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Gary Molander

Research Profile

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Publications

TOP 3
Marc Presset; Frederik Rombouts; Nicolas Fleury-Brégeot; Daniel Oehlrich; Gary A Molander
Synthesis and minisci reactions of organotrifluoroborato building blocks.
Gary A Molander; Kaitlin M Traister; Thiago Barcellos
Palladium-Catalyzed α-Arylation of 2-Chloroacetates and 2-Chloroacetamides.
Brittany A Tschaen; Jason R Schmink; Gary A Molander
Pd-catalyzed aldehyde to ester conversion: a hydrogen transfer approach.

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All Publications

2013: Marc Presset; Frederik Rombouts; Nicolas Fleury-Brégeot; Daniel Oehlrich; Gary A Molander
Synthesis and minisci reactions of organotrifluoroborato building blocks.
The Journal of organic chemistry 2013;78(9):4615-9.
2013: Gary A Molander; Kaitlin M Traister; Thiago Barcellos
Palladium-Catalyzed α-Arylation of 2-Chloroacetates and 2-Chloroacetamides.
The Journal of organic chemistry 2013;78(8):4123-31.
2013: Brittany A Tschaen; Jason R Schmink; Gary A Molander
Pd-catalyzed aldehyde to ester conversion: a hydrogen transfer approach.
Organic letters 2013;15(3):500-3.
2012: Nicolas Fleury-Brégeot; Floriane Beaumard; Virginie Colombel; Daniel Oehlrich; Marc Presset; Frederik Rombouts; Gary A Molander
Suzuki-Miyaura cross-coupling of potassium alkoxyethyltrifluoroborates: access to aryl/heteroarylethyloxy motifs.
The Journal of organic chemistry 2012;77(22):10399-408.
2012: Gary A Molander; Steven R Wisniewski
Stereospecific cross-coupling of secondary organotrifluoroborates: potassium 1-(benzyloxy)alkyltrifluoroborates.
Journal of the American Chemical Society 2012;134(40):16856-68.
2012: Gary A Molander; Sarah L J Trice; Steven M Kennedy
Scope of the two-step, one-pot palladium-catalyzed borylation/Suzuki cross-coupling reaction utilizing bis-boronic acid.
The Journal of organic chemistry 2012;77(19):8678-88.
2012: Gary A Molander; Sarah L J Trice; Steven M Kennedy
Palladium-catalyzed borylation of aryl and heteroaryl halides utilizing tetrakis(dimethylamino)diboron: one step greener.
Organic letters 2012;14(18):4814-7.
2012: Gary A Molander; Inji Shin
Potassium Boc-protected secondary aminomethyltrifluoroborates: synthesis and Suzuki-Miyaura cross-coupling reactions.
Organic letters 2012;14(17):4458-61.
2012: Gary A Molander; Kehinde Ajayi
Oxidative condensations to form benzimidazole-substituted potassium organotrifluoroborates.
Organic letters 2012;14(16):4242-5.
2012: Nicolas Fleury-Brégeot; Jessica Raushel; Deidre L Sandrock; Spencer D Dreher; Gary A Molander
Rapid and efficient access to secondary arylmethylamines.
Chemistry (Weinheim an der Bergstrasse, Germany) 2012;18(31):9564-70.
2012: Gary A Molander; Sarah L J Trice; Spencer D Dreher; Steven M Kennedy; Matthew T Tudge
Scope of the palladium-catalyzed aryl borylation utilizing bis-boronic acid.
Journal of the American Chemical Society 2012;134(28):11667-73.
2012: Gary A Molander; Inji Shin
Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl mesylates.
Organic letters 2012;14(12):3138-41.
2012: Gary A Molander; Livia N Cavalcanti
Nitrosation of aryl and heteroaryltrifluoroborates with nitrosonium tetrafluoroborate.
The Journal of organic chemistry 2012;77(9):4402-13.
2012: Virginie Colombel; Daniel Oehlrich; Marc Presset; Frederik Rombouts; Gary A Molander
Synthesis and reactivity of solid-supported organotrifluoroborates in Suzuki cross-coupling.
Organic letters 2012;14(7):1680-3.
2011: Gary A Molander; Laura Iannazzo
Palladium-catalyzed Hiyama cross-coupling of aryltrifluorosilanes with aryl and heteroaryl chlorides.
