
Inorganic chemistry 2003;42(2):605-11.
2002: Antonio G DiPasquale; Werner Kaminsky; James M Mayer
Oxygen-oxygen bond homolysis in a novel titanium(IV) alkylperoxide complex, Cp2Ti(OOtBu)Cl.
Journal of the American Chemical Society 2002;124(49):14534-5.
2002: James M Mayer; David A Hrovat; Jennie L Thomas; Weston Thatcher Borden
Proton-coupled electron transfer versus hydrogen atom transfer in benzyl/toluene, methoxyl/methanol, and phenoxyl/phenol self-exchange reactions.
Journal of the American Chemical Society 2002;124(37):11142-7.
2002: Anna S Larsen; Kun Wang; Mark A Lockwood; Gordon L Rice; Tae-Jin Won; Scott Lovell; Martin Sadílek; Frantisek Turecek; James M Mayer
Hydrocarbon oxidation by Bis-mu-oxo manganese dimers: electron transfer, hydride transfer, and hydrogen atom transfer mechanisms.
Journal of the American Chemical Society 2002;124(34):10112-23.
2002: Jasmine R Bryant; Janelle E Taves; James M Mayer
Oxidations of hydrocarbons by manganese(III) tris(hexafluoroacetylacetonate).
Inorganic chemistry 2002;41(10):2769-76.
2001: Justine P Roth; J C Yoder; T J Won; James M Mayer
Application of the Marcus cross relation to hydrogen atom transfer reactions.
Science (New York, N.Y.) 2001;294(5551):2524-6.
2001: Jake D Soper; Werner Kaminsky; James M Mayer
Activation of an anilido ligand for nucleophilic aromatic substitution by an oxidizing Os(IV) center.
Journal of the American Chemical Society 2001;123(23):5594-5.
2001: Brian K Bennett; Scott Lovell; James M Mayer
Nitrogen abstraction from nitriles by osmium(IV) complexes.
Journal of the American Chemical Society 2001;123(18):4336-7.
2001: Jake D Soper; Brian K Bennett; Scott Lovell; James M Mayer
Protonation and deprotonation of TpOs(NHPh)Cl(2): an unusually inert amido ligand.
Inorganic chemistry 2001;40(8):1888-93.
2001: Tom Crevier; Brian K Bennett; Jake D Soper; J A Bowman; Ahmad Dehestani; David A Hrovat; Scott Lovell; Werner Kaminsky; James M Mayer
C--N bond formation on addition of aryl carbanions to the electrophilic nitrido ligand in TpOs(N)Cl(2).
Journal of the American Chemical Society 2001;123(6):1059-71.