The Journal of organic chemistry 2011;76(21):9182-7.
2011: Gary A Molander; Floriane Beaumard; Terren K Niethamer
Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate.
The Journal of organic chemistry 2011;76(19):8126-30.
2011: Gary A Molander; Silas A McKee
Copper-catalyzed β-boration of α,β-unsaturated carbonyl compounds with tetrahydroxydiborane.
Organic letters 2011;13(17):4684-7.
2011: Gary A Molander; Livia N Cavalcanti
Metal-free chlorodeboronation of organotrifluoroborates.
The Journal of organic chemistry 2011;76(17):7195-203.
2011: Gary A Molander; Inji Shin
Synthesis and Suzuki-Miyaura cross-coupling reactions of potassium Boc-protected aminomethyltrifluoroborate with aryl and hetaryl halides.
Organic letters 2011;13(15):3956-9.
2011: Gary A Molander; Floriane Beaumard
Cross-coupling of mesylated phenol derivatives with potassium alkoxymethyltrifluoroborates.
Organic letters 2011;13(15):3948-51.
2011: Jessica Raushel; Deidre L Sandrock; Kanth V Josyula; Deborah Pakyz; Gary A Molander
Reinvestigation of aminomethyltrifluoroborates and their application in Suzuki-Miyaura cross-coupling reactions.
The Journal of organic chemistry 2011;76(8):2762-9.
2011: Gary A Molander; Virginie Colombel; Valerie A Braz
Direct alkylation of heteroaryls using potassium alkyl- and alkoxymethyltrifluoroborates.
Organic letters 2011;13(7):1852-5.
2011: Gary A Molander; Nicolas Fleury-Brégeot; Marie-Aude Hiebel
Synthesis and cross-coupling of sulfonamidomethyltrifluoroborates.
Organic letters 2011;13(7):1694-7.
2011: Gary A Molander; Floriane Beaumard
Cross-coupling of mesylated phenol derivatives with potassium ammonio- and amidomethyltrifluoroborates.
Organic letters 2011;13(5):1242-5.
2011: Gary A Molander; Livia N Cavalcanti
Oxidation of organotrifluoroborates via oxone.
The Journal of organic chemistry 2011;76(2):623-30.
2010: Gary A Molander; Sarah L J Trice; Spencer D Dreher
Palladium-catalyzed, direct boronic acid synthesis from aryl chlorides: a simplified route to diverse boronate ester derivatives.
Journal of the American Chemical Society 2010;132(50):17701-3.
2010: Deidre L Sandrock; Cheng-Yi Chen; Spencer D Dreher; Ludivine Jean-Gérard; Gary A Molander
Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.
Journal of the American Chemical Society 2010;132(48):17108-10.
2010: Gary A Molander; Marie-Aude Hiebel
Synthesis of amidomethyltrifluoroborates and their use in cross-coupling reactions.
Organic letters 2010;12(21):4876-9.
2010: Gary A Molander; Inji Shin; Ludivine Jean-Gérard
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of enantiomerically enriched potassium β-trifluoroboratoamides with various aryl- and hetaryl chlorides.
Organic letters 2010;12(19):4384-7.
2010: Gary A Molander; Floriane Beaumard
Nickel-catalyzed C-O activation of phenol derivatives with potassium heteroaryltrifluoroborates.
Organic letters 2010;12(18):4022-5.
2010: Gary A Molander; Jessica Raushel; Noel M Ellis
Synthesis of an acyltrifluoroborate and its fusion with azides to form amides.
The Journal of organic chemistry 2010;75(12):4304-6.
2009: Gary A Molander; Deidre L Sandrock
Potassium trifluoroborate salts as convenient, stable reagents for difficult alkyl transfers.
Current opinion in drug discovery & development 2009;12(6):811-23.
2009: Gary A Molander; Livia N Cavalcanti; Belgin Canturk; Po-Shen Pan; Lauren E Kennedy
Efficient hydrolysis of organotrifluoroborates via silica gel and water.
The Journal of organic chemistry 2009;74(19):7364-9.
2009: Young Ae Cho; Dong-Su Kim; Hong Ryul Ahn; Belgin Canturk; Gary A Molander; Jungyeob Ham
Preparation of potassium azidoaryltrifluoroborates and their cross-coupling with aryl halides.
Organic letters 2009;11(19):4330-3.
2009: Gary A Molander; Wilma Febo-Ayala; Ludivine Jean-Gérard
Condensation reactions to form oxazoline-substituted potassium organotrifluoroborates.
Organic letters 2009;11(17):3830-3.
2009: Gary A Molander; Ludivine Jean-Gérard
Use of potassium beta-trifluoroborato amides in Suzuki-Miyaura cross-coupling reactions.
The Journal of organic chemistry 2009;74(15):5446-50.
2009: Gary A Molander; Deidre L Sandrock
Utilization of potassium vinyltrifluoroborate in the development of a 1,2-dianion equivalent.
Organic letters 2009;11(11):2369-72.
2009: Gary A Molander; Ludivine Jean-Gérard
Scope of the Suzuki-Miyaura cross-coupling reaction of potassium trifluoroboratoketohomoenolates.
The Journal of organic chemistry 2009;74(3):1297-303.
2009: Gary A Molander; Belgin Canturk; Lauren E Kennedy
Scope of the Suzuki-Miyaura cross-coupling reactions of potassium heteroaryltrifluoroborates.
The Journal of organic chemistry 2009;74(3):973-80.
2009: Gary A Molander; Belgin Canturk
Organotrifluoroborates and monocoordinated palladium complexes as catalysts--a perfect combination for Suzuki-Miyaura coupling.
Angewandte Chemie (International ed. in English) 2009;48(49):9240-61.
2008: Gary A Molander; Paul E Gormisky
Cross-coupling of cyclopropyl- and cyclobutyltrifluoroborates with aryl and heteroaryl chlorides.
The Journal of organic chemistry 2008;73(19):7481-5.
2008: Gary A Molander; Noel M Ellis
Highly stereoselective synthesis of cis-alkenyl pinacolboronates and potassium cis-alkenyltrifluoroborates via a hydroboration/protodeboronation approach.
The Journal of organic chemistry 2008;73(17):6841-4.
2008: Gary A Molander; Wilma Febo-Ayala; Montserrat Ortega-Guerra
Facile synthesis of highly functionalized ethyltrifluoroborates.
The Journal of organic chemistry 2008;73(15):6000-2.
2008: Gary A Molander; David J Cooper
Functionalization of organotrifluoroborates: reductive amination.
The Journal of organic chemistry 2008;73(10):3885-91.
2008: Gary A Molander; Daniel E Petrillo
Suzuki-Miyaura cross-coupling of potassium trifluoroboratohomoenolates.
Organic letters 2008;10(9):1795-8.
2008: Gary A Molander; Paul E Gormisky; Deidre L Sandrock
Scope of aminomethylations via Suzuki-Miyaura cross-coupling of organotrifluoroborates.
The Journal of organic chemistry 2008;73(6):2052-7.
2007: Gary A Molander; Ludivine Jean-Gérard
Scope of the Suzuki-Miyaura aminoethylation reaction using organotrifluoroborates.
The Journal of organic chemistry 2007;72(22):8422-6.
2007: Gary A Molander; David J Cooper
Ozonolysis of unsaturated organotrifluoroborates.
The Journal of organic chemistry 2007;72(9):3558-60.
2007: Gary A Molander; Deidre L Sandrock
Aminomethylations via cross-coupling of potassium organotrifluoroborates with aryl bromides.
Organic letters 2007;9(8):1597-600.
2007: Gary A Molander; Noel Ellis
Organotrifluoroborates: protected boronic acids that expand the versatility of the Suzuki coupling reaction.
Accounts of chemical research 2007;40(4):275-86.
2007: Gary A Molander; Barbara Czakó; Michael Rheam
Construction of bicyclic ring systems via a transannular SmI2-mediated ketone-olefin cyclization strategy.
The Journal of organic chemistry 2007;72(5):1755-64.
2007: Gary A Molander; Jungyeob Ham; Belgin Canturk
Preparation and wittig reactions of organotrifluoroborato phosphonium ylides.
Organic letters 2007;9(5):821-4.
2007: Daniel E Petrillo; Rakesh K Kohli; Gary A Molander
Accurate mass determination of organotrifluoroborates.
Journal of the American Society for Mass Spectrometry 2007;18(3):404-5.
2007: Gary A Molander; Fabricio Vargas
Beta-aminoethyltrifluoroborates: efficient aminoethylations via Suzuki-Miyaura cross-coupling.
Organic letters 2007;9(2):203-6.
2006: Gary A Molander; Adam R Brown
Suzuki-Miyaura cross-coupling reactions of potassium vinyltrifluoroborate with aryl and heteroaryl electrophiles.
The Journal of organic chemistry 2006;71(26):9681-6.
2006: Gary A Molander; Maxwell D Elia
Suzuki-Miyaura cross-coupling reactions of benzyl halides with potassium aryltrifluoroborates.
The Journal of organic chemistry 2006;71(24):9198-202.
2006: Gary A Molander; Noel M Ellis
Linchpin synthons: metalation of aryl bromides bearing a potassium trifluoroborate moiety.
The Journal of organic chemistry 2006;71(19):7491-3.
2006: Gary A Molander; Ruth Figueroa
Synthesis of unsaturated organotrifluoroborates via Wittig and Horner-Wadsworth-Emmons olefination.
The Journal of organic chemistry 2006;71(16):6135-40.
2006: Gary A Molander; Daniel E Petrillo
Oxidation of hydroxyl-substituted organotrifluoroborates.
Journal of the American Chemical Society 2006;128(30):9634-5.
2006: Gary A Molander; Tiziano Fumagalli
Palladium(0)-catalyzed suzuki-miyaura cross-coupling reactions of potassium aryl- and heteroaryltrifluoroborates with alkenyl bromides.
The Journal of organic chemistry 2006;71(15):5743-7.
2006: Gary A Molander; Jungyeob Ham
Synthesis of functionalized organotrifluoroborates via the 1,3-dipolar cycloaddition of azides.
Organic letters 2006;8(13):2767-70.
2006: Gary A Molander; Jungyeob Ham
Synthesis of functionalized organotrifluoroborates via halomethyltrifluoroborates.
Organic letters 2006;8(10):2031-4.
2006: Gary A Molander; Yasuo Yokoyama
One-pot synthesis of trisubstituted conjugated dienes via sequential Suzuki-Miyaura cross-coupling with alkenyl- and alkyltrifluoroborates.
The Journal of organic chemistry 2006;71(6):2493-8.
2006: Gary A Molander; Erin M Sommers; Sharon R Baker
Palladium(0)-catalyzed synthesis of chiral ene-allenes using alkenyl trifluoroborates.
The Journal of organic chemistry 2006;71(4):1563-8.
2006: Gary A Molander; Barbara Czakó; David J St Jean
A general route toward the synthesis of the cladiellin skeleton utilizing a SmI2-mediated cyclization.
The Journal of organic chemistry 2006;71(3):1172-80.
2006: Gary A Molander; Ruth Figueroa
cis-dihydroxylation of unsaturated potassium alkyl- and aryltrifluoroborates.
Organic letters 2006;8(1):75-8.
2005: Gary A Molander; Luciana A Felix
Stereoselective Suzuki-Miyaura cross-coupling reactions of potassium alkenyltrifluoroborates with alkenyl bromides.
The Journal of organic chemistry 2005;70(10):3950-6.
2005: Gary A Molander; Elizabeth Pollina Cormier
Ketyl-allene cyclizations promoted by samarium(II) iodide.
The Journal of organic chemistry 2005;70(7):2622-6.
2004: Gary A Molander; Jason P Burke; Patrick J Carroll
Synthesis and application of chiral cyclopropane-based ligands in palladium-catalyzed allylic alkylation.
The Journal of organic chemistry 2004;69(23):8062-9.
2004: Gary A Molander; Florian Dehmel
Formal total synthesis of oximidine II via a Suzuki-type cross-coupling macrocyclization employing potassium organotrifluoroborates.
Journal of the American Chemical Society 2004;126(33):10313-8.
2004: Gary A Molander; David J St Jean; Julia Haas
Toward a general route to the eunicellin diterpenes: the asymmetric total synthesis of deacetoxyalcyonin acetate.
Journal of the American Chemical Society 2004;126(6):1642-3.
2003: Gary A Molander; Kelly M George; Lauren G Monovich
Total synthesis of (+)-isoschizandrin utilizing a samarium(II) iodide-promoted 8-endo ketyl-olefin cyclization.
The Journal of organic chemistry 2003;68(25):9533-40.
2003: Gary A Molander; Shawn K Pack
Determining the scope of the organolanthanide-catalyzed, sequential intramolecular amination/cyclization reaction: formation of substituted quinolizidines, indolizidines, and pyrrolizidines.
The Journal of organic chemistry 2003;68(24):9214-20.
2003: Gary A Molander; María Ribagorda
Expanding organoboron chemistry: epoxidation of potassium organotrifluoroborates.
Journal of the American Chemical Society 2003;125(37):11148-9.
2003: Gary A Molander; Chang-Soo Yun; María Ribagorda; Betina Biolatto
B-alkyl suzuki-miyaura cross-coupling reactions with air-stable potassium alkyltrifluoroborates.
The Journal of organic chemistry 2003;68(14):5534-9.
2003: Gary A Molander; Betina Biolatto
Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of potassium aryl- and heteroaryltrifluoroborates.
The Journal of organic chemistry 2003;68(11):4302-14.
2002: Gary A Molander; Carmem R Bernardi
Suzuki-Miyaura cross-coupling reactions of potassium alkenyltrifluoroborates.
The Journal of organic chemistry 2002;67(24):8424-9.
2002: Gary A Molander; Bryson W Katona; Fouzia Machrouhi
Development of the suzuki-miyaura cross-coupling reaction: use of air-stable potassium alkynyltrifluoroborates in aryl alkynylations.
The Journal of organic chemistry 2002;67(24):8416-23.
2002: Gary A Molander; Jan Antoinette C Romero
Lanthanocene catalysts in selective organic synthesis.
Chemical reviews 2002;102(6):2161-86.
2002: Gary A Molander; David J St Jean
Samarium(II) iodide-mediated intramolecular conjugate additions of alpha,beta-unsaturated lactones.
The Journal of organic chemistry 2002;67(11):3861-5.
2002: Gary A Molander; Betina Biolatto
Efficient ligandless palladium-catalyzed Suzuki reactions of potassium aryltrifluoroborates.
Organic letters 2002;4(11):1867-70.
2002: Gary A Molander; Giles A Brown; Isabel Storch de Gracia
Sequenced reactions with samarium(II) iodide. Sequential intramolecular Reformatsky/nucleophilic acyl substitution reactions for the synthesis of medium-sized carbocycles.
The Journal of organic chemistry 2002;67(10):3459-63.
2002: Gary A Molander; Marta Rodríguez Rivero
Suzuki cross-coupling reactions of potassium alkenyltrifluoroborates.
Organic letters 2002;4(1):107-9.
2001: Gary A Molander; M S Quirmbach; L F Silva; K C Spencer; Jaume Balsells
Toward the total synthesis of variecolin.
Organic letters 2001;3(15):2257-60.
2001: Gary A Molander; Y Le Huérou; G A Brown
Sequenced reactions with samarium(II) iodide. Sequential intramolecular Barbier cyclization/Grob fragmentation for the synthesis of medium-sized carbocycles.
The Journal of organic chemistry 2001;66(13):4511-6.
2001: Gary A Molander; E D Dowdy; S K Pack
A diastereoselective intramolecular hydroamination approach to the syntheses of (+)-, (+/-)-, and (-)-pinidinol.
The Journal of organic chemistry 2001;66(12):4344-7.
2001: Gary A Molander; T Ito
Cross-coupling reactions of potassium alkyltrifluoroborates with aryl and 1-alkenyl trifluoromethanesulfonates.
Organic letters 2001;3(3):393-6.
2001: Gary A Molander; D Pfeiffer
Organolanthanide-catalyzed cyclization/boration of 1,5- and 1,6-Dienes.
Organic letters 2001;3(3):361-3.
2000: Gary A Molander; C Köllner
Development of a protocol for eight- and nine-membered ring synthesis in the annulation of sp(2),sp(3)-hybridized organic dihalides with keto esters.
The Journal of organic chemistry 2000;65(24):8333-9.
2000: Gary A Molander; R M Rzasa
Hetero diels-alder reactions catalyzed by the metallocenium complex [Cp(2)Ce][BPh(4)].
The Journal of organic chemistry 2000;65(4):1215-7.